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91. 发明申请

US20100330370A1 ELECTROPOLYMERIZABLE SURFACTANT FOR DISPERSING CARBON NANOTUBES 审中-公开
标题翻译：用于分散碳纳米管的可电熔化表面活性剂
公开(公告)号：US20100330370A1
公开(公告)日：2010-12-30
申请号：US12865235
申请日：2009-01-28
申请人： Serge Cosnier , Michael Holzinger , Elena Rodica Ionescu
发明人： Serge Cosnier , Michael Holzinger , Elena Rodica Ionescu
IPC分类号： B32B27/00 , C08K3/04 , B05D3/14
CPC分类号： C09D4/00 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/34 , C01B2202/36 , C08K3/04 , C09D7/45 , C09D7/70 , C25D13/04 , C25D15/00 , Y10T428/2998
摘要： The disclosure concerns an aqueous composition comprising carbon nanotubes and a surfactant, characterized in that the carbon nanotubes are single-wall hydrophobic nanotubes and in that the surfactant is chosen among electropolymerizable surfactant monomers of formula (I): X—Y—Z (I) wherein: X is an electropolymerizable moiety selected from the group consisting of pyrrole, acetylene, phenol, aniline, thiophene, carbazole, indole and azulene Y is a hydrophobic hydrocarbon chain and Z is a polar group selected from the group consisting of quaternary ammonium salts, alkylphosphonates and sulfonates. The disclosure also relates to a method for the preparation of an aqueous composition as described above, comprising the following steps: i) solubilisation of the surfactant monomer ii) addition of the single-wall carbon nanotubes in the aqueous solution comprising said surfactant monomer, (iii) sonication of the resulting solution, and, optionally (iv) addition of a protein.
摘要翻译：本发明涉及包含碳纳米管和表面活性剂的水性组合物，其特征在于，碳纳米管是单壁疏水性纳米管，并且表面活性剂选自式（I）的可电共聚表面活性剂单体：X-Y-Z（I）其中：X是选自吡咯，乙炔，苯酚，苯胺，噻吩，咔唑，吲哚和薁的电可共聚部分。Y是疏水性烃链，Z是极性基团，选自季铵盐，烷基膦酸盐和磺酸盐。本公开还涉及如上所述的水性组合物的制备方法，包括以下步骤：i）表面活性剂单体的溶解ii）在包含所述表面活性剂单体的水溶液中加入单壁碳纳米管，（ iii）对所得溶液进行超声处理，和任选地（iv）加入蛋白质。

92. 发明授权

US07858799B2 Ionic organic compound 有权
标题翻译：离子有机化合物
公开(公告)号：US07858799B2
公开(公告)日：2010-12-28
申请号：US11883462
申请日：2006-01-30
申请人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
发明人： Masaru Yoshida , Nagatoshi Koumura , Nobuyuki Tamaoki , Hajime Kawanami , Hajime Matsumoto , Said Kazaoui , Nobutsugu Minami
IPC分类号： C07D211/84 , C07D401/04 , C09K11/65
CPC分类号： H01B1/122 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/28 , C07D213/75 , Y02P20/542
摘要： An ionic organic compound having a repeating unit of formula (I) can be synthesized easily from a readily available organic compound through a small number of reaction steps, can be produced without any purification technique such as chromatography, and can be used in a quite small amount for gelation of water or an ionic liquid without any other auxiliary solvent: [-(A-B-C)n-]•m(X) (I) wherein A represents a group having a quaternary ammonium cation which is formed from a heterocyclic compound having at least one nitrogen atom; B represents a functional group, which may have a substituent, selected from amide, urea, urethane and peptide groups; C represents a divalent hydrocarbon group, which may have a substituent, capable of linking between A and B; X represents an anion; n represents the number of repeating units; m represents the total number of anions; and n and m are the same integer. A hydrogel using the compound is stable under acidic conditions, capable of setting a large amount of water with a small amount thereof, and capable of quickly recovering the original elastic modulus against structural disruption caused by mechanical distortion. The hydrogel is capable of directly gelling an ionic liquid without other solvent such as water when causing gelation. Further, the hydrogel is capable of easily dispersing carbon nanotubes in water whose load on the environment is low.
摘要翻译：具有式（I）重复单元的离子有机化合物可以通过少量的反应步骤从容易获得的有机化合物容易地合成，可以在没有任何纯化技术如色谱法的情况下制备，并且可以用于相当小的不含任何其他辅助溶剂的水或离子液体的凝胶化量：[ - （ABC）n-]•m（X）（I）其中A表示具有季铵阳离子的基团，该季铵阳离子由杂环化合物形成，至少一个氮原子; B表示可以具有选自酰胺，脲，氨基甲酸酯和肽基团的取代基的官能团; C表示能够连接A和B的可具有取代基的二价烃基; X表示阴离子; n表示重复单元的数量; m表示阴离子总数; 并且n和m是相同的整数。使用该化合物的水凝胶在酸性条件下是稳定的，能够少量地设置大量的水，并且能够快速恢复原始的弹性模量，抵抗由机械变形引起的结构破坏。当凝胶化时，水凝胶能够直接凝胶化没有其它溶剂如水的离子液体。此外，水凝胶能够容易地将碳纳米管分散在环境负荷低的水中。

