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51. 发明授权

US5919871A Stabilization of a polymer by a stable free radical 失效
标题翻译：通过稳定的自由基稳定聚合物
公开(公告)号：US5919871A
公开(公告)日：1999-07-06
申请号：US597232
申请日：1996-02-06
申请人： Pascal Nicol , Muriel Plechot
发明人： Pascal Nicol , Muriel Plechot
IPC分类号： C08K5/16 , C08F4/00 , C08F12/00 , C08F12/02 , C08F279/02 , C08F291/00 , C08F293/00 , C08K5/17 , C08L23/00 , C08L25/00 , C08L33/00 , C08F8/00
CPC分类号： C08F291/00 , C08F279/02 , C08F293/00 , C08F4/00
摘要： The present invention relates to the stabilization of a polymer by a stable free radical and in particular to the use of a stable free radical for inhibiting the degradation of a polymer by a mechanism which does not involve oxygen. This use can be carried out when the polymer is in the presence or in the absence of oxygen. The degradation which can be inhibited can be a depolymerization or a crosslinking.
摘要翻译：本发明涉及通过稳定的自由基稳定聚合物，特别涉及使用稳定的自由基通过不涉及氧的机理来抑制聚合物的降解。当聚合物存在或不存在氧时，可以进行这种使用。可以抑制的降解可以是解聚或交联。

52. 发明授权

US5854364A Process for the controlled radical polymerization or copolymerization of (meth)acrylic, vinyl, vinylidene and diene monomers, and (co)polymers obtained 失效
标题翻译：（甲基）丙烯酸，乙烯基，亚乙烯基和二烯单体和（共）聚合物的受控自由基聚合或共聚方法
公开(公告)号：US5854364A
公开(公告)日：1998-12-29
申请号：US884087
申请日：1997-06-27
申请人： Thierry Senninger , Laurent Sanchez , Vincent Darcos , Dominique Lastecoueres , Jean-Baptiste Verlhac
发明人： Thierry Senninger , Laurent Sanchez , Vincent Darcos , Dominique Lastecoueres , Jean-Baptiste Verlhac
IPC分类号： C08F4/06 , C08F2/02 , C08F2/04 , C08F2/38 , C08F4/00 , C08F4/10 , C08F4/28 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/00 , C08F12/02 , C08F14/00 , C08F18/04 , C08F20/10 , C08F20/18 , C08F36/02 , C08F36/04 , C08F297/00 , C08F12/08 , C08F14/06 , C08F14/18 , C08F36/00
CPC分类号： C08F4/40 , C08F4/00
摘要： At least one of the monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of at least one radical-generator compound and at least one metal complex catalyst of formula Ma.sub.a (L).sub.n (M=Cu, Ag or Au; A=Hal, pseudohalogen or carboxylate; L=ligands of M chosen from those of formula ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 =H, C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic; Z.sup.1, Z.sup.2 and Z.sup.3 =one of the following: ##STR2## (R.sup.7 to R.sup.18 =H, C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic; R.sup.19 and R.sup.20 =H, Hal, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.10 alkoxy or --(CR.sup.21 R.sup.22)rNR.sup.23 R.sup.24, where R.sup.21, R.sup.22, R.sup.23 and R.sup.24 =H,C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic, and r=integer from 1 to 10; it being possible also for not more than two from among Z.sup.1, Z.sup.2 and Z.sup.3 each to represent H; o, p and q=integer from 1 to 10 and may also be 0 except if the associated residue Z.sup.1, Z.sup.2 or Z.sup.3, respectively, is --NR.sup.19 R.sup.20 ; a=1 or 2; n=1, 2 or 3.
摘要翻译：在至少一种自由基产生剂化合物和至少一种金属络合物的存在下，至少一种单体在本体，溶液，乳液或悬浮液中在可能低至0℃的温度下聚合或共聚式（A）的催化剂（M = Cu，Ag或Au; A = Hal，拟卤素或羧酸酯; L = M的配体选自式Ia，R2，R3，R4，R5和R6 = H，C 1 -C 10烷基，芳族或杂芳族; Z 1，Z 2和Z 3 =以下之一：R 1a和R 20 = H，Hal，C 1 -C 10烷基，C 1 -C 10烷氧基或 - （CR 21 R 22） rNR23R24，其中R21，R22，R23和R24 = H，C1-C10烷基，芳族或杂芳族，并且r = 1至10的整数;也可以在Z1，Z2和Z3中不超过两个表示 H; o，p和q = 1至10的整数，并且除了相关的残基Z1，Z2或Z3分别为-NR19R20; a = 1或2; n = 1,2或3之外，也可以为0。

