除草组合物转让专利

申请号 : CN200580024067.8

文献号 : CN1997279B

文献日 :

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发明人 : E·哈克E·罗斯H·戴特里奇

申请人 : 拜尔作物科学股份公司

摘要 :

一种含有有效量的组分(A)和(B)的除草剂组合物,其中组分(A)为一种或多种式(I)的除草剂或其盐,其中R1为H或式CZ1Z2Z3基团,其中Z1、Z2和Z3如权利要求1所定义,R2和R3各自为H、分别具有高达4个碳原子的烷基、卤烷基、烯基、卤烯基、炔基、卤炔基,或酰基,R4为H、(C1-C6)-烷基或(C1-C6)-烷氧基;R5、R6、R7和R8各自为H、(C1-C4)-烷基、(C1-C3)-卤烷基、卤素、(C1-C3)-烷氧基、(C1-C3)-卤烷氧基或氰基;A为CH2或0,或为直键,并且组分(B)为一种或多种选自下组化合物的除草剂:(B1)尤其适合苗前施用控制单子叶或双子叶有害植物的土壤作用除草剂,(B2)尤其适合苗后施用控制单子叶或双子叶有害植物的叶片作用除草剂,和(B3)适合苗前或苗后施用控制单子叶或双子叶有害植物的土壤作用和叶片作用除草剂。

权利要求 :

1.一种含有有效量的组分(A)和(B)的除草剂组合物,其中组分(A)为一种或多种式(I)的除草剂或其盐[除草剂(A)],

其中

R1为式CZ1Z2Z3基团,其中Z1为卤素

Z2为(C1-C4)-烷基并且

Z3为H或(C1-C4)-烷基,R2为H,

R3为H,

R4为H、(C1-C3)-烷基,R5、R6、R7和R8各自独立地为H、(C1-C3)-烷基、卤素、(C1-C3)-烷氧基,并且A为直键,

并且

组分(B)为选自下组的一种或多种结构的除草剂(B):(B2.1.1)草铵膦及其盐(B2.1.1.4)双丙氨酰膦及其盐(B2.1.2)草甘膦及其盐,和(B2.1.3)草硫膦,其中活性化合物组分(A)和(B)的重量比为1∶50至50∶1。

2.根据权利要求1的除草剂组合物,其中R1为式CZ1Z2Z3基团,其中Z1为氟,

Z2为甲基,

并且

Z3为H或甲基,

R2为H,

R3为H,

R4为H或甲基,

R5、R6、R7和R8各自独立地为H或甲基,并且A为直键。

3.根据权利要求1或2的除草剂组合物,其中组分(B)为一种或多种结构不同于分别所存在的除草剂(A)的除草剂(B),其选自下组:(B2.1.1)草铵膦,(B2.1.1.1)草胺膦铵盐,(B2.1.2)草甘膦,(B2.1.2.1)草甘膦异丙铵盐,(B2.1.3)草硫膦。

4.根据权利要求1或2所述的除草剂组合物,其中组分(B)为草铵膦铵盐(B2.1.1.1)。

5.根据权利要求4所述的除草剂组合物,其中除草剂组分(B)以5-5000g活性化合物每公顷的量施用。

6.根据权利要求1或2所述的除草剂组合物,其中组分(B)为草甘膦异丙铵盐(B2.1.2.1)。

7.根据权利要求6所述的除草剂组合物,其中除草剂组分(B)以5-5000g活性化合物每公顷的量施用。

8.根据权利要求1-7任一所述的除草剂组合物,其中除草剂组分(A)以5-500g活性化合物每公顷的量施用。

9.根据权利要求1至8任一所述的除草剂组合物,其包含一种或多种选自下组的其它组分:其它类型的植物保护剂活性物质和植物保护中的常规添加剂或制剂助剂。

10.一种控制有害植物的方法,该方法包括采用苗前方法、苗后方法或苗前和苗后的方法将权利要求1至9任一所述的除草剂组合物的除草剂一并或分别施用至植物、植物部分、植物种子或植物生长区域。

11.根据权利要求10的方法,该方法用于控制非作物土地或种植作物中的有害植物。

12.权利要求1至9任一所述的除草剂组合物用于控制有害植物的用途。

说明书 :

本发明涉及植物保护剂技术领域,其用于在非作物土地上或用于预处理种子或植作物中控制不期望植物生长,该植物保护剂作为除草活性化合物包含至少两种除草剂的组合,其中一种除草剂组分选自特定的双环取代的吖嗪类化合物。

来自在氨基上具有双环基团的N-取代的氨基-仲-三嗪结构的化合物已知用作除草剂(参见,例如WO-A-97/31904或US-A-6069114)。当采用苗前方法施用和采用苗后方法施用时,该化合物有效控制广谱的有害植物,该化合物非选择性用于控制不期望的植物生长或选择性用于任选地与植作物中可能的安全剂相组合。

这些除草剂控制有害植物的有效性是高水平的,然而,其通常取决于施用量、各自的剂型、有害植物谱、分别待控制的有害植物、气候和土壤条件等。进一步的标准是作用持久性或除草剂降解的速度。还任选地应考虑的是有害植物敏感度的变化,这在长期使用除草剂或区域受限制时会发生。在单个有害植物中活性的损失仅可以通过提高除草剂的施用量来得到一定程度的补偿,例如因为该过程不断降低了除草剂的选择性,或因为即使在更高施用量下活性未得到改善。在某些情形下,通过加入安全剂可以提高对作物的选择性。然而通常来说,目前仍然存在对于获得具有更低的活性化合物施用量的除草作用的方法的需求。更低的施用量不仅降低了所需施用的活性化合物的量,而且通常还降低了所需制剂助剂的量。这同时减少了经济投入并且提高了除草剂处理的生态相容性。

改善除草剂的施用特性的一种可能是可以将活性化合物与一种或多种提供所需的其它性能的其它活性化合物相组合。然而,多种活性化合物的组合使用通常产生物理和生物不相容现象,例如缺乏共制剂稳定性、活性化合物的分解或活性化合物之间的拮抗作用。相比之下,需要的是具有有利的活性特性、高稳定性和如有可能的预料不到的增效改良作用的活性化合物的组合物,所述的增效改良作用使得相比单独施用用于组合的活性化合物来说,降低了施用量。

已知其它除草剂与来自广义的经芳烷基基团N-取代的氨基-s-三嗪的除草剂的组合会产生增效作用(参见WO-A-00/16627)。其它除草剂与在氨基上具有双环基团的氨基-s-三嗪的组合物的具体实例在该文献中没有描述。除结构变化之外,由于一方面在氨基上具有芳基烷基基团与另一方面具有双环基团的氨基-s-三嗪化合物之间的相对大的差异,该差异也可以在改变的活性特征、对于双环取代的化合物,尤其是其单个的立体异构体的增效作用中观察到,这都是以相同的方式无法预料的。

出人意外地,现已发现当所述的除草剂类型的活性化合物与某些结构不同的除草剂组合使用时,其以尤其有利的方式控制不期望的植物。该组合物优选用于非作物土地、对于任选地加入安全剂的除草剂施用实质上耐受的种植作物和作物。

因此,本发明提供含有有效量的组分(A)和(B)的除草组合物,其中

组分(A)为一种或多种式(I)除草剂或其盐[除草剂(A)],

其中

R1为H或式CZ1Z2Z3基团,其中

Z1为H、卤素、(C1-C6)-烷基、(C1-C6)-卤烷基、[(C1-C4)-烷氧基]-(C1-C6)-烷基、(C3-C6)-环烷基,其是未经取代或经一个或多个选自下组基团取代的:卤素、(C1-C4)-烷基和(C1-C4)-卤烷基,或为(C2-C6)-烯基、(C2-C6)-炔基、(C2-C6)-卤烯基、(C4-C6)-环烯基、(C4-C6)-卤环烯基、(C1-C6)-烷氧基或(C1-C6)-卤烷氧基,

Z2为H、卤素、(C1-C6)-烷基或(C1-C4)-烷氧基;或

Z1和Z2连同CZ1Z2Z3基团的碳原子为(C3-C6)-环烷基或(C4-C6)-环烯基,其中最后两个所述基团中的每一个是未经取代或经一个或多个选自(C1-C4)-烷基取代的,并且

Z3为H、(C1-C6)-烷基、(C1-C4)-烷氧基或卤素,

R2和R3各自独立地为H、(C1-C4)-烷基、(C1-C4)-卤烷基、(C3-C4)-烯基、(C3-C4)-卤烯基、(C3-C4)-炔基、(C3-C4)-卤炔基或酰基,

R4为H、(C1-C6)-烷基或(C1-C6)-烷氧基,

R5、R6、R7和R8各自独立地为H、(C1-C4)-烷基、(C1-C3)-卤烷基、卤素、(C1-C3)-烷氧基、(C1-C3)-卤烷氧基或氰基,并且

A为式CH2或O的二价基团,或为直键,

并且

组分(B)为一种或多种结构不同于分别所存在的除草剂(A)的除草剂(B),其选自下组:

(B1)尤其适合苗前施用控制单子叶或双子叶有害植物的土壤作用除草剂,

(B2)尤其适合苗后施用控制单子叶或双子叶有害植物的叶片作用除草剂,和

(B3)适合苗前或苗后施用控制单子叶或双子叶有害植物的土壤作用和叶片作用除草剂。

本发明的除草剂组合物可以包含其它的组分,例如其它的控制有害生物体例如有害植物、损害植物的动物或损害植物的真菌的活性化合物,尤其是选自下组的化合物:除草剂、杀真菌剂、杀虫剂、杀螨剂(acaricides)、杀线虫剂和杀螨剂(miticides)以及相关物质,或其它不同类型的植物保护剂(例如安全剂、抗性诱导剂)、植物生长调节剂和/或植物保护中的制剂助剂和/或常规添加剂。在本文中,这些组分可以一起配制(最终制剂)并进行施用,或它们可以分别配制并一起施用,例如采用桶混方法或顺序施用。

以组分(A)存在的式(I)的单个除草剂在下文中也称作化合物(A)或活性化合物(A)。相应地,以组分(B)存在的单个除草剂在下文中也称作化合物(B)或活性化合物(B)。

当将活性化合物(A)和(B)一起施用时,观察到增效作用,当将化合物在一段时间分别施用时,也通常会产生增效作用。另一种可能性是以多份施用除草剂或除草组合物(顺序施用),例如可以在一次或多次苗前施用进行苗后施用,或可以在早期苗后施用后进行中期或晚期苗前施用。优选的是将所述的活性化合物的组合一并或几乎同时施用,任选地以多份的形式。然而,还可以在不同时间施用组合的单个活性化合物,这会是有利的。还可以与其它植物保护剂相结合,例如所述的活性化合物(杀真菌剂、杀虫剂、杀螨剂等)和/或多种助剂,施用于该系统的辅助剂和/或肥料。

采用苗前或苗后方法施用取决于所使用的范围,这应理解为指分别在当有害植物变得在地上可见的时间点之前或之后施用活性化合物,或分别在作物出苗前或作物出苗后施用活性化合物来控制有害植物。

通过以组合形式施用除草剂(A)和(B),可以获得优于可以预期的基于单个除草剂的已知性能的组合的施用性能。该增效作用使得例如降低了单个活性化合物的施用量、在相同施用量下更有效、控制迄今未能控制的品种(缺口)、更高的残余作用、更长时间的作用、更迅速起作用、延长了施用时间和/或降低了单独施用所需的次数,并且作为使用者的结果是杂草控制系统具有更为有利的经济性和生态性。

在对于除草活性组分(A)化合物的式(I)和随后的所有结构式中,适用如下定义:

式(I)还包括其特定的立体化学构型不能由该结构式清楚地表达的化合物的所有立体异构体,及其混合物。这类式(I)化合物含有一个或多个不对称的碳原子或其它双键,这在通式(I)中未明确显示。式(I)包括由其特定的空间形状定义的所有可能的立体异构体,例如对映异构体、非对映异构体、Z和E异构体,并且这些立体异构体可以通过常规方法由立体异构体混合物中获得,或另外通过与使用立体化学纯初始物质相结合的立体选择反应来制得。

通过形成适宜的无机或有机酸,例如HCl、HBr、H2SO4或HNO3,或另外的草酸或磺酸与碱性基团,例如氨基或烷基氨基的加合物,式(I)化合物能形成盐。以去质子化形式存在的适宜的取代基,如磺酸或羧酸,可与部分可质子化的基团如氨基形成内盐。

还可以通过采用农业上有用的阳离子替换适宜取代基例如磺酸或羧酸的氢来形成盐。这些盐为例如金属盐,尤其是碱金属盐或碱土金属盐,特别是钠盐和钾盐,或其它的铵盐,与有机胺的盐或季铵盐。

术语“(C1-C4)-烷基”是具有1至4个碳原子的开链烷基的简写符号,即其包含甲基、乙基、1-丙基、2-丙基、1-丁基、2-丁基、2-甲基丙基和叔丁基。相应地,具有更大碳原子范围的常规烷基,如“(C1-C6)-烷基”,还包含具有更大碳原子数的直链或支链烷基,即还包含具有5个和6个碳原子的烷基。

除非特别指定,对于包括组合基团的烃基如烷基、链烯基和炔基而言,更低的碳架,如具有1至6个碳原子,或在不饱和基团中具有2至6个碳原子是优选的。烷基,包括其组合意义,如烷氧基、卤烷基等为例如甲基,乙基,正-或异-丙基,正-、异-、叔-或2-丁基,戊基,己基如正-己基、异己基和1,3-二甲基丁基,庚基如正-庚基、1-甲基己基和1,4-二甲基戊基;链烯基和炔基指具有相应烷基含义的可能不饱和基团;链烯基为例如乙烯基、烯丙基、1-甲基-2-丙烯基、2-甲基-2-丙烯基、2-丁烯基、戊烯基、2-甲基戊烯基或己烯基,优选烯丙基、1-甲基丙-2-烯-1-基、2-甲基-丙-2-烯-1-基、丁-2-烯-1-基、丁-3-烯-1-基、1-甲基-丁-3-烯-1-基或1-甲基-丁-2-烯-1-基。(C2-C6)-炔基为例如乙炔基、炔丙基、1-甲基-2-丙炔基、2-甲基-2-丙炔基、2-丁炔基、2-戊炔基或2-己炔基,优选炔丙基、丁-2-炔-1-基、丁-3-炔-1-基或1-甲基-丁-3-炔-1-基。

环烷基指具有优选3-8个碳原子的饱和碳环系,例如为环丙基、环丁基、环戊基或环己基。

环烯基指具有优选4-8个碳原子的碳环非芳族部分不饱和环系,例如1-环丁烯基、2-环丁烯基、1-环戊烯基、2-环戊烯基、3-环戊烯基,或1-环己烯基、2-环己烯基、3-环己烯基、1,3-环己二烯基或1,4-环己二烯基。

卤素指例如氟、氯、溴或碘。卤烷基、卤烯基和卤炔基指烷基、烯基和炔基分别部分或完全由相同或不同的卤素原子,优选由氟、氯和溴,尤其是氟和氯所取代,例如单卤烷基,全卤烷基,CF3、CHF2、CH2F、CF3CF2、CH2FCHCl、CCl3、CHCl2、CH2CH2Cl;卤烷氧基为例如OCF3、OCHF2、OCH2F、CF3CF2O、OCH2CF3和OCH2CH2Cl;这相应地适用于卤烯基和其它经卤素取代的基团。

在具有碳原子的基团中,优选的是具有1至4个碳原子、尤其1或2个碳原子的基团。通常优选选自下组的取代基:卤素如氟和氯,(C1-C4)-烷基优选甲基或乙基,(C1-C4)-卤烷基优选三氟甲基,(C1-C4)-烷氧基优选甲氧基或乙氧基,(C1-C4)-卤烷氧基、硝基和氰基。本文尤其优选的是甲基、甲氧基、氟和氯取代基。

酰基指形式上通过从酸官能团除去羟基形成的有机酸基团,在酸中有机基团可以通过杂原子与酸官能团相连。酰基的实例为羧酸HO-CO-R的-CO-R基团以及源于此的酸根,如硫代羧酸,未经取代或经N-取代的亚氨基羧酸或碳酸单酯、经N-取代的氨基甲酸、磺酸、亚磺酸、经N-取代的亚磺酰氨基酸、磷酸、亚磷酸的基团。

酰基指,例如甲酰基、烷基羰基如[(C1-C4)-烷基]羰基、苯基羰基、烷氧羰基、苯氧羰基、苄氧羰基、烷基磺酰基、烷基亚磺酰基、N-烷基-1-亚氨基烷基以及其它有机酸基团。本发明中,在烷基或苯基部分如在烷基部分,该基团可以进一步经一个或多个选自下组的基团取代:卤素、烷氧基、苯基和苯氧基;在苯基部分取代基的实例为通常在经取代苯基中已提及的取代基团。

酰基优选为狭义上的酰基基团,即酸基团直接与有机基团的碳原子相连的有机酸基团,例如甲酰基,烷基羰基例如乙酰基或[(C1-C4)-烷基]羰基,苯基羰基、烷基磺酰基、烷基亚磺酰基和其它的有机酸基团。

若通常基团指定(定义)为“氢”,其指相连的氢原子。

基团(例如烷基)的“基-位置”指其连接点。

在下文中,简而言之,可以用于本发明的式(I)化合物及其盐还称作“本发明的化合物(I)”。

式(I)化合物大体上已知于WO 97/31904,并且可以通过其中所述的方法制得。尤其优选的是如下式(I)化合物或其盐,其中

R1为H或式CZ1Z2Z3基团,其中

Z1为H、卤素、(C1-C4)-烷基、(C1-C4)-卤烷基、[(C1-C4)-烷氧基]-(C1-C6)-烷基、(C3-C6)-环烷基,其是未经取代或经一个或多个选自(C1-C4)-烷基的基团取代的,或为

(C2-C4)-烯基、(C2-C4)-炔基、(C1-C4)-烷氧基或(C1-C4)-卤烷氧基;

Z2为H、卤素或(C1-C4)-烷基,或

Z1和Z2与连接这些基团的碳原子一起为(C3-C6)-环烷基,并且

Z3为H、(C1-C4)-烷基、(C1-C2)-烷氧基或卤素,

R2为H、(C1-C4)-烷基、(C1-C4)-卤烷基、(C3-C4)-烯基、(C3-C4)-卤烯基、(C3-C4)-炔基、(C3-C4)-卤炔基或具有1至12个碳原子的酰基(优选选自下组的酰基:甲酰基、苯基羰基、苯氧羰基,其中在最后2个所述基团中的苯基是未经取代或经-个或多个选自下组的基团取代的:卤素、(C1-C2)-烷基、(C1-C2)-卤烷基、(C1-C2)-烷氧基,(C1-C2)-卤烷氧基和硝基,或(C1-C6)-烷基-羰基、(C1-C6)-烷氧基-羰基或(C1-C6)-烷基-磺酰基),

R3为H、(C1-C4)-烷基或(C1-C4)-卤烷基,

R4为H、(C1-C3)-烷基或(C1-C3)-烷氧基,

R5、R6、R7和R8各自独立地为H、(C1-C3)-烷基、卤素、(C1-C3)-烷氧基,并且

A为式CH2或O的二价基团,或为直键,优选CH2或直键,尤其是直键。

优选如下的式(I)的光学活性化合物及其盐,其中在基于该位置的具有(R)-和(S)-构型的立体异构体部分中,在式(I)中标记为1的碳原子处的立体化学构型为具有60至100%(R),优选70-100%(R),尤其是80至100%(R)光学化学纯度的(R)-构型。假设该构型是利用Cahn/Ingold/Prelog系统来确定的,在位置1处的取代基的优先次序如下:

1.优先次序为经取代的NH;2.优先次序为键合至苯环;3.优先次序为其它的碳原子,4.优先次序为氢原子。

进一步优选的是如下的式(I)的光学活性化合物及其盐,其中R1为式CZ1Z2Z3的基团,其中CZ1Z2Z3如上所定义,尤其优选的化合物是其中在基于该位置的具有(R)-和(S)-构型的立体异构体含量中,在基团CZ1Z2Z3的碳原子处的立体化学构型为具有60至100%(R),优选70-100%(R),尤其是80至100%(R)光学化学纯度的(R,S)-构型或(R)-构型。

适宜的组合组分(A)为例如选自下表1的某些式(I)化合物。

对表1的注解:

在表1中,该化合物是通过主要组分的化学结构式来指定的,该组分以至少95重量%的化合物的化学纯度来存在。当然,也可以使用更低纯度的化合物。特别地,若化合物的次要组分主要或完全组成各化合物(A)的活性立体异构体,也可以在施用期间获得类似的效果。因此,优选的除草剂(A)还为两种或多种选自表1的化合物(A)的混合物。由于更易于制备的原因,实践中还尤其优选含有选自表1的化合物(A)作为主要成分和化合物(A)的立体异构体作为次要组分的除草剂(A),该优选的除草剂也在表1中提及。

若在表1中所述的化学结构式中,在碳原子处是立体化学取向的,并且利用Cahn、Ingold和Prelog系统来另外确定的立体化学取向,则该化合物的主要组分为在所示碳原子处具有R-或S-构型的立体异构体或立体异构体混合物;从而该化合物(A)是光学活性的。

若未通过R-或S-构型来确定立体化学,则主要组分为在所述碳原子处具有RS-构型(外消旋)的化合物。

若存在大量的立体异构中心,并且各构型具体由R或S来确定,则在所指定的中心存在具有所述立体化学的光学活性化合物。

若在大量的中心的情形下,不存在R-或S-构型,则该化合物为外消旋混合物,即其中所含有的非手性立体异构体(成对的对映异构体的对映异构体)以相同比例存在于混合物中。除非更详细地说明,在表1中,在具有大量立体异构中心的外消旋化合物(A)中,非对映异构体组分以大约相同的比例来存在。然而,对于实际应用而言,在具有大量立体异构中心的外消旋化合物中,具有不同比例的非对映组分的非对映异构体的混合物(分别以外消旋形式)是可能的。

在双环基团中,与氨基相连的碳原子为碳原子1。在旁边的基团(除基团为H外)中,直接与三嗪环相连的碳原子指定为1*。

表1:式(I)化合物(除草剂(A)):

除草剂(A)的施用量基本上是已知的,并且其范围为0.5至2000g的活性化合物/公顷,优选1至800g的活性化合物/公顷,尤其是5至500g的活性化合物/公顷。在本发明的组合物中,在本文所述的施用量中,相比单独施用而言,需要更低的所述活性化合物的施用量。

不同于化合物(A)的适宜的组合组分(B)[=组分(B)]为例如下组(B1)至(B3)的如下化合物,其中在多数情形下除草剂根据参考文献“The Pesticide Manual”(农药手册),第13版,British CropProtection Council 2003(其缩写为“PM”)的“通用名”来表示:

(B1)尤其适合苗前施用控制单子叶或双子叶有害植物的土壤作用除草剂,例如一种或多种选自下组的化合物:

(B1.1)尤其适合苗前施用控制单子叶和双子叶有害植物的土壤作用除草剂,例如一种或多种选自下组的化合物:

(B1.1.1)丁噻隆(PM,第929-930页),即1-(5-叔-丁基-1,3,4-噻二唑-2-基)-1,3-二甲基脲,

(B1.1.2)嘧磺隆(-甲酯)(PM,第929-930页),即2-(4,6-二甲基-嘧啶-2-基-氨基甲酰基氨磺酰基)苯甲酸甲酯,

(B1.1.3)flumioxazine(PM,第461-462页)即2-(7-氟-3,4-二氢-3-氧代-4-丙-2-炔基-2H-1,4-苯并嗪-6-基)-4,5,6,7-四氢-1H-异吲哚-1,3(2H)-二酮,

(B1.1.4)西玛津(PM,第891-892页),即6-氯-N,N′-二乙基-1,3,5-三嗪-2,4-二胺,

(B1.1.5)敌草腈(PM,第281-282页),即2,6-二氯苄腈,

(B1.1.6)氟乐灵(PM,第1012-1014页),即α,α,α-三氟-2,6-二硝基-N,N-二丙基-对-甲苯胺,

(B1.1.7)二甲戊灵(PM,第752-753页),即N-(1-乙基丙基)-2,6-二硝基-3,4-二甲代苯胺,

(B1.1.8)丙炔草酮(PM,第725-726页),即5-叔-丁基-3-[2,4-二氯-5-(丙-2-炔基氧基)苯基]-1,3,4-二唑-2(3H)-酮,

(B1.1.9)噻唑烟酸(PM,第961-962页),即2-二氟甲基-5-(4,5-二氢-1,3-噻唑-2-基)-4-异丁基-6-三氟甲基烟酸甲酯,

(B1.1.10)氨磺乐灵(PM,第723-724页),即4-(二丙基氨基)-3,5-二硝基苯磺酰胺,

(B1.1.11)炔苯酰草胺(PM,第833-834页),即3,5-二氯-N-(1,1-二甲基丙炔基)苯甲酰胺,

(B1.1.12)特草定(PM,第937-938页),即3-叔-丁基-5-氯-6-甲基尿嘧啶,

(B1.2)尤其适合苗前施用控制双子叶有害植物的土壤作用除草剂,例如一种或多种选自下组的化合物:

(B1.2.1)异酰草胺(PM,第587-588页),即N-[3-(1-乙基-1-甲基丙基)异唑-5-基]-2,6-二甲氧基苯甲酰胺,和

(B1.2.2)啶嘧磺隆(PM,第437-438页),即1-(4,6-二甲氧基嘧啶-2-基)-3-(3-三氟甲基-2-吡啶基磺酰基)脲,

和(B2)尤其适合苗后施用控制单子叶或双子叶有害植物的叶片作用除草剂,例如一种或多种选自下组的化合物:

(B2.1)尤其适合苗后施用控制单子叶和双子叶有害植物的叶片作用除草剂,例如一种或多种选自下组的化合物:

(B2.1.1)草铵膦(PM,第511-512页),即4-[羟基(甲基)膦酰基]-DL-氨基丁酸及其盐,优选铵盐(B2.1.1.1),钠盐(B2.1.1.2),以及活性L-异构体及其盐类(B2.1.1.3),以及三缩氨酸的双丙氨酰膦及其盐类(B2.1.1.4),即4-[羟基-(甲基)膦酰基]-L-高丙氨酰-L-丙氨酰-L-丙氨酸及其盐类,

(B2.1.2)草甘膦(PM,第513-516页),即N-(膦酰甲基)甘氨酸及其盐,优选其异丙铵盐(B2.1.2.1),其钠盐(B2.1.2.2),其铵盐(B2.1.2.3)以及其锍盐(B2.1.3)=草硫膦(参见如下),

(B2.1.3)草硫膦(PM,第513-516页),即N-(膦酰甲基)甘氨酸锍盐(参见草甘膦),

(B2.1.4)甲胂酸及其盐(PM,第656-658页),例如其单钠盐(B2.1.4.1)=MSMA(甲胂酸氢钠),以及其它盐类,例如甲胂酸氢钙(B2.1.4.2),二钠盐(DSMA)(B2.1.4.3),其单铵盐(MAMA)(B2.1.4.4),二(甲胂酸氢)钙(CMA)(B2.1.4.5);

(B2.1.5)甲酰氨磺隆(PM,第494-495页),即1-(4,6-二甲氧基嘧啶-2-基)-3-[2-(二甲基氨基甲酰基)-5-甲酰氨基苯磺酰基]脲,

(B2.1.6)碘磺隆及其酯和盐类(PM,第573-574页),即4-碘-2-[3-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基)脲基磺酰基]苯甲酸及其酯和盐类,优选其甲酯,碘磺隆甲酯及其盐(B2.1.6.1),并且其中尤其优选其钠盐,碘磺隆甲酯钠盐(B2.1.6.2),

(B2.1.7)氨唑草酮(PM,第26-27页),即4-氨基-N-叔-丁基-4,5-二氢-3-异丙基-5-氧基-1,2,4-1H-三唑-1-甲酰胺,

(B2.1.8)丙苯磺隆及其盐类(PM,第831-832页),即(4,5-二氢-4-甲基-5-氧基-3-丙氧基-1H-1,2,4-三唑-1-基羰基)(2-甲氧基羰基苯磺酰基)azanide及其盐,优选其钠盐(B2.1.8.1),

(B2.1.9)嗪草酮(PM,第675-676页),即4-氨基-6-叔-丁基-4,5-二氢-3-甲硫基-1,2,4-三嗪-5-酮,

(B2.1.10)甲磺隆及其酯和盐类(PM,第677-678页),即2-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基氨基甲酰基氨磺酰基)苯甲酸,优选其甲酯,甲磺隆甲酯(B2.1.10.1),

(B2.1.11)(B2.1.11)萘丙胺(PM,第695-697页),即2-(2-萘氧基)-N-苯基丙酰胺,

(B2.1.12)咪唑烟酸及其盐类(PM,第555-556页),即2-(4-异丙基-4-甲基-5-氧基-2-咪唑啉-2-基)烟酸及其盐类,优选其游离酸(B2.1.12.1)及其异丙铵(B2.1.12.2),

(B2.1.13)百草枯盐类(PM,第742-743页),即1,1’-二甲基-4,4’-联吡啶阳离子盐,优选其二氯化物,百草枯二氯化物(B2.1.13.1),

(B2.1.14)敌草快盐类(PM,第341-342页),即1,1’-乙烯基-2,2’-联吡啶二阳离子盐,优选二溴化物,敌草快二溴化物(B2.1.14.1),

(B2.2)尤其适合苗后施用控制双子叶有害植物的叶片作用除草剂,

例如一种或多种选自下组的化合物:

(B2.2.1)2,4-D及其酯和盐类(PM,第254-258页),即2,4-二氯苯氧基乙酸及其酯和盐类,

(B2.2.2)麦草畏及其盐类(PM,第278-280页),即3,6-二氯-2-甲氧基苯甲酸及其盐类,

(B2.2.3)三氯吡氧乙酸及其盐和酯类(PM,第1001-1002页),即3,5,6-三氯-2-吡啶基氧基乙酸及其盐和酯类,例如其游离酸(B2.2.3.1),其三乙基铵盐(B2.2.3.2)以及Butotyl酯(丁基乙基酯)(B2.2.3.3),

(B2.2.4)氟吡草腙及其盐和酯类(PM,第311-312页),即2-{1-[4-(3,5-二氟苯基)脲亚氨基]乙基}盐酸及其盐和酯类,例如其游离酸(B2.2.4.1)和钠盐(B2.2.4.2),

(B2.2.5)氯氟吡氧乙酸及其盐和酯类(PM,第478-481页),即4-氨基-3,5-二氯-6-氟-2-吡啶基氧基乙酸及其盐和酯类,例如其游离酸(B2.2.5.1),其2-丁氧基-1-甲基乙基酯(B2.2.5.2)以及其甲基庚酯(=1-甲基庚基酯)(B2.2.5.3),

(B2.2.6)噻吩磺隆甲酯(PM,第963-965页),即3-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基氨基甲酰基氨磺酰基)噻吩-2-甲酸甲酯,以及噻吩磺隆的游离酸(B2.2.6.1),

(B2.2.7)酰嘧磺隆(PM,第27-28页),即1-(4,6-二甲氧基嘧啶-2-基)-3-甲磺酰基(甲基)氨磺酰基脲及其盐类,

(B2.2.8)苯磺隆及其酯和盐类(PM,第996-998页),即2-[4-甲氧基-6-甲基-1,3,5-三嗪-2-基(甲基)氨基甲酰基氨磺酰基]苯甲酸及其酯和盐类,优选甲酯,苯磺隆甲酯(B2.2.8.1),

(B2.2.9)醚苯磺隆(PM,第990-991页),即1-[2-(2-氯乙氧基)苯基磺酰基]-3-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基)脲,

(B2.2.10)氨氯吡啶酸及其酯和盐类(PM,第782-785页),即4-氨基-3,5,6-三氯吡啶-2-甲酸(=4-氨基-3,5,6-三氯吡啶甲酸)及其酯和盐类,优选其游离酸(B2.2.10.1),其钾盐(B2.2.10.2),其二甲基铵盐(B2.2.10.3),其三(2-羟基丙基)铵盐(B2.2.10.4),其三(2-羟基乙基)铵盐(B2.2.10.5)及其异辛酯(B2.2.10.6),

(B2.2.11)唑酮草酯及其酯和盐类(PM,第143-144页),即(RS)-2-氯-3-[2-氯-5-(4-二氟甲基-4,5-二氢-3-甲基-5-氧基-1H-1,2,4-三唑-1-基)-4-氟苯基]丙酸及其酯和盐类,优选其乙酯,唑酮草酯乙酯(B2.2.11.1),

(B2.2.12)二氯吡啶酸及其酯和盐类(PM,第194-195页),即3,6-二氯吡啶-2-甲酸及其酯和盐类,优选其游离酸(B2.2.12.1)以及乙醇胺酯,二氯吡啶酸乙醇胺酯(B2.2.12.2),

(B2.2.13)氟丙嘧草酯(PM,第120-121页),即1-(烯丙氧基羰基)-1-甲基乙基2-氯-5-[1,2,3,6-四氢-3-甲基-2,6-二氧代-4-(三氟甲基)嘧啶-1-基]-苯甲酸酯,

(B2.2.14)杀草强(PM,第30-32页),即1H-1,2,4-三唑-3-基胺,

(B2.3)尤其适合苗后施用控制单子叶有害植物的叶片作用除草剂,

例如如下化合物:

(B2.3.1)二氯喹啉酸(PM,第869-870页),即3,7-二氯喹啉-8-甲酸,

(B3)适合苗前或苗后施用控制单子叶或双子叶有害植物的土壤和叶片作用除草剂,

例如一种或多种选自下组的化合物:

(B3.1)尤其适合苗后施用控制单子叶或双子叶有害植物的土壤和叶片作用除草剂,

例如一种或多种选自下组的化合物:

(B3.1.1)乙氧氟草醚(PM,第738-739页)(=2-氯-1-(3-乙氧基-4-硝基苯氧基)-4-(三氟甲基)苯),

(B3.1.2)敌草隆(PM,第347-348页),即3-(3,4-二氯苯基)-1,1-二甲基脲,

(B3.1.3)除草定(PM,第106-107页),即5-溴-3-仲-丁基-6-甲基尿嘧啶,

(B3.1.4)氟草敏(PM,第869-870页),即4-氯-5-甲基氨基-2-(α,α,α-三氟-间-甲苯基)哒嗪-3(2H)-酮,

(B3.1.5)唑啶草酮(PM,第1043页),即2-(2,4-二氯-5-丙-2-炔基氧基苯基)-5,6,7,8-四氢-1,2,4-三唑[4,3-a]吡啶-3(2H)-酮,

(B3.1.6)氯磺隆(PM,第176-177页),即1-(2-氯苯基磺酰基)-3-(4-甲氧基-6-甲基-1,3,5-三嗪-2-基)脲,

(B3.1.7)甲咪唑烟酸(PM,第554-555页),即(RS)-2-(4-异丙基-4-甲基-5-氧代-2-咪唑啉-2-基)-5-甲基烟酸,

(B3.1.8)草酮(PM,第727-728页),即5-叔-丁基-3-(2,4-二氯-5-异丙氧基苯基)-1,3,4-二唑-2(3H)-酮,

(B3.1.9)吡氟酰草胺(PM,第427-311页),即2’,4’-二氟-2-(α,α,α-三氟-间-甲苯氧基)烟酰苯胺,

(B3.1.10)莠灭净(PM,第25-26页),N2-乙基-N4-异丙基-6-甲硫基-1,3,5-三嗪-2,4-二胺,

(B3.1.11)砜嘧磺隆(PM,第881-882页),1-(4,6-二甲氧基嘧啶-2-基)-3-(3-乙基磺酰基-2-吡啶磺酰基)脲,及其盐类,

(B3.1.12)三氟啶磺隆(PM,第1008-1009页),1-(4,6-二甲氧基嘧啶-2-基)-3-[3-(2,2,2-三氟乙氧基)-2-嘧啶基磺酰基]脲,及其盐类,优选其钠盐(B3.1.12.1),