93. 发明申请

US20100324315A1 POLY(CITRIC ACID) FUNCTIONALIZED CARBON NANOTUBE DRUG DELIVERY SYSTEM 有权
标题翻译：聚（亚硝酸）官能化碳纳米管药物输送系统
公开(公告)号：US20100324315A1
公开(公告)日：2010-12-23
申请号：US12870943
申请日：2010-08-30
申请人： Fatemeh Atyabi , Mohsen Adeli , Zahra Sobhani , Rassoul Dinarvand , Mohammad Hossein Ghahremani
发明人： Fatemeh Atyabi , Mohsen Adeli , Zahra Sobhani , Rassoul Dinarvand , Mohammad Hossein Ghahremani
IPC分类号： C07D305/14 , C07C59/245
CPC分类号： A61K9/0092 , A61K47/6921 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/34 , C01B2202/36 , C07B41/12 , C07D305/14 , Y10S977/742 , Y10S977/752 , Y10S977/906
摘要： A method for synthesizing carbon nanotube drug carriers and the carbon nanotube drug carriers are disclosed. Initially, carbon nanotubes, nitric acid, and sulfuric acid are mixed to oxidize carbon nanotubes in a first mixture. The oxidized carbon nanotubes are then extracted from the first mixture. The oxidized carbon nanotubes and monohydrated citric acid are mixed to synthesize carbon nanotubes grafted with poly(citric acid) in a second mixture. The carbon nanotubes grafted with poly(citric acid) are then extracted from the second mixture. The carbon nanotubes grafted with poly(citric acid) and 4-(dimethylamino)pyridine are dissolved in anhydrous dimethylformamide in a third mixture. Next, a mixture that comprises a drug is added to the third mixture to synthesize the carbon nanotubes grafted with poly(citric acid) and the drug in a fourth mixture. Then, the carbon nanotubes grafted with poly(citric acid) and the drug are extracted from the fourth mixture.
摘要翻译：公开了碳纳米管药物载体和碳纳米管药物载体的合成方法。首先，将碳纳米管，硝酸和硫酸混合以在第一混合物中氧化碳纳米管。然后从第一混合物中提取氧化的碳纳米管。将氧化的碳纳米管和一水合柠檬酸混合以合成在第二混合物中用聚（柠檬酸）接枝的碳纳米管。然后从第二混合物中提取用聚（柠檬酸）接枝的碳纳米管。用聚（柠檬酸）和4-（二甲基氨基）吡啶接枝的碳纳米管以第三混合物溶解在无水二甲基甲酰胺中。接下来，将包含药物的混合物加入到第三混合物中，以合成在第四混合物中接枝有聚（柠檬酸）和药物的碳纳米管。然后，从第四混合物中提取用聚（柠檬酸）和药物接枝的碳纳米管。

94. 发明授权

US07854914B2 Soluble carbon nanotubes 失效
标题翻译：可溶性碳纳米管
公开(公告)号：US07854914B2
公开(公告)日：2010-12-21
申请号：US12404095
申请日：2009-03-13
申请人： William E. Ford , Jurina Wessels , Akio Yasuda
发明人： William E. Ford , Jurina Wessels , Akio Yasuda
IPC分类号： D01F9/12 , C09C1/56
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , C08G18/0847 , C08G18/701 , C08K7/24 , Y02P20/135 , Y10S977/745 , Y10S977/746 , Y10S977/748 , Y10T428/2991 , Y10T428/2998 , Y10T428/30
摘要： The present invention relates to a method of solubilizing carbon nanotubes, to carbon nanotubes produced thereby and to uses of said carbon nanotubes.
摘要翻译：本发明涉及一种使碳纳米管增溶的方法，由碳纳米管制成的碳纳米管和所述碳纳米管的用途。

