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31. 发明申请

US20130158229A1 PROCESSES FOR THE PRODUCTION OF HYDROGENATED PRODUCTS AND DERIVATIVES THEREOF 审中-公开
标题翻译：生产氢化产物及其衍生物的方法
公开(公告)号：US20130158229A1
公开(公告)日：2013-06-20
申请号：US13701589
申请日：2011-06-10
申请人： Olan S. Fruchey , Leo E. Manzer , Dilum Dunuwila , Brian T. Keen , Brooke A. Albin , Nye A. Clinton , Bernard D. Dombek
发明人： Olan S. Fruchey , Leo E. Manzer , Dilum Dunuwila , Brian T. Keen , Brooke A. Albin , Nye A. Clinton , Bernard D. Dombek
IPC分类号： C07D313/04 , C07D223/10 , C07C29/147
CPC分类号： C07D313/04 , C07C29/147 , C07C29/149 , C07C51/02 , C07D223/10 , C12P7/44 , C12P17/08 , C07C31/20 , C07C55/14
摘要： A process for making a hydrogenated product comprising caprolactone (CLO) and 1,6-hexanediol (HDO) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).
摘要翻译：制备由含有己二酸二铵（DAA）或己二酸单铵（MAA）的发酵液得到的己二酸（AA）的己内酯（CLO）和1,6-己二醇（HDO）及其衍生物的氢化产物的方法。

32. 发明申请

US20120277487A1 Process for Removing Aldehydes from Ethanol Reaction Mixture 有权
标题翻译：从乙醇反应混合物中去除醛的方法
公开(公告)号：US20120277487A1
公开(公告)日：2012-11-01
申请号：US13197749
申请日：2011-08-03
申请人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic
发明人： David Lee , Adam Orosco , Lincoln Sarager , R. Jay Warner , Radmila Jevtic
IPC分类号： C07C29/147 , B01D3/00
CPC分类号： C07C29/149 , C07C29/80 , C07C31/08
摘要： A process for purifying an ethanol stream that comprises byproduct, such as aldehyde, acetals, and/or esters, but withdrawing a sidestream comprising ethanol from a distillation column. The sidestream may have a reduced concentration of aldehyde that reduces the formation of acetals in subsequent purification of the ethanol stream.
摘要翻译：一种纯化乙醇流的方法，其包括副产物，例如醛，缩醛和/或酯，但是从蒸馏塔中取出包含乙醇的侧流。侧流可能具有降低的醛浓度，从而在乙醇流的随后纯化中减少缩醛的形成。

33. 发明申请

US20120172453A1 METHODS FOR TREATING NEURODEGENERATIVE DISEASES 审中-公开
标题翻译：治疗神经损伤性疾病的方法
公开(公告)号：US20120172453A1
公开(公告)日：2012-07-05
申请号：US13223244
申请日：2011-08-31
申请人： Ben A. Barres , Naoki Nakayama , Hiroaki Serizawa , Ankush B. Argade
发明人： Ben A. Barres , Naoki Nakayama , Hiroaki Serizawa , Ankush B. Argade
IPC分类号： A61K31/121 , C07C29/147 , C07C45/65 , C07D317/12 , A61P25/28 , A61P25/00 , C12N5/0793 , C07C49/203 , C07C45/59
CPC分类号： A61K31/121 , A61K9/10 , C07B2200/09 , C07C29/147 , C07C45/59 , C07C45/676 , C07C49/203 , C07C67/343 , C07C69/738 , C07C69/587 , C07C33/02
摘要： This invention relates to the 5-cis and 5-trans isomers of geranylgeranyl acetone, preferably such synthetic isomers, and pharmaceutical compositions containing such isomers. Other aspects of this invention relate to the use of geranylgeranyl acetone and its isomers in methods for inhibiting neural death, increasing neural activity, and increasing axon growth and cell viability. Geranylgeranyl acetone is a known anti-ulcer drug used commercially and in clinical situations. GGA has also been shown to exert cytoprotective effects on a variety of organs, such as the eye, brain, and heart.
摘要翻译：本发明涉及香叶基香叶基丙酮的5-顺式和5-反式异构体，优选这种合成异构体，以及含有这些异构体的药物组合物。本发明的其它方面涉及er牛儿基ger牛酮丙酮及其异构体在抑制神经死亡，增加神经活性和增加轴突生长和细胞活力的方法中的用途。香叶基香叶基丙酮是已知的抗溃疡药物，其商业和临床情况下使用。 GGA也被证明会对各种器官（如眼睛，脑部和心脏）发挥细胞保护作用。

34. 发明申请

US20110124894A1 METHOD FOR OBTAINING LONG CHAIN ALIPHATIC ALCOHOLS AND FATTY ACIDS FROM SUGAR CANE MUD AND RELATED WAX ESTERS 审中-公开
标题翻译：获取长链脂肪醇和脂肪酸的方法，由糖类和相关品种
公开(公告)号：US20110124894A1
公开(公告)日：2011-05-26
申请号：US12625797
申请日：2009-11-25
申请人： Rafael Almagro
发明人： Rafael Almagro
IPC分类号： C07C29/147 , C09K3/00 , C11B1/00 , C07J1/00
CPC分类号： C07J9/00 , C07C29/095 , C07C67/56 , C11C1/025 , C07C31/125 , C07C69/26
摘要： Methods are provided for the extraction of wax esters from sugar cane mud, isolation of the wax, saponification of the wax, either after isolation or in an intermediate un-isolated form to provide higher primary aliphatic alcohols (HPAA's) and fatty acids having nutritional and medicinal uses. The solid waste resulting from the process can be disposed of or utilized as a soil substitute following an optional water wash. Additionally, methods are provided for providing modified forms of the sugar cane mud or cachaza having reduced volumes and/or water content that require less storage space and capable of being stored for long periods of time with little or no biological degradation.
摘要翻译：提供了用于从甘蔗泥浆中提取蜡酯的方法，分离蜡，分离蜡或在分离后或以中间体非分离形式提供蜡，以提供更高级的伯脂肪醇（HPAA）和脂肪酸，其具有营养和药用。由该方法产生的固体废物可以经过任选的水洗处理或用作土壤代用品。此外，提供了用于提供改进形式的甘蔗泥浆或具有减少的体积和/或水含量的方法，其需要较少的储存空间并且能够在很少或没有生物降解的情况下长时间储存。