(B3.1.13)烟嘧磺隆(PM,第702-703页),1-(4,6-二甲氧基嘧啶-2-基)-3-(3-二甲基氨基甲酰基-2-吡啶基磺酰基)脲,及其盐类,

(B3.1.14)磺草灵及其盐类(PM,第38-39页),优选磺草灵,即磺胺酰基氨基甲酸甲酯(B3.1.14.1)及其钠盐(B3.1.14.2),

(B3.1.15)异唑草酮(PM,第589-590页),(5-环丙基-4-异唑基)-[2-(甲基磺酰基)-4-(三氟甲基)苯基]甲酮,

(B3.2)尤其适合苗后施用控制双子叶有害植物的土壤和叶片作用除草剂,

例如一种或多种选自下组的化合物:

(B3.2.1)环嗪酮(PM,第539-540页),即3-环己基-6-二甲基氨基-1-甲基-1,3,5-三嗪-2,4-(1H,3H)-二酮,

(B3.2.2)甲磺草胺(PM,第910-911页),即2′,4′-二氯-5′-(4-二氟甲基-4,5-二氢-3-甲基-5-氧代-1H-1,2,4-三唑-1-基)甲基磺酰苯胺,

(B 3.2.3)扑杀通(PM,第810-811页),即N2,N4-二-异丙基-6-甲氧基-1,3,5-三嗪-2,4-二胺。

对于上述组合物而言,优选的是含有选自组(A)的除草剂和选自组(B)的除草剂的组合物。此外,本发明的组合物可以与其它活性化合物一起使用,例如所提及的活性化合物(除草剂、杀真菌剂、杀虫剂、杀螨剂等)和/或植物生长调节剂,或制剂助剂和植物保护中常规添加剂。

因此,本发明还提供含有本发明活性化合物组合物与制剂助剂,任选地其它添加剂和任选地其它植物保护剂的除草组合物。

本发明还提供其使用或施用方法,其中将本发明的活性化合物组合物用作除草剂和植物生长调节剂,优选用作其中含有增效有效量的各种活性化合物组合的除草剂和植物生长调节剂。

下面,特定的除草剂组合物(Aa)+(Bb)由术语Ka.b来表示,其中a为表1中除草剂(A)号数的各自编号[化合物(A1)至(A127)的编号1至127],并且b为下表2中除草剂组分(B)的各自编号[化合物(B1.1.1)至(B3.2.3)的编号1至103]:

表2:除草剂组分B的编号(参见下表2a至2i)

表2a

编号    组分B   1   (B1.1.1)   2   (B1.1.2)   3   (B1.1.3)   4   (B1.1.4)   5   (B1.1.5)

表2b

编号  组分B 6 (B1.1.6) 7 (B1.1.7) 8 (B1.1.8) 9 (B1.1.9) 10 (B1.1.10)

表2c

编号  组分B 11 (B1.1.11) 12 (B1.1.12) 13 (B1.2.1) 14 (B1.2.2)    