95. 发明申请

US20100300358A1 APPARATUS FOR PRODUCING SINGLE-WALL CARBON NANOTUBES 有权
标题翻译：用于生产单壁碳纳米管的装置
公开(公告)号：US20100300358A1
公开(公告)日：2010-12-02
申请号：US11565740
申请日：2006-12-01
申请人： Olivier SMILJANIC , Barry L. STANSFIELD
发明人： Olivier SMILJANIC , Barry L. STANSFIELD
IPC分类号： C23C16/00
CPC分类号： B82Y30/00 , B01J19/088 , B01J2219/0871 , B01J2219/0875 , B01J2219/0892 , B01J2219/0894 , B82Y40/00 , C01B32/162 , C01B2202/02 , D01F9/127 , Y10S977/843 , Y10S977/844
摘要： There is provided an apparatus for producing single-wall carbon nanotubes. The apparatus comprises a plasma torch having a plasma tube adapted to receive an inert gas and form an inert gas plasma; a feeder adapted to direct a carbon-containing substance and a metal catalyst towards said inert gas plasma so that the carbon-containing substance and the metal catalyst contact said inert gas plasma downstream of where said inert gas is introduced in said plasma tube, to thereby form a plasma comprising atoms or molecules of carbon and the atoms of said metal; and a condenser for condensing the atoms or molecules of carbon and the atoms of said metal to form single-wall carbon nanotubes.
摘要翻译：提供了一种用于制备单壁碳纳米管的装置。该装置包括等离子体焰炬，其具有适于接收惰性气体并形成惰性气体等离子体的等离子体管; 一种适于将含碳物质和金属催化剂引向所述惰性气体等离子体的进料器，使得含碳物质和金属催化剂接触所述惰性气体在所述等离子体管中引入所述惰性气体的下游，形成包含碳原子或分子和所述金属的原子的等离子体; 以及用于冷凝碳原子或分子和所述金属的原子以形成单壁碳纳米管的冷凝器。

96. 发明授权

US07833366B1 Method for making single walled carbon nanotubes by activation with hydrazoic acid 失效
标题翻译：用叠氮酸活化制备单壁碳纳米管的方法
公开(公告)号：US07833366B1
公开(公告)日：2010-11-16
申请号：US11998982
申请日：2007-10-31
申请人： Farhad Forohar , Magdy Bichay
发明人： Farhad Forohar , Magdy Bichay
IPC分类号： C06B45/00 , C06B45/04 , C06B35/00 , D03D23/00 , D03D43/00
CPC分类号： C06B45/20 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/178 , C01B2202/02 , C01B2202/10 , C06B23/005
摘要： The present invention relates generally to methods of making carbon nanotubes, and more particularly to the interaction of single wall carbon nanotubes with hydrazoic acid to introduce energetic azide groups into the nanotubes to form activated carbon nanotubes.
摘要翻译：本发明一般涉及制备碳纳米管的方法，更具体地说涉及单壁碳纳米管与氢氮酸的相互作用，以将能量叠氮化物基团引入到纳米管中以形成活性碳纳米管。

97. 发明申请

US20100283008A1 Carbon Nanotube Compositions and Methods for Production Thereof 审中-公开
标题翻译：碳纳米管组合物及其生产方法
公开(公告)号：US20100283008A1
公开(公告)日：2010-11-11
申请号：US12679864
申请日：2008-09-24
申请人： Juan G. Duque , Matteo Pasquali , Howard K. Schmidt , Laurent Cogent , A. Nicholas G. Parra-Vasquez
发明人： Juan G. Duque , Matteo Pasquali , Howard K. Schmidt , Laurent Cogent , A. Nicholas G. Parra-Vasquez
IPC分类号： C09K11/02 , B01J13/06
CPC分类号： B82Y30/00 , A61B18/28 , A61N5/062 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/28 , C01P2004/04 , C01P2004/13 , C09C1/44
摘要： Compositions comprising at least one type of carbon nanotube, at least one surfactant, and at least one polymer are disclosed. The compositions provide stable fluorescence over a wide range of pH in various embodiments. In some embodiments, the compositions are biocompatible. Methods for preparing the compositions from at least one pre-formed polymer are disclosed. Methods for preparing the compositions from at least one monomer are disclosed. Heating methods utilizing the compositions are disclosed.
摘要翻译：公开了包含至少一种类型的碳纳米管，至少一种表面活性剂和至少一种聚合物的组合物。在各种实施方案中，组合物在宽范围的pH下提供稳定的荧光。在一些实施方案中，组合物是生物相容的。公开了从至少一种预成型聚合物制备组合物的方法。公开了从至少一种单体制备组合物的方法。公开了利用组合物的加热方法。