53. 发明授权

US5830959A Process for the production of vinylaromatic polymers with a high degree of syndiotacticity 失效
标题翻译：用于制备具有高度间同立构规整度的乙烯基芳族聚合物的方法
公开(公告)号：US5830959A
公开(公告)日：1998-11-03
申请号：US944783
申请日：1997-10-06
申请人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
发明人： Riccardo Po' , Nicoletta Cardi , Roberto Santi
IPC分类号： C08F4/646 , C08F12/08 , C08F12/02
CPC分类号： C08F12/08 , C08F4/65912
摘要： Process for the preparation of crystalline vinylaromatic polymers with a high degree of syndiotacticity which comprises polymerizing vinylaromatic monomers in the presence of a catalytic system essentially consisting of: a) a complex of titanium selected from those having the general formula: (CpR.sub.1 R.sub.2 R.sub.3 R.sub.4 R.sub.5)TiX.sub.3 (I) wherein the groups R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent a hydrogen atom or C.sub.1 -C.sub.10 alkyl groups; X represents a hydrogen atom, a halogen such as chlorine, a C.sub.1 -C.sub.10 alkyl or oxyalkyl radical or a C.sub.6 -C.sub.12 oxyaryl radical; b) an alkylaluminoxane; and c) an organic derivative of tin; characterized in that the alkylaluminoxane is methylaluminoxane (MAO) treated at 20.degree.-80.degree. C. under vacuum for 1-100 hours and the organic derivative of tin is tin tetraphenyl.
摘要翻译：用于制备具有高程度间同立构规整度的结晶乙烯基芳族聚合物的方法，其包括在催化体系存在下聚合乙烯基芳族单体，所述催化体系基本上由以下组成：a）选自具有以下通式的那些钛络合物：（CpR1R2R3R4R5）TiX3（I ）其中基团R 1，R 2，R 3，R 4和R 5表示氢原子或C 1 -C 10烷基; X表示氢原子，卤素如氯，C1-C10烷基或烷氧基或C6-C12氧芳基; b）烷基铝氧烷; 和c）锡的有机衍生物; 其特征在于烷基铝氧烷是在20-80℃下真空处理1-100小时的甲基铝氧烷（MAO），锡的有机衍生物是四苯基锡。

54. 发明授权

US5550203A Functionalized amine initiators for anionic polymerization 失效
标题翻译：用于阴离子聚合的官能化胺引发剂
公开(公告)号：US5550203A
公开(公告)日：1996-08-27
申请号：US460305
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
IPC分类号： C08F4/46 , C08F4/48 , C08F12/04 , C08F36/04 , C08F12/02 , C08F36/06 , C08F36/08
CPC分类号： C08F12/04 , C08F36/04
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures:M--Q.sub.n --Z--N(A(R.sup.1 R.sup.2 R.sup.3)).sub.2or ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译：制备以下一般结构的单官能胺引发剂的烃溶液的方法：选自锂，钠和钾的M-Qn-ZN（A（R1R2R3））2金属，Q是饱和或通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的不饱和烃基; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表Ⅳa的元素，R 1，R 2和R 3独立地选自氢，取代的烷基，环烷基，芳基或取代的芳基，m是0至7的整数，n是整数 1至5个，通过该方法制备的单官能胺引发剂，在聚合过程中使用引发剂和通过聚合方法制备的聚合物。

55. 发明授权

US4783514A Polymeric monoarylcyclobutane compositions 失效
标题翻译：聚合单芳基环丁烷组合物
公开(公告)号：US4783514A
公开(公告)日：1988-11-08
申请号：US872372
申请日：1986-06-09
申请人： Robert A. Kirchhoff , Alan K. Schrock , Stephen F. Hahn
发明人： Robert A. Kirchhoff , Alan K. Schrock , Stephen F. Hahn
IPC分类号： C07C13/44 , C07C1/00 , C07C13/38 , C07C15/58 , C07C67/00 , C07D207/38 , C07D207/44 , C07D207/452 , C07F7/08 , C08F10/00 , C08F12/00 , C08F12/02 , C08F12/08 , C08F12/32 , C08F22/36 , C08F32/08 , C08F38/00 , C08F232/08 , C08G61/00 , C08G61/02 , C08G61/06
CPC分类号： C07D207/452 , C07C13/44 , C07C255/00 , C07D207/38 , C07F7/0809 , C08F12/32 , C08F38/00 , C08G61/00
摘要： Polymeric compositions are comprised of, in polymerized form, a monomer which contains one reactive arylcyclobutane moiety.
摘要翻译：聚合物组合物以聚合形式包含含有一个反应性芳基环丁烷部分的单体。