[0180]表2d  编号  组分B   15 (B2.1.1)   16 (B2.1.1.1)   17 (B2.1.1.2)   18 (B2.1.1.3)   19 (B2.1.1.4)   20 (B2.1.2)   21 (B2.1.2.1)   22 (B2.1.2.2)   23 (B2.1.2.3)   24 (B2.1.3)   25 (B2.1.4)   26 (B2.1.4.1)   27 (B2.1.4.2)   28 (B2.1.4.3)   29 (B2.1.4.4)   30 (B2.1.4.5)   31 (B2.1.5)   32 (B2.1.6)   33 (B2.1.6.1)   34 (B2.1.6.2)   35 (B2.1.7)
  编号  组分B   36 (B2.1.8)   37 (B2.1.8.1)   38 (B2.1.9)
表2e
编号  组分B 39 (B2.1.10) 40 (B2.1.10.1) 41 (B2.1.11) 42 (B2.1.12) 43 (B2.1.12.1) 44 (B2.1.12.2) 45 (B2.1.13) 46 (B2.1.13.1) 47 (B2.1.14) 48 (B2.1.14.1) 49 (B2.2.1) 50 (B2.2.2) 51 (B2.2.3) 52 (B2.2.3.1) 53 (B2.2.3.2) 54 (B2.2.3.3) 55 (B2.2.4) 56 (B2.2.4.1) 57 (B2.2.4.2) 58 (B2.2.5) 59 (B2.2.5.1) 60 (B2.2.5.2) 61 (B2.2.5.3) 62 (B2.2.6)
表2f
编号  组分B 63 (B2.2.6.1) 64 (B2.2.7) 65 (B2.2.8) 66 (B2.2.8.1) 67 (B2.2.9) 68 (B2.2.10) 69 (B2.2.10.1) 70 (B2.2.10.2) 71 (B2.2.10.3) 72 (B2.2.10.4) 73 (B2.2.10.5) 74 (B2.2.10.6)
编号  组分B 75 (B2.2.11) 76 (B2.2.11.1) 77 (B2.2.12) 78 (B2.2.12.1) 79 (B2.2.12.2) 80 (B2.2.13) 81 (B2.2.14) 82 (B2.3.1)                
[0186]表2g编号  组分B 83 (B3.1.1) 84 (B3.1.2) 85 (B3.1.3) 86 (B3.1.4) 87 (B3.1.5) 88 (B3.1.6) 89 (B3.1.7) 90 (B3.1.8) 91 (B3.1.9)
表2h
编号  组分B 92 (B3.1.10) 93 (B3.1.11) 94 (B3.1.12) 95 (B3.1.12.1) 96 (B3.1.13) 97 (B3.1.14) 98 (B3.1.14.1) 99 (B3.1.14.2) 100 (B3.1.15)
表2i
编号 组分B 101 (B3.2.1) 102 (B3.2.2) 103 (B3.2.3)            
编号 组分B            
实施例:因此,在简短的注解中,除草剂(A5)和(B2.1.2.3)的组合表示为K5.23。
优选组合物的实例为:
选自除草剂组(A1)至(A127)和除草剂组(B1)或(B2)或(B3)的除草剂,例如选自(A1)至(A127)的除草剂和选自组(B1.1)、(B1.2)、(B2.1)、(B2.2)、(B2.3)、(B3.1)或(B3.2)的除草剂,特别是如下组合物之一:
K1.1,K1.2,K1.3,K1.4,K1.5,K1.6,K1.7,K1.8,K1.9,K1.10,K1.11,K1.12,K1.13,
K1.14,K1.15,K1.16,K1.17,K1.18,K1.19,K1.20,K1.21,K1.22,K1.23,K1.24,
K1.25,K1.26,K1.27,K1.28,K1.29,K1.30,K1.31,K1.32,K1.33,K1.34,K1.35,
K1.36,K1.37,K1.38,K1.39,K1.40,K1.41,K1.42,K1.43,K1.44,K1.45,K1.46,
K1.47,K1.48,K1.49,K1.50,K1.51,K1.52,K1.53,K1.54,K1.55,K1.56,K1.57,
K1.58,K1.59,K1.60,K1.61,K1.62,K1.63,K1.64,K1.65,K1.66,K1.67,K1.68,
K1.69,K1.70,K1.71,K1.72,K1.73,K1.74,K1.75,K1.76,K1.77,K1.78,K1.79,
K1.80,K1.81,K1.82,K1.83,K1.84,K1.85,K1.86,K1.87,K1.88,K1.89,K1.90,
K1.91,K1.92,K1.93,K1.94,K1.95,K1.96,K1.97,K1.98,K1.99,K1.100,K1.101,
K1.102,K1.103,
K2.1,K2.2,K2.3,K2.4,K2.5,K2.6,K2.7,K2.8,K2.9,K2.10,K2.11,K2.12,K2.13,
K2.14,K2.15,K2.16,K2.17,K2.18,K2.19,K2.20,K2.21,K2.22,K2.23,K2.24,
K2.25,K2.26,K2.27,K2.28,K2.29,K2.30,K2.31,K2.32,K2.33,K2.34,K2.35,
K2.36,K2.37,K2.38,K2.39,K2.40,K2.41,K2.42,K2.43,K2.44,K2.45,K2.46,
K2.47,K2.48,K2.49,K2.50,K2.51,K2.52,K2.53,K2.54,K2.55,K2.56,K2.57,
K2.58,K2.59,K2.60,K2.61,K2.62,K2.63,K2.64,K2.65,K2.66,K2.67,K2.68,
K2.69,K2.70,K2.71,K2.72,K2.73,K2.74,K2.75,K2.76,K2.77,K2.78,K2.79,
K2.80,K2.81,K2.82,K2.83,K2.84,K2.85,K2.86,K2.87,K2.88,K2.89,K2.90,
K2.91,K2.92,K2.93,K2.94,K2.95,K2.96,K2.97,K2.98,K2.99,K2.100,K2.101,
K2.102,K2.103,
K3.1,K3.2,K3.3,K3.4,K3.5,K3.6,K3.7,K3.8,K3.9,K3.10,K3.11,K3.12,K3.13,
K3.14,K3.15,K3.16,K3.17,K3.18,K3.19,K3.20,K3.21,K3.22,K3.23,K3.24,
K3.25,K3.26,K3.27,K3.28,K3.29,K3.30,K3.31,K3.32,K3.33,K3.34,K3.35,
K3.36,K3.37,K3.38,K3.39,K3.40,K3.41,K3.42,K3.43,K3.44,K3.45,K3.46,
K3.47,K3.48,K3.49,K3.50,K3.51,K3.52,K3.53,K3.54,K3.55,K3.56,K3.57,
K3.58,K3.59,K3.60,K3.61,K3.62,K3.63,K3.64,K3.65,K3.66,K3.67,K3.68,
K3.69,K3.70,K3.71,K3.72,K3.73,K3.74,K3.75,K3.76,K3.77,K3.78,K3.79,
K3.80,K3.81,K3.82,K3.83,K3.84,K3.85,K3.86,K3.87,K3.88,K3.89,K3.90,
K3.91,K3.92,K3.93,K3.94,K3.95,K3.96,K3.97,K3.98,K3.99,K3.100,K3.101,
K3.102,K3.103,
K4.1,K4.2,K4.3,K4.4,K4.5,K4.6,K4.7,K4.8,K4.9,K4.10,K4.11,K4.12,K4.13,
K4.14,K4.15,K4.16,K4.17,K4.18,K4.19,K4.20,K4.21,K4.22,K4.23,K4.24,
K4.25,K4.26,K4.27,K4.28,K4.29,K4.30,K4.31,K4.32,K4.33,K4.34,K4.35,
K4.36,K4.37,K4.38,K4.39,K4.40,K4.41,K4.42,K4.43,K4.44,K4.45,K4.46,
K4.47,K4.48,K4.49,K4.50,K4.51,K4.52,K4.53,K4.54,K4.55,K4.56,K4.57,
K4.58,K4.59,K4.60,K4.61,K4.62,K4.63,K4.64,K4.65,K4.66,K4.67,K4.68,
K4.69,K4.70,K4.71,K4.72,K4.73,K4.74,K4.75,K4.76,K4.77,K4.78,K4.79,
K4.80,K4.81,K4.82,K4.83,K4.84,K4.85,K4.86,K4.87,K4.88,K4.89,K4.90,
K4.91,K4.92,K4.93,K4.94,K4.95,K4.96,K4.97,K4.98,K4.99,K4.100,K4.101,
K4.102,K4.103,
K5.1,K5.2,K5.3,K5.4,K5.5,K5.6,K5.7,K5.8,K5.9,K5.10,K5.11,K5.12,K5.13,
K5.14,K5.15,K5.16,K5.17,K5.18,K5.19,K5.20,K5.21,K5.22,K5.23,K5.24,
K5.25,K5.26,K5.27,K5.28,K5.29,K5.30,K5.31,K5.32,K5.33,K5.34,K5.35,
K5.36,K5.37,K5.38,K5.39,K5.40,K5.41,K5.42,K5.43,K5.44,K5.45,K5.46,
K5.47,K5.48,K5.49,K5.50,K5.51,K5.52,K5.53,K5.54,K5.55,K5.56,K5.57,
K5.58,K5.59,K5.60,K5.61,K5.62,K5.63,K5.64,K5.65,K5.66,K5.67,K5.68,
K5.69,K5.70,K5.71,K5.72,K5.73,K5.74,K5.75,K5.76,K5.77,K5.78,K5.79,
K5.80,K5.81,K5.82,K5.83,K5.84,K5.85,K5.86,K5.87,K5.88,K5.89,K5.90,
K5.91,K5.92,K5.93,K5.94,K5.95,K5.96,K5.97,K5.98,K5.99,K5.100,K5.101,
K5.102,K5.103,
K6.1,K6.2,K6.3,K6.4,K6.5,K6.6,K6.7,K6.8,K6.9,K6.10,K6.11,K6.12,K6.13,
K6.14,K6.15,K6.16,K6.17,K6.18,K6.19,K6.20,K6.21,K6.22,K6.23,K6.24,
K6.25,K6.26,K6.27,K6.28,K6.29,K6.30,K6.31,K6.32,K6.33,K6.34,K6.35,
K6.36,K6.37,K6.38,K6.39,K6.40,K6.41,K6.42,K6.43,K6.44,K6.45,K6.46,
K6.47,K6.48,K6.49,K6.50,K6.51,K6.52,K6.53,K6.54,K6.55,K6.56,K6.57,
K6.58,K6.59,K6.60,K6.61,K6.62,K6.63,K6.64,K6.65,K6.66,K6.67,K6.68,
K6.69,K6.70,K6.71,K6.72,K6.73,K6.74,K6.75,K6.76,K6.77,K6.78,K6.79,
K6.80,K6.81,K6.82,K6.83,K6.84,K6.85,K6.86,K6.87,K6.88,K6.89,K6.90,
K6.91,K6.92,K6.93,K6.94,K6.95,K6.96,K6.97,K6.98,K6.99,K6.100,K6.101,
K6.102,K6.103,
K7.1,K7.2,K7.3,K7.4,K7.5,K7.6,K7.7,K7.8,K7.9,K7.10,K7.11,K7.12,K7.13,
K7.14,K7.15,K7.16,K7.17,K7.18,K7.19,K7.20,K7.21,K7.22,K7.23,K7.24,
K7.25,K7.26,K7.27,K7.28,K7.29,K7.30,K7.31,K7.32,K7.33,K7.34,K7.35,
K7.36,K7.37,K7.38,K7.39,K7.40,K7.41,K7.42,K7.43,K7.44,K7.45,K7.46,
K7.47,K7.48,K7.49,K7.50,K7.51,K7.52,K7.53,K7.54,K7.55,K7.56,K7.57,
K7.58,K7.59,K7.60,K7.61,K7.62,K7.63,K7.64,K7.65,K7.66,K7.67,K7.68,
K7.69,K7.70,K7.71,K7.72,K7.73,K7.74,K7.75,K7.76,K7.77,K7.78,K7.79,
K7.80,K7.81,K7.82,K7.83,K7.84,K7.85,K7.86,K7.87,K7.88,K7.91,K7.92,
K7.93,K7.94,K7.95,K7.96,K7.97,K7.98,K7.99,K7.100,K7.101,K7.102,K7.103,
K8.1,K8.2,K8.3,K8.4,K8.5,K8.6,K8.7,K8.8,K8.9,K8.10,K8.11,K8.12,K8.13,
K8.14,K8.15,K8.16,K8.17,K8.18,K8.19,K8.20,K8.21,K8.22,K8.23,K8.24,
K8.25,K8.26,K8.27,K8.28,K8.29,K8.30,K8.31,K8.32,K8.33,K8.34,K8.35,
K8.36,K8.37,K8.38,K8.39,K8.40,K8.41,K8.42,K8.43,K8.44,K8.45,K8.46,
K8.47,K8.48,K8.49,K8.50,K8.51,K8.52,K8.53,K8.54,K8.55,K8.56,K8.57,
K8.58,K8.59,K8.60,K8.61,K8.62,K8.63,K8.64,K8.65,K8.66,K8.67,K8.68,
K8.69,K8.70,K8.71,K8.72,K8.73,K8.74,K8.75,K8.76,K8.77,K8.78,K8.79,
K8.80,K8.81,K8.82,K8.83,K8.84,K8.85,K8.86,K8.87,K8.88,K8.89,K8.90,
K8.91,K8.92,K8.93,K8.94,K8.95,K8.96,K8.97,K8.98,K8.99,K8.100,K8.101,
K8.102,K8.103,
K9.1,K9.2,K9.3,K9.4,K9.5,K9.6,K9.7,K9.8,K9.9,K9.10,K9.11,K9.12,K9.13,
K9.14,K9.15,K9.16,K9.17,K9.18,K9.19,K9.20,K9.21,K9.22,K9.23,K9.24,
K9.25,K9.26,K9.27,K9.28,K9.29,K9.30,K9.31,K9.32,K9.33,K9.34,K9.35,
K9.36,K9.37,K9.38,K9.39,K9.40,K9.41,K9.42,K9.43,K9.44,K9.45,K9.46,
K9.47,K9.48,K9.49,K9.50,K9.51,K9.52,K9.53,K9.54,K9.55,K9.56,K9.57,
K9.58,K9.59,K9.60,K9.61,K9.62,K9.63,K9.64,K9.65,K9.66,K9.67,K9.68,
K9.69,K9.70,K9.71,K9.72,K9.73,K9.74,K9.75,K9.76,K9.77,K9.78,K9.79,
K9.80,K9.81,K9.82,K9.83,K9.84,K9.85,K9.86,K9.87,K9.88,K9.89,K9.90,
K9.91,K9.92,K9.93,K9.94,K9.95,K9.96,K9.97,K9.98,K9.99,K9.100,K9.101,
K9.102,K9.103,
K10.1,K10.2,K10.3,K10.4,K10.5,K10.6,K10.7,K10.8,K10.9,K10.10,K10.11,
K10.12,K10.13,K10.14,K10.15,K10.16,K10.17,K10.18,K10.19,K10.20,K10.21,
K10.22,K10.23,K10.24,K10.25,K10.26,K10.27,K10.28,K10.29,K10.30,K10.31,
K10.32,K10.33,K10.34,K10.35,K10.36,K10.37,K10.38,K10.39,K10.40,K10.41,
K10.42,K10.43,K10.44,K10.45,K10.46,K10.47,K10.48,K10.49,K10.50,K10.51,
K10.52,K10.53,K10.54,K10.55,K10.56,K10.57,K10.58,K10.59,K10.60,K10.61,
K10.62,K10.63,K10.64,K10.65,K10.66,K10.67,K10.68,K10.69,K10.70,K10.71,
K10.72,K10.73,K10.74,K10.75,K10.76,K10.77,K10.78,K10.79,K10.80,K10.81,
K10.82,K10.83,K10.84,K10.85,K10.86,K10.87,K10.88,K10.89,K10.90,K10.91,
K10.92,K10.93,K10.94,K10.95,K10.96,K10.97,K10.98,K10.99,K10.100,
K10.101,K10.102,K10.103,
K11.1,K11.2,K11.3,K11.4,K11.5,K11.6,K11.7,K11.8,K11.9,K11.10,K11.11,
K11.12,K11.13,K11.14,K11.15,K11.16,K11.17,K11.18,K11.19,K11.20,K11.21,
K11.22,K11.23,K11.24,K11.25,K11.26,K11.27,K11.28,K11.29,K11.30,K11.31,
K11.32,K11.33,K11.34,K11.35,K11.36,K11.37,K11.38,K11.39,K11.40,K11.41,
K11.42,K11.43,K11.44,K11.45,K11.46,K11.47,K11.48,K11.49,K11.50,K11.51,
K11.52,K11.53,K11.54,K11.55,K11.56,K11.57,K11.58,K11.59,K11.60,K11.61,
K11.62,K11.63,K11.64,K11.65,K11.66,K11.67,K11.68,K11.69,K11.70,K11.71,
K11.72,K11.73,K11.74,K11.75,K11.76,K11.77,K11.78,K11.79,K11.80,K11.81,
K11.82,K11.83,K11.84,K11.85,K11.86,K11.87,K11.88,K11.89,K11.90,K11.91,
K11.92,K11.93,K11.94,K11.95,K11.96,K11.97,K11.98,K11.99,K11.100,
K11.101,K11.102,K11.103,
K12.1,K12.2,K12.3,K12.4,K12.5,K12.6,K12.7,K12.8,K12.9,K12.10,K12.11,
K12.12,K12.13,K12.14,K12.15,K12.16,K12.17,K12.18,K12.19,K12.20,K12.21,
K12.22,K12.23,K12.24,K12.25,K12.26,K12.27,K12.28,K12.29,K12.30,K12.31,
K12.32,K12.33,K12.34,K12.35,K12.36,K12.37,K12.38,K12.39,K12.40,K12.41,
K12.42,K12.43,K12.44,K12.45,K12.46,K12.47,K12.48,K12.49,K12.50,K12.51,
K12.52,K12.53,K12.54,K12.55,K12.56,K12.57,K12.58,K12.59,K12.60,K12.61,
K12.62,K12.63,K12.64,K12.65,K12.66,K12.67,K12.68,K12.69,K12.70,K12.71,
K12.72,K12.73,K12.74,K12.75,K12.76,K12.77,K12.78,K12.79,K12.80,K12.81,
K12.82,K12.83,K12.84,K12.85,K12.86,K12.87,K12.88,K12.89,K12.90,K12.91,
K12.92,K12.93,K12.94,K12.95,K12.96,K12.97,K12.98,K12.99,K12.100,
K12.101,K12.102,K12.103,
K13.1,K13.2,K13.3,K13.4,K13.5,K13.6,K13.7,K13.8,K13.9,K13.10,K13.11,
K13.12,K13.13,K13.14,K13.15,K13.16,K13.17,K13.18,K13.19,K13.20,K13.21,
K13.22,K13.23,K13.24,K13.25,K13.26,K13.27,K13.28,K13.29,K13.30,K13.31,
K13.32,K13.33,K13.34,K13.35,K13.36,K13.37,K13.38,K13.39,K13.40,K13.41,
K13.42,K13.43,K13.44,K13.45,K13.46,K13.47,K13.48,K13.49,K13.50,K13.51,
K13.52,K13.53,K13.54,K13.55,K13.56,K13.57,K13.58,K13.59,K13.60,K13.61,
K13.62,K13.63,K13.64,K13.65,K13.66,K13.67,K13.68,K13.69,K13.70,K13.71,
K13.72,K13.73,K13.74,K13.75,K13.76,K13.77,K13.78,K13.79,K13.80,K13.81,
K13.82,K13.83,K13.84,K13.85,K13.86,K13.87,K13.88,K13.89,K13.90,K13.91,
K13.92,K13.93,K13.94,K13.95,K13.96,K13.97,K13.98,K13.99,K13.100,
K13.101,K13.102,K13.103,
K14.1,K14.2,K14.3,K14.4,K14.5,K14.6,K14.7,K14.8,K14.9,K14.10,K14.11,
K14.12,K14.13,K14.14,K14.15,K14.16,K14.17,K14.18,K14.19,K14.20,K14.21,
K14.22,K14.23,K14.24,K14.25,K14.26,K14.27,K14.28,K14.29,K14.30,K14.31,
K14.32,K14.33,K14.34,K14.35,K14.36,K14.37,K14.38,K14.39,K14.40,K14.41,
K14.42,K14.43,K14.44,K14.45,K14.46,K14.47,K14.48,K14.49,K14.50,K14.51,
K14.52,K14.53,K14.54,K14.55,K14.56,K14.57,K14.58,K14.59,K14.60,K14.61,
K14.62,K14.63,K14.64,K14.65,K14.66,K14.67,K14.68,K14.69,K14.70,K14.71,
K14.72,K14.73,K14.74,K14.75,K14.76,K14.77,K14.78,K14.79,K14.80,K14.81,
K14.82,K14.83,K14.84,K14.85,K14.86,K14.87,K14.88,K14.89,K14.90,K14.91,
K14.92,K14.93,K14.94,K14.95,K14.96,K14.97,K14.98,K14.99,K14.100,
K14.101,K14.102,K14.103,
K15.1,K15.2,K15.3,K15.4,K15.5,K15.6,K15.7,K15.8,K15.9,K15.10,K15.11,
K15.12,K15.13,K15.14,K15.15,K15.16,K15.17,K15.18,K15.19,K15.20,K15.21,
K15.22,K15.23,K15.24,K15.25,K15.26,K15.27,K15.28,K15.29,K15.30,K15.31,
K15.32,K15.33,K15.34,K15.35,K15.36,K15.37,K15.38,K15.39,K15.40,K15.41,
K15.42,K15.43,K15.44,K15.45,K15.46,K15.47,K15.48,K15.49,K15.50,K15.51,
K15.52,K15.53,K15.54,K15.55,K15.56,K15.57,K15.58,K15.59,K15.60,K15.61,
K15.62,K15.63,K15.64,K15.65,K15.66,K15.67,K15.68,K15.69,K15.70,K15.71,
K15.72,K15.73,K15.74,K15.75,K15.76,K15.77,K15.78,K15.79,K15.80,K15.81,
K15.82,K15.83,K15.84,K15.85,K15.86,K15.87,K15.88,K15.89,K15.90,K15.91,
K15.92,K15.93,K15.94,K15.95,K15.96,K15.97,K15.98,K15.99,K15.100,
K15.101,K15.102,K15.103,
K16.1,K16.2,K16.3,K16.4,K16.5,K16.6,K16.7,K16.8,K16.9,K16.10,K16.11,
K16.12,K16.13,K16.14,K16.15,K16.16,K16.17,K16.18,K16.19,K16.20,K16.21,
K16.22,K16.23,K16.24,K16.25,K16.26,K16.27,K16.28,K16.29,K16.30,K16.31,
K16.32,K16.33,K16.34,K16.35,K16.36,K16.37,K16.38,K16.39,K16.40,K16.41,
K16.42,K16.43,K16.44,K16.45,K16.46,K16.47,K16.48,K16.49,K16.50,K16.51,
K16.52,K16.53,K16.54,K16.55,K16.56,K16.57,K16.58,K16.59,K16.60,K16.61,
K16.62,K16.63,K16.64,K16.65,K16.66,K16.67,K16.68,K16.69,K16.70,K16.71,
K16.72,K16.73,K16.74,K16.75,K16.76,K16.77,K16.78,K16.79,K16.80,K16.81,
K16.82,K16.83,K16.84,K16.85,K16.86,K16.87,K16.88,K16.89,K16.90,K16.91,
K16.92,K16.93,K16.94,K16.95,K16.96,K16.97,K16.98,K16.99,K16.100,
K16.101,K16.102,K16.103,
K17.1,K17.2,K17.3,K17.4,K17.5,K17.6,K17.7,K17.8,K17.9,K17.10,K17.11,
K17.12,K17.13,K17.14,K17.15,K17.16,K17.17,K17.18,K17.19,K17.20,K17.21,
K17.22,K17.23,K17.24,K17.25,K17.26,K17.27,K17.28,K17.29,K17.30,K17.31,
K17.32,K17.33,K17.34,K17.35,K17.36,K17.37,K17.38,K17.39,K17.40,K17.41,
K17.42,K17.43,K17.44,K17.45,K17.46,K17.47,K17.48,K17.49,K17.50,K17.51,
K17.52,K17.53,K17.54,K17.55,K17.56,K17.57,K17.58,K17.59,K17.60,K17.61,
K17.62,K17.63,K17.64,K17.65,K17.66,K17.67,K17.68,K17.69,K17.70,K17.71,
K17.72,K17.73,K17.74,K17.75,K17.76,K17.77,K17.78,K17.79,K17.80,K17.81,
K17.82,K17.83,K17.84,K17.85,K17.86,K17.87,K17.88,K17.89,K17.90,K17.91,
K17.92,K17.93,K17.94,K17.95,K17.89,K17.90,K17.91,K17.92,K17.93,K17.94,
K17.95,K17.96,K17.97,K17.98,K17.99,K17.100,K17.101,K17.102,K17.103,
K18.1,K18.2,K18.3,K18.4,K18.5,K18.6,K18.7,K18.8,K18.9,K18.10,K18.11,
K18.12,K18.13,K18.14,K18.15,K18.16,K18.17,K18.18,K18.19,K18.20,K18.21,
K18.22,K18.23,K18.24,K18.25,K18.26,K18.27,K18.28,K18.29,K18.30,K18.31,
K18.32,K18.33,K18.34,K18.35,K18.36,K18.37,K18.38,K18.39,K18.40,K18.41,
K18.42,K18.43,K18.44,K18.45,K18.46,K18.47,K18.48,K18.49,K18.50,K18.51,
K18.52,K18.53,K18.54,K18.55,K18.56,K18.57,K18.58,K18.59,K18.60,K18.61,
K18.62,K18.63,K18.64,K18.65,K18.66,K18.67,K18.68,K18.69,K18.70,K18.71,
K18.72,K18.73,K18.74,K18.75,K18.76,K18.77,K18.78,K18.79,K18.80,K18.81,
K18.82,K18.83,K18.84,K18.85,K18.86,K18.87,K18.88,K18.89,K18.90,K18.91,
K18.92,K18.93,K18.94,K18.95,K18.96,K18.97,K18.98,K18.99,K18.100,
K18.101,K18.102,K18.103,
K19.1,K19.2,K19.3,K19.4,K19.5,K19.6,K19.7,K19.8,K19.9,K19.10,K19.11,
K19.12,K19.13,K19.14,K19.15,K19.16,K19.17,K19.18,K19.19,K19.20,K19.21,
K19.22,K19.23,K19.24,K19.25,K19.26,K19.27,K19.28,K19.29,K19.30,K19.31,
K19.32,K19.33,K19.34,K19.35,K19.36,K19.37,K19.38,K19.39,K19.40,K19.41,
K19.42,K19.43,K19.44,K19.45,K19.46,K19.47,K19.48,K19.49,K19.50,K19.51,
K19.52,K19.53,K19.54,K19.55,K19.56,K19.57,K19.58,K19.59,K19.60,K19.61,
K19.62,K19.63,K19.64,K19.65,K19.66,K19.67,K19.68,K19.69,K19.70,K19.71,
K19.72,K19.73,K19.74,K19.75,K19.76,K19.77,K19.78,K19.79,K19.80,K19.81,
K19.82,K19.83,K19.84,K19.85,K19.86,K19.87,K19.88,K19.89,K19.90,K19.91,
K19.92,K19.93,K19.94,K19.95,K19.96,K19.97,K19.98,K19.99,K19.100,
K19.101,K19.102,K19.103,
K20.1,K20.2,K20.3,K20.4,K20.5,K20.6,K20.7,K20.8,K20.9,K20.10,K20.11,
K20.12,K20.13,K20.14,K20.15,K20.16,K20.17,K20.18,K20.19,K20.20,K20.21,
K20.22,K20.23,K20.24,K20.25,K20.26,K20.27,K20.28,K20.29,K20.30,K20.31,
K20.32,K20.33,K20.34,K20.35,K20.36,K20.37,K20.38,K20.39,K20.40,K20.41,
K20.42,K20.43,K20.44,K20.45,K20.46,K20.47,K20.48,K20.49,K20.50,K20.51,
K20.52,K20.53,K20.54,K20.55,K20.56,K20.57,K20.58,K20.59,K20.60,K20.61,
K20.62,K20.63,K20.64,K20.65,K20.66,K20.67,K20.68,K20.69,K20.70,K20.71,
K20.72,K20.73,K20.74,K20.75,K20.76,K20.77,K20.78,K20.79,K20.80,K20.81,
K20.82,K20.83,K20.84,K20.85,K20.86,K20.87,K20.88,K20.89,K20.90,K20.91,
K20.92,K20.93,K20.94,K20.95,K20.96,K20.97,K20.98,K20.99,K20.100,
K20.101,K20.102,K20.103,
K21.1,K21.2,K21.3,K21.4,K21.5,K21.6,K21.7,K21.8,K21.9,K21.10,K21.11,
K21.12,K21.13,K21.14,K21.15,K21.16,K21.17,K21.18,K21.19,K21.20,K21.21,
K21.22,K21.23,K21.24,K21.25,K21.26,K21.27,K21.28,K21.29,K21.30,K21.31,
K21.32,K21.33,K21.34,K21.35,K21.36,K21.37,K21.38,K21.39,K21.40,K21.41,
K21.42,K21.43,K21.44,K21.45,K21.46,K21.47,K21.48,K21.49,K21.50,K21.51,
K21.52,K21.53,K21.54,K21.55,K21.56,K21.57,K21.58,K21.59,K21.60,K21.61,
K21.62,K21.63,K21.64,K21.65,K21.66,K21.67,K21.68,K21.69,K21.70,K21.71,
K21.72,K21.73,K21.74,K21.75,K21.76,K21.77,K21.78,K21.79,K21.80,K21.81,
K21.82,K21.83,K21.84,K21.85,K21.86,K21.87,K21.88,K21.89,K21.90,K21.91,
K21.92,K21.93,K21.94,K21.95,K21.96,K21.97,K21.98,K21.99,K21.100,
K21.101,K21.102,K21.103,
K22.1,K22.2,K22.3,K22.4,K22.5,K22.6,K22.7,K22.8,K22.9,K22.10,K22.11,
K22.12,K22.13,K22.14,K22.15,K22.16,K22.17,K22.18,K22.19,K22.20,K22.21,
K22.22,K22.23,K22.24,K22.25,K22.26,K22.27,K22.28,K22.29,K22.30,K22.31,
K22.32,K22.33,K22.34,K22.35,K22.36,K22.37,K22.38,K22.39,K22.40,K22.41,
K22.42,K22.43,K22.44,K22.45,K22.46,K22.47,K22.48,K22.49,K22.50,K22.51,
K22.52,K22.53,K22.54,K22.55,K22.56,K22.57,K22.58,K22.59,K22.60,K22.61,
K22.62,K22.63,K22.64,K22.65,K22.66,K22.67,K22.68,K22.69,K22.70,K22.71,
K22.72,K22.73,K22.74,K22.75,K22.76,K22.77,K22.78,K22.79,K22.80,K22.81,
K22.82,K22.83,K22.84,K22.85,K22.86,K22.87,K22.88,K22.89,K22.90,K22.91,
K22.92,K22.93,K22.94,K22.95,K22.96,K22.97,K22.98,K22.99,K22.100,
K22.101,K22.102,K22.103,
K23.1,K23.2,K23.3,K23.4,K23.5,K23.6,K23.7,K23.8,K23.9,K23.10,K23.11,
K23.12,K23.13,K23.14,K23.15,K23.16,K23.17,K23.18,K23.19,K23.20,K23.21,
K23.22,K23.23,K23.24,K23.25,K23.26,K23.27,K23.28,K23.29,K23.30,K23.31,
K23.32,K23.33,K23.34,K23.35,K23.36,K23.37,K23.38,K23.39,K23.40,K23.41,
K23.42,K23.43,K23.44,K23.45,K23.46,K23.47,K23.48,K23.49,K23.50,K23.51,
K23.52,K23.53,K23.54,K23.55,K23.56,K23.57,K23.58,K23.59,K23.60,K23.61,
K23.62,K23.63,K23.64,K23.65,K23.66,K23.67,K23.68,K23.69,K23.70,K23.71,
K23.72,K23.73,K23.74,K23.75,K23.76,K23.77,K23.78,K23.79,K23.80,K23.81,
K23.82,K23.83,K23.84,K23.85,K23.86,K23.87,K23.88,K23.89,K23.90,K23.91,
K23.92,K23.93,K23.94,K23.95,K23.96,K23.97,K23.98,K23.99,K23.100,
K23.101,K23.102,K23.103,
K24.1,K24.2,K24.3,K24.4,K24.5,K24.6,K24.7,K24.8,K24.9,K24.10,K24.11,
K24.12,K24.13,K24.14,K24.15,K24.16,K24.17,K24.18,K24.19,K24.20,K24.21,
K24.22,K24.23,K24.24,K24.25,K24.26,K24.27,K24.28,K24.29,K24.30,K24.31,
K24.32,K24.33,K24.34,K24.35,K24.36,K24.37,K24.38,K24.39,K24.40,K24.41,
K24.42,K24.43,K24.44,K24.45,K24.46,K24.47,K24.48,K24.49,K24.50,K24.51,
K24.52,K24.53,K24.54,K24.55,K24.56,K24.57,K24.58,K24.59,K24.60,K24.61,
K24.62,K24.63,K24.64,K24.65,K24.66,K24.67,K24.68,K24.69,K24.70,K24.71,
K24.72,K24.73,K24.74,K24.75,K24.76,K24.77,K24.78,K24.79,K24.80,K24.81,
K24.82,K24.83,K24.84,K24.85,K24.86,K24.87,K24.88,K24.89,K24.90,K24.91,
K24.92,K24.93,K24.94,K24.95,K24.96,K24.97,K24.98,K24.99,K24.100,
K24.101,K24.102,K24.103,
K25.1,K25.2,K25.3,K25.4,K25.5,K25.6,K25.7,K25.8,K25.9,K25.10,K25.11,
K25.12,K25.13,K25.14,K25.15,K25.16,K25.17,K25.18,K25.19,K25.20,K25.21,
K25.22,K25.23,K25.24,K25.25,K25.26,K25.27,K25.28,K25.29,K25.30,K25.31,
K25.32,K25.33,K25.34,K25.35,K25.36,K25.37,K25.38,K25.39,K25.40,K25.41,
K25.42,K25.43,K25.44,K25.45,K25.46,K25.47,K25.48,K25.49,K25.50,K25.51,
K25.52,K25.53,K25.54,K25.55,K25.56,K25.57,K25.58,K25.59,K25.60,K25.61,
K25.62,K25.63,K25.64,K25.65,K25.66,K25.67,K25.68,K25.69,K25.70,K25.71,
K25.72,K25.73,K25.74,K25.75,K25.76,K25.77,K25.78,K25.79,K25.80,K25.81,
K25.82,K25.83,K25.84,K25.85,K25.86,K25.87,K25.88,K25.89,K25.90,K25.91,
K25.92,K25.93,K25.94,K25.95,K25.96,K25.97,K25.98,K25.99,K25.100,
K25.101,K25.102,K25.103,
K26.1,K26.2,K26.3,K26.4,K26.5,K26.6,K26.7,K26.8,K26.9,K26.10,K26.11,
K26.12,K26.13,K26.14,K26.15,K26.16,K26.17,K26.18,K26.19,K26.20,K26.21,
K26.22,K26.23,K26.24,K26.25,K26.26,K26.27,K26.28,K26.29,K26.30,K26.31,
K26.32,K26.33,K26.34,K26.35,K26.36,K26.37,K26.38,K26.39,K26.40,K26.41,
K26.42,K26.43,K26.44,K26.45,K26.46,K26.47,K26.48,K26.49,K26.50,K26.51,
K26.52,K26.53,K26.54,K26.55,K26.56,K26.57,K26.58,K26.59,K26.60,K26.61,
K26.62,K26.63,K26.64,K26.65,K26.66,K26.67,K26.68,K26.69,K26.70,K26.71,
K26.72,K26.73,K26.74,K26.75,K26.76,K26.77,K26.78,K26.79,K26.80,K26.81,
K26.82,K26.83,K26.84,K26.85,K26.86,K26.87,K26.88,K26.89,K26.90,K26.91,
K26.92,K26.93,K26.94,K26.95,K26.96,K26.97,K26.98,K26.99,K26.100,
K26.101,K26.102,K26.103,
K27.1,K27.2,K27.3,K27.4,K27.5,K27.6,K27.7,K27.8,K27.9,K27.10,K27.11,
K27.12,K27.13,K27.14,K27.15,K27.16,K27.17,K27.18,K27.19,K27.20,K27.21,
K27.22,K27.23,K27.24,K27.25,K27.26,K27.27,K27.28,K27.29,K27.30,K27.31,
K27.32,K27.33,K27.34,K27.35,K27.36,K27.37,K27.38,K27.39,K27.40,K27.41,
K27.42,K27.43,K27.44,K27.45,K27.46,K27.47,K27.48,K27.49,K27.50,K27.51,
K27.52,K27.53,K27.54,K27.55,K27.56,K27.57,K27.58,K27.59,K27.60,K27.61,
K27.62,K27.63,K27.64,K27.65,K27.66,K27.67,K27.68,K27.69,K27.70,K27.71,
K27.72,K27.73,K27.74,K27.75,K27.76,K27.77,K27.78,K27.79,K27.80,K27.81,
K27.82,K27.83,K27.84,K27.85,K27.86,K27.87,K27.88,K27.89,K27.90,K27.91,
K27.92,K27.93,K27.94,K27.95,K27.96,K27.97,K27.98,K27.99,K27.100,
K27.101,K27.102,K27.103,
K28.1,K28.2,K28.3,K28.4,K28.5,K28.6,K28.7,K28.8,K28.9,K28.10,K28.11,
K28.12,K28.13,K28.14,K28.15,K28.16,K28.17,K28.18,K28.19,K28.20,K28.21,
K28.22,K28.23,K28.24,K28.25,K28.26,K28.27,K28.28,K28.29,K28.30,K28.31,
K28.32,K28.33,K28.34,K28.35,K28.36,K28.37,K28.38,K28.39,K28.40,K28.41,
K28.42,K28.43,K28.44,K28.45,K28.46,K28.47,K28.48,K28.49,K28.50,K28.51,
K28.52,K28.53,K28.54,K28.55,K28.56,K28.57,K28.58,K28.59,K28.60,K28.61,
K28.62,K28.63,K28.64,K28.65,K28.66,K28.67,K28.68,K28.69,K28.70,K28.71,
K28.72,K28.73,K28.74,K28.75,K28.76,K28.77,K28.78,K28.79,K28.80,K28.81,
K28.82,K28.83,K28.84,K28.85,K28.86,K28.87,K28.88,K28.89,K28.90,K28.91,
K28.92,K28.93,K28.94,K28.95,K28.96,K28.97,K28.98,K28.99,K28.100,
K28.101,K28.102,K28.103,
K29.1,K29.2,K29.3,K29.4,K29.5,K29.6,K29.7,K29.8,K29.9,K29.10,K29.11,
K29.12,K29.13,K29.14,K29.15,K29.16,K29.17,K29.18,K29.19,K29.20,K29.21,
K29.22,K29.23,K29.24,K29.25,K29.26,K29.27,K29.28,K29.29,K29.30,K29.31,
K29.32,K29.33,K29.34,K29.35,K29.36,K29.37,K29.38,K29.39,K29.40,K29.41,
K29.42,K29.43,K29.44,K29.45,K29.46,K29.47,K29.48,K29.49,K29.50,K29.51,
K29.52,K29.53,K29.54,K29.55,K29.56,K29.57,K29.58,K29.59,K29.60,K29.61,
K29.62,K29.63,K29.64,K29.65,K29.66,K29.67,K29.68,K29.69,K29.70,K29.71,
K29.72,K29.73,K29.74,K29.75,K29.76,K29.77,K29.78,K29.79,K29.80,K29.81,
K29.82,K29.83,K29.84,K29.85,K29.86,K29.87,K29.88,K29.89,K29.90,K29.91,
K29.92,K29.93,K29.94,K29.95,K29.96,K29.97,K29.98,K29.99,K29.100,
K29.101,K29.102,K29.103,
K30.1,K30.2,K30.3,K30.4,K30.5,K30.6,K30.7,K30.8,K30.9,K30.10,K30.11,
K30.12,K30.13,K30.14,K30.15,K30.16,K30.17,K30.18,K30.19,K30.20,K30.21,
K30.22,K30.23,K30.24,K30.25,K30.26,K30.27,K30.28,K30.29,K30.30,K30.31,
K30.32,K30.33,K30.34,K30.35,K30.36,K30.37,K30.38,K30.39,K30.40,K30.41,
K30.42,K30.43,K30.44,K30.45,K30.46,K30.47,K30.48,K30.49,K30.50,K30.51,