98. 发明授权

US07820245B2 Method of synthesizing single-wall carbon nanotubes 有权
标题翻译：合成单壁碳纳米管的方法
公开(公告)号：US07820245B2
公开(公告)日：2010-10-26
申请号：US11655424
申请日：2007-01-19
申请人： Zhi Zheng , Yuan Yao , Liang Liu , Shou-Shan Fan
发明人： Zhi Zheng , Yuan Yao , Liang Liu , Shou-Shan Fan
IPC分类号： C23C16/00
CPC分类号： C23C14/165 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C23C14/5853 , C30B25/00 , C30B29/602 , Y10S977/89 , Y10S977/891
摘要： A method for synthesizing single-wall carbon nanotubes (SWNTs) generally includes the steps of: providing a substrate having an upper portion comprised of indium tin oxide; forming an aluminum layer on the upper portion of the substrate; forming a catalyst layer on the aluminum layer to obtain a treated substrate; annealing the treated substrate so as to transform the catalyst layer into a plurality of oxidized catalyst particles on the substrate; and growing a plurality of single-wall carbon nanotubes on the treated substrate using a chemical vapor deposition process.
摘要翻译：合成单壁碳纳米管（SWNT）的方法通常包括以下步骤：提供具有由铟锡氧化物构成的上部的基材; 在所述基板的上部形成铝层; 在铝层上形成催化剂层，得到经处理的基材; 对经处理的基板进行退火，以将催化剂层转化为基板上的多个氧化催化剂颗粒; 以及使用化学气相沉积工艺在经处理的衬底上生长多个单壁碳纳米管。

99. 发明授权

US07807127B1 Functionalization of carbon nanotubes 失效
标题翻译：碳纳米管的功能化
公开(公告)号：US07807127B1
公开(公告)日：2010-10-05
申请号：US11417294
申请日：2006-04-14
申请人： Farhad Forohar , Craig Whitaker , William M. Koppes
发明人： Farhad Forohar , Craig Whitaker , William M. Koppes
IPC分类号： D01F9/12
CPC分类号： B82Y40/00 , B82Y10/00 , B82Y30/00 , C01B32/174 , C01B2202/02 , H01L51/0049 , Y10S977/745 , Y10S977/748
摘要： The present invention relates to a carbon nanotube that contains nitrogen based functional groups (such as nitro, nitroso, N-oxide, oxime, hydroxylamine, diazo, azo, and azide) that are covalently attached to lattice carbons of the carbon nanotube, directly or via a chemical linker. The present invention also relates to methods for the preparation of the carbon nanotube from an amino-functionalized carbon nanotube via an amino oxidation reaction. The synthetic methods of the present invention allow the nitrogen based functional groups to be attached selectively to one of two distinct regions of the carbon nanotube, the ends or the sidewall, and thus enable the synthesis of a carbon nanotube having nitrogen based functional groups substantially concentrated on either the ends or the sidewall of the carbon nanotube.
摘要翻译：本发明涉及碳纳米管，其直接或间接地共价连接到碳纳米管的格子状碳上的氮基官能团（例如硝基，亚硝基，N-氧化物，肟，羟胺，重氮，偶氮和叠氮化物）通过化学接头。本发明还涉及通过氨基氧化反应从氨基官能化的碳纳米管制备碳纳米管的方法。本发明的合成方法允许氮基官能团选择性地连接到碳纳米管，末端或侧壁的两个不同区域中的一个，从而能够合成具有基本上浓度的基于氮的官能团的碳纳米管在碳纳米管的两端或侧壁上。

100. 发明申请

US20100247381A1 PROCESSES AND APPLICATIONS OF CARBON NANOTUBE DISPERSIONS 审中-公开
标题翻译：碳纳米管分散体的工艺和应用
公开(公告)号：US20100247381A1
公开(公告)日：2010-09-30
申请号：US12792963
申请日：2010-06-03
申请人： Arjun G. Yodh , Mohammad F. Islam , Alan T. Johnson, JR. , Danvers E. Johnston
发明人： Arjun G. Yodh , Mohammad F. Islam , Alan T. Johnson, JR. , Danvers E. Johnston
IPC分类号： G01N33/00 , D01F9/12 , C09K5/00 , H01B1/04 , C07C211/02 , C07C53/00 , C07C11/00 , B05D5/00 , B32B3/10 , H05K1/00 , G21G4/00
CPC分类号： C04B35/62625 , B82Y10/00 , B82Y15/00 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B2202/02 , C04B35/117 , C04B35/14 , C04B35/46 , C04B35/624 , C04B35/6263 , C04B35/63 , C04B35/632 , C04B2235/444 , C04B2235/448 , C04B2235/483 , C04B2235/526 , C04B2235/5264 , C04B2235/5288 , C08K7/24 , G01N33/551 , Y10T428/24612 , Y10T428/24802 , Y10T428/249921
摘要： Disclosed are copolymers of carbon nanotubes, as well as processes and applications of carbon nanotube dispersions. Carbon nanotube emulsions and related technology are also disclosed. The controlled deposition of carbon nanotubes on substrates is also provided. Methods of purifying single-walled carbon nanotubes are also provided. Devices made according to the disclosed methods are further described herein.
摘要翻译：公开了碳纳米管的共聚物，以及碳纳米管分散体的工艺和应用。还公开了碳纳米管乳液和相关技术。还提供了碳纳米管在基底上的受控沉积。还提供了纯化单壁碳纳米管的方法。根据所公开的方法制造的装置在本文中进一步描述。

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