57. 发明公开

EP2010578A2 COPOLYMERS USEFUL AS DEMULSIFIERS AND CLARIFIERS 有权
标题翻译：聚合物制备破乳剂和澄清
公开(公告)号：EP2010578A2
公开(公告)日：2009-01-07
申请号：EP07760379.3
申请日：2007-04-10
申请人： BAKER HUGHES INCORPORATED
发明人： BEHLES, Jacqueline
IPC分类号： C08F12/02 , C08F12/30 , C08F14/14 , C08F14/16 , C08F18/00 , C08F20/00 , C08F20/10
CPC分类号： C08F2/24 , C08F212/08 , C08F220/06 , C08F220/18 , C10G33/04 , C10G2300/1088 , C10G2300/1096 , C10G2300/202 , C10G2300/805 , C08F2/26
摘要： A copolymer useful as a demulsifier or water clarifier may be prepared by polymerizing at least one aromatic monomer having one or more polymerizable double bonds; at least one oleophilic monomer having one or more polymerizable double bonds; at least one ionizable monomer having a polymerizable double bond; and at least one hydrophilic monomer having one or more polymerizable double bonds, under polymerization conditions sufficient to prepare a copolymer. The copolymer may, in some embodiments, be prepared and used as a latex.

58. 发明公开

EP1874463A1 NANOCATALYST ANCHORED ONTO ACID FUNCTIONALIZED SOLID SUPPORT AND METHODS OF MAKING AND USING SAME 有权
标题翻译：在固相载体SÄUREFUNKTIONALISIERTEM挂靠纳米催化剂及其制备方法和用途
公开(公告)号：EP1874463A1
公开(公告)日：2008-01-09
申请号：EP05852861.3
申请日：2005-12-06
申请人： Headwaters Technology Innovation LLC
发明人： ZHOU, Bing , RUETER, Michael , PARASHER, Sukesh
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/44 , C08F12/02 , C08F112/02
CPC分类号： B01J35/0013 , B01J23/38 , B01J27/053 , B01J27/08 , B01J29/06 , B01J31/1625 , B01J37/0219 , C01B15/026
摘要： Supported catalysts include a solid support such as silica that is functionalized to have inorganic acid functional groups attached thereto. Active catalyst particles are supported on the functionalized support material. The acid functionalized support material is made by reacting a solid support with an inorganic acid containing agent such as sulfuric acid or para-toluene sulfonic acid. An organic anchoring agent is used to form and anchor catalyst nanoparticles to the acid functionalized support material. The supported catalyst can be sized and shaped for use in any type of reactor, including a fixed bed or fluidized bed reactor. The methods of the present invention also include a process for the direct synthesis of hydrogen peroxide using the supported catalyst.

59. 发明公开

EP1292627A1 HYDROGENATED MONOVINYLIDENE AROMATIC POLYMER COMPOSITIONS 有权
标题翻译：氢化亚乙烯基芳族聚合物组合物
公开(公告)号：EP1292627A1
公开(公告)日：2003-03-19
申请号：EP01905407.1
申请日：2001-02-02
申请人： Dow Global Technologies Inc.
发明人： HAHN, Stephen, F. , MARRA, Jill, R.
IPC分类号： C08F12/02
CPC分类号： C08L51/003 , C08F8/04 , C08F257/02 , C08L51/006 , C08L53/025 , C08F12/00 , C08L2666/02 , C08L2666/24
摘要： The present invention is directed to a composition comprising: a) a hydrogenated aromatic polymer, wherein the hydrogenated aromatic polymer has an aromatic hydrogenation level of at least 90 percent, b) an inorganic filler, and c) optionally, a hydrogenated aromatic polymer, wherein the hydrogenated polymer has an aromatic hydrogenation level of at least 90 percent and contains a polar functional group.

60. 发明授权

EP0785957B1 NON-LINEAR STYRENIC POLYMER COMPOSITIONS AND ARTICLES PREPARED THEREFROM 失效
标题翻译：非线性聚苯乙烯化合物和对象由其MADE
公开(公告)号：EP0785957B1
公开(公告)日：1998-05-20
申请号：EP95939668.0
申请日：1995-10-11
申请人： THE DOW CHEMICAL COMPANY
发明人： DEMIRÖRS, Mehmet , SLEECKX, Jozef, Julius , VOLLENBERG, Peter, Hendrikus , VO, Chau, V. , WELSH, Gary, C.
IPC分类号： C08F12/02
CPC分类号： C08F12/04 , C08F2/02

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