K30.52,K30.53,K30.54,K30.55,K30.56,K30.57,K30.58,K30.59,K30.60,K30.61,
K30.62,K30.63,K30.64,K30.65,K30.66,K30.67,K30.68,K30.69,K30.70,K30.71,
K30.72,K30.73,K30.74,K30.75,K30.76,K30.77,K30.78,K30.79,K30.80,K30.81,
K30.82,K30.83,K30.84,K30.85,K30.86,K30.87,K30.88,K30.89,K30.90,K30.91,
K30.92,K30.93,K30.94,K30.95,K30.96,K30.97,K30.98,K30.99,K30.100,
K30.101,K30.102,K30.103,
K31.1,K31.2,K31.3,K31.4,K31.5,K31.6,K31.7,K31.8,K31.9,K31.10,K31.11,
K31.12,K31.13,K31.14,K31.15,K31.16,K31.17,K31.18,K31.19,K31.20,K31.21,
K31.22,K31.23,K31.24,K31.25,K31.26,K31.27,K31.28,K31.29,K31.30,K31.31,
K31.32,K31.33,K31.34,K31.35,K31.36,K31.37,K31.38,K31.39,K31.40,K31.41,
K31.42,K31.43,K31.44,K31.45,K31.46,K31.47,K31.48,K31.49,K31.50,K31.51,
K31.52,K31.53,K31.54,K31.55,K31.56,K31.57,K31.58,K31.59,K31.60,K31.61,
K31.62,K31.63,K31.64,K31.65,K31.66,K31.67,K31.68,K31.69,K31.70,K31.71,
K31.72,K31.73,K31.74,K31.75,K31.76,K31.77,K31.78,K31.79,K31.80,K31.81,
K31.82,K31.83,K31.84,K31.85,K31.86,K31.87,K31.88,K31.89,K31.90,K31.91,
K31.92,K31.93,K31.94,K31.95,K31.96,K31.97,K31.98,K31.99,K31.100,
K31.101,K31.102,K31.103,
K32.1,K32.2,K32.3,K32.4,K32.5,K32.6,K32.7,K32.8,K32.9,K32.10,K32.11,
K32.12,K32.13,K32.14,K32.15,K32.16,K32.17,K32.18,K32.19,K32.20,K32.21,
K32.22,K32.23,K32.24,K32.25,K32.26,K32.27,K32.28,K32.29,K32.30,K32.31,
K32.32,K32.33,K32.34,K32.35,K32.36,K32.37,K32.38,K32.39,K32.40,K32.41,
K32.42,K32.43,K32.44,K32.45,K32.46,K32.47,K32.48,K32.49,K32.50,K32.51,
K32.52,K32.53,K32.54,K32.55,K32.56,K32.57,K32.58,K32.59,K32.60,K32.61,
K32.62,K32.63,K32.64,K32.65,K32.66,K32.67,K32.68,K32.69,K32.70,K32.71,
K32.72,K32.73,K32.74,K32.75,K32.76,K32.77,K32.78,K32.79,K32.80,K32.81,
K32.82,K32.83,K32.84,K32.85,K32.86,K32.87,K32.88,K32.89,K32.90,K32.91,
K32.92,K32.93,K32.94,K32.95,K32.96,K32.97,K32.98,K32.99,K32.100,
K32.101,K32.102,K32.103,
K33.1,K33.2,K33.3,K33.4,K33.5,K33.6,K33.7,K33.8,K33.9,K33.10,K33.11,
K33.12,K33.13,K33.14,K33.15,K33.16,K33.17,K33.18,K33.19,K33.20,K33.21,
K33.22,K33.23,K33.24,K33.25,K33.26,K33.27,K33.28,K33.29,K33.30,K33.31,
K33.32,K33.33,K33.34,K33.35,K33.36,K33.37,K33.38,K33.39,K33.40,K33.41,
K33.42,K33.43,K33.44,K33.45,K33.46,K33.47,K33.48,K33.49,K33.50,K33.51,
K33.52,K33.53,K33.54,K33.55,K33.56,K33.57,K33.58,K33.59,K33.60,K33.61,
K33.62,K33.63,K33.64,K33.65,K33.66,K33.67,K33.68,K33.69,K33.70,K33.71,
K33.72,K33.73,K33.74,K33.75,K33.76,K33.77,K33.78,K33.79,K33.80,K33.81,
K33.82,K33.83,K33.84,K33.85,K33.86,K33.87,K33.88,K33.89,K33.90,K33.91,
K33.92,K33.93,K33.94,K33.95,K33.96,K33.97,K33.98,K33.99,K33.100,
K33.101,K33.102,K33.103,
K34.1,K34.2,K34.3,K34.4,K34.5,K34.6,K34.7,K34.8,K34.9,K34.10,K34.11,
K34.12,K34.13,K34.14,K34.15,K34.16,K34.17,K34.18,K34.19,K34.20,K34.21,
K34.22,K34.23,K34.24,K34.25,K34.26,K34.27,K34.28,K34.29,K34.30,K34.31,
K34.32,K34.33,K34.34,K34.35,K34.36,K34.37,K34.38,K34.39,K34.40,K34.41,
K34.42,K34.43,K34.44,K34.45,K34.46,K34.47,K34.48,K34.49,K34.50,K34.51,
K34.52,K34.53,K34.54,K34.55,K34.56,K34.57,K34.58,K34.59,K34.60,K34.61,
K34.62,K34.63,K34.64,K34.65,K34.66,K34.67,K34.68,K34.69,K34.70,K34.71,
K34.72,K34.73,K34.74,K34.75,K34.76,K34.77,K34.78,K34.79,K34.80,K34.81,
K34.82,K34.83,K34.84,K34.85,K34.86,K34.87,K34.88,K34.89,K34.90,K34.91,
K34.92,K34.93,K34.94,K34.95,K34.96,K34.97,K34.98,K34.99,K34.100,
K34.101,K34.102,K34.103,
K35.1,K35.2,K35.3,K35.4,K35.5,K35.6,K35.7,K35.8,K35.9,K35.10,K35.11,
K35.12,K35.13,K35.14,K35.15,K35.16,K35.17,K35.18,K35.19,K35.20,K35.21,
K35.22,K35.23,K35.24,K35.25,K35.26,K35.27,K35.28,K35.29,K35.30,K35.31,
K35.32,K35.33,K35.34,K35.35,K35.36,K35.37,K35.38,K35.39,K35.40,K35.41,
K35.42,K35.43,K35.44,K35.45,K35.46,K35.47,K35.48,K35.49,K35.50,K35.51,
K35.52,K35.53,K35.54,K35.55,K35.56,K35.57,K35.58,K35.59,K35.60,K35.61,
K35.62,K35.63,K35.64,K35.65,K35.66,K35.67,K35.68,K35.69,K35.70,K35.71,
K35.72,K35.73,K35.74,K35.75,K35.76,K35.77,K35.78,K35.79,K35.80,K35.81,
K35.82,K35.83,K35.84,K35.85,K35.86,K35.87,K35.88,K35.89,K35.90,K35.91,
K35.92,K35.93,K35.94,K35.95,K35.96,K35.97,K35.98,K35.99,K35.100,
K35.101,K35.102,K35.103,
K36.1,K36.2,K36.3,K36.4,K36.5,K36.6,K36.7,K36.8,K36.9,K36.10,K36.11,
K36.12,K36.13,K36.14,K36.15,K36.16,K36.17,K36.18,K36.19,K36.20,K36.21,
K36.22,K36.23,K36.24,K36.25,K36.26,K36.27,K36.28,K36.29,K36.30,K36.31,
K36.32,K36.33,K36.34,K36.35,K36.36,K36.37,K36.38,K36.39,K36.40,K36.41,
K36.42,K36.43,K36.44,K36.45,K36.46,K36.47,K36.48,K36.49,K36.50,K36.51,
K36.52,K36.53,K36.54,K36.55,K36.56,K36.57,K36.58,K36.59,K36.60,K36.61,
K36.62,K36.63,K36.64,K36.65,K36.66,K36.67,K36.68,K36.69,K36.70,K36.71,
K36.72,K36.73,K36.74,K36.75,K36.76,K36.77,K36.78,K36.79,K36.80,K36.81,
K36.82,K36.83,K36.84,K36.85,K36.86,K36.87,K36.88,K36.89,K36.90,K36.91,
K36.92,K36.93,K36.94,K36.95,K36.96,K36.97,K36.98,K36.99,K36.100,
K36.101,K36.102,K36.103,
K37.1,K37.2,K37.3,K37.4,K37.5,K37.6,K37.7,K37.8,K37.9,K37.10,K37.11,
K37.12,K37.13,K37.14,K37.15,K37.16,K37.17,K37.18,K37.19,K37.20,K37.21,
K37.22,K37.23,K37.24,K37.25,K37.26,K37.27,K37.28,K37.29,K37.30,K37.31,
K37.32,K37.33,K37.34,K37.35,K37.36,K37.37,K37.38,K37.39,K37.40,K37.41,
K37.42,K37.43,K37.44,K37.45,K37.46,K37.47,K37.48,K37.49,K37.50,K37.51,
K37.52,K37.53,K37.54,K37.55,K37.56,K37.57,K37.58,K37.59,K37.60,K37.61,
K37.62,K37.63,K37.64,K37.65,K37.66,K37.67,K37.68,K37.69,K37.70,K37.71,
K37.72,K37.73,K37.74,K37.75,K37.76,K37.77,K37.78,K37.79,K37.80,K37.81,
K37.82,K37.83,K37.84,K37.85,K37.86,K37.87,K37.88,K37.89,K37.90,K37.91,
K37.92,K37.93,K37.94,K37.95,K37.96,K37.97,K37.98,K37.99,K37.100,
K37.101,K37.102,K37.103,
K38.1,K38.2,K38.3,K38.4,K38.5,K38.6,K38.7,K38.8,K38.9,K38.10,K38.11,
K38.12,K38.13,K38.14,K38.15,K38.16,K38.17,K38.18,K38.19,K38.20,K38.21,
K38.22,K38.23,K38.24,K38.25,K38.26,K38.27,K38.28,K38.29,K38.30,K38.31,
K38.32,K38.33,K38.34,K38.35,K38.36,K38.37,K38.38,K38.39,K38.40,K38.41,
K38.42,K38.43,K38.44,K38.45,K38.46,K38.47,K38.48,K38.49,K38.50,K38.51,
K38.52,K38.53,K38.54,K38.55,K38.56,K38.57,K38.58,K38.59,K38.60,K38.61,
K38.62,K38.63,K38.64,K38.65,K38.66,K38.67,K38.68,K38.69,K38.70,K38.71,
K38.72,K38.73,K38.74,K38.75,K38.76,K38.77,K38.78,K38.79,K38.80,K38.81,
K38.82,K38.83,K38.84,K38.85,K38.86,K38.87,K38.88,K38.89,K38.90,K38.91,
K38.92,K38.93,K38.94,K38.95,K38.96,K38.97,K38.98,K38.99,K38.100,
K38.101,K38.102,K38.103,
K39.1,K39.2,K39.3,K39.4,K39.5,K39.6,K39.7,K39.8,K39.9,K39.10,K39.11,
K39.12,K39.13,K39.14,K39.15,K39.16,K39.17,K39.18,K39.19,K39.20,K39.21,
K39.22,K39.23,K39.24,K39.25,K39.26,K39.27,K39.28,K39.29,K39.30,K39.31,
K39.32,K39.33,K39.34,K39.35,K39.36,K39.37,K39.38,K39.39,K39.40,K39.41,
K39.42,K39.43,K39.44,K39.45,K39.46,K39.47,K39.48,K39.49,K39.50,K39.51,
K39.52,K39.53,K39.54,K39.55,K39.56,K39.57,K39.58,K39.59,K39.60,K39.61,
K39.62,K39.63,K39.64,K39.65,K39.66,K39.67,K39.68,K39.69,K39.70,K39.71,
K39.72,K39.73,K39.74,K39.75,K39.76,K39.77,K39.78,K39.79,K39.80,K39.81,
K39.82,K39.83,K39.84,K39.85,K39.86,K39.87,K39.88,K39.89,K39.90,K39.91,
K39.92,K39.93,K39.94,K39.95,K39.96,K39.97,K39.98,K39.99,K39.100,
K39.101,K39.102,K39.103,
K40.1,K40.2,K40.3,K40.4,K40.5,K40.6,K40.7,K40.8,K40.9,K40.10,K40.11,
K40.12,K40.13,K40.14,K40.15,K40.16,K40.17,K40.18,K40.19,K40.20,K40.21,
K40.22,K40.23,K40.24,K40.25,K40.26,K40.27,K40.28,K40.29,K40.30,K40.31,
K40.32,K40.33,K40.34,K40.35,K40.36,K40.37,K40.38,K40.39,K40.40,K40.41,
K40.42,K40.43,K40.44,K40.45,K40.46,K40.47,K40.48,K40.49,K40.50,K40.51,
K40.52,K40.53,K40.54,K40.55,K40.56,K40.57,K40.58,K40.59,K40.60,K40.61,
K40.62,K40.63,K40.64,K40.65,K40.66,K40.67,K40.68,K40.69,K40.70,K40.71,
K40.72,K40.73,K40.74,K40.75,K40.76,K40.77,K40.78,K40.79,K40.80,K40.81,
K40.82,K40.83,K40.84,K40.85,K40.86,K40.87,K40.88,K40.89,K40.90,K40.91,
K40.92,K40.93,K40.94,K40.95,K40.96,K40.97,K40.98,K40.99,K40.100,
K40.101,K40.102,K40.103,
K41.1,K41.2,K41.3,K41.4,K41.5,K41.6,K41.7,K41.8,K41.9,K41.10,K41.11,
K41.12,K41.13,K41.14,K41.15,K41.16,K41.17,K41.18,K41.19,K41.20,K41.21,
K41.22,K41.23,K41.24,K41.25,K41.26,K41.27,K41.28,K41.29,K41.30,K41.31,
K41.32,K41.33,K41.34,K41.35,K41.36,K41.37,K41.38,K41.39,K41.40,K41.41,
K41.42,K41.43,K41.44,K41.45,K41.46,K41.47,K41.48,K41.49,K41.50,K41.51,
K41.52,K41.53,K41.54,K41.55,K41.56,K41.57,K41.58,K41.59,K41.60,K41.61,
K41.62,K41.63,K41.64,K41.65,K41.66,K41.67,K41.68,K41.69,K41.70,K41.71,
K41.72,K41.73,K41.74,K41.75,K41.76,K41.77,K41.78,K41.79,K41.80,K41.81,
K41.82,K41.83,K41.84,K41.85,K41.86,K41.87,K41.88,K41.89,K41.90,K41.91,
K41.92,K41.93,K41.94,K41.95,K41.96,K41.97,K41.98,K41.99,K41.100,
K41.101,K41.102,K41.103,
K42.1,K42.2,K42.3,K42.4,K42.5,K42.6,K42.7,K42.8,K42.9,K42.10,K42.11,
K42.12,K42.13,K42.14,K42.15,K42.16,K42.17,K42.18,K42.19,K42.20,K42.21,
K42.22,K42.23,K42.24,K42.25,K42.26,K42.27,K42.28,K42.29,K42.30,K42.31,
K42.32,K42.33,K42.34,K42.35,K42.36,K42.37,K42.38,K42.39,K42.40,K42.41,
K42.42,K42.43,K42.44,K42.45,K42.46,K42.47,K42.48,K42.49,K42.50,K42.51,
K42.52,K42.53,K42.54,K42.55,K42.56,K42.57,K42.58,K42.59,K42.60,K42.61,
K42.62,K42.63,K42.64,K42.65,K42.66,K42.67,K42.68,K42.69,K42.70,K42.71,
K42.72,K42.73,K42.74,K42.75,K42.76,K42.77,K42.78,K42.79,K42.80,K42.81,
K42.82,K42.83,K42.84,K42.85,K42.86,K42.87,K42.88,K42.89,K42.90,K42.91,
K42.92,K42.93,K42.94,K42.95,K42.96,K42.97,K42.98,K42.99,K42.100,
K42.101,K42.102,K42.103,
K43.1,K43.2,K43.3,K43.4,K43.5,K43.6,K43.7,K43.8,K43.9,K43.10,K43.11,
K43.12,K43.13,K43.14,K43.15,K43.16,K43.17,K43.18,K43.19,K43.20,K43.21,
K43.22,K43.23,K43.24,K43.25,K43.26,K43.27,K43.28,K43.29,K43.30,K43.31,
K43.32,K43.33,K43.34,K43.35,K43.36,K43.37,K43.38,K43.39,K43.40,K43.41,
K43.42,K43.43,K43.44,K43.45,K43.46,K43.47,K43.48,K43.49,K43.50,K43.51,
K43.52,K43.53,K43.54,K43.55,K43.56,K43.57,K43.58,K43.59,K43.60,K43.61,
K43.62,K43.63,K43.64,K43.65,K43.66,K43.67,K43.68,K43.69,K43.70,K43.71,
K43.72,K43.73,K43.74,K43.75,K43.76,K43.77,K43.78,K43.79,K43.80,K43.81,
K43.82,K43.83,K43.84,K43.85,K43.86,K43.87,K43.88,K43.89,K43.90,K43.91,
K43.92,K43.93,K43.94,K43.95,K43.96,K43.97,K43.98,K43.99,K43.100,
K43.101,K43.102,K43.103,
K44.1,K44.2,K44.3,K44.4,K44.5,K44.6,K44.7,K44.8,K44.9,K44.10,K44.11,
K44.12,K44.13,K44.14,K44.15,K44.16,K44.17,K44.18,K44.19,K44.20,K44.21,
K44.22,K44.23,K44.24,K44.25,K44.26,K44.27,K44.28,K44.29,K44.30,K44.31,
K44.32,K44.33,K44.34,K44.35,K44.36,K44.37,K44.38,K44.39,K44.40,K44.41,
K44.42,K44.43,K44.44,K44.45,K44.46,K44.47,K44.48,K44.49,K44.50,K44.51,
K44.52,K44.53,K44.54,K44.55,K44.56,K44.57,K44.58,K44.59,K44.60,K44.61,
K44.62,K44.63,K44.64,K44.65,K44.66,K44.67,K44.68,K44.69,K44.70,K44.71,
K44.72,K44.73,K44.74,K44.75,K44.76,K44.77,K44.78,K44.79,K44.80,K44.81,
K44.82,K44.83,K44.84,K44.85,K44.86,K44.87,K44.88,K44.89,K44.90,K44.91,
K44.92,K44.93,K44.94,K44.95,K44.96,K44.97,K44.98,K44.99,K44.100,
K44.101,K44.102,K44.103,
K45.1,K45.2,K45.3,K45.4,K45.5,K45.6,K45.7,K45.8,K45.9,K45.10,K45.11,
K45.12,K45.13,K45.14,K45.15,K45.16,K45.17,K45.18,K45.19,K45.20,K45.21,
K45.22,K45.23,K45.24,K45.25,K45.26,K45.27,K45.28,K45.29,K45.30,K45.31,
K45.32,K45.33,K45.34,K45.35,K45.36,K45.37,K45.38,K45.39,K45.40,K45.41,
K45.42,K45.43,K45.44,K45.45,K45.46,K45.47,K45.48,K45.49,K45.50,K45.51,
K45.52,K45.53,K45.54,K45.55,K45.56,K45.57,K45.58,K45.59,K45.60,K45.61,
K45.62,K45.63,K45.64,K45.65,K45.66,K45.67,K45.68,K45.69,K45.70,K45.71,
K45.72,K45.73,K45.74,K45.75,K45.76,K45.77,K45.78,K45.79,K45.80,K45.81,
K45.82,K45.83,K45.84,K45.85,K45.86,K45.87,K45.88,K45.89,K45.90,K45.91,
K45.92,K45.93,K45.94,K45.95,K45.96,K45.97,K45.98,K45.99,K45.100,
K45.101,K45.102,K45.103,
K46.1,K46.2,K46.3,K46.4,K46.5,K46.6,K46.7,K46.8,K46.9,K46.10,K46.11,
K46.12,K46.13,K46.14,K46.15,K46.16,K46.17,K46.18,K46.19,K46.20,K46.21,
K46.22,K46.23,K46.24,K46.25,K46.26,K46.27,K46.28,K46.29,K46.30,K46.31,
K46.32,K46.33,K46.34,K46.35,K46.36,K46.37,K46.38,K46.39,K46.40,K46.41,
K46.42,K46.43,K46.44,K46.45,K46.46,K46.47,K46.48,K46.49,K46.50,K46.51,
K46.52,K46.53,K46.54,K46.55,K46.56,K46.57,K46.58,K46.59,K46.60,K46.61,
K46.62,K46.63,K46.64,K46.65,K46.66,K46.67,K46.68,K46.69,K46.70,K46.71,
K46.72,K46.73,K46.74,K46.75,K46.76,K46.77,K46.78,K46.79,K46.80,K46.81,
K46.82,K46.83,K46.84,K46.85,K46.86,K46.87,K46.88,K46.89,K46.90,K46.91,
K46.92,K46.93,K46.94,K46.95,K46.96,K46.97,K46.98,K46.99,K46.100,
K46.101,K46.102,K46.103,
K47.1,K47.2,K47.3,K47.4,K47.5,K47.6,K47.7,K47.8,K47.9,K47.10,K47.11,
K47.12,K47.13,K47.14,K47.15,K47.16,K47.17,K47.18,K47.19,K47.20,K47.21,
K47.22,K47.23,K47.24,K47.25,K47.26,K47.27,K47.28,K47.29,K47.30,K47.31,
K47.32,K47.33,K47.34,K47.35,K47.36,K47.37,K47.38,K47.39,K47.40,K47.41,
K47.42,K47.43,K47.44,K47.45,K47.46,K47.47,K47.48,K47.49,K47.50,K47.51,
K47.52,K47.53,K47.54,K47.55,K47.56,K47.57,K47.58,K47.59,K47.60,K47.61,
K47.62,K47.63,K47.64,K47.65,K47.66,K47.67,K47.68,K47.69,K47.70,K47.71,
K47.72,K47.73,K47.74,K47.75,K47.76,K47.77,K47.78,K47.79,K47.80,K47.81,
K47.82,K47.83,K47.84,K47.85,K47.86,K47.87,K47.88,K47.89,K47.90,K47.91,
K47.92,K47.93,K47.94,K47.95,K47.96,K47.97,K47.98,K47.99,K47.100,
K47.101,K47.102,K47.103,
K48.1,K48.2,K48.3,K48.4,K48.5,K48.6,K48.7,K48.8,K48.9,K48.10,K48.11,
K48.12,K48.13,K48.14,K48.15,K48.16,K48.17,K48.18,K48.19,K48.20,K48.21,
K48.22,K48.23,K48.24,K48.25,K48.26,K48.27,K48.28,K48.29,K48.30,K48.31,
K48.32,K48.33,K48.34,K48.35,K48.36,K48.37,K48.38,K48.39,K48.40,K48.41,
K48.42,K48.43,K48.44,K48.45,K48.46,K48.47,K48.48,K48.49,K48.50,K48.51,
K48.52,K48.53,K48.54,K48.55,K48.56,K48.57,K48.58,K48.59,K48.60,K48.61,
K48.62,K48.63,K48.64,K48.65,K48.66,K48.67,K48.68,K48.69,K48.70,K48.71,
K48.72,K48.73,K48.74,K48.75,K48.76,K48.77,K48.78,K48.79,K48.80,K48.81,
K48.82,K48.83,K48.84,K48.85,K48.86,K48.87,K48.88,K48.89,K48.90,K48.91,
K48.92,K48.93,K48.94,K48.95,K48.96,K48.97,K48.98,K48.99,K48.100,
K48.101,K48.102,K48.103,
K49.1,K49.2,K49.3,K49.4,K49.5,K49.6,K49.7,K49.8,K49.9,K49.10,K49.11,
K49.12,K49.13,K49.14,K49.15,K49.16,K49.17,K49.18,K49.19,K49.20,K49.21,
K49.22,K49.23,K49.24,K49.25,K49.26,K49.27,K49.28,K49.29,K49.30,K49.31,
K49.32,K49.33,K49.34,K49.35,K49.36,K49.37,K49.38,K49.39,K49.40,K49.41,
K49.42,K49.43,K49.44,K49.45,K49.46,K49.47,K49.48,K49.49,K49.50,K49.51,
K49.52,K49.53,K49.54,K49.55,K49.56,K49.57,K49.58,K49.59,K49.60,K49.61,
K49.62,K49.63,K49.64,K49.65,K49.66,K49.67,K49.68,K49.69,K49.70,K49.71,
K49.72,K49.73,K49.74,K49.75,K49.76,K49.77,K49.78,K49.79,K49.80,K49.81,
K49.82,K49.83,K49.84,K49.85,K49.86,K49.87,K49.88,K49.89,K49.90,K49.91,
K49.92,K49.93,K49.94,K49.95,K49.96,K49.97,K49.98,K49.99,K49.100,
K49.101,K49.102,K49.103,
K50.1,K50.2,K50.3,K50.4,K50.5,K50.6,K50.7,K50.8,K50.9,K50.10,K50.11,
K50.12,K50.13,K50.14,K50.15,K50.16,K50.17,K50.18,K50.19,K50.20,K50.21,
K50.22,K50.23,K50.24,K50.25,K50.26,K50.27,K50.28,K50.29,K50.30,K50.31,
K50.32,K50.33,K50.34,K50.35,K50.36,K50.37,K50.38,K50.39,K50.40,K50.41,
K50.42,K50.43,K50.44,K50.45,K50.46,K50.47,K50.48,K50.49,K50.50,K50.51,
K50.52,K50.53,K50.54,K50.55,K50.56,K50.57,K50.58,K50.59,K50.60,K50.61,
K50.62,K50.63,K50.64,K50.65,K50.66,K50.67,K50.68,K50.69,K50.70,K50.71,
K50.72,K50.73,K50.74,K50.75,K50.76,K50.77,K50.78,K50.79,K50.80,K50.81,
K50.82,K50.83,K50.84,K50.85,K50.86,K50.87,K50.88,K50.89,K50.90,K50.91,
K50.92,K50.93,K50.94,K50.95,K50.96,K50.97,K50.98,K50.99,K50.100,
K50.101,K50.102,K50.103,
K51.1,K51.2,K51.3,K51.4,K51.5,K51.6,K51.7,K51.8,K51.9,K51.10,K51.11,
K51.12,K51.13,K51.14,K51.15,K51.16,K51.17,K51.18,K51.19,K51.20,K51.21,
K51.22,K51.23,K51.24,K51.25,K51.26,K51.27,K51.28,K51.29,K51.30,K51.31,
K51.32,K51.33,K51.34,K51.35,K51.36,K51.37,K51.38,K51.39,K51.40,K51.41,
K51.42,K51.43,K51.44,K51.45,K51.46,K51.47,K51.48,K51.49,K51.50,K51.51,
K51.52,K51.53,K51.54,K51.55,K51.56,K51.57,K51.58,K51.59,K51.60,K51.61,
K51.62,K51.63,K51.64,K51.65,K51.66,K51.67,K51.68,K51.69,K51.70,K51.71,
K51.72,K51.73,K51.74,K51.75,K51.76,K51.77,K51.78,K51.79,K51.80,K51.81,
K51.82,K51.83,K51.84,K51.85,K51.86,K51.87,K51.88,K51.89,K51.90,K51.91,
K51.92,K51.93,K51.94,K51.95,K51.96,K51.97,K51.98,K51.99,K51.100,
K51.101,K51.102,K51.103,
K52.1,K52.2,K52.3,K52.4,K52.5,K52.6,K52.7,K52.8,K52.9,K52.10,K52.11,
K52.12,K52.13,K52.14,K52.15,K52.16,K52.17,K52.18,K52.19,K52.20,K52.21,
K52.22,K52.23,K52.24,K52.25,K52.26,K52.27,K52.28,K52.29,K52.30,K52.31,
K52.32,K52.33,K52.34,K52.35,K52.36,K52.37,K52.38,K52.39,K52.40,K52.41,
K52.42,K52.43,K52.44,K52.45,K52.46,K52.47,K52.48,K52.49,K52.50,K52.51,
K52.52,K52.53,K52.54,K52.55,K52.56,K52.57,K52.58,K52.59,K52.60,K52.61,
K52.62,K52.63,K52.64,K52.65,K52.66,K52.67,K52.68,K52.69,K52.70,K52.71,
K52.72,K52.73,K52.74,K52.75,K52.76,K52.77,K52.78,K52.79,K52.80,K52.81,
K52.82,K52.83,K52.84,K52.85,K52.86,K52.87,K52.88,K52.89,K52.90,K52.91,
K52.92,K52.93,K52.94,K52.95,K52.96,K52.97,K52.98,K52.99,K52.100,
K52.101,K52.102,K52.103,
K53.1,K53.2,K53.3,K53.4,K53.5,K53.6,K53.7,K53.8,K53.9,K53.10,K53.11,
K53.12,K53.13,K53.14,K53.15,K53.16,K53.17,K53.18,K53.19,K53.20,K53.21,
K53.22,K53.23,K53.24,K53.25,K53.26,K53.27,K53.28,K53.29,K53.30,K53.31,
K53.32,K53.33,K53.34,K53.35,K53.36,K53.37,K53.38,K53.39,K53.40,K53.41,
K53.42,K53.43,K53.44,K53.45,K53.46,K53.47,K53.48,K53.49,K53.50,K53.51,
K53.52,K53.53,K53.54,K53.55,K53.56,K53.57,K53.58,K53.59,K53.60,K53.61,
K53.62,K53.63,K53.64,K53.65,K53.66,K53.67,K53.68,K53.69,K53.70,K53.71,
K53.72,K53.73,K53.74,K53.75,K53.76,K53.77,K53.78,K53.79,K53.80,K53.81,
K53.82,K53.83,K53.84,K53.85,K53.86,K53.87,K53.88,K53.89,K53.90,K53.91,
K53.92,K53.93,K53.94,K53.95,K53.96,K53.97,K53.98,K53.99,K53.100,
K53.101,K53.102,K53.103,
K54.1,K54.2,K54.3,K54.4,K54.5,K54.6,K54.7,K54.8,K54.9,K54.10,K54.11,
K54.12,K54.13,K54.14,K54.15,K54.16,K54.17,K54.18,K54.19,K54.20,K54.21,
K54.22,K54.23,K54.24,K54.25,K54.26,K54.27,K54.28,K54.29,K54.30,K54.31,
K54.32,K54.33,K54.34,K54.35,K54.36,K54.37,K54.38,K54.39,K54.40,K54.41,
K54.42,K54.43,K54.44,K54.45,K54.46,K54.47,K54.48,K54.49,K54.50,K54.51,
K54.52,K54.53,K54.54,K54.55,K54.56,K54.57,K54.58,K54.59,K54.60,K54.61,
K54.62,K54.63,K54.64,K54.65,K54.66,K54.67,K54.68,K54.69,K54.70,K54.71,
K54.72,K54.73,K54.74,K54.75,K54.76,K54.77,K54.78,K54.79,K54.80,K54.81,
K54.82,K54.83,K54.84,K54.85,K54.86,K54.87,K54.88,K54.89,K54.90,K54.91,
K54.92,K54.93,K54.94,K54.95,K54.96,K54.97,K54.98,K54.99,K54.100,
K54.101,K54.102,K54.103,
K55.1,K55.2,K55.3,K55.4,K55.5,K55.6,K55.7,K55.8,K55.9,K55.10,K55.11,
K55.12,K55.13,K55.14,K55.15,K55.16,K55.17,K55.18,K55.19,K55.20,K55.21,
K55.22,K55.23,K55.24,K55.25,K55.26,K55.27,K55.28,K55.29,K55.30,K55.31,
K55.32,K55.33,K55.34,K55.35,K55.36,K55.37,K55.38,K55.39,K55.40,K55.41,
K55.42,K55.43,K55.44,K55.45,K55.46,K55.47,K55.48,K55.49,K55.50,K55.51,
K55.52,K55.53,K55.54,K55.55,K55.56,K55.57,K55.58,K55.59,K55.60,K55.61,
K55.62,K55.63,K55.64,K55.65,K55.66,K55.67,K55.68,K55.69,K55.70,K55.71,
K55.72,K55.73,K55.74,K55.75,K55.76,K55.77,K55.78,K55.79,K55.80,K55.81,
K55.82,K55.83,K55.84,K55.85,K55.86,K55.87,K55.88,K55.89,K55.90,K55.91,
K55.92,K55.93,K55.94,K55.95,K55.96,K55.97,K55.98,K55.99,K55.100,
K55.101,K55.102,K55.103,
K56.1,K56.2,K56.3,K56.4,K56.5,K56.6,K56.7,K56.8,K56.9,K56.10,K56.11,
K56.12,K56.13,K56.14,K56.15,K56.16,K56.17,K56.18,K56.19,K56.20,K56.21,
K56.22,K56.23,K56.24,K56.25,K56.26,K56.27,K56.28,K56.29,K56.30,K56.31,
K56.32,K56.33,K56.34,K56.35,K56.36,K56.37,K56.38,K56.39,K56.40,K56.41,
K56.42,K56.43,K56.44,K56.45,K56.46,K56.47,K56.48,K56.49,K56.50,K56.51,
K56.52,K56.53,K56.54,K56.55,K56.56,K56.57,K56.58,K56.59,K56.60,K56.61,
K56.62,K56.63,K56.64,K56.65,K56.66,K56.67,K56.68,K56.69,K56.70,K56.71,
K56.72,K56.73,K56.74,K56.75,K56.76,K56.77,K56.78,K56.79,K56.80,K56.81,
K56.82,K56.83,K56.84,K56.85,K56.86,K56.87,K56.88,K56.89,K56.90,K56.91,
K56.92,K56.93,K56.94,K56.95,K56.96,K56.97,K56.98,K56.99,K56.100,
K56.101,K56.102,K56.103,
K57.1,K57.2,K57.3,K57.4,K57.5,K57.6,K57.7,K57.8,K57.9,K57.10,K57.11,
K57.12,K57.13,K57.14,K57.15,K57.16,K57.17,K57.18,K57.19,K57.20,K57.21,
K57.22,K57.23,K57.24,K57.25,K57.26,K57.27,K57.28,K57.29,K57.30,K57.31,
K57.32,K57.33,K57.34,K57.35,K57.36,K57.37,K57.38,K57.39,K57.40,K57.41,
K57.42,K57.43,K57.44,K57.45,K57.46,K57.47,K57.48,K57.49,K57.50,K57.51,
K57.52,K57.53,K57.54,K57.55,K57.56,K57.57,K57.58,K57.59,K57.60,K57.61,
K57.62,K57.63,K57.64,K57.65,K57.66,K57.67,K57.68,K57.69,K57.70,K57.71,
K57.72,K57.73,K57.74,K57.75,K57.76,K57.77,K57.78,K57.79,K57.80,K57.81,
K57.82,K57.83,K57.84,K57.85,K57.86,K57.87,K57.88,K57.89,K57.90,K57.91,
K57.92,K57.93,K57.94,K57.95,K57.96,K57.97,K57.98,K57.99,K57.100,
K57.101,K57.102,K57.103,
K58.1,K58.2,K58.3,K58.4,K58.5,K58.6,K58.7,K58.8,K58.9,K58.10,K58.11,
K58.12,K58.13,K58.14,K58.15,K58.16,K58.17,K58.18,K58.19,K58.20,K58.21,
K58.22,K58.23,K58.24,K58.25,K58.26,K58.27,K58.28,K58.29,K58.30,K58.31,
K58.32,K58.33,K58.34,K58.35,K58.36,K58.37,K58.38,K58.39,K58.40,K58.41,
K58.42,K58.43,K58.44,K58.45,K58.46,K58.47,K58.48,K58.49,K58.50,K58.51,
K58.52,K58.53,K58.54,K58.55,K58.56,K58.57,K58.58,K58.59,K58.60,K58.61,
K58.62,K58.63,K58.64,K58.65,K58.66,K58.67,K58.68,K58.69,K58.70,K58.71,
K58.72,K58.73,K58.74,K58.75,K58.76,K58.77,K58.78,K58.79,K58.80,K58.81,
K58.82,K58.83,K58.84,K58.85,K58.86,K58.87,K58.88,K58.89,K58.90,K58.91,
K58.92,K58.93,K58.94,K58.95,K58.96,K58.97,K58.98,K58.99,K58.100,
K58.101,K58.102,K58.103,
K59.1,K59.2,K59.3,K59.4,K59.5,K59.6,K59.7,K59.8,K59.9,K59.10,K59.11,
K59.12,K59.13,K59.14,K59.15,K59.16,K59.17,K59.18,K59.19,K59.20,K59.21,
K59.22,K59.23,K59.24,K59.25,K59.26,K59.27,K59.28,K59.29,K59.30,K59.31,
K59.32,K59.33,K59.34,K59.35,K59.36,K59.37,K59.38,K59.39,K59.40,K59.41,
K59.42,K59.43,K59.44,K59.45,K59.46,K59.47,K59.48,K59.49,K59.50,K59.51,
K59.52,K59.53,K59.54,K59.55,K59.56,K59.57,K59.58,K59.59,K59.60,K59.61,
K59.62,K59.63,K59.64,K59.65,K59.66,K59.67,K59.68,K59.69,K59.70,K59.71,
K59.72,K59.73,K59.74,K59.75,K59.76,K59.77,K59.78,K59.79,K59.80,K59.81,
K59.82,K59.83,K59.84,K59.85,K59.86,K59.87,K59.88,K59.89,K59.90,K59.91,
K59.92,K59.93,K59.94,K59.95,K59.96,K59.97,K59.98,K59.99,K59.100,
K59.101,K59.102,K59.103,
K60.1,K60.2,K60.3,K60.4,K60.5,K60.6,K60.7,K60.8,K60.9,K60.10,K60.11,
K60.12,K60.13,K60.14,K60.15,K60.16,K60.17,K60.18,K60.19,K60.20,K60.21,
K60.22,K60.23,K60.24,K60.25,K60.26,K60.27,K60.28,K60.29,K60.30,K60.31,
K60.32,K60.33,K60.34,K60.35,K60.36,K60.37,K60.38,K60.39,K60.40,K60.41,
K60.42,K60.43,K60.44,K60.45,K60.46,K60.47,K60.48,K60.49,K60.50,K60.51,
K60.52,K60.53,K60.54,K60.55,K60.56,K60.57,K60.58,K60.59,K60.60,K60.61,
K60.62,K60.63,K60.64,K60.65,K60.66,K60.67,K60.68,K60.69,K60.70,K60.71,
K60.72,K60.73,K60.74,K60.75,K60.76,K60.77,K60.78,K60.79,K60.80,K60.81,
K60.82,K60.83,K60.84,K60.85,K60.86,K60.87,K60.88,K60.89,K60.90,K60.91,
K60.92,K60.93,K60.94,K60.95,K60.96,K60.97,K60.98,K60.99,K60.100,
K60.101,K60.102,K60.103,
K61.1,K61.2,K61.3,K61.4,K61.5,K61.6,K61.7,K61.8,K61.9,K61.10,K61.11,
K61.12,K61.13,K61.14,K61.15,K61.16,K61.17,K61.18,K61.19,K61.20,K61.21,
K61.22,K61.23,K61.24,K61.25,K61.26,K61.27,K61.28,K61.29,K61.30,K61.31,
K61.32,K61.33,K61.34,K61.35,K61.36,K61.37,K61.38,K61.39,K61.40,K61.41,
K61.42,K61.43,K61.44,K61.45,K61.46,K61.47,K61.48,K61.49,K61.50,K61.51,
K61.52,K61.53,K61.54,K61.55,K61.56,K61.57,K61.58,K61.59,K61.60,K61.61,
K61.62,K61.63,K61.64,K61.65,K61.66,K61.67,K61.68,K61.69,K61.70,K61.71,
K61.72,K61.73,K61.74,K61.75,K61.76,K61.77,K61.78,K61.79,K61.80,K61.81,
K61.82,K61.83,K61.84,K61.85,K61.86,K61.87,K61.88,K61.89,K61.90,K61.91,
K61.92,K61.93,K61.94,K61.95,K61.96,K61.97,K61.98,K61.99,K61.100,
K61.101,K61.102,K61.103,
K62.1,K62.2,K62.3,K62.4,K62.5,K62.6,K62.7,K62.8,K62.9,K62.10,K62.11,
K62.12,K62.13,K62.14,K62.15,K62.16,K62.17,K62.18,K62.19,K62.20,K62.21,
K62.22,K62.23,K62.24,K62.25,K62.26,K62.27,K62.28,K62.29,K62.30,K62.31,
K62.32,K62.33,K62.34,K62.35,K62.36,K62.37,K62.38,K62.39,K62.40,K62.41,
K62.42,K62.43,K62.44,K62.45,K62.46,K62.47,K62.48,K62.49,K62.50,K62.51,
K62.52,K62.53,K62.54,K62.55,K62.56,K62.57,K62.58,K62.59,K62.60,K62.61,
K62.62,K62.63,K62.64,K62.65,K62.66,K62.67,K62.68,K62.69,K62.70,K62.71,
K62.72,K62.73,K62.74,K62.75,K62.76,K62.77,K62.78,K62.79,K62.80,K62.81,
K62.82,K62.83,K62.84,K62.85,K62.86,K62.87,K62.88,K62.89,K62.90,K62.91,
K62.92,K62.93,K62.94,K62.95,K62.96,K62.97,K62.98,K62.99,K62.100,
K62.101,K62.102,K62.103,
K63.1,K63.2,K63.3,K63.4,K63.5,K63.6,K63.7,K63.8,K63.9,K63.10,K63.11,
K63.12,K63.13,K63.14,K63.15,K63.16,K63.17,K63.18,K63.19,K63.20,K63.21,
K63.22,K63.23,K63.24,K63.25,K63.26,K63.27,K63.28,K63.29,K63.30,K63.31,
K63.32,K63.33,K63.34,K63.35,K63.36,K63.37,K63.38,K63.39,K63.40,K63.41,
K63.42,K63.43,K63.44,K63.45,K63.46,K63.47,K63.48,K63.49,K63.50,K63.51,
K63.52,K63.53,K63.54,K63.55,K63.56,K63.57,K63.58,K63.59,K63.60,K63.61,
K63.62,K63.63,K63.64,K63.65,K63.66,K63.67,K63.68,K63.69,K63.70,K63.71,
K63.72,K63.73,K63.74,K63.75,K63.76,K63.77,K63.78,K63.79,K63.80,K63.81,
K63.82,K63.83,K63.84,K63.85,K63.86,K63.87,K63.88,K63.89,K63.90,K63.91,
K63.92,K63.93,K63.94,K63.95,K63.96,K63.97,K63.98,K63.99,K63.100,
K63.101,K63.102,K63.103,
K64.1,K64.2,K64.3,K64.4,K64.5,K64.6,K64.7,K64.8,K64.9,K64.10,K64.11,
K64.12,K64.13,K64.14,K64.15,K64.16,K64.17,K64.18,K64.19,K64.20,K64.21,
K64.22,K64.23,K64.24,K64.25,K64.26,K64.27,K64.28,K64.29,K64.30,K64.31,
K64.32,K64.33,K64.34,K64.35,K64.36,K64.37,K64.38,K64.39,K64.40,K64.41,
K64.42,K64.43,K64.44,K64.45,K64.46,K64.47,K64.48,K64.49,K64.50,K64.51,
K64.52,K64.53,K64.54,K64.55,K64.56,K64.57,K64.58,K64.59,K64.60,K64.61,
K64.62,K64.63,K64.64,K64.65,K64.66,K64.67,K64.68,K64.69,K64.70,K64.71,
K64.72,K64.73,K64.74,K64.75,K64.76,K64.77,K64.78,K64.79,K64.80,K64.81,
K64.82,K64.83,K64.84,K64.85,K64.86,K64.87,K64.88,K64.89,K64.90,K64.91,
K64.92,K64.93,K64.94,K64.95,K64.96,K64.97,K64.98,K64.99,K64.100,
K64.101,K64.102,K64.103,
K65.1,K65.2,K65.3,K65.4,K65.5,K65.6,K65.7,K65.8,K65.9,K65.10,K65.11,
K65.12,K65.13,K65.14,K65.15,K65.16,K65.17,K65.18,K65.19,K65.20,K65.21,
K65.22,K65.23,K65.24,K65.25,K65.26,K65.27,K65.28,K65.29,K65.30,K65.31,
K65.32,K65.33,K65.34,K65.35,K65.36,K65.37,K65.38,K65.39,K65.40,K65.41,
K65.42,K65.43,K65.44,K65.45,K65.46,K65.47,K65.48,K65.49,K65.50,K65.51,
K65.52,K65.53,K65.54,K65.55,K65.56,K65.57,K65.58,K65.59,K65.60,K65.61,
K65.62,K65.63,K65.64,K65.65,K65.66,K65.67,K65.68,K65.69,K65.70,K65.71,
K65.72,K65.73,K65.74,K65.75,K65.76,K65.77,K65.78,K65.79,K65.80,K65.81,
K65.82,K65.83,K65.84,K65.85,K65.86,K65.87,K65.88,K65.89,K65.90,K65.91,
K65.92,K65.93,K65.94,K65.95,K65.96,K65.97,K65.98,K65.99,K65.100,
K65.101,K65.102,K65.103,
K66.1,K66.2,K66.3,K66.4,K66.5,K66.6,K66.7,K66.8,K66.9,K66.10,K66.11,
K66.12,K66.13,K66.14,K66.15,K66.16,K66.17,K66.18,K66.19,K66.20,K66.21,
K66.22,K66.23,K66.24,K66.25,K66.26,K66.27,K66.28,K66.29,K66.30,K66.31,
K66.32,K66.33,K66.34,K66.35,K66.36,K66.37,K66.38,K66.39,K66.40,K66.41,
K66.42,K66.43,K66.44,K66.45,K66.46,K66.47,K66.48,K66.49,K66.50,K66.51,
K66.52,K66.53,K66.54,K66.55,K66.56,K66.57,K66.58,K66.59,K66.60,K66.61,
K66.62,K66.63,K66.64,K66.65,K66.66,K66.67,K66.68,K66.69,K66.70,K66.71,
K66.72,K66.73,K66.74,K66.75,K66.76,K66.77,K66.78,K66.79,K66.80,K66.81,
K66.82,K66.83,K66.84,K66.85,K66.86,K66.87,K66.88,K66.89,K66.90,K66.91,
K66.92,K66.93,K66.94,K66.95,K66.96,K66.97,K66.98,K66.99,K66.100,
K66.101,K66.102,K66.103,
K67.1,K67.2,K67.3,K67.4,K67.5,K67.6,K67.7,K67.8,K67.9,K67.10,K67.11,
K67.12,K67.13,K67.14,K67.15,K67.16,K67.17,K67.18,K67.19,K67.20,K67.21,
K67.22,K67.23,K67.24,K67.25,K67.26,K67.27,K67.28,K67.29,K67.30,K67.31,
K67.32,K67.33,K67.34,K67.35,K67.36,K67.37,K67.38,K67.39,K67.40,K67.41,
K67.42,K67.43,K67.44,K67.45,K67.46,K67.47,K67.48,K67.49,K67.50,K67.51,
K67.52,K67.53,K67.54,K67.55,K67.56,K67.57,K67.58,K67.59,K67.60,K67.61,
K67.62,K67.63,K67.64,K67.65,K67.66,K67.67,K67.68,K67.69,K67.70,K67.71,
K67.72,K67.73,K67.74,K67.75,K67.76,K67.77,K67.78,K67.79,K67.80,K67.81,
K67.82,K67.83,K67.84,K67.85,K67.86,K67.87,K67.88,K67.89,K67.90,K67.91,
K67.92,K67.93,K67.94,K67.95,K67.96,K67.97,K67.98,K67.99,K67.100,
K67.101,K67.102,K67.103,
K68.1,K68.2,K68.3,K68.4,K68.5,K68.6,K68.7,K68.8,K68.9,K68.10,K68.11,
K68.12,K68.13,K68.14,K68.15,K68.16,K68.17,K68.18,K68.19,K68.20,K68.21,
K68.22,K68.23,K68.24,K68.25,K68.26,K68.27,K68.28,K68.29,K68.30,K68.31,
K68.32,K68.33,K68.34,K68.35,K68.36,K68.37,K68.38,K68.39,K68.40,K68.41,
K68.42,K68.43,K68.44,K68.45,K68.46,K68.47,K68.48,K68.49,K68.50,K68.51,
K68.52,K68.53,K68.54,K68.55,K68.56,K68.57,K68.58,K68.59,K68.60,K68.61,
K68.62,K68.63,K68.64,K68.65,K68.66,K68.67,K68.68,K68.69,K68.70,K68.71,
K68.72,K68.73,K68.74,K68.75,K68.76,K68.77,K68.78,K68.79,K68.80,K68.81,
K68.82,K68.83,K68.84,K68.85,K68.86,K68.87,K68.88,K68.89,K68.90,K68.91,
K68.92,K68.93,K68.94,K68.95,K68.96,K68.97,K68.98,K68.99,K68.100,
K68.101,K68.102,K68.103,
K69.1,K69.2,K69.3,K69.4,K69.5,K69.6,K69.7,K69.8,K69.9,K69.10,K69.11,
K69.12,K69.13,K69.14,K69.15,K69.16,K69.17,K69.18,K69.19,K69.20,K69.21,
K69.22,K69.23,K69.24,K69.25,K69.26,K69.27,K69.28,K69.29,K69.30,K69.31,
K69.32,K69.33,K69.34,K69.35,K69.36,K69.37,K69.38,K69.39,K69.40,K69.41,
K69.42,K69.43,K69.44,K69.45,K69.46,K69.47,K69.48,K69.49,K69.50,K69.51,
K69.52,K69.53,K69.54,K69.55,K69.56,K69.57,K69.58,K69.59,K69.60,K69.61,
K69.62,K69.63,K69.64,K69.65,K69.66,K69.67,K69.68,K69.69,K69.70,K69.71,
K69.72,K69.73,K69.74,K69.75,K69.76,K69.77,K69.78,K69.79,K69.80,K69.81,
K69.82,K69.83,K69.84,K69.85,K69.86,K69.87,K69.88,K69.89,K69.90,K69.91,
K69.92,K69.93,K69.94,K69.95,K69.96,K69.97,K69.98,K69.99,K69.100,
K69.101,K69.102,K69.103,
K70.1,K70.2,K70.3,K70.4,K70.5,K70.6,K70.7,K70.8,K70.9,K70.10,K70.11,
K70.12,K70.13,K70.14,K70.15,K70.16,K70.17,K70.18,K70.19,K70.20,K70.21,
K70.22,K70.23,K70.24,K70.25,K70.26,K70.27,K70.28,K70.29,K70.30,K70.31,
K70.32,K70.33,K70.34,K70.35,K70.36,K70.37,K70.38,K70.39,K70.40,K70.41,
K70.42,K70.43,K70.44,K70.45,K70.46,K70.47,K70.48,K70.49,K70.50,K70.51,
K70.52,K70.53,K70.54,K70.55,K70.56,K70.57,K70.58,K70.59,K70.60,K70.61,
K70.62,K70.63,K70.64,K70.65,K70.66,K70.67,K70.68,K70.69,K70.70,K70.71,
K70.72,K70.73,K70.74,K70.75,K70.76,K70.77,K70.78,K70.79,K70.80,K70.81,
K70.82,K70.83,K70.84,K70.85,K70.86,K70.87,K70.88,K70.89,K70.90,K70.91,
K70.92,K70.93,K70.94,K70.95,K70.96,K70.97,K70.98,K70.99,K70.100,
K70.101,K70.102,K70.103,
K71.1,K71.2,K71.3,K71.4,K71.5,K71.6,K71.7,K71.8,K71.9,K71.10,K71.11,
K71.12,K71.13,K71.14,K71.15,K71.16,K71.17,K71.18,K71.19,K71.20,K71.21,
K71.22,K71.23,K71.24,K71.25,K71.26,K71.27,K71.28,K71.29,K71.30,K71.31,
K71.32,K71.33,K71.34,K71.35,K71.36,K71.37,K71.38,K71.39,K71.40,K71.41,
K71.42,K71.43,K71.44,K71.45,K71.46,K71.47,K71.48,K71.49,K71.50,K71.51,
K71.52,K71.53,K71.54,K71.55,K71.56,K71.57,K71.58,K71.59,K71.60,K71.61,
K71.62,K71.63,K71.64,K71.65,K71.66,K71.67,K71.68,K71.69,K71.70,K71.71,
K71.72,K71.73,K71.74,K71.75,K71.76,K71.77,K71.78,K71.79,K71.80,K71.81,
K71.82,K71.83,K71.84,K71.85,K71.86,K71.87,K71.88,K71.89,K71.90,K71.91,
K71.92,K71.93,K71.94,K71.95,K71.96,K71.97,K71.98,K71.99,K71.100,
K71.101,K71.102,K71.103,
K72.1,K72.2,K72.3,K72.4,K72.5,K72.6,K72.7,K72.8,K72.9,K72.10,K72.11,
K72.12,K72.13,K72.14,K72.15,K72.16,K72.17,K72.18,K72.19,K72.20,K72.21,
K72.22,K72.23,K72.24,K72.25,K72.26,K72.27,K72.28,K72.29,K72.30,K72.31,
K72.32,K72.33,K72.34,K72.35,K72.36,K72.37,K72.38,K72.39,K72.40,K72.41,
K72.42,K72.43,K72.44,K72.45,K72.46,K72.47,K72.48,K72.49,K72.50,K72.51,
K72.52,K72.53,K72.54,K72.55,K72.56,K72.57,K72.58,K72.59,K72.60,K72.61,
K72.62,K72.63,K72.64,K72.65,K72.66,K72.67,K72.68,K72.69,K72.70,K72.71,
K72.72,K72.73,K72.74,K72.75,K72.76,K72.77,K72.78,K72.79,K72.80,K72.81,
K72.82,K72.83,K72.84,K72.85,K72.86,K72.87,K72.88,K72.89,K72.90,K72.91,
K72.92,K72.93,K72.94,K72.95,K72.96,K72.97,K72.98,K72.99,K72.100,
K72.101,K72.102,K72.103,
K73.1,K73.2,K73.3,K73.4,K73.5,K73.6,K73.7,K73.8,K73.9,K73.10,K73.11,
K73.12,K73.13,K73.14,K73.15,K73.16,K73.17,K73.18,K73.19,K73.20,K73.21,
K73.22,K73.23,K73.24,K73.25,K73.26,K73.27,K73.28,K73.29,K73.30,K73.31,
K73.32,K73.33,K73.34,K73.35,K73.36,K73.37,K73.38,K73.39,K73.40,K73.41,
K73.42,K73.43,K73.44,K73.45,K73.46,K73.47,K73.48,K73.49,K73.50,K73.51,
K73.52,K73.53,K73.54,K73.55,K73.56,K73.57,K73.58,K73.59,K73.60,K73.61,
K73.62,K73.63,K73.64,K73.65,K73.66,K73.67,K73.68,K73.69,K73.70,K73.71,
K73.72,K73.73,K73.74,K73.75,K73.76,K73.77,K73.78,K73.79,K73.80,K73.81,
K73.82,K73.83,K73.84,K73.85,K73.86,K73.87,K73.88,K73.89,K73.90,K73.91,
K73.92,K73.93,K73.94,K73.95,K73.96,K73.97,K73.98,K73.99,K73.100,
K73.101,K73.102,K73.103,
K74.1,K74.2,K74.3,K74.4,K74.5,K74.6,K74.7,K74.8,K74.9,K74.10,K74.11,
K74.12,K74.13,K74.14,K74.15,K74.16,K74.17,K74.18,K74.19,K74.20,K74.21,
K74.22,K74.23,K74.24,K74.25,K74.26,K74.27,K74.28,K74.29,K74.30,K74.31,
K74.32,K74.33,K74.34,K74.35,K74.36,K74.37,K74.38,K74.39,K74.40,K74.41,
K74.42,K74.43,K74.44,K74.45,K74.46,K74.47,K74.48,K74.49,K74.50,K74.51,
K74.52,K74.53,K74.54,K74.55,K74.56,K74.57,K74.58,K74.59,K74.60,K74.61,
K74.62,K74.63,K74.64,K74.65,K74.66,K74.67,K74.68,K74.69,K74.70,K74.71,
K74.72,K74.73,K74.74,K74.75,K74.76,K74.77,K74.78,K74.79,K74.80,K74.81,
K74.82,K74.83,K74.84,K74.85,K74.86,K74.87,K74.88,K74.89,K74.90,K74.91,
K74.92,K74.93,K74.94,K74.95,K74.96,K74.97,K74.98,K74.99,K74.100,
K74.101,K74.102,K74.103,
K75.1,K75.2,K75.3,K75.4,K75.5,K75.6,K75.7,K75.8,K75.9,K75.10,K75.11,
K75.12,K75.13,K75.14,K75.15,K75.16,K75.17,K75.18,K75.19,K75.20,K75.21,
K75.22,K75.23,K75.24,K75.25,K75.26,K75.27,K75.28,K75.29,K75.30,K75.31,
K75.32,K75.33,K75.34,K75.35,K75.36,K75.37,K75.38,K75.39,K75.40,K75.41,
K75.42,K75.43,K75.44,K75.45,K75.46,K75.47,K75.48,K75.49,K75.50,K75.51,
K75.52,K75.53,K75.54,K75.55,K75.56,K75.57,K75.58,K75.59,K75.60,K75.61,
K75.62,K75.63,K75.64,K75.65,K75.66,K75.67,K75.68,K75.69,K75.70,K75.71,
K75.72,K75.73,K75.74,K75.75,K75.76,K75.77,K75.78,K75.79,K75.80,K75.81,
K75.82,K75.83,K75.84,K75.85,K75.86,K75.87,K75.88,K75.89,K75.90,K75.91,
K75.92,K75.93,K75.94,K75.95,K75.96,K75.97,K75.98,K75.99,K75.100,
K75.101,K75.102,K75.103,
K76.1,K76.2,K76.3,K76.4,K76.5,K76.6,K76.7,K76.8,K76.9,K76.10,K76.11,
K76.12,K76.13,K76.14,K76.15,K76.16,K76.17,K76.18,K76.19,K76.20,K76.21,
K76.22,K76.23,K76.24,K76.25,K76.26,K76.27,K76.28,K76.29,K76.30,K76.31,
K76.32,K76.33,K76.34,K76.35,K76.36,K76.37,K76.38,K76.39,K76.40,K76.41,
K76.42,K76.43,K76.44,K76.45,K76.46,K76.47,K76.48,K76.49,K76.50,K76.51,
K76.52,K76.53,K76.54,K76.55,K76.56,K76.57,K76.58,K76.59,K76.60,K76.61,
K76.62,K76.63,K76.64,K76.65,K76.66,K76.67,K76.68,K76.69,K76.70,K76.71,
K76.72,K76.73,K76.74,K76.75,K76.76,K76.77,K76.78,K76.79,K76.80,K76.81,
K76.82,K76.83,K76.84,K76.85,K76.86,K76.87,K76.88,K76.89,K76.90,K76.91,
K76.92,K76.93,K76.94,K76.95,K76.96,K76.97,K76.98,K76.99,K76.100,
K76.101,K76.102,K76.103,
K77.1,K77.2,K77.3,K77.4,K77.5,K77.6,K77.7,K77.8,K77.9,K77.10,K77.11,
K77.12,K77.13,K77.14,K77.15,K77.16,K77.17,K77.18,K77.19,K77.20,K77.21,
K77.22,K77.23,K77.24,K77.25,K77.26,K77.27,K77.28,K77.29,K77.30,K77.31,
K77.32,K77.33,K77.34,K77.35,K77.36,K77.37,K77.38,K77.39,K77.40,K77.41,
K77.42,K77.43,K77.44,K77.45,K77.46,K77.47,K77.48,K77.49,K77.50,K77.51,
K77.52,K77.53,K77.54,K77.55,K77.56,K77.57,K77.58,K77.59,K77.60,K77.61,
K77.62,K77.63,K77.64,K77.65,K77.66,K77.67,K77.68,K77.69,K77.70,K77.71,
K77.72,K77.73,K77.74,K77.75,K77.76,K77.77,K77.78,K77.79,K77.80,K77.81,
K77.82,K77.83,K77.84,K77.85,K77.86,K77.87,K77.88,K77.89,K77.90,K77.91,
K77.92,K77.93,K77.94,K77.95,K77.96,K77,97,K77.98,K77.99,K77.100,
K77.101,K77.102,K77.103,
K78.1,K78.2,K78.3,K78.4,K78.5,K78.6,K78.7,K78.8,K78.9,K78.10,K78.11,
K78.12,K78.13,K78.14,K78.15,K78.16,K78.17,K78.18,K78.19,K78.20,K78.21,
K78.22,K78.23,K78.24,K78.25,K78.26,K78.27,K78.28,K78.29,K78.30,K78.31,
K78.32,K78.33,K78.34,K78.35,K78.36,K78.37,K78.38,K78.39,K78.40,K78.41,
K78.42,K78.43,K78.44,K78.45,K78.46,K78.47,K78.48,K78.49,K78.50,K78.51,
K78.52,K78.53,K78.54,K78.55,K78.56,K78.57,K78.58,K78.59,K78.60,K78.61,
K78.62,K78.63,K78.64,K78.65,K78.66,K78.67,K78.68,K78.69,K78.70,K78.71,
K78.72,K78.73,K78.74,K78.75,K78.76,K78.77,K78.78,K78.79,K78.80,K78.81,
K78.82,K78.83,K78.84,K78.85,K78.86,K78.87,K78.88,K78.89,K78.90,K78.91,
K78.92,K78.93,K78.94,K78.95,K78.96,K78.97,K78.98,K78.99,K78.100,
K78.101,K78.102,K78.103,
K79.1,K79.2,K79.3,K79.4,K79.5,K79.6,K79.7,K79.8,K79.9,K79.10,K79.11,
K79.12,K79.13,K79.14,K79.15,K79.16,K79.17,K79.18,K79.19,K79.20,K79.21,
K79.22,K79.23,K79.24,K79.25,K79.26,K79.27,K79.28,K79.29,K79.30,K79.31,
K79.32,K79.33,K79.34,K79.35,K79.36,K79.37,K79.38,K79.39,K79.40,K79.41,
K79.42,K79.43,K79.44,K79.45,K79.46,K79.47,K79.48,K79.49,K79.50,K79.51,
K79.52,K79.53,K79.54,K79.55,K79.56,K79.57,K79.58,K79.59,K79.60,K79.61,
K79.62,K79.63,K79.64,K79.65,K79.66,K79.67,K79.68,K79.69,K79.70,K79.71,
K79.72,K79.73,K79.74,K79.75,K79.76,K79.77,K79.78,K79.79,K79.80,K79.81,
K79.82,K79.83,K79.84,K79.85,K79.86,K79.87,K79.88,K79.89,K79.90,K79.91,
K79.92,K79.93,K79.94,K79.95,K79.96,K79.97,K79.98,K79.99,K79.100,
K79.101,K79.102,K79.103,
K80.1,K80.2,K80.3,K80.4,K80.5,K80.6,K80.7,K80.8,K80.9,K80.10,K80.11,
K80.12,K80.13,K80.14,K80.15,K80.16,K80.17,K80.18,K80.19,K80.20,K80.21,
K80.22,K80.23,K80.24,K80.25,K80.26,K80.27,K80.28,K80.29,K80.30,K80.31,
K80.32,K80.33,K80.34,K80.35,K80.36,K80.37,K80.38,K80.39,K80.40,K80.41,
K80.42,K80.43,K80.44,K80.45,K80.46,K80.47,K80.48,K80.49,K80.50,K80.51,
K80.52,K80.53,K80.54,K80.55,K80.56,K80.57,K80.58,K80.59,K80.60,K80.61,
K80.62,K80.63,K80.64,K80.65,K80.66,K80.67,K80.68,K80.69,K80.70,K80.71,
K80.72,K80.73,K80.74,K80.75,K80.76,K80.77,K80.78,K80.79,K80.80,K80.81,
K80.82,K80.83,K80.84,K80.85,K80.86,K80.87,K80.88,K80.89,K80.90,K80.91,
K80.92,K80.93,K80.94,K80.95,K80.96,K80.97,K80.98,K80.99,K80.100,
K80.101,K80.102,K80.103,
K81.1,K81.2,K81.3,K81.4,K81.5,K81.6,K81.7,K81.8,K81.9,K81.10,K81.11,
K81.12,K81.13,K81.14,K81.15,K81.16,K81.17,K81.18,K81.19,K81.20,K81.21,
K81.22,K81.23,K81.24,K81.25,K81.26,K81.27,K81.28,K81.29,K81.30,K81.31,
K81.32,K81.33,K81.34,K81.35,K81.36,K81.37,K81.38,K81.39,K81.40,K81.41,
K81.42,K81.43,K81.44,K81.45,K81.46,K81.47,K81.48,K81.49,K81.50,K81.51,
K81.52,K81.53,K81.54,K81.55,K81.56,K81.57,K81.58,K81.59,K81.60,K81.61,
K81.62,K81.63,K81.64,K81.65,K81.66,K81.67,K81.68,K81.69,K81.70,K81.71,
K81.72,K81.73,K81.74,K81.75,K81.76,K81.77,K81.78,K81.79,K81.80,K81.81,
K81.82,K81.83,K81.84,K81.85,K81.86,K81.87,K81.88,K81.89,K81.90,K81.91,
K81.92,K81.93,K81.94,K81.95,K81.96,K81.97,K81.98,K81.99,K81.100,
K81.101,K81.102,K81.103,
K82.1,K82.2,K82.3,K82.4,K82.5,K82.6,K82.7,K82.8,K82.9,K82.10,K82.11,
K82.12,K82.13,K82.14,K82.15,K82.16,K82.17,K82.18,K82.19,K82.20,K82.21,
K82.22,K82.23,K82.24,K82.25,K82.26,K82.27,K82.28,K82.29,K82.30,K82.31,
K82.32,K82.33,K82.34,K82.35,K82.36,K82.37,K82.38,K82.39,K82.40,K82.41,
K82.42,K82.43,K82.44,K82.45,K82.46,K82.47,K82.48,K82.49,K82.50,K82.51,
K82.52,K82.53,K82.54,K82.55,K82.56,K82.57,K82.58,K82.59,K82.60,K82.61,
K82.62,K82.63,K82.64,K82.65,K82.66,K82.67,K82.68,K82.69,K82.70,K82.71,
K82.72,K82.73,K82.74,K82.75,K82.76,K82.77,K82.78,K82.79,K82.80,K82.81,
K82.82,K82.83,K82.84,K82.85,K82.86,K82.87,K82.88,K82.89,K82.90,K82.91,
K82.92,K82.93,K82.94,K82.95,K82.96,K82.97,K82.98,K82.99,K82.100,
K82.101,K82.102,K82.103,
K83.1,K83.2,K83.3,K83.4,K83.5,K83.6,K83.7,K83.8,K83.9,K83.10,K83.11,
K83.12,K83.13,K83.14,K83.15,K83.16,K83.17,K83.18,K83.19,K83.20,K83.21,
K83.22,K83.23,K83.24,K83.25,K83.26,K83.27,K83.28,K83.29,K83.30,K83.31,
K83.32,K83.33,K83.34,K83.35,K83.36,K83.37,K83.38,K83.39,K83.40,K83.41,
K83.42,K83.43,K83.44,K83.45,K83.46,K83.47,K83.48,K83.49,K83.50,K83.51,
K83.52,K83.53,K83.54,K83.55,K83.56,K83.57,K83.58,K83.59,K83.60,K83.61,
K83.62,K83.63,K83.64,K83.65,K83.66,K83.67,K83.68,K83.69,K83.70,K83.71,
K83.72,K83.73,K83.74,K83.75,K83.76,K83.77,K83.78,K83.79,K83.80,K83.81,
K83.82,K83.83,K83.84,K83.85,K83.86,K83.87,K83.88,K83.89,K83.90,K83.91,
K83.92,K83.93,K83.94,K83.95,K83.96,K83.97,K83.98,K83.99,K83.100,
K83.101,K83.102,K83.103,
K84.1,K84.2,K84.3,K84.4,K84.5,K84.6,K84.7,K84.8,K84.9,K84.10,K84.11,
K84.12,K84.13,K84.14,K84.15,K84.16,K84.17,K84.18,K84.19,K84.20,K84.21,
K84.22,K84.23,K84.24,K84.25,K84.26,K84.27,K84.28,K84.29,K84.30,K84.31,
K84.32,K84.33,K84.34,K84.35,K84.36,K84.37,K84.38,K84.39,K84.40,K84.41,
K84.42,K84.43,K84.44,K84.45,K84.46,K84.47,K84.48,K84.49,K84.50,K84.51,
K84.52,K84.53,K84.54,K84.55,K84.56,K84.57,K84.58,K84.59,K84.60,K84.61,
K84.62,K84.63,K84.64,K84.65,K84.66,K84.67,K84.68,K84.69,K84.70,K84.71,
K84.72,K84.73,K84.74,K84.75,K84.76,K84.77,K84.78,K84.79,K84.80,K84.81,
K84.82,K84.83,K84.84,K84.85,K84.86,K84.87,K84.88,K84.89,K84.90,K84.91,
K84.92,K84.93,K84.94,K84.95,K84.96,K84.97,K84.98,K84.99,K84.100,
K84.101,K84.102,K84.103,
K85.1,K85.2,K85.3,K85.4,K85.5,K85.6,K85.7,K85.8,K85.9,K85.10,K85.11,
K85.12,K85.13,K85.14,K85.15,K85.16,K85.17,K85.18,K85.19,K85.20,K85.21,
K85.22,K85.23,K85.24,K85.25,K85.26,K85.27,K85.28,K85.29,K85.30,K85.31,
K85.32,K85.33,K85.34,K85.35,K85.36,K85.37,K85.38,K85.39,K85.40,K85.41,
K85.42,K85.43,K85.44,K85.45,K85.46,K85.47,K85.48,K85.49,K85.50,K85.51,
K85.52,K85.53,K85.54,K85.55,K85.56,K85.57,K85.58,K85.59,K85.60,K85.61,
K85.62,K85.63,K85.64,K85.65,K85.66,K85.67,K85.68,K85.69,K85.70,K85.71,
K85.72,K85.73,K85.74,K85.75,K85.76,K85.77,K85.78,K85.79,K85.80,K85.81,
K85.82,K85.83,K85.84,K85.85,K85.86,K85.87,K85.88,K85.89,K85.90,K85.91,
K85.92,K85.93,K85.94,K85.95,K85.96,K85.97,K85.98,K85.99,K85.100,
K85.101,K85.102,K85.103,
K86.1,K86.2,K86.3,K86.4,K86.5,K86.6,K86.7,K86.8,K86.9,K86.10,K86.11,
K86.12,K86.13,K86.14,K86.15,K86.16,K86.17,K86.18,K86.19,K86.20,K86.21,
K86.22,K86.23,K86.24,K86.25,K86.26,K86.27,K86.28,K86.29,K86.30,K86.31,
K86.32,K86.33,K86.34,K86.35,K86.36,K86.37,K86.38,K86.39,K86.40,K86.41,
K86.42,K86.43,K86.44,K86.45,K86.46,K86.47,K86.48,K86.49,K86.50,K86.51,
K86.52,K86.53,K86.54,K86.55,K86.56,K86.57,K86.58,K86.59,K86.60,K86.61,
K86.62,K86.63,K86.64,K86.65,K86.66,K86.67,K86.68,K86.69,K86.70,K86.71,
K86.72,K86.73,K86.74,K86.75,K86.76,K86.77,K86.78,K86.79,K86.80,K86.81,
K86.82,K86.83,K86.84,K86.85,K86.86,K86.87,K86.88,K86.89,K86.90,K86.91,
K86.92,K86.93,K86.94,K86.95,K86.96,K86.97,K86.98,K86.99,K86.100,
K86.101,K86.102,K86.103,
K87.1,K87.2,K87.3,K87.4,K87.5,K87.6,K87.7,K87.8,K87.9,K87.10,K87.11,
K87.12,K87.13,K87.14,K87.15,K87.16,K87.17,K87.18,K87.19,K87.20,K87.21,
K87.22,K87.23,K87.24,K87.25,K87.26,K87.27,K87.28,K87.29,K87.30,K87.31,
K87.32,K87.33,K87.34,K87.35,K87.36,K87.37,K87.38,K87.39,K87.40,K87.41,
K87.42,K87.43,K87.44,K87.45,K87.46,K87.47,K87.48,K87.49,K87.50,K87.51,
K87.52,K87.53,K87.54,K87.55,K87.56,K87.57,K87.58,K87.59,K87.60,K87.61,
K87.62,K87.63,K87.64,K87.65,K87.66,K87.67,K87.68,K87.69,K87.70,K87.71,
K87.72,K87.73,K87.74,K87.75,K87.76,K87.77,K87.78,K87.79,K87.80,K87.81,
K87.82,K87.83,K87.84,K87.85,K87.86,K87.87,K87.88,K87.89,K87.90,K87.91,
K87.92,K87.93,K87.94,K87.95,K87.96,K87.97,K87.98,K87.99,K87.100,
K87.101,K87.102,K87.103,
K88.1,K88.2,K88.3,K88.4,K88.5,K88.6,K88.7,K88.8,K88.9,K88.10,K88.11,
K88.12,K88.13,K88.14,K88.15,K88.16,K88.17,K88.18,K88.19,K88.20,K88.21,
K88.22,K88.23,K88.24,K88.25,K88.26,K88.27,K88.28,K88.29,K88.30,K88.31,
K88.32,K88.33,K88.34,K88.35,K88.36,K88.37,K88.38,K88.39,K88.40,K88.41,
K88.42,K88.43,K88.44,K88.45,K88.46,K88.47,K88.48,K88.49,K88.50,K88.51,
K88.52,K88.53,K88.54,K88.55,K88.56,K88.57,K88.58,K88.59,K88.60,K88.61,
K88.62,K88.63,K88.64,K88.65,K88.66,K88.67,K88.68,K88.69,K88.70,K88.71,
K88.72,K88.73,K88.74,K88.75,K88.76,K88.77,K88.78,K88.79,K88.80,K88.81,
K88.82,K88.83,K88.84,K88.85,K88.86,K88.87,K88.88,K88.89,K88.90,K88.91,
K88.92,K88.93,K88.94,K88.95,K88.96,K88.97,K88.98,K88.99,K88.100,
K88.101,K88.102,K88.103,
K89.1,K89.2,K89.3,K89.4,K89.5,K89.6,K89.7,K89.8,K89.9,K89.10,K89.11,
K89.12,K89.13,K89.14,K89.15,K89.16,K89.17,K89.18,K89.19,K89.20,K89.21,
K89.22,K89.23,K89.24,K89.25,K89.26,K89.27,K89.28,K89.29,K89.30,K89.31,
K89.32,K89.33,K89.34,K89.35,K89.36,K89.37,K89.38,K89.39,K89.40,K89.41,
K89.42,K89.43,K89.44,K89.45,K89.46,K89.47,K89.48,K89.49,K89.50,K89.51,
K89.52,K89.53,K89.54,K89.55,K89.56,K89.57,K89.58,K89.59,K89.60,K89.61,
K89.62,K89.63,K89.64,K89.65,K89.66,K89.67,K89.68,K89.69,K89.70,K89.71,
K89.72,K89.73,K89.74,K89.75,K89.76,K89.77,K89.78,K89.79,K89.80,K89.81,
K89.82,K89.83,K89.84,K89.85,K89.86,K89.87,K89.88,K89.89,K89.90,K89.91,
K89.92,K89.93,K89.94,K89.95,K89.96,K89.97,K89.98,K89.99,K89.100,
K89.101,K89.102,K89.103,
K90.1,K90.2,K90.3,K90.4,K90.5,K90.6,K90.7,K90.8,K90.9,K90.10,K90.11,
K90.12,K90.13,K90.14,K90.15,K90.16,K90.17,K90.18,K90.19,K90.20,K90.21,
K90.22,K90.23,K90.24,K90.25,K90.26,K90.27,K90.28,K90.29,K90.30,K90.31,
K90.32,K90.33,K90.34,K90.35,K90.36,K90.37,K90.38,K90.39,K90.40,K90.41,
K90.42,K90.43,K90.44,K90.45,K90.46,K90.47,K90.48,K90.49,K90.50,K90.51,
K90.52,K90.53,K90.54,K90.55,K90.56,K90.57,K90.58,K90.59,K90.60,K90.61,
K90.62,K90.63,K90.64,K90.65,K90.66,K90.67,K90.68,K90.69,K90.70,K90.71,
K90.72,K90.73,K90.74,K90.75,K90.76,K90.77,K90.78,K90.79,K90.80,K90.81,
K90.82,K90.83,K90.84,K90.85,K90.86,K90.87,K90.88,K90.89,K90.90,K90.91,
K90.92,K90.93,K90.94,K90.95,K90.96,K90.97,K90.98,K90.99,K90.100,
K90.101,K90.102,K90.103,
K91.1,K91.2,K91.3,K91.4,K91.5,K91.6,K91.7,K91.8,K91.9,K91.10,K91.11,
K91.12,K91.13,K91.14,K91.15,K91.16,K91.17,K91.18,K91.19,K91.20,K91.21,
K91.22,K91.23,K91.24,K91.25,K91.26,K91.27,K91.28,K91.29,K91.30,K91.31,
K91.32,K91.33,K91.34,K91.35,K91.36,K91.37,K91.38,K91.39,K91.40,K91.41,
K91.42,K91.43,K91.44,K91.45,K91.46,K91.47,K91.48,K91.49,K91.50,K91.51,
K91.52,K91.53,K91.54,K91.55,K91.56,K91.57,K91.58,K91.59,K91.60,K91.61,
K91.62,K91.63,K91.64,K91.65,K91.66,K91.67,K91.68,K91.69,K91.70,K91.71,
K91.72,K91.73,K91.74,K91.75,K91.76,K91.77,K91.78,K91.79,K91.80,K91.81,
K91.82,K91.83,K91.84,K91.85,K91.86,K91.87,K91.88,K91.89,K91.90,K91.91,
K91.92,K91.93,K91.94,K91.95,K91.96,K91.97,K91.98,K91.99,K91.100,
K91.101,K91.102,K91.103,
K92.1,K92.2,K92.3,K92.4,K92.5,K92.6,K92.7,K92.8,K92.9,K92.10,K92.11,
K92.12,K92.13,K92.14,K92.15,K92.16,K92.17,K92.18,K92.19,K92.20,K92.21,
K92.22,K92.23,K92.24,K92.25,K92.26,K92.27,K92.28,K92.29,K92.30,K92.31,
K92.32,K92.33,K92.34,K92.35,K92.36,K92.37,K92.38,K92.39,K92.40,K92.41,
K92.42,K92.43,K92.44,K92.45,K92.46,K92.47,K92.48,K92.49,K92.50,K92.51,
K92.52,K92.53,K92.54,K92.55,K92.56,K92.57,K92.58,K92.59,K92.60,K92.61,
K92.62,K92.63,K92.64,K92.65,K92.66,K92.67,K92.68,K92.69,K92.70,K92.71,
K92.72,K92.73,K92.74,K92.75,K92.76,K92.77,K92.78,K92.79,K92.80,K92.81,
K92.82,K92.83,K92.84,K92.85,K92.86,K92.87,K92.88,K92.89,K92.90,K92.91,
K92.92,K92.93,K92.94,K92.95,K92.96,K92.97,K92.98,K92.99,K92.100,
K92.101,K92.102,K92.103,
K93.1,K93.2,K93.3,K93.4,K93.5,K93.6,K93.7,K93.8,K93.9,K93.10,K93.11,
K93.12,K93.13,K93.14,K93.15,K93.16,K93.17,K93.18,K93.19,K93.20,K93.21,
K93.22,K93.23,K93.24,K93.25,K93.26,K93.27,K93.28,K93.29,K93.30,K93.31,
K93.32,K93.33,K93.34,K93.35,K93.36,K93.37,K93.38,K93.39,K93.40,K93.41,
K93.42,K93.43,K93.44,K93.45,K93.46,K93.47,K93.48,K93.49,K93.50,K93.51,
K93.52,K93.53,K93.54,K93.55,K93.56,K93.57,K93.58,K93.59,K93.60,K93.61,
K93.62,K93.63,K93.64,K93.65,K93.66,K93.67,K93.68,K93.69,K93.70,K93.71,
K93.72,K93.73,K93.74,K93.75,K93.76,K93.77,K93.78,K93.79,K93.80,K93.81,
K93.82,K93.83,K93.84,K93.85,K93.86,K93.87,K93.88,K93.89,K93.90,K93.91,
K93.92,K93.93,K93.94,K93.95,K93.96,K93.97,K93.98,K93.99,K93.100,
K93.101,K93.102,K93.103,
K94.1,K94.2,K94.3,K94.4,K94.5,K94.6,K94.7,K94.8,K94.9,K94.10,K94.11,
K94.12,K94.13,K94.14,K94.15,K94.16,K94.17,K94.18,K94.19,K94.20,K94.21,
K94.22,K94.23,K94.24,K94.25,K94.26,K94.27,K94.28,K94.29,K94.30,K94.31,
K94.32,K94.33,K94.34,K94.35,K94.36,K94.37,K94.38,K94.39,K94.40,K94.41,
K94.42,K94.43,K94.44,K94.45,K94.46,K94.47,K94.48,K94.49,K94.50,K94.51,
K94.52,K94.53,K94.54,K94.55,K94.56,K94.57,K94.58,K94.59,K94.60,K94.61,
K94.62,K94.63,K94.64,K94.65,K94.66,K94.67,K94.68,K94.69,K94.70,K94.71,
K94.72,K94.73,K94.74,K94.75,K94.76,K94.77,K94.78,K94.79,K94.80,K94.81,
K94.82,K94.83,K94.84,K94.85,K94.86,K94.87,K94.88,K94.89,K94.90,K94.91,
K94.92,K94.93,K94.94,K94.95,K94.96,K94.97,K94.98,K94.99,K94.100,
K94.101,K94.102,K94.103,
K95.1,K95.2,K95.3,K95.4,K95.5,K95.6,K95.7,K95.8,K95.9,K95.10,K95.11,
K95.12,K95.13,K95.14,K95.15,K95.16,K95.17,K95.18,K95.19,K95.20,K95.21,
K95.22,K95.23,K95.24,K95.25,K95.26,K95.27,K95.28,K95.29,K95.30,K95.31,
K95.32,K95.33,K95.34,K95.35,K95.36,K95.37,K95.38,K95.39,K95.40,K95.41,
K95.42,K95.43,K95.44,K95.45,K95.46,K95.47,K95.48,K95.49,K95.50,K95.51,
K95.52,K95.53,K95.54,K95.55,K95.56,K95.57,K95.58,K95.59,K95.60,K95.61,
K95.62,K95.63,K95.64,K95.65,K95.66,K95.67,K95.68,K95.69,K95.70,K95.71,
K95.72,K95.73,K95.74,K95.75,K95.76,K95.77,K95.78,K95.79,K95.80,K95.81,
K95.82,K95.83,K95.84,K95.85,K95.86,K95.87,K95.88,K95.89,K95.90,K95.91,
K95.92,K95.93,K95.94,K95.95,K95.96,K95.97,K95.98,K95.99,K95.100,
K95.101,K95.102,K95.103,
K96.1,K96.2,K96.3,K96.4,K96.5,K96.6,K96.7,K96.8,K96.9,K96.10,K96.11,
K96.12,K96.13,K96.14,K96.15,K96.16,K96.17,K96.18,K96.19,K96.20,K96.21,
K96.22,K96.23,K96.24,K96.25,K96.26,K96.27,K96.28,K96.29,K96.30,K96.31,
K96.32,K96.33,K96.34,K96.35,K96.36,K96.37,K96.38,K96.39,K96.40,K96.41,
K96.42,K96.43,K96.44,K96.45,K96.46,K96.47,K96.48,K96.49,K96.50,K96.51,
K96.52,K96.53,K96.54,K96.55,K96.56,K96.57,K96.58,K96.59,K96.60,K96.61,
K96.62,K96.63,K96.64,K96.65,K96.66,K96.67,K96.68,K96.69,K96.70,K96.71,
K96.72,K96.73,K96.74,K96.75,K96.76,K96.77,K96.78,K96.79,K96.80,K96.81,
K96.82,K96.83,K96.84,K96.85,K96.86,K96.87,K96.88,K96.89,K96.90,K96.91,
K96.92,K96.93,K96.94,K96.95,K96.96,K96.97,K96.98,K96.99,K96.100,
K96.101,K96.102,K96.103,
K97.1,K97.2,K97.3,K97.4,K97.5,K97.6,K97.7,K97.8,K97.9,K97.10,K97.11,
K97.12,K97.13,K97.14,K97.15,K97.16,K97.17,K97.18,K97.19,K97.20,K97.21,
K97.22,K97.23,K97.24,K97.25,K97.26,K97.27,K97.28,K97.29,K97.30,K97.31,
K97.32,K97.33,K97.34,K97.35,K97.36,K97.37,K97.38,K97.39,K97.40,K97.41,
K97.42,K97.43,K97.44,K97.45,K97.46,K97.47,K97.48,K97.49,K97.50,K97.51,
K97.52,K97.53,K97.54,K97.55,K97.56,K97.57,K97.58,K97.59,K97.60,K97.61.
K97.62,K97.63,K97.64,K97.65,K97.66,K97.67,K97.68,K97.69,K97.70,K97.71,
K97.72,K97.73,K97.74,K97.75,K97.76,K97.77,K97.78,K97.79,K97.80,K97.81,
K97.82,K97.83,K97.84,K97.85,K97.86,K97.87,K97.88,K97.89,K97.90,K97.91,
K97.92,K97.93,K97.94,K97.95,K97.96,K97.97,K97.98,K97.99,K97.100,
K97.101,K97.102,K97.103,
K98.1,K98.2,K98.3,K98.4,K98.5,K98.6,K98.7,K98.8,K98.9,K98.10,K98.11,
K98.12,K98.13,K98.14,K98.15,K98.16,K98.17,K98.18,K98.19,K98.20,K98.21,
K98.22,K98.23,K98.24,K98.25,K98.26,K98.27,K98.28,K98.29,K98.30,K98.31,
K98.32,K98.33,K98.34,K98.35,K98.36,K98.37,K98.38,K98.39,K98.40,K98.41,
K98.42,K98.43,K98.44,K98.45,K98.46,K98.47,K98.48,K98.49,K98.50,K98.51,
K98.52,K98.53,K98.54,K98.55,K98.56,K98.57,K98.58,K98.59,K98.60,K98.61,
K98.62,K98.63,K98.64,K98.65,K98.66,K98.67,K98.68,K98.69,K98.70,K98.71,
K98.72,K98.73,K98.74,K98.75,K98.76,K98.77,K98.78,K98.79,K98.80,K98.81,
K98.82,K98.83,K98.84,K98.85,K98.86,K98.87,K98.88,K98.89,K98.90,K98.91,
K98.92,K98.93,K98.94,K98.95,K98.96,K98.97,K98.98,K98.99,K98.100,
K98.101,K98.102,K98.103,
K99.1,K99.2,K99.3,K99.4,K99.5,K99.6,K99.7,K99.8,K99.9,K99.10,K99.11,
K99.12,K99.13,K99.14,K99.15,K99.16,K99.17,K99.18,K99.19,K99.20,K99.21,
K99.22,K99.23,K99.24,K99.25,K99.26,K99.27,K99.28,K99.29,K99.30,K99.31,
K99.32,K99.33,K99.34,K99.35,K99.36,K99.37,K99.38,K99.39,K99.40,K99.41,
K99.42,K99.43,K99.44,K99.45,K99.46,K99.47,K99.48,K99.49,K99.50,K99.51,
K99.52,K99.53,K99.54,K99.55,K99.56,K99.57,K99.58,K99.59,K99.60,K99.61,
K99.62,K99.63,K99.64,K99.65,K99.66,K99.67,K99.68,K99.69,K99.70,K99.71,
K99.72,K99.73,K99.74,K99.75,K99.76,K99.77,K99.78,K99.79,K99.80,K99.81,
K99.82,K99.83,K99.84,K99.85,K99.86,K99.87,K99.88,K99.89,K99.90,K99.91,
K99.92,K99.93,K99.94,K99.95,K99.96,K99.97,K99.98,K99.99,K99.100,
K99.101,K99.102,K99.103,
K100.1,K100.2,K100.3,K100.4,K100.5,K100.6,K100.7,K100.8,K100.9,K100.10,
K100.11,K100.12,K100.13,K100.14,K100.15,K100.16,K100.17,K100.18,
K100.19,K100.20,K100.21,K100.22,K100.23,K100.24,K100.25,K100.26,
K100.27,K100.28,K100.29,K100.30,K100.31,K100.32,K100.33,K100.34,
K100.35,K100.36,K100.37,K100.38,K100.39,K100.40,K100.41,K100.42,
K100.43,K100.44,K100.45,K100.46,K100.47,K100.48,K100.49,K100.50,
K100.51,K100.52,K100.53,K100.54,K100.55,K100.56,K100.57,K100.58,
K100.59,K100.60,K100.61,K100.62,K100.63,K100.64,K100.65,K100.66,
K100.67,K100.68,K100.69,K100.70,K100.71,K100.72,K100.73,K100.74,
K100.75,K100.76,K100.77,K100.78,K100.79,K100.80,K100.81,K100.82,
K100.83,K100.84,K100.85,K100.86,K100.87,K100.88,K100.89,K100.90,
K100.91,K100.92,K100.93,K100.94,K100.95,K100.96,K100.97,K100.98,
K100.99,K100.100,K100.101,K100.102,K100.103,
K101.1,K101.2,K101.3,K101.4,K101.5,K101.6,K101.7,K101.8,K101.9,K101.10,
K101.11,K101.12,K101.13,K101.14,K101.15,K101.16,K101.17,K101.18,
K101.19,K101.20,K101.21,K101.22,K101.23,K101.24,K101.25,K101.26,
K101.27,K101.28,K101.29,K101.30,K101.31,K101.32,K101.33,K101.34,
K101.35,K101.36,K101.37,K101.38,K101.39,K101.40,K101.41,K101.42,
K101.43,K101.44,K101.45,K101.46,K101.47,K101.48,K101.49,K101.50,
K101.51,K101.52,K101.53,K101.54,K101.55,K101.56,K101.57,K101.58,
K101.59,K101.60,K101.61,K101.62,K101.63,K101.64,K101.65,K101.66,
K101.67,K101.68,K101.69,K101.70,K101.71,K101.72,K101.73,K101.74,
K101.75,K101.76,K101.77,K101.78,K101.79,K101.80,K101.81,K101.82,
K101.83,K101.84,K101.85,K101.86,K101.87,K101.88,K101.89,K101.90,
K101.91,K101.92,K101.93,K101.94,K101.95,K101.96,K101.97,K101.98,
K101.99,K101.100,K101.101,K101.102,K101.103,
K102.1,K102.2,K102.3,K102.4,K102.5,K102.6,K102.7,K102.8,K102.9,K102.10,
K102.11,K102.12,K102.13,K102.14,K102.15,K102.16,K102.17,K102.18,
K102.19,K102.20,K102.21,K102.22,K102.23,K102.24,K102.25,K102.26,
K102.27,K102.28,K102.29,K102.30,K102.31,K102.32,K102.33,K102.34,
K102.35,K102.36,K102.37,K102.38,K102.39,K102.40,K102.41,K102.42,
K102.43,K102.44,K102.45,K102.46,K102.47,K102.48,K102.49,K102.50,
K102.51,K102.52,K102.53,K102.54,K102.55,K102.56,K102.57,K102.58,
K102.59,K102.60,K102.61,K102.62,K102.63,K102.64,K102.65,K102.66,
K102.67,K102.68,K102.69,K102.70,K102.71,K102.72,K102.73,K102.74,
K102.75,K102.76,K102.77,K102.78,K102.79,K102.80,K102.81,K102.82,
K102.83,K102.84,K102.85,K102.86,K102.87,K102.88,K102.89,K102.90,
K102.91,K102.92,K102.93,K102.94,K102.95,K102.96,K102.97,K102.98,
K102.99,K102.100,K102.101,K102.102,K102.103,
K103.1,K103.2,K103.3,K103.4,K103.5,K103.6,K103.7,K103.8,K103.9,K103.10,
K103.11,K103.12,K103.13,K103.14,K103.15,K103.16,K103.17,K103.18,
K103.19,K103.20,K103.21,K103.22,K103.23,K103.24,K103.25,K103.26,
K103.27,K103.28,K103.29,K103.30,K103.31,K103.32,K103.33,K103.34,
K103.35,K103.36,K103.37,K103.38,K103.39,K103.40,K103.41,K103.42,
K103.43,K103.44,K103.45,K103.46,K103.47,K103.48,K103.49,K103.50,
K103.51,K103.52,K103.53,K103.54,K103.55,K103.56,K103.57,K103.58,
K103.59,K103.60,K103.61,K103.62,K103.63,K103.64,K103.65,K103.66,
K103.67,K103.68,K103.69,K103.70,K103.71,K103.72,K103.73,K103.74,
K103.75,K103.76,K103.77,K103.78,K103.79,K103.80,K103.81,K103.82,
K103.83,K103.84,K103.85,K103.86,K103.87,K103.88,K103.89,K103.90,
K103.91,K103.92,K103.93,K103.94,K103.95,K103.96,K103.97,K103.98,
K103.99,K103.100,K103.101,K103.102,K103.103,
K104.1,K104.2,K104.3,K104.4,K104.5,K104.6,K104.7,K104.8,K104.9,K104.10,
K104.11,K104.12,K104.13,K104.14,K104.15,K104.16,K104.17,K104.18,
K104.19,K104.20,K104.21,K104.22,K104.23,K104.24,K104.25,K104.26,
K104.27,K104.28,K104.29,K104.30,K104.31,K104.32,K104.33,K104.34,
K104.35,K104.36,K104.37,K104.38,K104.39,K104.40,K104.41,K104.42,
K104.43,K104.44,K104.45,K104.46,K104.47,K104.48,K104.49,K104.50,
K104.51,K104.52,K104.53,K104.54,K104.55,K104.56,K104.57,K104.58,
K104.59,K104.60,K104.61,K104.62,K104.63,K104.64,K104.65,K104.66,
K104.67,K104.68,K104.69,K104.70,K104.71,K104.72,K104.73,K104.74,
K104.75,K104.76,K104.77,K104.78,K104.79,K104.80,K104.81,K104.82,
K104.83,K104.84,K104.85,K104.86,K104.87,K104.88,K104.89,K104.90,
K104.91,K104.92,K104.93,K104.94,K104.95,K104.96,K104.97,K104.98,
K104.99,K104.100,K104.101,K104.102,K104.103,
K105.1,K105.2,K105.3,K105.4,K105.5,K105.6,K105.7,K105.8,K105.9,K105.10,
K105.11,K105.12,K105.13,K105.14,K105.15,K105.16,K105.17,K105.18,
K105.19,K105.20,K105.21,K105.22,K105.23,K105.24,K105.25,K105.26,
K105.27,K105.28,K105.29,K105.30,K105.31,K105.32,K105.33,K105.34,
K105.35,K105.36,K105.37,K105.38,K105.39,K105.40,K105.41,K105.42,
K105.43,K105.44,K105.45,K105.46,K105.47,K105.48,K105.49,K105.50,
K105.51,K105.52,K105.53,K105.54,K105.55,K105.56,K105.57,K105.58,
K105.59,K105.60,K105.61,K105.62,K105.63,K105.64,K105.65,K105.66,
K105.67,K105.68,K105.69,K105.70,K105.71,K105.72,K105.73,K105.74,
K105.75,K105.76,K105.77,K105.78,K105.79,K105.80,K105.81,K105.82,
K105.83,K105.84,K105.85,K105.86,K105.87,K105.88,K105.89,K105.90,
K105.91,K105.92,K105.93,K105.94,K105.95,K105.96,K105.97,K105.98,
K105.99,K105.100,K105.101,K105.102,K105.103,
K106.1,K106.2,K106.3,K106.4,K106.5,K106.6,K106.7,K106.8,K106.9,K106.10,
K106.11,K106.12,K106.13,K106.14,K106.15,K106.16,K106.17,K106.18,
K106.19,K106.20,K106.21,K106.22,K106.23,K106.24,K106.25,K106.26,
K106.27,K106.28,K106.29,K106.30,K106.31,K106.32,K106.33,K106.34,
K106.35,K106.36,K106.37,K106.38,K106.39,K106.40,K106.41,K106.42,
K106.43,K106.44,K106.45,K106.46,K106.47,K106.48,K106.49,K106.50,
K106.51,K106.52,K106.53,K106.54,K106.55,K106.56,K106.57,K106.58,
K106.59,K106.60,K106.61,K106.62,K106.63,K106.64,K106.65,K106.66,
K106.67,K106.68,K106.69,K106.70,K106.71,K106.72,K106.73,K106.74,
K106.75,K106.76,K106.77,K106.78,K106.79,K106.80,K106.81,K106.82,
K106.83,K106.84,K106.85,K106.86,K106.87,K106.88,K106.89,K106.90,
K106.91,K106.92,K106.93,K106.94,K106.95,K106.96,K106.97,K106.98,
K106.99,K106.100,K106.101,K106.102,K106.103,
K107.1,K107.2,K107.3,K107.4,K107.5,K107.6,K107.7,K107.8,K107.9,K107.10,
K107.11,K107.12,K107.13,K107.14,K107.15,K107.16,K107.17,K107.18,
K107.19,K107.20,K107.21,K107.22,K107.23,K107.24,K107.25,K107.26,
K107.27,K107.28,K107.29,K107.30,K107.31,K107.32,K107.33,K107.34,
K107.35,K107.36,K107.37,K107.38,K107.39,K107.40,K107.41,K107.42,
K107.43,K107.44,K107.45,K107.46,K107.47,K107.48,K107.49,K107.50,
K107.51,K107.52,K107.53,K107.54,K107.55,K107.56,K107.57,K107.58,
K107.59,K107.60,K107.61,K107.62,K107.63,K107.64,K107.65,K107.66,
K107.67,K107.68,K107.69,K107.70,K107.71,K107.72,K107.73,K107.74,
K107.75,K107.76,K107.77,K107.78,K107.79,K107.80,K107.81,K107.82,
K107.83,K107.84,K107.85,K107.86,K107.87,K107.88,K107.89,K107.90,
K107.91,K107.92,K107.93,K107.94,K107.95,K107.96,K107.97,K107.98,
K107.99,K107.100,K107.101,K107.102,K107.103,
K108.1,K108.2,K108.3,K108.4,K108.5,K108.6,K108.7,K108.8,K108.9,K108.10,
K108.11,K108.12,K108.13,K108.14,K108.15,K108.16,K108.17,K108.18,
K108.19,K108.20,K108.21,K108.22,K108.23,K108.24,K108.25,K108.26,
K108.27,K108.28,K108.29,K108.30,K108.31,K108.32,K108.33,K108.34,
K108.35,K108.36,K108.37,K108.38,K108.39,K108.40,K108.41,K108.42,
K108.43,K108.44,K108.45,K108.46,K108.47,K108.48,K108.49,K108.50,
K108.51,K108.52,K108.53,K108.54,K108.55,K108.56,K108.57,K108.58,
K108.59,K108.60,K108.61,K108.62,K108.63,K108.64,K108.65,K108.66,
K108.67,K108.68,K108.69,K108.70,K108.71,K108.72,K108.73,K108.74,
K108.75,K108.76,K108.77,K108.78,K108.79,K108.80,K108.81,K108.82,
K108.83,K108.84,K108.85,K108.86,K108.87,K108.88,K108.89,K108.90,
K108.91,K108.92,K108.93,K108.94,K108.95,K108.96,K108.97,K108.98,
K108.99,K108.100,K108.101,K108.102,K108.103,
K109.1,K109.2,K109.3,K109.4,K109.5,K109.6,K109.7,K109.8,K109.9,K109.10,
K109.11,K109.12,K109.13,K109.14,K109.15,K109.16,K109.17,K109.18,
K109.19,K109.20,K109.21,K109.22,K109.23,K109.24,K109.25,K109.26,
K109.27,K109.28,K109.29,K109.30,K109.31,K109.32,K109.33,K109.34,
K109.35,K109.36,K109.37,K109.38,K109.39,K109.40,K109.41,K109.42,
K109.43,K109.44,K109.45,K109.46,K109.47,K109.48,K109.49,K109.50,
K109.51,K109.52,K109.53,K109.54,K109.55,K109.56,K109.57,K109.58,
K109.59,K109.60,K109.61,K109.62,K109.63,K109.64,K109.65,K109.66,
K109.67,K109.68,K109.69,K109.70,K109.71,K109.72,K109.73,K109.74,
K109.75,K109.76,K109.77,K109.78,K109.79,K109.80,K109.81,K109.82,
K109.83,K109.84,K109.85,K109.86,K109.87,K109.88,K109.89,K109.90,
K109.91,K109.92,K109.93,K109.94,K109.95,K109.96,K109.97,K109.98,
K109.99,K109.100,K109.101,K109.102,K109.103,
K110.1,K110.2,K110.3,K110.4,K110.5,K110.6,K110.7,K110.8,K110.9,K110.10,
K110.11,K110.12,K110.13,K110.14,K110.15,K110.16,K110.17,K110.18,
K110.19,K110.20,K110.21,K110.22,K110.23,K110.24,K110.25,K110.26,
K110.27,K110.28,K110.29,K110.30,K110.31,K110.32,K110.33,K110.34,
K110.35,K110.36,K110.37,K110.38,K110.39,K110.40,K110.41,K110.42,
K110.43,K110.44,K110.45,K110.46,K110.47,K110.48,K110.49,K110.50,
K110.51,K110.52,K110.53,K110.54,K110.55,K110.56,K110.57,K110.58,
K110.59,K110.60,K110.61,K110.62,K110.63,K110.64,K110.65,K110.66,
K110.67,K110.68,K110.69,K110.70,K110.71,K110.72,K110.73,K110.74,
K110.75,K110.76,K110.77,K110.78,K110.79,K110.80,K110.81,K110.82,
K110.83,K110.84,K110.85,K110.86,K110.87,K110.88,K110.89,K110.90,
K110.91,K110.92,K110.93,K110.94,K110.95,K110.96,K110.97,K110.98,
K110.99,K110.100,K110.101,K110.102,K110.103,
K111.1,K111.2,K111.3,K111.4,K111.5,K111.6,K111.7,K111.8,K111.9,K111.10,
K111.11,K111.12,K111.13,K111.14,K111.15,K111.16,K111.17,K111.18,
K111.19,K111.20,K111.21,K111.22,K111.23,K111.24,K111.25,K111.26,
K111.27,K111.28,K111.29,K111.30,K111.31,K111.32,K111.33,K111.34,
K111.35,K111.36,K111.37,K111.38,K111.39,K111.40,K111.41,K111.42,
K111.43,K111.44,K111.45,K111.46,K111.47,K111.48,K111.49,K111.50,
K111.51,K111.52,K111.53,K111.54,K111.55,K111.56,K111.57,K111.58,
K111.59,K111.60,K111.61,K111.62,K111.63,K111.64,K111.65,K111.66,
K111.67,K111.68,K111.69,K111.70,K111.71,K111.72,K111.73,K111.74,
K111.75,K111.76,K111.77,K111.78,K111.79,K111.80,K111.81,K111.82,
K111.83,K111.84,K111.85,K111.86,K111.87,K111.88,K111.89,K111.90,
K111.91,K111.92,K111.93,K111.94,K111.95,K111.96,K111.97,K111.98,
K111.99,K111.100,K111.101,K111.102,K111.103,
K112.1,K112.2,K112.3,K112.4,K112.5,K112.6,K112.7,K112.8,K112.9,K112.10,
K112.11,K112.12,K112.13,K112.14,K112.15,K112.16,K112.17,K112.18,
K112.19,K112.20,K112.21,K112.22,K112.23,K112.24,K112.25,K112.26,    
K112.27,K112.28,K112.29,K112.30,K112.31,K112.32,K112.33,K112.34,
K112.35,K112.36,K112.37,K112.38,K112.39,K112.40,K112.41,K112.42,
K112.43,K112.44,K112.45,K112.46,K112.47,K112.48,K112.49,K112.50,
K112.51,K112.52,K112.53,K112.54,K112.55,K112.56,K112.57,K112.58,
K112.59,K112.60,K112.61,K112.62,K112.63,K112.64,K112.65,K112.66,
K112.67,K112.68,K112.69,K112.70,K112.71,K112.72,K112.73,K112.74,
K112.75,K112.76,K112.77,K112.78,K112.79,K112.80,K112.81,K112.82,
K112.83,K112.84,K112.85,K112.86,K112.87,K112.88,K112.89,K112.90,
K112.91,K112.92,K112.93,K112.94,K112.95,K112.96,K112.97,K112.98,
K112.99,K112.100,K112.101,K112.102,K112.103,
K113.1,K113.2,K113.3,K113.4,K113.5,K113.6,K113.7,K113.8,K113.9,K113.10,
K113.11,K113.12,K113.13,K113.14,K113.15,K113.16,K113.17,K113.18,
K113.19,K113.20,K113.21,K113.22,K113.23,K113.24,K113.25,K113.26,
K113.27,K113.28,K113.29,K113.30,K113.31,K113.32,K113.33,K113.34,
K113.35,K113.36,K113.37,K113.38,K113.39,K113.40,K113.41,K113.42,
K113.43,K113.44,K113.45,K113.46,K113.47,K113.48,K113.49,K113.50,
K113.51,K113.52,K113.53,K113.54,K113.55,K113.56,K113.57,K113.58,
K113.59,K113.60,K113.61,K113.62,K113.63,K113.64,K113.65,K113.66,
K113.67,K113.68,K113.69,K113.70,K113.71,K113.72,K113.73,K113.74,
K113.75,K113.76,K113.77,K113.78,K113.79,K113.80,K113.81,K113.82,
K113.83,K113.84,K113.85,K113.86,K113.87,K113.88,K113.89,K113.90,
K113.91,K113.92,K113.93,K113.94,K113.95,K113.96,K113.97,K113.98,
K113.99,K113.100,K113.101,K113.102,K113.103,
K114.1,K114.2,K114.3,K114.4,K114.5,K114.6,K114.7,K114.8,K114.9,K114.10,
K114.11,K114.12,K114.13,K114.14,K114.15,K114.16,K114.17,K114.18,
K114.19,K114.20,K114.21,K114.22,K114.23,K114.24,K114.25,K114.26,
K114.27,K114.28,K114.29,K114.30,K114.31,K114.32,K114.33,K114.34,
K114.35,K114.36,K114.37,K114.38,K114.39,K114.40,K114.41,K114.42,
K114.43,K114.44,K114.45,K114.46,K114.47,K114.48,K114.49,K114.50,
K114.51,K114.52,K114.53,K114.54,K114.55,K114.56,K114.57,K114.58,
K114.59,K114.60,K114.61,K114.62,K114.63,K114.64,K114.65,K114.66,
K114.67,K114.68,K114.69,K114.70,K114.71,K114.72,K114.73,K114.74,
K114.75,K114.76,K114.77,K114.78,K114.79,K114.80,K114.81,K114.82,
K114.83,K114.84,K114.85,K114.86,K114.87,K114.88,K114.89,K114.90,
K114.91,K114.92,K114.93,K114.94,K114.95,K114.96,K114.97,K114.98,
K114.99,K114.100,K114.101,K114.102,K114.103,
K115.1,K115.2,K115.3,K115.4,K115.5,K115.6,K115.7,K115.8,K115.9,K115.10,
K115.11,K115.12,K115.13,K115.14,K115.15,K115.16,K115.17,K115.18,
K115.19,K115.20,K115.21,K115.22,K115.23,K115.24,K115.25,K115.26,
K115.27,K115.28,K115.29,K115.30,K115.31,K115.32,K115.33,K115.34,
K115.35,K115.36,K115.37,K115.38,K115.39,K115.40,K115.41,K115.42,
K115.43,K115.44,K115.45,K115.46,K115.47,K115.48,K115.49,K115.50,
K115.51,K115.52,K115.53,K115.54,K115.55,K115.56,K115.57,K115.58,
K115.59,K115.60,K115.61,K115.62,K115.63,K115.64,K115.65,K115.66,
K115.67,K115.68,K115.69,K115.70,K115.71,K115.72,K115.73,K115.74,
K115.75,K115.76,K115.77,K115.78,K115.79,K115.80,K115.81,K115.82,
K115.83,K115.84,K115.85,K115.86,K115.87,K115.88,K115.89,K115.90,
K115.91,K115.92,K115.93,K115.94,K115.95,K115.96,K115.97,K115.98,
K115.99,K115.100,K115.101,K115.102,K115.103,
K116.1,K116.2,K116.3,K116.4,K116.5,K116.6,K116.7,K116.8,K116.9,K116.10,
K116.11,K116.12,K116.13,K116.14,K116.15,K116.16,K116.17,K116.18,
K116.19,K116.20,K116.21,K116.22,K116.23,K116.24,K116.25,K116.26,
K116.27,K116.28,K116.29,K116.30,K116.31,K116.32,K116.33,K116.34,
K116.35,K116.36,K116.37,K116.38,K116.39,K116.40,K116.41,K116.42,
K116.43,K116.44,K116.45,K116.46,K116.47,K116.48,K116.49,K116.50,
K116.51,K116.52,K116.53,K116.54,K116.55,K116.56,K116.57,K116.58,
K116.59,K116.60,K116.61,K116.62,K116.63,K116.64,K116.65,K116.66,
K116.67,K116.68,K116.69,K116.70,K116.71,K116.72,K116.73,K116.74,
K116.75,K116.76,K116.77,K116.78,K116.79,K116.80,K116.81,K116.82,
K116.83,K116.84,K116.85,K116.86,K116.87,K116.88,K116.89,K116.90,
K116.91,K116.92,K116.93,K116.94,K116.95,K116.96,K116.97,K116.98,
K116.99,K116.100,K116.101,K116.102,K116.103,
K117.1,K117.2,K117.3,K117.4,K117.5,K117.6,K117.7,K117.8,K117.9,K117.10,
K117.11,K117.12,K117.13,K117.14,K117.15,K117.16,K117.17,K117.18,
K117.19,K117.20,K117.21,K117.22,K117.23,K117.24,K117.25,K117.26,
K117.27,K117.28,K117.29,K117.30,K117.31,K117.32,K117.33,K117.34,
K117.35,K117.36,K117.37,K117.38,K117.39,K117.40,K117.41,K117.42,
K117.43,K117.44,K117.45,K117.46,K117.47,K117.48,K117.49,K117.50,
K117.51,K117.52,K117.53,K117.54,K117.55,K117.56,K117.57,K117.58,
K117.59,K117.60,K117.61,K117.62,K117.63,K117.64,K117.65,K117.66,
K117.67,K117.68,K117.69,K117.70,K117.71,K117.72,K117.73,K117.74,
K117.75,K117.76,K117.77,K117.78,K117.79,K117.80,K117.81,K117.82,
K117.83,K117.84,K117.85,K117.86,K117.87,K117.88,K117.89,K117.90,
K117.91,K117.92,K117.93,K117.94,K117.95,K117.96,K117.97,K117.98,
K117.99,K117.100,K117.101,K117.102,K117.103,
K118.1,K118.2,K118.3,K118.4,K118.5,K118.6,K118.7,K118.8,K118.9,K118.10,
K118.11,K118.12,K118.13,K118.14,K118.15,K118.16,K118.17,K118.18,
K118.19,K118.20,K118.21,K118.22,K118.23,K118.24,K118.25,K118.26,
K118.27,K118.28,K118.29,K118.30,K118.31,K118.32,K118.33,K118.34,
K118.35,K118.36,K118.37,K118.38,K118.39,K118.40,K118.41,K118.42,
K118.43,K118.44,K118.45,K118.46,K118.47,K118.48,K118.49,K118.50,
K118.51,K118.52,K118.53,K118.54,K118.55,K118.56,K118.57,K118.58,
K118.59,K118.60,K118.61,K118.62,K118.63,K118.64,K118.65,K118.66,
K118.67,K118.68,K118.69,K118.70,K118.71,K118.72,K118.73,K118.74,
K118.75,K118.76,K118.77,K118.78,K118.79,K118.80,K118.81,K118.82,
K118.83,K118.84,K118.85,K118.86,K118.87,K118.88,K118.89,K118.90,
K118.91,K118.92,K118.93,K118.94,K118.95,K118.96,K118.97,K118.98,
K118.99,K118.100,K118.101,K118.102,K118.103,
K119.1,K119.2,K119.3,K119.4,K119.5,K119.6,K119.7,K119.8,K119.9,K119.10,
K119.11,K119.12,K119.13,K119.14,K119.15,K119.16,K119.17,K119.18,
K119.19,K119.20,K119.21,K119.22,K119.23,K119.24,K119.25,K119.26,
K119.27,K119.28,K119.29,K119.30,K119.31,K119.32,K119.33,K119.34,
K119.35,K119.36,K119.37,K119.38,K119.39,K119.40,K119.41,K119.42,
K119.43,K119.44,K119.45,K119.46,K119.47,K119.48,K119.49,K119.50,
K119.51,K119.52,K119.53,K119.54,K119.55,K119.56,K119.57,K119.58.
K119.59,K119.60,K119.61,K119.62,K119.63,K119.64,K119.65,K119.66,
K119.67,K119.68,K119.69,K119.70,K119.71,K119.72,K119.73,K119.74,
K119.75,K119.76,K119.77,K119.78,K119.79,K119.80,K119.81,K119.82,
K119.83,K119.84,K119.85,K119.86,K119.87,K119.88,K119.89,K119.90,
K119.91,K119.92,K119.93,K119.94,K119.95,K119.96,K119.97,K119.98,
K119.99,K119.100,K119.101,K119.102,K119.103,
K120.1,K120.2,K120.3,K120.4,K120.5,K120.6,K120.7,K120.8,K120.9,K120.10,
K120.11,K120.12,K120.13,K120.14,K120.15,K120.16,K120.17,K120.18,
K120.19,K120.20,K120.21,K120.22,K120.23,K120.24,K120.25,K120.26,
K120.27,K120.28,K120.29,K120.30,K120.31,K120.32,K120.33,K120.34,
K120.35,K120.36,K120.37,K120.38,K120.39,K120.40,K120.41,K120.42,
K120.43,K120.44,K120.45,K120.46,K120.47,K120.48,K120.49,K120.50,
K120.51,K120.52,K120.53,K120.54,K120.55,K120.56,K120.57,K120.58.
K120.59,K120.60,K120.61,K120.62,K120.63,K120.64,K120.65,K120.66,
K120.67,K120.68,K120.69,K120.70,K120.71,K120.72,K120.73,K120.74,
K120.75,K120.76,K120.77,K120.78,K120.79,K120.80,K120.81,K120.82,
K120.83,K120.84,K120.85,K120.86,K120.87,K120.88,K120.89,K120.90,
K120.91,K120.92,K120.93,K120.94,K120.95,K120.96,K120.97,K120.98,
K120.99,K120.100,K120.101,K120.102,K120.103,
K121.1,K121.2,K121.3,K121.4,K121.5,K121.6,K121.7,K121.8,K121.9,K121.10,
K121.11,K121.12,K121.13,K121.14,K121.15,K121.16,K121.17,K121.18,
K121.19,K121.20,K121.21,K121.22,K121.23,K121.24,K121.25,K121.26.
K121.27,K121.28,K121.29,K121.30,K121.31,K121.32,K121.33,K121.34,
K121.35,K121.36,K121.37,K121.38,K121.39,K121.40,K121.41,K121.42,
K121.43,K121.44,K121.45,K121.46,K121.47,K121.48,K121.49,K121.50,
K121.51,K121.52,K121.53,K121.54,K121.55,K121.56,K121.57,K121.58,
K121.59,K121.60,K121.61,K121.62,K121.63,K121.64,K121.65,K121.66,
K121.67,K121.68,K121.69,K121.70,K121.71,K121.72,K121.73,K121.74,
K121.75,K121.76,K121.77,K121.78,K121.79,K121.80,K121.81,K121.82,
K121.83,K121.84,K121.85,K121.86,K121.87,K121.88,K121.89,K121.90,
K121.91,K121.92,K121.93,K121.94,K121.95,K121.96,K121.97,K121.98,
K121.99,K121.100,K121.101,K121.102,K121.103,
K122.1,K122.2,K122.3,K122.4,K122.5,K122.6,K122.7,K122.8,K122.9,K122.10,
K122.11,K122.12,K122.13,K122.14,K122.15,K122.16,K122.17,K122.18,
K122.19,K122.20,K122.21,K122.22,K122.23,K122.24,K122.25,K122.26,
K122.27,K122.28,K122.29,K122.30,K122.31,K122.32,K122.33,K122.34,
K122.35,K122.36,K122.37,K122.38,K122.39,K122.40,K122.41,K122.42,
K122.43,K122.44,K122.45,K122.46,K122.47,K122.48,K122.49,K122.50,
K122.51,K122.52,K122.53,K122.54,K122.55,K122.56,K122.57,K122.58,
K122.59,K122.60,K122.61,K122.62,K122.63,K122.64,K122.65,K122.66,
K122.67,K122.68,K122.69,K122.70,K122.71,K122.72,K122.73,K122.74,
K122.75,K122.76,K122.77,K122.78,K122.79,K122.80,K122.81,K122.82,
K122.83,K122.84,K122.85,K122.86,K122.87,K122.88,K122.89,K122.90,
K122.91,K122.92,K122.93,K122.94,K122.95,K122.96,K122.97,K122.98,
K122.99,K122.100,K122.101,K122.102,K122.103,
K123.1,K123.2,K123.3,K123.4,K123.5,K123.6,K123.7,K123.8,K123.9,K123.10,
K123.11,K123.12,K123.13,K123.14,K123.15,K123.16,K123.17,K123.18,
K123.19,K123.20,K123.21,K123.22,K123.23,K123.24,K123.25,K123.26,
K123.27,K123.28,K123.29,K123.30,K123.31,K123.32,K123.33,K123.34,
K123.35,K123.36,K123.37,K123.38,K123.39,K123.40,K123.41,K123.42,
K123.43,K123.44,K123.45,K123.46,K123.47,K123.48,K123.49,K123.50,
K123.51,K123.52,K123.53,K123.54,K123.55,K123.56,K123.57,K123.58,
K123.59,K123.60,K123.61,K123.62,K123.63,K123.64,K123.65,K123.66,
K123.67,K123.68,K123.69,K123.70,K123.71,K123.72,K123.73,K123.74,
K123.75,K123.76,K123.77,K123.78,K123.79,K123.80,K123.81,K123.82,
K123.83,K123.84,K123.85,K123.86,K123.87,K123.88,K123.89,K123.90,
K123.91,K123.92,K123.93,K123.94,K123.95,K123.96,K123.97,K123.98,
K123.99,K123.100,K123.101,K123.102,K123.103,
K124.1,K124.2,K124.3,K124.4,K124.5,K124.6,K124.7,K124.8,K124.9,K124.10,
K124.11,K124.12,K124.13,K124.14,K124.15,K124.16,K124.17,K124.18,
K124.19,K124.20,K124.21,K124.22,K124.23,K124.24,K124.25,K124.26,
K124.27,K124.28,K124.29,K124.30,K124.31,K124.32,K124.33,K124.34,
K124.35,K124.36,K124.37,K124.38,K124.39,K124.40,K124.41,K124.42,
K124.43,K124.44,K124.45,K124.46,K124.47,K124.48,K124.49,K124.50,
K124.51,K124.52,K124.53,K124.54,K124.55,K124.56,K124.57,K124.58,
K124.59,K124.60,K124.61,K124.62,K124.63,K124.64,K124.65,K124.66,
K124.67,K124.68,K124.69,K124.70,K124.71,K124.72,K124.73,K124.74,
K124.75,K124.76,K124.77,K124.78,K124.79,K124.80,K124.81,K124.82,
K124.83,K124.84,K124.85,K124.86,K124.87,K124.88,K124.89,K124.90,
K124.91,K124.92,K124.93,K124.94,K124.95,K124.96,K124.97,K124.98,
K124.99,K124.100,K124.101,K124.102,K124.103,
K125.1,K125.2,K125.3,K125.4,K125.5,K125.6,K125.7,K125.8,K125.9,K125.10,
K125.11,K125.12,K125.13,K125.14,K125.15,K125.16,K125.17,K125.18,
K125.19,K125.20,K125.21,K125.22,K125.23,K125.24,K125.25,K125.26,
K125.27,K125.28,K125.29,K125.30,K125.31,K125.32,K125.33,K125.34,
K125.35,K125.36,K125.37,K125.38,K125.39,K125.40,K125.41,K125.42,
K125.43,K125.44,K125.45,K125.46,K125.47,K125.48,K125.49,K125.50,
K125.51,K125.52,K125.53,K125.54,K125.55,K125.56,K125.57,K125.58,
K125.59,K125.60,K125.61,K125.62,K125.63,K125.64,K125.65,K125.66,
K125.67,K125.68,K125.69,K125.70,K125.71,K125.72,K125.73,K125.74,
K125.75,K125.76,K125.77,K125.78,K125.79,K125.80,K125.81,K125.82,
K125.83,K125.84,K125.85,K125.86,K125.87,K125.88,K125.89,K125.90,
K125.91,K125.92,K125.93,K125.94,K125.95,K125.96,K125.97,K125.98,
K125.99,K125.100,K125.101,K125.102,K125.103,
K126.1,K126.2,K126.3,K126.4,K126.5,K126.6,K126.7,K126.8,K126.9,K126.10,
K126.11,K126.12,K126.13,K126.14,K126.15,K126.16,K126.17,K126.18,
K126.19,K126.20,K126.21,K126.22,K126.23,K126.24,K126.25,K126.26,
K126.27,K126.28,K126.29,K126.30,K126.31,K126.32,K126.33,K126.34,
K126.35,K126.36,K126.37,K126.38,K126.39,K126.40,K126.41,K126.42,
K126.43,K126.44,K126.45,K126.46,K126.47,K126.48,K126.49,K126.50,
K126.51,K126.52,K126.53,K126.54,K126.55,K126.56,K126.57,K126.58,
K126.59,K126.60,K126.61,K126.62,K126.63,K126.64,K126.65,K126.66,
K126.67,K126.68,K126.69,K126.70,K126.71,K126.72,K126.73,K126.74,
K126.75,K126.76,K126.77,K126.78,K126.79,K126.80,K126.81,K126.82,
K126.83,K126.84,K126.85,K126.86,K126.87,K126.88,K126.89,K126.90,
K126.91,K126.92,K126.93,K126.94,K126.95,K126.96,K126.97,K126.98,
K126.99,K126.100,K126.101,K126.102,K126.103,
K127.1,K127.2,K127.3,K127.4,K127.5,K127.6,K127.7,K127.8,K127.9,K127.10,
K127.11,K127.12,K127.13,K127.14,K127.15,K127.16,K127.17,K127.18,
K127.19,K127.20,K127.21,K127.22,K127.23,K127.24,K127.25,K127.26,
K127.27,K127.28,K127.29,K127.30,K127.31,K127.32,K127.33,K127.34,
K127.35,K127.36,K127.37,K127.38,K127.39,K127.40,K127.41,K127.42,
K127.43,K127.44,K127.45,K127.46,K127.47,K127.48,K127.49,K127.50,
K127.51,K127.52,K127.53,K127.54,K127.55,K127.56,K127.57,K127.58,
K127.59,K127.60,K127.61,K127.62,K127.63,K127.64,K127.65,K127.66,
K127.67,K127.68,K127.69,K127.70,K127.71,K127.72,K127.73,K127.74,
K127.75,K127.76,K127.77,K127.78,K127.79,K127.80,K127.81,K127.82,
K127.83,K127.84,K127.85,K127.86,K127.87,K127.88,K127.89,K127.90,
K127.91,K127.92,K127.93,K127.94,K127.95,K127.96,K127.97,K127.98,
K127.99,K127.100,K127.101,K127.102和K127.103.
除草剂(B)的施用量通常是已知的并且其常规范围为1g至8000g AS/ha(g AS/ha=g活性物质/公顷),优选范围为5g至5000gAS/ha。
在本发明的混合物中,在本文中所述的施用量中,相比单个施用而言,需要所述活性化合物的更低施用量。重量比(A)∶(B)取决于有效施用量,通常范围为1∶8000至800∶1,优选1∶100至100∶1,尤其是1∶50至50∶1。
优选一种或多种化合物(A)与一种或多种组(B1)或(B2)或(B3)的化合物的除草组合物。
进一步优选根据如下方案的化合物(A)与一种或多种化合物(B)的组合物:
(A)+(B1)+(B2)、(A)+(B1)+(B3)、(A)+(B2)+(B3)或(A)+(B1)+(B2)+(B3)。
本发明的组合物可以进一步与其它活性化合物一起使用,例如除草剂、安全剂、杀真菌剂、杀虫剂和植物生长调节剂,或制剂助剂和植物保护中常规添加剂。
添加剂为例如肥料和着色剂。本发明尤其重要的加入一种或多种其它不同结构的活性化合物或安全剂[活性化合物(C)]的组合物,例如根据如下方案:
(A)+(B1)+(C)、(A)+(B2)+(C)、(A)+(B3)+(C)、(A)+(B1)+(B2)+(C)、(A)+(B1)+(B3)+(C)、(A)+(B2)+(B3)+(C)或(A)+(B1)+(B2)+(B3)+(C)。
对于具有三种或多种活性化合物的最后所述类型的组合物而言,若其含有本发明的两种化合物的组合物,并且相对于所述的两种化合物的组合物而言,如下所述的优选条件尤其也适用于本发明的两种化合物的组合物。
在某些情形下,基于两种化合物的组合物而言,即使组(A)的不同活性化合物的组合物是增效的,具有其它增效作用的尤其有利的三种化合物的组合物是可能的。
优选适用于非选择性施用的活性化合物(A)和(B)的组合物。
尤其优选活性化合物(A)与选自下组的活性化合物(B)的组合物:
西玛津(B1.1.4)、二甲戊灵(B1.1.7)、丙炔草酮(B1.1.8)、异酰草胺(B1.2.1)、甲酰氨磺隆(B2.1.5)、碘磺隆(B2.1.6)、碘磺隆钠盐(B2.1.6.2)、氨唑草酮(B2.1.7)、丙苯磺隆(B2.1.8)、丙苯磺隆钠盐(B2.1.8.1)、赛克津(B2.1.9)、草铵膦(B2.1.1)、草铵膦铵盐(B2.1.1.1)、草甘膦(B2.1.2)、草甘膦-异丙铵盐(B2.1.2.1)、甲嘧磺隆(B2.1.3)、甲磺隆(B2.1.10)、甲磺隆甲酯(B2.1.10.1)、咪唑烟酸(B2.1.12)、咪唑烟酸(B2.1.12.1)、咪唑烟酸-异丙铵盐(B2.1.12.2)、百草枯(B2.1.13)、百草枯二氯化物(B2.1.13.1)、三氯吡氧乙酸(B2.2.3)、三氯吡氧乙酸(B2.2.3.1)、三氯吡氧乙酸-三乙基铵盐(B2.2.3.2)、定草酯(B2.2.3.3)、酰嘧磺隆(B2.2.7)、杀草强(B2.2.14)、敌草隆(B3.2)、乙氧氟草醚(B3.1.1)、草酮(B3.1.8)、吡氟酰草胺(B3.1.9)、除草定(B3.3)和氟草敏(B3.4)。
本发明尤其优选的是活性化合物(A)与选自下组的活性化合物(B)的组合物:
丙炔草酮(B1.1.8)、草铵膦(B2.1.1)、草铵膦铵盐(B2.1.1.1)、草甘膦(B2.1.2)、草甘膦-异丙铵盐(B2.1.2.1)、甲嘧磺隆(B2.1.3)、甲酰氨磺隆(B2.1.5)、碘磺隆(B2.1.6)、碘磺隆钠盐(B2.1.6.2)、氨唑草酮(B2.1.7)、丙苯磺隆(B2.1.8)、丙苯磺隆钠盐(B2.1.8.1)、赛克津(B2.1.9)、酰嘧磺隆(B2.2.7)、乙氧氟草醚(B 3.1.1)、草酮(B3.1.8)、吡氟酰草胺(B3.1.9)和敌草隆(B3.2),尤其是草铵膦(B2.1.1)、草铵膦铵盐(B2.1.1.1)、草甘膦(B2.1.2)、草甘膦-异丙铵盐(B2.1.2.1)、甲嘧磺隆(B2.1.3)和乙氧氟草醚(B3.1.1)。
本发明的除草组合物也可以与其它的除草剂和植物生长调节剂相组合,例如以扩大活性谱。
这类其它组合组分的实例是具有组合物中所包含的除草剂(B)的不同结构的除草活性化合物或植物生长调节剂,其描述于例如手册“The Pesticide Manual(农药手册)”,第13版,2003,The BritishCrop Protection Council,或the e-Pesticide Manual Version 3(2003)中,或另外在“Compendium of Pesticide Common Names”(通过互联网可查询的)中以及在所引用文献中的商品名和“通用名”。
下面实例所述的除草剂和植物生长调节剂是根据“国际标准化组织”(ISO)以标准活性化合物名称,或通过其化学名称或代码来表示的:
乙草胺(acetochlor)、三氟羧草醚(acifluorfen(-sodium))、苯草醚(aclonifen)、AKH 7088,即[[[1-[5-[2-氯基-4-(三氟甲基)苯氧基]-2-硝苯基]-2-甲氧基亚乙基]氨基]氧基]乙酸及其甲酯、甲草胺(alachlor)、禾草灭(alloxydim(-sodium))、莠灭净(ametryn)、氨唑草酮(amicarbazone)、amidochlor、酰嘧磺隆(amidosulfuron)、aminopyralid、杀草强(amitrol(氨基三嗪))、AMS(即氨基磺酸酯)、莎稗磷(anilofos)、磺草灵(asulam)、莠去津(atrazine)、唑啶草酮(azafenidin)、四唑嘧磺隆(azimsulfuron)(DPX-A8947)、叠氮津(aziprotryn)、燕麦灵(barban)、BAS 516H,即5-氟-2-苯基-4H-3,1-苯并嗪-4-酮、氟丁酰草胺(beflubutamid)、草除灵(benazolin(-ethyl))、氟草胺(benfluralin)、呋草黄(benfuresate)、苄嘧磺隆(bensulfuron(-甲基))、地散磷(bensulide)、灭草松(bentazone(-sodium))、双苯嘧草酮(benzfendizone)、benzobicyclone、吡草酮(benzofenap)、氟磺胺草(benzofluor)、新燕灵(benzoylprop(-ethyl))、噻草隆(benzthiazuron)、双丙氨酰膦(bialaphos(bilanafos))、治草醚(bifenox)、双嘧苯甲酸(bispyribac(-sodium))、除草定(bromacil)、溴丁酰草胺(bromobutide)、杀草全(bromofenoxim)、溴苯腈(bromoxynil)、bromuron、特克草(buminafos)、羟草酮(busoxinone)、丁草胺(butachlor)、butafenacil、抑草膦(butamifos)、丁烯草胺(butenachlor)、草噻咪(buthidazole)、地乐胺(butralin)、丁苯草酮(butroxydim)、苏达灭(butylate)、唑酰草胺(cafenstrole)(CH-900)、双酰草胺(carbetamide)、唑酮草酯(carfentrazone(-ethyl))、醌肟草(caloxydim)、CDAA(即2-氯-N,N-二-2-丙烯基乙酰胺)、CDEC(即二乙基二硫代氨基甲酸-2-氯烯丙酯)、甲氧除草醚(chlomethoxyfen)、草灭平(chloramben)、炔禾灵丁酯(chlorazifop-butyl)、氯溴隆(chlorbromuron)、氯草灵(chlorbufam)、伐草克(chlorfenac)、chlorfenprop、氯甲丹(chlorflurenol-甲基)、杀草敏(chloridazon)、氯嘧黄隆(chlorimuron(-ethyl))、草枯醚(chlornitrofen)、绿麦隆(chlorotoluron)、枯草隆(chloroxuron)、氯苯胺灵(chlorpropham)、氯磺隆(chlorsulfuron);敌草索二甲酯(chlorthal-dimethyl)、草克乐(chlorthiamid)、绿麦隆(chlortoluron)、cinidon(-methyl或-ethyl)、环庚草醚(cinmethylin)、醚黄隆(cinosulfuron)、烯草酮(clethodim)、clefoxydim、炔草酯(clodinafop)及其酯衍生物(例如炔草丙酯)、异草松(clomazone)、稗草胺(clomeprop)、调果酸(cloprop)、环己烯草酮(cloproxydim)、二氯吡啶酸(clopyralid)、clopyrasulfuron(-methyl)、唑嘧磺胺(cloransulam(-methyl))、cumyluron(JC 940)、草净津(cyanazine)、草灭特(cycloate)、环丙黄隆(cyclosulfamuron)(AC 104)、噻草酮(cycloxydim)、环莠隆(cycluron)、氰氟草酯(cyhalofop)及其酯衍生物(例如丁酯,DEH-112)、莎草快(cyperquat)、环草津(cyprazine)、环唑草胺(cyprazole)、香草隆(daimuron)、2,4-D、2,4-DB、茅草枯(dalapon)、棉隆(dazomet)、甜菜安(desmedipham)、敌草净(desmetryn)、燕麦敌(di-allate)、麦草畏(dicamba)、敌草腈(dichlobenil)、2,4-滴丙酸(dichlorprop(-P))、禾草灵(diclofop)及其酯类(如禾草灵甲酯)、双氯磺草胺(diclosulam)、乙酰甲草胺(diethatyl(-ethyl))、枯莠隆(difenoxuron)、野燕枯(difenzoquat)、吡氟酰草胺(diflufenican)、氟吡草腙(diflufenzopyr)、唑隆(dimefuron)、哌草丹(dimepiperate)、二甲草胺(dimethachlor)、异戊乙净(dimethametryn)、噻吩草胺(dimethenamid)(SAN-582H)、噻吩草胺(dimethenamid(-P))、异草松(dimethazone)、噻节因(dimethipin)、dimexyflam、dimetrasulfuron、敌乐胺(dinitramine)、地乐酚(dinoseb)、特乐酚(dinoterb)、双甲酰草胺(diphenamid)、异丙净(dipropetryn)、草乃敌(diquat)、氟硫草定(dithiopyr)、敌草隆(diuron)、DNOC、草止津(eglinazine-ethyl)、EL 77(即5-氰基-1-(1,1-二甲乙基)-N-甲基-1H-吡唑-4-羧酰胺)、草藻灭(endothal)、epoprodan、EPTC、禾草畏(esprocarb)、丁氟消草(ethalfluralin)、胺苯黄隆(ethametsulfuron-methyl)、噻二唑隆(ethidimuron)、嗪丁草(ethiozin)、乙呋草黄(ethofumesate)、氯氟草醚(ethoxyfen)及其酯(例如乙酯,HC-252)、乙氧嘧磺隆(ethoxysulfuron)、乙氧苯草胺(etobenzanid(HW52))、F5231(即N-[2-氯-4-氟-5-[4-(3-氟丙基)-4,5-二氢-5-氧代-1H-四唑-1-基]苯基]乙基磺酰胺、2,4,5-涕丙酸(fenoprop)、fenoxan、唑禾草灵(fenoxaprop)及高唑禾草灵及其酯(例如高唑禾草灵乙酯和唑禾草灵乙酯)、fenoxydim、四唑酰草胺(fentrazamide)、非草隆(fenuron)、氟燕灵(flamprop(-methyl或-isopropyl或-isopropyl-L)、啶嘧黄隆(flazasulfuron)、双氟磺草胺(florasulam)、吡氟禾草灵(fluazifop)和精吡氟禾草灵及其酯类(例如吡氟禾草灵丁酯和精吡氟禾草灵丁酯)、fluazolate、flucarbazone(-sodium)、flucetosulfuron、氟消草(fluchloralin)、氟噻草胺(flufenacet(FOE 5043))、flufenpyr、氟唑啶草(flumetsulam)、flumeturon、酰亚胺苯氧乙酸(flumiclorac(-pentyl))、丙炔氟草胺(flumioxazin)(S-482)、flumipropyn、氟草隆(fluometuron)、氟咯草酮(fluorochloridone)、三氟硝草醚(fluorodifen)、乙羧氟草醚(fluoroglycofen(-ethyl))、氟胺草唑(flupoxam)(KNW-739)、flupropacil(UBIC-4243)、fluproanate、氟啶嘧磺隆(flupyrsulfuron(-methyl或-sodium))、抑草丁(flureno(-butyl))、氟草酮(fluridone)、氟咯草酮(flurochloridone)、氟草烟(fluroxypyr(-meptyl))、呋嘧醇(flurprimidol)、呋草酮(flurtamone)、达草氟(fluthiacet(-methyl))、噻唑草酰胺(fluthiamide)(也以氟噻草胺(flufenacet)公开)、氟黄胺草醚(fomesafen)、甲酰氨磺隆(foramsulfuron)、膦铵素(fosamine)、解草唑(furilazole(MON13900))、氟呋草醚(furyloxyfen)、草铵膦(glufosinate(-ammonium))、草甘膦(glyphosate(-isopropylammonium))、氟硝磺酰胺(halosafen)、吡氯黄隆(halosulfuron(-methyl))及其酯(例如甲酯,NC-319)、吡氟氯禾灵(haloxyfop)及其酯、精吡氟氯禾灵(即R-吡氟氯禾灵)及其酯、HC-252(diphenyl ether)、六嗪酮(hexazinone)、咪草酸甲酯(imazamethabenz-(methyl))、imazamethapyr、甲氧咪草烟(imazamox)、imazapic、灭草烟(imazapyr)、灭草喹(imazaquin)及盐类如铵盐、imazethamethapyr、咪唑乙烟酸(imazethapyr)、咪唑磺隆(imazosulfuron)、茚草酮(indanofan)、碘磺隆(iodosulfuron-(methyl)-(sodium))、碘苯腈(ioxynil)、丁环隆(isocarbamid)、异乐灵(isopropalin)、异丙隆(isoproturon)、异隆(isouron)、异草胺(isoxaben)、异氯草酮(isoxachlortole)、异唑草酮(isoxaflutole)、异草醚(isoxapyrifop)、特胺灵(karbutilate)、乳氟禾草灵(lactofen)、环草定(lenacil)、利谷隆(linuron)、2甲4氯(MCPA)、MCPA-thioethyl、2甲4氯丁酸(MCPB)、2甲4氯丙酸(mecoprop(-P))、苯噻草胺(mefenacet)、氟草磺(mefluidid)、mepisulfuron(LGC-42153)、叠磺隆(mesosulfuron(-methyl))、甲基磺草酮(mesotrione)、威百亩(metam)、metamifop、苯嗪草酮(metamitron)、吡草胺(metazachlor)、噻唑隆(methabenzthiazuron)、灭草唑(methazole)、去草酮(methoxyphenone)、甲基杀草隆(methyldymron)、色满隆(metobenzuron)、秀谷隆(metobromuron)、异丙甲草胺((S-)metolachlor)、唑草磺胺(metosulam)(XRD 511)、甲氧隆(metoxuron)、嗪草酮(metribuzin)、甲黄隆(metsulfuron-methyl)、MK-616、禾草敌(molinate);杀草利(monalide)、单脲硫酸二氢酯(monocarbamide dihydrogensulfate)、绿谷隆(monolinuron)、灭草隆(monuron)、MT 128(即6-氯-N-(3-氯-2-丙烯基)-5-甲基-N-苯基-3-哒嗪胺)、MT 5950(即N-[3-氯代-4-(1-甲基乙基)-苯基]-2-甲基戊酰胺)、萘丙胺(naproanilide)、敌草胺(napropamide)、萘草胺(naptalam)、NC 310(即4-(2,4-二氯苯甲酰基)-1-甲基-5-苄氧基吡唑)、草不隆(neburon)、烟嘧黄隆(nicosulfuron)、nipyraclophen、磺乐灵(nitralin)、除草醚(nitrofen)、硝氟草醚(nitrofluorfen)、达草灭(norflurazon)、坪草丹(orbencarb)、氨磺乐灵(oryzalin)、炔丙唑草(oxadiargyl)(RP-020630)、草酮(oxadiazone)、环氧嘧磺隆(oxasulfuron)、嗪草酮(oxaziclomefone)、乙氧氟草醚(oxyfluorfen)、百草枯(paraquat)、克草猛(pebulate)、壬酸(pelargonic acid)、胺硝草(pendimethalin)、penoxulam、甲氯酰草胺(pentanochlor)、环戊草酮(pentoxazone)、氟草磺胺(perfluidone)、pethoxamid、棉胺宁(phenisopham)、苯敌草(phenmedipham)、氨氯吡啶酸(picloram)、picolinafen、pinoxaden(NOA-407855=flucetsulfuron)、派草磷(piperophos)、piributcarb、pirifenop-butyl、丙草胺(pretilachlor)、氟嘧黄隆(primisulfuron(-methyl))、丙苯磺隆(procarbazone(-sodium))、环氰津(procyazine)、氨基丙氟灵(prodiamine)、profluazole、环丙氟灵(profluralin)、丙草止津(proglinazine(-ethyl))、扑灭通(prometon)、扑草净(prometryn)、毒草安(propachlor)、敌稗(propanil)、草酸(propaquizafop)、扑草津(propazine)、苯胺灵(propham)、异丙草胺(propisochlor)、propoxycarbazone(-sodium)、炔苯酰草胺(propyzamide)、磺亚胺草(prosulfalin)、苄草丹(prosulfocarb)、氟磺隆(prosulfuron)(CGA-152005)、丙炔草胺(prynachlor)、双唑草腈(pyraclonil)、氟唑草酯(pyraflufen(-ethyl))、吡唑特(pyrazolinate)、杀草敏(pyrazon)、吡嘧黄隆(pyrazosulfuron(-ethyl))、苄草唑(pyrazoxyfen)、嘧啶肟草醚(pyribenzoxim)、稗草丹(pyributicarb)、pyridafol、哒草特(pyridate)、环酯草醚(pyriftalid)、pyrimidobac(-methyl)、嘧草硫醚(pyrithiobac(-sodium))(KIH-2031)、pyroxofop及其酯(例如炔丙酯)、二氯喹啉酸(quinclorac)、喹草酸(quinmerac)、灭藻醌(quinoclamine)、quinofop及其酯衍生物、喹禾灵(quizalofop)和精喹禾灵及其酯衍生物例如喹禾灵乙酯、精喹禾灵四氢糠基酯和精喹禾灵乙酯、renriduron、砜嘧黄隆(rimsulfuron)(DPX-E9636)、S275(即2-[4-氯-2-氟-5-(2-丙炔基氧基)苯基]-4,5,6,7-四氢-2H-吲唑)、仲丁通(secbumeton)、烯禾定(sethoxydim)、环草隆(siduron)、西玛津(simazine)、西草净(simetryn)、SN 106279(即2-[[7-[2-氯-4-(三氟甲基)苯氧基]-2-萘基]氧基]丙酸及其甲酯)、磺草酮(sulcotrione)、磺胺草唑(sulfentrazone)(FMC-97285,F-6285)、sulfazuron、嘧黄隆(sulfometuron(-methyl))、甲嘧磺隆(sulfosate)(ICI-A0224)、磺酰磺隆(sulfosulfuron)、TCA、牧草胺(tebutam)(GCP-5544)、丁噻隆(tebuthiuron)、tepraloxydim、特草定(terbacil)、特草灵(terbucarb)、仲丁草胺(terbuchlor)、特丁通(terbumeton)、特丁津(terbuthylazine)、去草净(terbutryn)、TFH 450(即N,N-二乙基-3-[(2-乙基-6-甲基苯基)磺酰基]-1H-1,2,4-三唑-1-羧酰胺)、噻醚草胺(thenylchlor)(NSK-850)、thiafluamide、噻氟隆(thiazafluron)、噻唑烟酸(thiazopyr)(Mon-13200)、噻二唑草胺(thidiazimin)(SN-24085)、噻苯隆(thidiazuron)、噻吩磺隆(thifensulfuron(-methyl))、杀草丹(thiobencarb)、仲草丹(tiocarbazil)、topramezone(BAS-670H)、三甲苯草酮(tralkoxydim)、野麦畏(tri-allate)、醚苯黄隆(triasulfuron)、三嗪氟草胺(triaziflam)、triazofenamide、苯磺隆(tribenuron(-methyl))、2,3,6-三氟氯苯甲酸(2,3,6-TBA)、三氯吡氧乙酸(triclopyr)、灭草环(tridiphane)、草达津(trietazine)、三氟啶磺隆(trifloxysulfuron(-sodium))、氟乐灵(trifluralin)、氟胺黄隆(triflusulfuron)及其酯(例如甲酯,DPX-66037)、三甲隆(trimeturon)、三氟甲磺隆(tritosulfuron)、tsitodef、灭敌草(vernolate)、WL 110547(即5-苯氧基-1-[3-(三氟甲基)苯基]-1H-四唑、HOK-201、HOK-202、UBH-509、D-489、LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0774、TH-547、DOWCO-535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127、KIH-2023和KIH5996。
若各名称(通用名)包括超过一种形式的活性化合物,则该名称优选定义为市售形式。
根据图示(A)+(B)+(C*)或另外根据图示(A)+(B)+(C1*)+(C2*)等,则所述的各种其它活性化合物(=活性化合物(C*)、(C1*)、(C2*)等)可以优选与两种化合物的组合物K1.1至K127.103之一相组合。本发明还包括其中化合物(C*)、(C1*)或(C2*)选自化合物(B)组的多元组合物,但存在于各两种化合物的组合物中的化合物(B)不相同。
活性化合物(A)与多种活性化合物(B)的多元组合物为,例如:
(A)+(B3.2)+(B2.1.4),优选(A)+敌草隆(B3.2)+MSMA(B2.1.4.1),尤其以1-800g AS/ha(A)和500-2000g AS/ha(B3.2)和1000-3000g AS/ha(B2.1.4.1)的量;
(A)+(B3.2)+(B2.1.13),优选(A)+敌草隆(B3.2)+百草枯二氯化物(B2.1.13.1),尤其以1-800g AS/ha(A)和100-500g AS/ha(B3.2)和100-1000g AS/ha(B2.1.13.1)的量;
(A)+(B3.2)+(B2.2.14),优选(A)+敌草隆(B3.2)+杀草强(B2.2.14),以1-800g AS/ha(A)和100-500g AS/ha(B3.2)和100-500g AS/ha(B2.2.14)的量;
(A)+(B3.2)+(B2.1.1),优选(A)+敌草隆(B3.2)+草铵膦铵盐(B2.1.1.1),尤其以1-800g AS/ha(A)和500-2000g AS/ha(B3.2)和100-1000g AS/ha(B2.1.1.1)的量;
(A)+(B3.2)+(B2.1.2),优选(A)+敌草隆(B3.2)+草甘膦异丙铵盐(B2.1.2.1),尤其以1-800g AS/ha(A)和500-2000g AS/ha(B3.2)和500-1500g AS/ha(B2.1.2.1)的量;
(A)+(B3.2)+(B2.1.2)+石油,优选(A)+敌草隆(B3.2)+草甘膦异丙铵盐(B2.1.2.1)+矿物油,尤其以1-800g AS/ha(A)和500-2000g AS/ha(B3.2)和500-1500g AS/ha(B2.1.2.1)和100-500g/ha矿物油的量;
(A)+(B3.1.9)+(B2.1.2),优选(A)+吡氟酰草胺(B3.1.9)+草甘膦异丙铵盐(B2.1.2.1),尤其以1-800g AS/ha(A)和50-500gAS/ha(B3.1.9)和500-1500g AS/ha(B2.1.2.1)的量;
(A)+(B1.1.4)+(B3.1.10),优选(A)+西玛津(B1.1.4)+莠灭净(B3.1.10),以1-800g AS/ha(A)和1000-2500g AS/ha(B1.1.4)和1000-2500g AS/ha(B3.1.10)的量;
(A)+(B1.2.1)+(B1.1.10),优选(A)+异酰草胺(B1.2.1)+氨磺乐灵(B1.1.10),以1-800g AS/ha(A)和10-250g AS/ha(B1.2.1)和1000-3500g AS/ha B1.1.10)的量;
(A)+(B3.1.1)+(B1.1.10),优选(A)+乙氧氟草醚(B3.1.1)+氨磺乐灵(B1.1.10),尤其以1-800g AS/ha (A)和500-2000g AS/ha(B3.1.1)和1000-5000g AS/ha(B1.1.10)的量。
所述的量是施用量(g AS/ha=活性化合物克/公顷),并且也如此定义在共制剂、预混物、桶混物或组合活性化合物的顺序施用中的比例。
该组合物可以采用苗前方法和苗后方法施用。该组合物苗前和苗后施用于有害植物,并且在选择性控制有害植物中,将该组合物苗前或苗后施用于作物。混合形式也是可以的,例如在作物出苗后于有害植物苗前或苗后阶段进行控制。
其它适宜的组合组分包括植物保护活性化合物(称为“安全剂”或“解毒剂”),其能防止或降低除草剂在作物中的植物毒性作用。
适用于本发明上述除草活性化合物(A)或除草剂(A)和(B)的组合物或常规组合物的安全剂为,例如下组化合物:
a)二氯苯基吡唑啉-3-羧酸类化合物,优选化合物例如描述于WO-A 91/07874中的1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1)(“吡咯二酸二乙酯”,PM,第622-623页),以及相关化合物;
b)二氯苯基吡唑羧酸衍生物,优选化合物例如EP-A-333 131和EP-A-269 806中所描述的1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5),以及相关化合物;
c)三唑羧酸类化合物,优选化合物例如解草唑(乙酯),即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)以及相关化合物(EP-A-174 562和EP-A-346 620);
d)5-苄基-或5-苯基-2-异唑啉-3-羧酸类或5,5-二苯基-2-异唑啉-3-羧酸化合物,优选化合物例如描述于WO91/08202中的5-(2,4-二氯苄基)-2-异唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异唑啉-3-羧酸酯(S1-8)以及相关化合物,或描述于德国专利申请(WO-A-95/07897)中的5,5-二苯基-2-异唑啉羧酸乙酯(S1-9)(″双苯羧酸乙酯″,PM,第588页)或5,5-二苯基-2-异唑啉羧酸正丙酯(S1-10),或5-(4-氟苯基)-5-苯基-2-异唑啉-3-羧酸乙酯(S1-11)。
e)8-喹啉氧基乙酸类化合物(S2),优选化合物如描述于EP-A-86750、EP-A-94 349和EP-A-191 736或EP-A-492 366中的(5-氯-8-喹啉氧基)1-甲基己-1-基乙酸酯(通用名“解草酯”(S2-1)(参见PM,第196-197页),
(5-氯-8-喹啉氧基)乙酸-1,3-二甲基丁-1-基酯(S2-2),
(5-氯-8-喹啉氧基)乙酸-4-烯丙氧基丁基酯(S2-3),
(5-氯-8-喹啉氧基)乙酸-1-烯丙氧基丙-2-基酯(S2-4),
(5-氯-8-喹啉氧基)乙酸-乙酯(S2-5),
(5-氯-8-喹啉氧基)乙酸甲酯(S2-6),
(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7),
(5-氯-8-喹啉氧基)乙酸2-(2-亚丙基亚氨基氧基)-1-乙基酯(S2-8),
(5-氯-8-喹啉氧基)乙酸2-氧代-丙-1-基酯(S2-9),
以及相关化合物。
f)(5-氯-8-喹啉氧基)丙二酸类化合物,优选化合物描述于EP-A-0 582 198中的(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)丙二酸甲基乙基酯以及相关化合物,
g)苯氧基乙酸或-丙酸衍生物或芳族羧酸活性化合物,例如2,4-二氯苯氧基乙酸(酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2甲4氯丙酸)、MCPA或3,6-二氯-2-甲氧基苯甲酸(酯)(麦草畏),
h)吡啶类活性化合物,例如“解草啶”(PM,第406页)(=4,6-二氯-2-苯基吡啶),
i)二氯乙酰胺类活性化合物,例如,
“烯丙酰草胺”(PM,第284页)(=N,N-二烯丙基-2,2-二氯乙酰胺),
“R-29148”(=3-二氯乙酰基-2,2,5-三甲基-1,3-唑烷,其来自Stauffer),
“解草嗪”(PM,第72-73页)(=4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并嗪),
“PPG-1292”(=N-烯丙基-N-[(1,3-二氧杂环戊烷-2-基)甲基]二氯乙酰胺,其来自PPG公司),
“DK-24”(=N-烯丙基-N-[(烯丙基氨基羰基)甲基]二氯乙酰胺,来自Sagro-Chem公司),
“AD-67”或“MOM 4660”(=3-二氯乙酰基-1-氧杂-3-氮杂螺[4,5]癸烷,来自Nitrokemia或Monsanto),
“diclonon”或“BAS145138”或“LAB145138”(=3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷,来自BASF)和
“解草唑”或“MON 13900”(参见PM,507)(=(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基唑烷),
j)二氯丙酮衍生物类活性化合物,例如
“MG 191”(CAS Reg.No.96420-72-3)(=2-二氯甲基-2-甲基-1,3-二氧杂环戊烷,来自Nitrokemia),
k)氧亚氨基化合物类的活性化合物,它们已知用作拌种剂,例如,
“解草腈”(PM,第724-725页)(=(Z)-1,3-二氧杂环戊烷-2-基甲氧亚氨基(苯基)乙腈,
“氟草肟”(PM,第490页)(=1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧杂环戊烷-2-基甲基)肟,以及
“解草胺腈”或“-CGA-43089”(PM,第1056页)(=(Z)-氰基甲氧亚氨基(苯基)乙腈),
l)噻唑羧酸酯类活性化合物,已知其用作拌种剂,例如
“解草胺”(PM,第473-474页)(=2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯),已知其作为拌种安全剂以防止甲草胺和异丙甲草胺所引起的损害,
m)萘二羧酸衍生物类活性化合物,已知其用作拌种剂,例如“萘二甲酐”(PM,第1083页)(=1,8-萘二甲酸酐),
n)色满乙酸衍生物类活性化合物,例如
“CL 304415”(CAS Reg.No.31541-57-8)(=2-(4-羧基色满-4-基)乙酸,来自American Cyanamid),
o)具有控制有害植物的部分除草活性作用的活性化合物,例如
“派草丹”或“MY-93”(PM,第315-317页)(=S-1-甲基-1-苯基乙基派啶-1-硫代羧酸酯),
“香草隆”或“SK 23”(PM,第259页)(=1-(1-甲基-1-苯基乙基)-3-对-甲苯基脲),
“苄草隆”=“JC-940”(=3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲,参见JP-A-60087254),
“苯草酮”或“NK 049”(=3,3’-二甲基-4-甲氧基二苯甲酮),
“CSB”(=1-溴-4-(氯甲基磺酰基)苯)(CAS Reg.No.54091-06-4,来自Kumiai),
p)式(S3)的N-酰基磺酰胺类化合物及其盐,

其已知于例如WO-A-97/45016中,和
q)式(S4)的酰基氨磺酰基苯甲酰胺类化合物或其盐,

其已知于例如WO-A-99/16744中,例如化合物4-(2-甲氧基苯甲酰基氨磺酰基)-N-环丙基苯甲酰胺(S3)。
在上述的安全剂中,(S1-1)、(S1-9)、(S2-1)和(S3),尤其是(S1-1)和(S1-9)是特别优选的。
部分安全剂已经如上所述作为除草剂,因此除对有害植物的除草作用外,其还具有对作物的保护作用。
根据图示(A)+(B)+(C),所述的组a)至q)的各种安全剂可以作为其它活性化合物(C)优选与所述的两种化合物的组合物K1.1至K127.103之一相组合,所述的两种化合物的组合物含有具有不同于所述化合物(C)结构的化合物(B)。
本发明的除草组合物可以包含其它组分,例如其它控制有害生物体例如有害植物、损害植物的动物或损害植物的真菌的活性化合物,尤其是选自除草剂、杀真菌剂、杀虫剂、杀螨剂、杀线虫剂和杀螨剂,以及相关物质的活性化合物。
可以用于与本发明除草组合物相组合的杀真菌活性化合物优选是市售活性化合物,例如(类似于除草剂,活性化合物通常由其通用名来表示):
2-苯基苯酚(2-phenylphenol);8-羟基喹啉硫酸盐(8-hydroxyquinoline sulfate);acibenzolar-S-methyl;actinovate;aldimorph;amidoflumet;氨丙膦酸(ampropylfos);氨丙膦酸钾(ampropylfos-potassium);andoprim;敌菌灵(anilazine);氧唑环(azaconazole);嘧菌酯(azoxystrobin);苯霜灵(benalaxyl);麦锈灵(benodanil);苯菌灵(benomyl);benthiavalicarb-isopropyl;苄烯酸(benzamacril);苄烯酸-异丁酯(benzamacril-isobutyl);乐杀螨(binapacryl);联苯(biphenyl);联苯三唑醇(bitertanol);灭瘟素(blasticidin-S);boscalid;糠菌素(bromuconazole);硫嘧菌灵(bupirimate);丁硫啶(buthiobate);氨丁烷(butylamine);石硫合剂(calciumpolysulfide);capsimycin;敌菌丹(captafol);克菌丹(captan);多菌灵(carbendazim);萎锈灵(carboxin);环丙酰菌胺(carpropamid);carvone;灭螨锰(chinomethionat);灭瘟唑(chlobenthiazone);苯咪唑菌(chlorfenazole);地茂散(chloroneb);百菌清(chlorothalonil);乙菌利(chlozolinate);顺式-1-(4-氯苯基)-2-(1H-1,2,4-三唑-1-基)环庚醇;clozylacon;氰霜唑(cyazofamid);cyflufenamid;霜脲氰(cymoxanil);环丙唑醇(cyproconazole);嘧菌环胺(cyprodinil);酯菌胺(cyprofuram);咪草酯(Dagger G);咪菌威(debacarb);苯氟磺胺(dichlofluanid);二氯萘醌(dichlone);双氯酚(dichlorophen);双氯氰菌胺(diclocymet);哒菌酮(diclomezine);氯硝胺(dicloran);乙霉威(diethofencarb);苯嘧甲环唑(difenoconazole);diflumetorim;二甲嘧酚(dimethirimol);烯酰啉(dimethomorph);dimoxystrobin;烯唑醇(diniconazole);烯唑醇-M(diniconazole-M);二硝酯(dinocap);二苯胺(diphenylamine);吡菌硫(dipyrithione);灭菌磷(ditalimfos);二氰蒽醌(dithianon);多果定(dodine);肼菌酮(drazoxolon);克瘟散(edifenphos);氟环唑(epoxiconazole);噻唑菌胺(ethaboxam);乙嘧酚(ethirimol);土菌灵(etridiazole);唑菌酮(famoxadone);咪唑菌酮(fenamidone);咪菌腈(fenapanil);氯苯嘧啶醇(fenarimol);腈苯唑(fenbuconazole);甲呋酰胺(fenfuram);环酰菌胺(fenhexamid);种衣酯(fenitropan);氰菌胺(fenoxanil);fenpiclonil;苯锈啶(fenpropidin);丁苯吗啉(fenpropimorph);福美铁(ferbam);氟啶胺(fluazinam);氟螨噻(flubenzimine);咯菌腈(fludioxonil);氟酰菌胺(flumetover);氟吗啉(flumorph);氟氯菌核利(fluoromide);fluoxastrobin;氟喹唑(fluquinconazole);呋嘧醇(flurprimidol);氟硅唑(flusilazol);磺菌胺(flusulfamide);氟酰胺(flutolanil);粉唑醇(flutriafol);灭菌丹(folpet);藻菌磷(fosetyl-A1);藻菌磷(fosetyl-sodium);麦穗宁(fuberidazole);呋霜灵(furalaxyl);呋吡唑灵(furametpyr);灭菌胺(furcarbanil);拌种胺(furmecyclox);双胍盐(guazatine);六氯苯(hexachlorobenzene);己唑醇(hexaconazole);恶霉灵(hymexazol);抑霉唑(imazalil);亚胺唑(imibenconazole);双胍辛胺乙酸盐(iminoctadine triacetate);双八胍盐(iminoctadine tris(albesilate));iodocarb;种菌唑(ipconazole);异稻瘟净(iprobenfos);异菌脲(iprodione);异丙菌胺(iprovalicarb);irumamycin;稻瘟灵(isoprothiolane);氯苯咪菌酮(isovaledione);春雷霉素(kasugamycin);亚胺菌(kresoxim-methyl);代森锰锌(mancozeb);代森锰(maneb);meferimzone;嘧菌胺(mepanipyrim);灭锈胺(mepronil);甲霜灵(metalaxyl);精甲霜灵(metalaxyl-M);叶菌唑(metconazole);磺菌威(methasulfocarb);呋菌胺(methfuroxam);1-(2,3-二氢-2,2-二甲基-1H-茚-1-基)-1H-咪唑-5-甲酸甲酯;2-[[[环丙基[(4-甲氧基苯基)亚氨基]甲基]硫基]甲基]-α-(甲氧基亚甲基)苯乙酸甲酯;2-[2-[3-(4-氯苯基)-1-甲基-亚丙烯基氨基氧基甲基]苯基]-3-甲氧基丙烯酸甲酯;代森联(metiram);苯氧菌胺(metominostrobin);metrafenone;噻菌胺(metsulfovax);米多霉素(mildiomycin);碳酸单钾(monopotassium carbonate);腈菌唑(myclobutanil);甲菌利(myclozolin);代森钠(nabam);N-(3-乙基-3,5,5-三甲基环己基)-3-甲酰基氨基-2-羟基-苯甲酰胺;N-(6-甲氧基-3-吡啶基)环丙烷羧酰胺;N-丁基-8-(1,1-二甲基乙基)-1-氧杂螺[4.5]癸-3-胺;多马霉素(natamycin);异丙消(nitrothal-isopropyl);noviflumuron;氟苯嘧啶醇(nuarimol);呋酰胺(ofurace);orysastrobin;霜灵(oxadixyl);喹菌酮(oxolinicacid);咪唑(oxpoconazole);氧化萎锈灵(oxycarboxin);oxyfenthiin;多效唑(paclobutrazol);稻瘟酯(pefurazoate);戊菌唑(penconazole);戊菌隆(pencycuron);penthiopyrad;氯瘟磷(phosdiphen);四氯苯酞(phthalide);picobenzamid;picoxystrobin;病花灵(piperalin);多氧霉素(polyoxins);polyoxorim;噻菌灵(probenazole);咪鲜胺(prochloraz);腐霉利(procymidone);霜霉威(propamocarb);propanosine-sodium;丙环唑(propiconazole);丙森锌(propineb);proquinazid;prothioconazole;pyraclostrobin;吡菌磷(pyrazophos);啶斑肟(pyrifenox);嘧霉胺(pyrimethanil);咯喹酮(pyroquilon);氟吡呋醚(pyroxyfur);pyrrolnitrine;唑喹菌酮(quinconazole);苯氧喹啉(quinoxyfen);五氯硝基苯(quintozene);silthiofam;硅氟唑(simeconazole);四硫代碳酸钠(sodiumtetrathiocarbonate);螺茂胺(spiroxamine);硫(sulfur);戊唑醇(tebuconazole);叶枯酞(tecloftalam);四氯硝基苯(tecnazene);四环唑(tetcyclacis);四氟醚唑(tetraconazole);噻菌灵(thiabendazole);噻菌腈(thicyofen);噻氟菌胺(thifluzamide);硫菌灵(thiophanate-methyl);福美双(thiram);tiadinil;tioxymid;tolclofos-methyl;甲苯氟磺胺(tolylfluanid);三唑酮(triadimefon);三唑醇(triadimenol);丁基三唑(triazbutil);咪唑嗪(triazoxide);tricyclamide;三环唑(tricyclazole);十三吗啉(tridemorph);trifloxystrobin;氟菌唑(triflumizole);嗪氨灵(triforine);灭菌唑(triticonazole);烯效唑(uniconazole);有效霉素(validamycinA);乙烯菌核利(vinclozolin);代森锌(zineb);福美锌(ziram);苯酰菌胺(zoxamide);(2S)-N-[2-[4-[[3-(4-氯苯基)-2-丙炔基]氧基]-3-甲氧基苯基]乙基]-3-甲基-2-[(甲基磺酰基)氨基]-丁酰胺;1-(1-萘基)-1H-吡咯-2,5-二酮;2,3,5,6-四氯-4-(甲基磺酰基)吡啶;2,4-二氢-5-甲氧基-2-甲基-4-[[[[1-[3-(三氟甲基)苯基]亚乙基]氨基]氧基]甲基]苯基]-3H-1,2,3-三唑-3-酮;2-氨基-4-甲基-N-苯基-5-噻唑甲酰胺;2-氯-N-(2,3-二氢-1,1,3-三甲基-1H-茚-4-基)-3-吡啶甲酰胺;3,4,5-三氯-2,6-吡啶二腈;3-[(3-溴-6-氟-2-甲基-1H-吲哚-1-基)磺酰基]-N,N-二甲基-1H-1,2,4-三唑-1-磺酰胺;铜盐和铜制品,例如波尔多液混合物;氢氧化铜;环烷酸铜;氯氧化铜;硫酸铜;硫杂灵;氧化铜(I);代森锰铜;喹啉铜。
优选的杀真菌剂选自下组:苯霜灵(benalaxyl)、联苯三唑醇(bitertanol)、糠菌唑(bromuconazole)、敌菌丹(captafol)、多菌灵(carbendazim)、环丙酰菌胺(carpropamid)、氰霜唑(cyazofamid)、环丙唑醇(cyproconazole)、乙霉威(diethofencarb)、敌瘟磷(edifenphos)、丁苯吗啉(fenpropimorph)、毒菌锡(fentine)、氟喹唑(fluquinconazole)、藻菌磷(fosetyl)、fluoroimide、灭菌丹(folpet)、双瓜辛胺(iminoctadine)、iprodionem、异丙菌胺(iprovalicarb)、春雷霉素(kasugamycin)、代森锰(maneb)、代森钠(nabam)、戊菌隆(pencycuron)、咪鲜胺(prochloraz)、霜霉威(propamocarb)、丙森锌(propineb)、嘧霉胺(pyrimethanil)、螺环菌胺(spiroxamine)、五氯硝基苯(quintozene)、戊唑醇(tebuconazole)、甲苯氟磺胺(tolylfluanid)、三唑酮(triadimefon)、三唑醇(triadimenol)、肟菌酯(trifloxystrobin)、代森锌(zineb)。
杀虫剂、杀螨剂、杀线虫剂、杀螨剂和相关活性化合物为例如(类似于除草剂和杀真菌剂,化合物任选地以其通用名来表示):
棉铃威(alanycarb),涕灭威(aldicarb),涕灭砜威(aldoxycarb),除害威(allyxycarb),灭害威(aminocarb),虫威(bendiocarb),丙硫克百威(benfuracarb),合必威(bufencarb),畜虫威(butacarb),丁酮威(butocarboxim),丁酮砜威(butoxycarboxim),甲萘威(carbaryl),克百威(carbofuran),丁硫克百威(carbosulfan),cloethocarb,敌蝇威(dimetilan),乙硫苯威(ethiofencarb),仲丁威(fenobucarb),苯硫威(fenothiocarb),伐虫脒(formetanate),呋线威(furathiocarb),异丙威(isoprocarb),威百亩(metam-sodium),甲硫威(methiocarb),灭多威(methomyl),速灭威(metolcarb),杀线威(oxamyl),抗蚜威(pirimicarb),猛杀威(promecarb),残杀威(propoxur),硫双威(thiodicarb),久效威(thiofanox),混杀威(trimethacarb),XMC,灭杀威(xylylcarb),乙酰乙胺磷(acephate),甲基吡磷(azamethiphos),谷硫磷(azinphos(-甲酯,-乙酯),溴硫磷乙酯(bromophos-ethyl),bromfenvinfos(-methyl),特嘧硫磷(butathiofos),硫线磷(cadusafos),三硫磷(carbophenothion)、氯氧磷(chlorethoxyfos)、毒虫畏(chlorfenvinphos)、氯甲硫磷(chlormephos)、毒死蜱(chlorpyrifos(-methyl/-ethyl))、蝇毒磷(coumaphos)、苯腈磷(cyanofenphos)、杀螟腈(cyanophos)、毒虫畏(chlorfenvinphos)、甲基一0五九(demeton-S-methyl)、磺吸磷(demeton-S-methylsulphon)、氯亚胺硫磷(dialifos)、二嗪磷(diazinon)、除线磷(dichlofenthion)、敌敌畏/DDVP、百治磷(dicrotophos)、乐果(dimethoate)、甲基毒虫畏(dimethylvinphos)、蔬果磷(dioxabenzofos)、乙拌磷(disulfoton)、EPN、乙硫磷(ethion)、灭线磷(ethoprophos)、乙嘧硫磷(etrimfos)、伐灭磷(famphur)、苯线磷(fenamiphos)、杀螟硫磷(fenitrothion)、线虫磷(fensulfothion)、倍硫磷(fenthion)、吡氟硫磷(flupyrazofos)、地虫硫磷(fonofos)、安硫磷(formothion)、丁苯硫磷(fosmethilan)、噻唑磷(fosthiazate)、庚烯磷(heptenophos)、碘硫磷(iodofenphos)、异稻瘟净(iprobenfos)、氯唑磷(isazofos)、异柳磷(isofenphos)、异丙基O-水杨酸盐(isopropyl O-salicylate)、唑磷(isoxathion)、马拉硫磷(malathion)、灭蚜磷(mecarbam)、虫螨畏(methacrifos)、甲胺磷(methamidophos)、杀扑磷(methidathion)、速灭磷(mevinphos)、久效磷(monocrotophos)、二溴磷(naled)、氧乐果(omethoate)、砜吸磷(oxydemeton-methyl)、对硫磷(parathion(-methyl/-ethyl))、稻丰散(phenthoate)、甲拌磷(phorate)、伏杀硫磷(phosalone)、亚胺硫磷(phosmet)、磷胺(phosphamidon)、磷虫威(phosphocarb)、辛硫磷(phoxim)、嘧啶磷(pirimiphos(-methyl/-ethyl))、丙溴磷(profenofos)、丙虫磷(propaphos)、胺丙畏(propetamphos)、丙硫磷(prothiofos)、发硫磷(prothoate)、吡唑硫磷(pyraclofos)、哒嗪硫磷(pyridaphenthion)、pyridathion、喹硫磷(quinalphos)、硫线磷(sebufos)、治螟磷(sulfotep)、硫丙磷(sulprofos)、丁基嘧啶磷(tebupirimfos)、双硫磷(temephos)、特丁磷(terbufos)、杀虫畏(tetrachlorvinphos)、甲基乙拌磷(thiometon)、三唑磷(triazophos)、triclorfon、蚜灭磷(vamidothion)、氟丙菊酯(acrinathrin)、烯丙菊酯(d-顺-反式,d-反式)、β-氟氯氰菊酯(beta-cyfluthrin)、氟氯菊酯(bifenthrin)、生物烯丙菊酯(bioallethrin)、生物烯丙菊酯-S-环戊基-异构体、bioethanomethrin、生物氯菊酯(biopermethrin)、生物苄呋菊酯(bioresmethrin)、chlovaporthrin、顺式-氯氰菊酯(cis-cypermethrin)、顺式-苄呋菊酯(cis-resmethrin)、顺式-氯菊酯(cis-permethrin)、clocythrin、乙氰菊酯(cycloprothrin)、氟氯氰菊酯(cyfluthrin)、氯氟氰菊酯(cyhalothrin)、氯氰菊酯(α-、β-、θ-、ζ-)、苯醚氰菊酯(cyphenothrin)、溴氰菊酯(deltamethrin)、右旋烯炔菊酯(1R-异构体)、S-氰戊菊酯(esfenvalerate)、醚菊酯(etofenprox)、五氟苯菊酯(fenfluthrin)、甲氰菊酯(fenpropathrin)、fenpyrithrin、氰戊菊酯(fenvalerate)、flubrocythrinate、氟氰戊菊酯(flucythrinate)、三氟醚菊酯(flufenprox)、氟氯苯菊酯(flumethrin)、氟胺氰菊酯(fluvalinate)、fubfenprox、γ-氯氟氰菊酯(gamma-cyhalothrin)、咪炔菊酯(imiprothrin)、噻嗯菊酯(kadethrin)、λ-氯氟氰菊酯(lambda-cyhalothrin)、metofluthrin、氯菊酯(顺式-、反式-)、苯醚菊酯(1R-反式异构体)、炔酮菊酯(prallethrin)、profluthrin、protrifenbute、反灭虫菊(pyresmethrin)、苄呋菊酯(resmethrin)、RU 15525、氟硅菊酯(silafluofen)、氟胺氰菊酯(tau-fluvalinate)、七氟菊酯(tefluthrin)、环戊烯丙菊酯(terallethrin)、胺菊酯(-1R-异构体)、四溴菊酯(tralomethrin)、四氟苯菊酯(transfluthrin)、ZXI 8901、除虫菊素(除虫菊)、DDT、茚虫威(indoxacarb)、啶虫脒(acetamiprid)、clothianidin、呋虫胺(dinotefuran)、吡虫啉(imidacloprid)、烯啶虫胺(nitenpyram)、硝虫噻嗪(nithiazine)、噻虫啉(thiacloprid)、噻虫嗪(thiamethoxam)、烟碱(nicotine)、杀虫磺(bensultap)、杀螟丹(cartap)、毒杀芬(camphechlor)、氯丹(chlordane)、硫丹(endosulfan)、γ-HCH、HCH、七氯(heptachlor)、林丹(lindane)、甲氧滴滴涕(methoxychlor)、多杀菌素(spinosad)、acetoprole、ethiprole、氟虫腈(fipronil)、氟吡唑虫(vaniliprole)、齐墩螨素(avermectin)、emamectin、emamectin-benzoate、双氢除虫菌素(ivermectin)、milbemycin、苯虫醚(diofenolan)、保幼醚(epofenonane)、苯氧威(fenoxycarb)、烯虫乙酯(hydroprene)、烯虫炔酯(kinoprene)、烯虫酯(methoprene)、蚊蝇醚(pyripfoxifen)、烯虫硫酯(triprene)、环虫酰肼(chromafenozide)、氯虫酰肼(halofenozide)、甲氧虫酰肼(methoxyfenozide)、虫酰肼(tebufenozide)、bistrifluron、chlofluazuron、除虫脲(diflubenzuron)、啶蜱脲(fluazuron)、氟螨脲(flucycloxuron)、氟虫脲(flufenoxuron)、氟铃脲(hexaflumuron)、虱螨脲(lufenuron)、氟酰脲(novaluron)、noviflumuron、氟幼脲(penfluron)、氟苯脲(teflubenzuron)、杀铃脲(triflumuron)、噻嗪酮(buprofezin)、灭蝇胺(cyromazine)、丁醚脲(diafenthiuron)、三唑锡(azocyclotin)、三环锡(cyhexatin)、杀螨锡(fenbutatin-oxide)、溴虫腈(chlorfenapyr)、binapacyrl、消螨通(dinobuton)、二硝酯(dinocap)、DNOC、喹螨醚(fenazaquin)、唑螨酯(fenpyroximate)、嘧螨醚(pyrimidifen)、哒螨灵(pyridaben)、吡螨胺(tebufenpyrad)、tolfenpyrad、伏蚁腙(hydramethylnon)、三氯杀螨醇(dicofol)、鱼藤酮(rotenone)、灭螨醌(acequinocyl)、嘧螨酯(fluacrypyrim)、苏云金杆菌菌株(Bacillus thuringiensis strains)、spirodiclofen、spiromesifen、3-(2,5-二甲基苯基)-8-甲氧基-2-氧基-1-氮杂螺[4.5]癸-3-烯-4-基乙基碳酸酯(别名:碳酸,3-(2,5-二甲基苯基)-8-甲氧基-2-氧基-1-氮杂螺[4.5]癸-3-烯-4-基乙基酯,CAS-Reg.-No.:382608-10-8)以及碳酸,顺式-3-(2,5-二甲基苯基)-8-甲氧基-2-氧基-1-氮杂螺[4.5]癸-3-烯-4-基乙基酯(CAS-Reg.-No.:203313-25-1)、flonicamid、双甲脒(amitraz)、炔螨特(propargite)、N2-[1,1-二甲基-2-(甲基磺酰基)乙基]-3-碘代-N1-[2-甲基-4-[1,2,2,2-四氟-1-(三氟甲基)乙基]苯基]-1,2-苯二甲酰胺(CAS-Reg.-No.:272451-65-7)、硫环杀(thiocyclamhydrogen oxalate)、杀虫双(thiosultap-sodium)、印楝素(azadirachtin)、杆菌属(Bacillus spec.)、Beauveria spec.、十二碳二烯醇(codlemone)、Metarrhizium spec.、Paecilomycesspec.、thuringiensin、轮枝孢菌属(Verticillium spec.)、磷化铝(aluminum phosphide)、溴甲烷(methyl bromide)、硫酰氟(sulfuryl fluoride)、冰晶石(cryolite)、flonicamid、吡蚜酮(pymetrozine)、四螨嗪(clofentezine)、乙螨唑(etoxazole)、噻螨酮(hexythiazox)、amidoflumet、benclothiaz、苯螨特(benzoximate)、联苯肼酯(bifenazate)、溴螨酯(bromopropylate)、噻嗪酮(buprofezin)、灭螨猛(chinomethionat)、杀虫脒(chlordimeform)、乙酯杀螨醇(chlorobenzilate)、氯化苦(chloropicrin)、clothiazoben、cycloprene、环虫腈(dicyclanil)、fenoxacrim、氟硝二苯胺(fentrifanil)、氟螨噻(flubenzimine)、flufenerim、flutenzin、诱虫十六酯(gossyplure)、灭蚊腙(hydramethylnone)、japonilure、虫酮(metoxadiazone)、石油(petroleum)、增效醚(piperonyl butoxide)、油酸钾(potassiumoleate)、pyridalyl、氟虫胺(sulfluramid)、三氟杀螨砜(tetradifon)、杀螨硫醚(tetrasui)、苯螨噻(triarathene)、增效炔醚(verbutin)。
优选与除草剂一起使用的杀虫剂为例如如下化合物:
啶虫脒(acetamiprid)、氟丙菊酯(acrinathrin)、涕灭威(aldicarb)、双甲脒(amitraz)、acinphos-methyl、氟氯氰菊酯(cyfluthrin)、甲萘威(carbaryl)、氯氰菊酯(cypermethrin)、溴氰菊酯(deltamethrin)、硫丹(endosulfan)、灭线磷(ethoprophos)、苯线磷(fenamiphos)、倍硫磷(fenthion)、氟虫腈(fipronil)、吡虫啉(imidacloprid)、甲胺磷(methamidophos)、甲硫威(methiocarb)、杀螺胺(niclosamide)、磺吸磷(oxydemeton-methyl)、丙硫磷(prothiophos)、氟硅菊酯(silafluofen)、噻虫啉(thiacloprid)、硫双威(thiodicarb)、四溴菊酯(tralomethrin)、三唑磷(triazophos)、敌百虫(trichlorfon)、杀铃脲(triflumuron)、特丁磷(terbufos)、地虫硫磷(fonofos)、甲拌磷(phorate)、毒死蜱(chlorpyriphos)、克百威(carbofuran)、七氟菊酯(tefluthrin)。
本发明活性化合物组合物适用于在非作物土地,在小路、铁轨、工业地带(“工业杂草控制”)或在种植作物中,例如温带、亚热带和热带气候或地理区域控制广谱的杂草。种植作物的实例为油椰、坚果(例如杏、榛子、胡桃、澳大利亚坚果)、椰子、浆果、油棕、橡胶树、柑橘(例如橙子、柠檬、桔子)、香蕉、菠萝、棉花、甘蔗、茶、咖啡、可可等。它们还适用于水果种植中(例如仁果类水果,例如苹果、梨、樱桃、芒果、猕猴桃)以及葡萄栽培中。该组合物还可以用于制备用于播种的土壤(“烧光”、“不耕作”或“零耕作(zero-till)”法)或待收获后进行处理(“化学休耕”)。该活性化合物组合物的潜在应用扩展至树木作物的杂草控制,例如幼小的圣诞树作物或桉树种植,分别于种植前或移植后进行施用(也可以采用顶部处理)。
该组合物还可以用于经济重要作物的选择性作物,例如谷物(小麦、大麦、燕麦)、玉米、水稻、甜菜、甘蔗、油菜、棉花和大豆。当将活性化合物(A)和(B)用于作物例如谷物和玉米中时,根据作物,其可以便利地在施用一定量的安全剂以防止或降低对作物的损害。
本发明的多元组合物(=除草组合物)就除草作用和选择性而言是增效有效的,并且考虑到杂草谱,该组合物具有有利的作用。该组合物具有控制广谱性经济重要的单子叶或双子叶有害植物的优良除草活性。该活性化合物甚至有效地控制从根茎、根状茎或其它多年生器官发芽的不容易控制的多年生杂草。在本文中,该活性物质是否是播种前、苗前或苗后施用是无关紧要的。优选采用种植作物早期播种后苗前方法或苗后方法进行施用来控制还未出苗或已经出苗的有害植物。该施用还可以结合到具有重复分开施用(顺序施用,连续的)的杂草管理系统(weed-management)中。
具体地,可以提及由本发明的活性化合物组合物控制的单子叶和双子叶杂草植物的部分代表性实例,而这些列举不限制特定种类。
对于单子叶杂草种类而言,例如该组合物控制如下杂草:一年生的剪股颖属(Agrostis),看麦娘属(Alopecurus),阿披拉草属(Apera),燕麦属(Avena),臂形草属(Brachicaria),雀麦属(Bromus),龙爪茅属(Dactyloctenium),马唐属(Digitaria),稗属(Echinochloa),荸荠属(Eleocharis),牛筋草属(Eleusine),羊茅属(Festuca),飘拂草属(Fimbristylis),鸭嘴草属(Ischaemum),黑麦草属(Lolium),雨久花属(Monochoria),黍属(Panicum),雀稗属(Paspalum),虉草属(Phalaris),梯牧草属(Phleum),早熟禾属(Poa),慈姑属(Sagittaria),藨草属(Scirpus),狗尾草属(Setaria),尖瓣花属(Sphenoclea)和莎草属(Cyperus),以及多年生杂草冰草属(Agropyron)、狗牙根属(Cynodon)、白茅属(Imperata)和高梁属(Sorghum),以及多年生的莎草属。
在双子叶杂草中,作用谱扩大至如下种类,例如一年生的猪殃殃属(Galium)、蔓长春花属(Viola)、婆婆纳属(Veronica)、野芝麻属(Lamium)、繁缕属(Stellaria)、苋属(Amaranthus)、白芥属(Sinapis)、番薯属(Ipomoea)、母菊属(Matricaria)、苘麻属(Abutilon)和黄花稔属(Sida),以及多年生的旋花属(Convolvulus)、蓟属(Cirsium)、酸模属(Rumex)和蒿属(Artemisia)杂草。
还观察到控制如下双子叶有害植物的除草作用:例如豚草属(Ambrosia)、春黄菊属(Anthemis)、飞廉属(Carduus)、矢车菊属(Centaurea)、藜属(Chenopodium)、曼陀罗属(Datura)、刺酸模属(Emex)、鼬瓣花属(Galeopsis)、牛滕菊属(Galinsoga)、地肤属(Kochia)、独行菜属(Lepidium)、母草属(Lindernia)、罂粟属(Papaver)、Portlaca、蓼属(Polygonum)、毛茛属(Ranunculus)、蔊菜属(Rorippa)、节节菜属(Rotala)、Seneceio、田箐属(Sesbania)、茄属(Solanum)、苦苣菜属(Sonchus)、蒲公英属(Taraxacum)、车轴草属(Trifolium)、Urtica和苍耳属(Xanthium)。
如果在苗前将本发明的活性化合物组合物施加于土壤表面,则完全阻止杂草出苗,或杂草植物生长至子叶期就停止生长,最后在经过三至四周之后就完全死亡。
当将活性物质苗后施用至植物绿色部分,在处理后的极短时间内生长急剧停止,并且杂草停留在施药时的生长期,或在一定时间之后完全死亡,从而以这种方式在早期并且持续地消除对作物有害的杂草竞争。
本发明的除草组合物具有显著的迅速起效和长效的除草作用。通常来说,本发明组合物中的活性化合物具有利的耐雨水性。尤其有利的是用于该除草组合物中并且有效的化合物(A)和(B)的剂量可调至低量,使得对土壤的作用最小。由此使得本发明的组合物首先不仅能够用于敏感作物中,而且实际上避免了对地下水的污染。本发明的活性化合物的组合物使得所需的活性化合物施用量得以大大地减少。
当将(A)+(B)类除草剂一并使用时,观察到超加合(=增效)作用。这表示组合物的活性超过了所使用各除草剂的预期活性之和。该增效作用使得施用量得以降低、可控制的阔叶杂草和禾本科杂草谱更广、更快速地产生除草作用、作用持续时间更长、仅一次或几次施用可更好的控制有害植物,以及延长了施用时间。在某些情形下,该组合物还减少了有害组分如氮或油酸的量,以及其进入土壤的量。
如上经确认的特征和优点有利于控制杂草以保持农作物远离不期望的竞争植物,从而确保和/或提高了产品的质量和数量。该新组合物显著地优于现有技术产品所具有的性能。
尽管本发明的组合物具有控制单子叶和双子叶杂草的显著除草活性,然而作物仅受到较小程度的损害。
本发明的部分组合物对作物还具有突出的生长调节性能。它们调节性地参与植物的新陈代谢,因此可通过例如引发脱水和生长充实而有目的地影响植物成分并且促进收获。此外,也适用于一般性控制并且抑制不期望的植物生长,而同时在该过程中不伤害植物。由于可以减少或完全预防倒伏,抑制植物生长在许多单子叶及双子叶作物中扮演着重要的角色。
由于其除草和植物生长调节性能,该组合物也可用于控制已知的或仍在开发的转基因植物中的有害植物。通常而言,除对本发明组合物的抗性外,转基因植物具有特别优越的性能,例如对植物病害或植物病原体的抗性,例如对某些昆虫或微生物如真菌、细菌或病毒的抗性。其它的特殊性质涉及例如收成产物的数量、质量、储藏性能、组分和特定成分。因此,转基因植物以经提高的淀粉含量或经改良的淀粉品质,或那些具有不同的脂肪酸组分的收成产物而著称。
培育比已知植物具有改良性质的新颖植物的传统途径是例如经典的培育方法和突变种的制造。可选择的是,借助基因工程方法可产生具有改变性质的新颖植物(参照例如EP-A-0221044、EP-A-0131624)。例如,下列的几项描述:
-用基因工程技术改变作物用于改良植物中合成的淀粉(例如WO 92/11376、WO 92/14827、WO 91/19806),
-对其它除草剂例如磺酰脲显示抗性的转基因作物(EP-A-0257993、US-A-5013659),
-具有产生苏云金芽孢杆菌毒素(Bt毒素)能力的转基因作物,其使该植物对抗特定害虫(EP-A-0142924,EP-A-0193259),
-具有改良脂肪酸组成的转基因作物(WO 91/13972)。
大量可制备具有改良性质的新颖转基因植物的分子生物技术基本上是已知的;参照例如,Sambrook等,1989,Molecular Cloning(分子克隆),A Laboratory Manual,第二版,Cold Spring HarborLaboratory Press,Cold Spring Harbor,NY;或Winnacker“Geneund Klone”[基因和克隆],VCH Weinheim,第二版1996或Christou,“Trends in Plant Science”1(1996)423-431。
为了进行此类基因工程改造,可以将核酸分子导入质粒中,其可通过DNA序列的重组技术产生突变或使序列发生改变。使用上述的标准方法,可以例如调换碱基、去除部份序列或加入天然序列或合成序列。为了使DNA片段彼此连结,可以加入接合体或连接体。
具有降低活性的基因产物的植物细胞可以例如通过下列方式制备:表达至少一种相应的反义RNA、有义RNA达到协同抑制效果,或表现至少一种具有适宜的构筑的核糖酶,其特异性切割上述提到的基因产物的转录本。
对此,既可以使用一种DNA分子,其含有基因产物的全部的编码序列(包括可能存在的两侧翼序列),也可以使用另一种DNA分子,其只含有部分的编码序列,该序列部份必须足够长以引起在细胞中的反义效果。也可以使用DNA序列,其具有与基因产物的编码序列高度的同源性,但不是完全地相同。
当在植物中表达核酸分子时,经合成的蛋白质可定位于植物细胞的任意区室内。然而,要达到定位于某一特定区室,可以例如使编码区与确保特定区室定位的DNA序列连结。此类序列是本领域技术人员所熟悉的(参见例如,Braun等,EMBO J.11(1992),3219-3227;Wolter等,Proc.Natl.Acad.Sci.USA 85(1988),846-850;Sonnewald等,Plant J.1(1991),95-106)。
通过已知的技术可以使转基因植物细胞再生成整株植物。该转基因植物基本上可以是任意所需植物种类的植物,既包括单子叶植物又包括双子叶植物。由此,同源的(即天然的)基因或基因序列的过度表达、遏抑或抑制,或通过异源的(即外来的)基因或基因序列的表达可以获得具有经改变的性质的转基因植物。
因此,本发明还提供一种控制不期望植物的方法,优选用于非作物土地或种植作物中,其中将一种或多种除草剂类(A)和一种或多种除草剂类(B)施用至有害植物、植物部分或其种子,或施用至栽培区域。
本发明还提供将化合物(A)+(B)的新组合物优选在非作物土地或种植作物中用于控制有害植物的用途。
本发明的活性化合物组合物还可以以两种组分,任选地与其它活性化合物、添加剂和/或常规制剂助剂的混合制剂形式来存在,随后将其用水稀释后以常规方式施用,或将通过用水一并稀释的各组分以桶混物来加以制备,其可以分别配制或部分分别配制。
分别视其主要的生物和/或化学物理参数而定,可以以多种方式配制化合物(A)和(B)或其组合物。适宜的制剂实例为:可湿性粉剂(WP)、乳油(EC)、含水溶液(SL)、乳液(EW)如水包油及油包水乳液、可喷雾溶液或乳液、油或水基的分散剂、油分散剂(OD)、悬乳剂、悬浮剂(SC)、粉剂(DP)、拌种剂、撒播和土壤施用颗粒剂或水分散性颗粒剂(WG)、ULV-制剂、微胶囊剂和蜡类。
所述各种制剂类型基本上是已知的,并例如在:Winnacker-Küchler,“Chemische Technologie(化学技术)”,第7册,C.HanserVerlag Munich,第四版,1986,van Valkenburg,“PesticideFormulations(农药制剂)”,Marcel Dekker N.Y.,1973;K.Martens,“Spray Drying”Handbook(喷雾干燥手册),第三版,1979,G.GoodwinLtd.London中有描述。
所需助剂,如惰性材料、表面活性剂、溶剂及其它的添加剂同样是已知的并例如在:Watkins,“Handbook of Insecticide DustDiluents and Carriers(杀虫粉尘稀释液和载体手册)”,第二版,Darland Books,Caldwell N.J.,H.v.Olphen,“Introduction toClay Colloid Chemistry(粘土胶体化学入门)”,第二版,J.Wiley&Sons,N.Y.;Marsden,“Solvents Guide(溶剂指南)”,第二版,Interscience,N.Y.1950;McCutcheon′s,“Detergents andEmulsifiers Annual”,MC Publ.Corp.,Ridgewood N.J.;Sisleyand Wood,“Encyclopedia of Surface Active Agents(表面活性剂百科全书)”,Chem.Publ.Co.Inc.,N.Y.1964;Schnfeldt,“Grenzflchenaktive thylenoxidaddukte(表面活性的环氧乙烷加成物)”,Wiss.Verlagsgesell.,Stuttgart 1976;Winnacker-Küchler,“Chemische Technologie”,第7册,C.HanserVerlag München,第四版,1986中有描述。
基于这些制剂,还可以制备与其它农药活性化合物例如其它除草剂、杀真菌剂或杀虫剂,以及安全剂、肥料和/或生长调节剂的组合物,例如以预混物或桶混物形式。
可湿性粉剂是均匀分散在水中的制剂,其除了活性化合物,以及除了稀释剂或惰性物质外,还含有离子型或非离子型表面活性剂(润湿剂、分散剂),例如:聚乙氧基化的烷基酚类、聚乙氧基化的脂肪醇类、聚乙氧基化的脂肪胺类、脂肪醇聚二醇醚硫酸酯、烷磺酸酯类或烷基苯磺酸酯类、2,2′-二萘甲烷-6,6′-二磺酸钠、木质磺酸钠、二丁基萘磺酸钠或油酰甲基牛磺酸钠。
乳油的制备是通过将活性化合物溶解在有机溶剂中,如丁醇、环己酮、二甲基甲酰胺、二甲苯或其它沸点较高的芳族或烃或添加一种或多种离子型和/或非离子型表面活性剂(乳化剂)的有机溶剂混合物。可以使用的乳化剂的实例是:烷芳基磺酸的钙盐(如十二烷基苯磺酸钙),或非离子型乳化剂,如脂肪酸聚乙二醇酯、烷芳基聚乙二醇醚、脂肪醇聚乙二醇醚、环氧丙烷/环氧乙烷缩合产物、烷基聚醚、脱水山梨糖醇酯例如山梨糖醇脂肪酸酯或聚氧乙烯脱水山梨糖醇酯,例如聚氧乙烯脱水山梨糖醇脂肪酸酯。
粉剂是将活性化合物与磨成细粉状的固体物质加以磨碎而得,所述固体物质例如:滑石、天然粘土(如高岭土、膨润土和叶蜡石)或硅藻土。
粒剂的制备可以通过将活性化合物喷洒在吸附性粒状的惰性物质上,或将活性化合物浓缩物借助粘合剂(如聚乙烯醇,聚丙烯酸钠或矿物油)涂敷在载体(如砂、高岭土或粒状惰性物质)的表面上。适宜的活性化合物可以使用制造肥粒颗料的常规方法并任选地与肥料的混合物一同粒化。水分散性粒剂通常是利用常规方法如喷雾式干燥法、流体化床式制粒法、碟式制粒法、用高速搅拌器混合法混合和无固体惰性物质的挤压制备而成。
该农业化学制剂通常含有0.1~99重量%,尤其是2~95重量%的类型A和/或B的活性化合物,如下浓度通常取决于制剂类型。可湿性粉剂中,活性化合物的浓度通常为约10~95重量%,至100重量%的余量由常规制剂组分构成。在乳油中,活性化合物的浓度可为约5~80重量%。
粉剂形式的制剂通常含有5~20重量%的活性化合物,而可喷雾溶液含有约0.2~25重量%的活性化合物。
水分散颗粒剂中,活性化合物的含量部分取决于活性化合物是否以液态或固态形式,以及取决于使用的粒化助剂和填料等。水分散颗粒剂中,活性化合物的含量为例如介于10和90重量%之间。
此外,上述活性化合物制剂可任选地分别包含常用的添加剂如粘合剂、润湿剂、分散剂、乳化剂、防腐剂、防冻剂、溶剂、填料、颜料、载体、消泡剂、蒸发抑制剂、pH调节剂和粘度调节剂。
就使用而言,将商购可得形式的制剂任选以常规方式稀释,例如在可湿性粉剂、乳油、分散液和水分散颗粒剂中用水稀释。粉剂、土壤颗粒剂、撒布的颗粒剂和可喷雾溶液形式的制剂通常在使用前不用任何其它惰性物质稀释。
该活性化合物可以施用至植物、植物部分、植物种子或栽培区域(大田土壤),优选施用至绿色植物和植物部分,并且任选地还施用至大田土壤。
可能的使用是将以桶混物形式的活性化合物一并施用,其中以最佳制剂形式的各活性化合物的浓缩制剂在桶中与水一并混合,并且施用所得的喷雾混合物。
由于各组分的量已经以彼此恰当的比例存在,因此本发明活性化合物(A)和(B)的组合物的共除草制剂具有易于施用的优点。此外,制剂中的助剂可以彼此间最佳相配,然而不同制剂的桶混物会导致不期望的助剂的结合。
A.常规的制剂实施例
a)粉剂的制备是将10重量份的活性化合物/活性化合物混合物与90重量份的滑石(作为惰性物质)加以混合,将该混合物在锤磨机中粉碎。
b)在水中易于分散的可湿性粉剂的制备是将25重量份的活性化合物/活性化合物混合物,64重量份的含高岭土的石英作为惰性物质,10重量份的木质磺酸钾和1重量份的油酰甲基牛磺酸钠作为润湿剂和分散剂加以混合,将该混合物在栓型碟式磨粉机上研磨该混合物。
c)在水中易于分散的分散性浓缩物的制备是将20重量份的活性化合物/活性化合物混合物、6重量份的烷基酚聚乙二醇醚(Triton X207)、3重量份的异十三烷醇聚乙二醇醚(8 EO)和71重量份的链烷烃矿物油(沸点范围约255至277℃以上)加以混合,并且在球磨机上研磨该混合物至小于5微米的细度。
d)乳油是由下列物质组成:15重量份的活性化合物/活性化合物混合物,75重量份的环己酮作为溶剂和10重量份的氧乙基化的壬酚作为乳化剂。
e)水分散颗粒剂是利用下列方式制得:将
75重量份的活性化合物/活性化合物混合物,
10重量份的木质磺酸钙,
5重量份的月桂硫酸钠,
3重量份的聚乙烯醇和
7重量份的高岭土
加以混合,将该混合物在栓型碟式磨粉机中磨成细粉,将粉末在流体化床中通过喷洒作为粒化液体的水以使之粒化。
f)水分散颗粒剂也可通过于胶体磨上将下列物质均质化且预先粉碎
25重量份的活性化合物/活性化合物混合物,
5重量份的2,2′-二萘基甲烷-6,6′-二磺酸钠,
2重量份的油酰甲基牛磺酸钠,
1重量份的聚乙烯醇,
17重量份的碳酸钙和
50重量份的水,
随后将该混合物在球磨机中磨成细粉,在喷雾塔中利用单物质喷嘴将如此得到的悬浮体加以雾化和干燥。
B.生物实施例
1.苗前除草作用
将单子叶和双子叶有害植物的种子或根茎块置于盆中的砂壤土中并覆上土壤。随后在300~800升水/公顷的施用量下(经换算),将以浓缩的水溶液、可湿性粉剂或乳油形式配制的组合物以不同剂量的水溶液、悬浮液或乳液形式施加至土壤表面。处理之后,将盆置于温室中并保持适于杂草的良好生长条件。试验进行3至4周后,在试验植物出苗后,与未处理对照相比,目测评价对植物或出苗的损害。如结果所示,本发明的组合物具有控制广谱禾本类杂草和阔叶杂草的显著苗前除草活性。
计算和评价增效除草效果:
通过将经处理的盆(土壤)与未处理对照相比,目测计算活性化合物或活性化合物混合物的除草效果。记录所有地上植物部分的损害和发育。以百分比来进行计算(100%作用=所有植物死亡或未出苗;50%作用=50%的植物和绿色植物部分死亡或未出苗;0%作用=无可识别的作用=类似于对照盆)。将4次重复(盆)的记录数据进行平均。
当施用本发明的组合物时,通常在有害植物种类上观察到的除草效果超过当单独施用时所存在的除草效果之和。可选的是,在某些情形下观察到与单个产品相比,需要更低施用量的除草组合物以获得对有害植物种类的相同效果。这种作用或效果的增加、或施用量的减少强烈暗示了增效作用。
当在试验中观察到的数据已经超过单独施用的数据之和时,其同样超过了根据Colby公式的预期值,该预期值是利用如下公式来计算的并且同样看作表明增效作用(参见S.R.Colby;Weeds(杂草)15(1967),第20至22页中):
E=A+B-(A·B/100)
在该公式中:
A=在a g AS/ha施用量下,活性化合物(A)的作用%;
B=在b g AS/ha施用量下,活性化合物(B)的作用%;
E=在组合施用量a+b g AS/ha下,组合物(A)+(B)的预期作用值%。
在试验中观察到的数据显示,在适宜的低剂量下,组合物的活性超过根据Colby公式的预期值。
2.苗后除草作用
将单子叶和双子叶杂草的种子和根茎块置于盆中的砂壤土中并覆上土壤,并于温室中在良好的生长条件(提供温度、大气湿度、水)下生长。播种3周后,在三叶阶段用本发明组合物处理试验植物。随后在300~800升水/公顷的施用量下(经换算),将以可湿性粉剂或乳油形式配制的本发明组合物以不同剂量喷雾至绿色植物部分。将试验植物置于理想的生长条件下的温室中3至4周后,与未处理对照相比目测计算制剂的效果(如实施例所计算)。本发明组合物还具有控制广谱的经济重要性禾本类杂草和阔叶杂草的良好苗后除草作用。
在此处,观察到本发明组合物的效果通常超过当单独施用除草剂的效果之和。在试验中所观察到的值显示,在适宜的低剂量下,组合物的活性超过根据Colby公式(参见以实施例1来计算)的预期值。
3.苗前和苗后除草作用(室外试验)
相应于部分1和2的温室试验,该试验在露天小区进行。类似于部分1和2中的测试进行计算。
4.除草作用和作物耐受性(室外试验)
作物在自然室外条件下的露天小区生长,并且布置典型有害植物的种子或根茎块或利用天然杂草生长。待有害植物出苗后并且作物通常在2-至4叶期,用本发明的组合物进行处理;在某些情形下(如所示),进行苗前施用单个活性化合物或活性化合物组合物,或部分苗前和/或苗后进行连续处理。
在种植作物中,仅仅通常用活性化合物处理各作物之间的土壤。
待施用后,例如施用后2、4、6和8周,通过与未处理对照相比目测计算制剂的效果(参见实施例1中的计算)。同样地在室外试验中,本发明组合物具有控制广谱经济重要性禾本类杂草和阔叶杂草的增效除草活性。相比较显示,本发明的组合物在多数情形下具有高于、在某些情形下显著高于单个除草剂活性之和的除草活性,从而表明增效作用。此外,实际计算的效果高于根据Colby公式的预期值(参见以实施例1来计算),这也表明增效作用。与之相反的是,作为用除草组合物处理的结果,作物仅受到很小程度的损害。
5.具体的试验实施例
如下缩写用于说明书和下表中:
g AS/ha=克活性物质(=100%活性化合物)/公顷:
单独施用的活性之和以EA来表示;
根据Colby公式的预期值以EC来表示;
实施例5.1
根据与部分2相结合的部分3的常规实施例来测试某些组合物的除草活性(苗后方法)。其结果概括于表2中。
表2
    活性化合物(s)      施用量    [g AS/ha]     除草作用[%]       粗茎早熟禾     紫羊茅         (A11)     200     0     0     (B2.1.1.1)     600     88     87     (A11)+(B2.1.1.1)      200+600      94  (EA=88,EC=88)     95    (EA=87,EC=87)
在表2中的缩写:
条件:室外试验
在有害植物阶段21(种植开始(Bestockungsbeginn))进行施用,处理后35天进行评价
(A11)=来自于表1的化合物(A11)(化合物(A))=2-氨基-4-[(1R)-6-甲基茚满-1-基氨基]-6-[(1R)-1-氟乙基]-1,3,5-三嗪
(B2.1.1.1)=草铵膦铵盐
实施例5.2
根据与部分2相结合的部分3的常规实施例来测试某些组合物的除草活性(苗后方法)。其结果概括于表3中。
表3
    活性化合物(s)       施用量    [g AS/ha]     除草作用[%]     多花黑麦草     (A11)      200    300     20    50     (B2.1.2.1)     1080     18     (A11)+    (B2.1.2.1)     200+1080      88    (EA=38,EC=35)
在表3中的缩写:
条件:室外试验
在有害植物2-5叶期进行施用(苗后),处理后55天进行评价
(A11)=来自于表1的化合物(A11)(化合物(A))=2-氨基-4-[(1R)-6-甲基茚满-1-基氨基]-6-[(1R)-1-氟乙基]-1,3,5-三嗪
(B2.1.2.1)=草甘膦异丙铵盐