35. 发明授权

US07847134B2 Process of producing monohydric alcohols from monocarboxylic acids or derivatives thereof 有权
标题翻译：由一元羧酸或其衍生物生产一元醇的方法
公开(公告)号：US07847134B2
公开(公告)日：2010-12-07
申请号：US12594025
申请日：2009-02-27
申请人： Jung Ho Lee , Jong San Chang , Young Kyu Hwang , Hyun Kwan Shin , Kwang Myung Cho , Bong Keun Song , Yong Hwan Kim
发明人： Jung Ho Lee , Jong San Chang , Young Kyu Hwang , Hyun Kwan Shin , Kwang Myung Cho , Bong Keun Song , Yong Hwan Kim
IPC分类号： C07C29/147
CPC分类号： C07C29/149 , B01J23/626 , B01J23/6567 , B01J23/8966 , B01J37/0009 , B01J37/031 , B01J37/10 , B01J37/18 , B01J2523/00 , C07C31/12 , B01J2523/27 , B01J2523/43 , B01J2523/821 , B01J2523/74 , B01J2523/828 , B01J2523/845 , B01J2523/17 , B01J2523/47 , B01J2523/41
摘要： Disclosed herein is a method for producing monohydric alcohols from monocarboxylic acids or derivatives thereof using a catalyst comprising ruthenium (Ru) and tin (Sn) using zinc oxide (ZnO) as both a catalyst support and an active promoter; a catalyst prepared by adding an inorganic binder such as silica, alumina or titania in a limited range to the catalyst comprising the above components in order to impart a shaping ability to the catalyst; or, a modified catalyst reformed by adding at least one reducing component selected from the group consisting of Co, Ni, Cu, Ag, Rh, Pd, Re, Ir, and Pt to the catalyst in order to improve the reducing ability of the catalyst. By using such catalysts, the method according to the present invention is advantageous in that the monohydric alcohols can be prepared in high yield regardless of whether the monocarboxylic acids contain water or not, the monohydric alcohols can be economically prepared because the catalysts can be operated under mild reaction conditions and also exhibits high selectivity and productivity compared to conventional catalysts, and the catalysts have excellent long-term reaction stability so as to be advantageous for industrial applications.
摘要翻译：本文公开了使用氧化锌（ZnO）作为催化剂载体和活性促进剂两者，使用包含钌（Ru）和锡（Sn）的催化剂由一元羧酸或其衍生物生产一元醇的方法; 通过在包含上述组分的催化剂的有限范围内加入无机粘合剂如二氧化硅，氧化铝或二氧化钛制备的催化剂，以赋予催化剂成型能力; 或者，通过向催化剂中添加选自Co，Ni，Cu，Ag，Rh，Pd，Re，Ir和Pt中的至少一种还原成分而改性的改性催化剂，以提高催化剂的还原能力。通过使用这样的催化剂，根据本发明的方法的优点在于，一元醇可以以高产率制备，而不管单羧酸是否含有水，一元醇可经济地制备，因为催化剂可以在温和的反应条件，并且与常规催化剂相比表现出高选择性和生产率，并且催化剂具有优异的长期反应稳定性，从而有利于工业应用。

36. 发明申请

US20080293976A1 NANO-STRUCTURE SUPPORTED SOLID REGENERATIVE POLYAMINE AND POLYAMINE POLYOL ABSORBENTS FOR THE SEPARATION OF CARBON DIOXIDE FROM GAS MIXTURES INCLUDING THE AIR 有权
标题翻译：用于从包括空气的气体混合物分离二氧化碳的纳米结构支持的固体再生聚酰胺和聚氨酯多元醇吸收剂
公开(公告)号：US20080293976A1
公开(公告)日：2008-11-27
申请号：US11780244
申请日：2007-07-19
申请人： George A. Olah , Alain Goepert , Sergio Meth , G.K. Surya Prakash
发明人： George A. Olah , Alain Goepert , Sergio Meth , G.K. Surya Prakash
IPC分类号： B01D53/02 , B01J20/00 , B01J20/08 , B01J20/10 , B01D53/30 , C07C41/09 , C07C29/04 , C07C1/20 , B01D53/12 , B01J20/20 , B01J20/22 , C07C29/147
CPC分类号： C07C29/04 , B01D53/025 , B01D53/1475 , B01D2257/504 , B01J20/103 , B01J20/28007 , B01J20/28061 , B01J20/3021 , B01J20/3204 , B01J20/3251 , B01J20/3253 , B01J20/3272 , B01J20/3425 , B01J20/3483 , B01J20/3491 , B82Y30/00 , C07C1/20 , C07C29/149 , C07C41/09 , Y02C10/04 , Y02C10/06 , Y02C10/08 , Y02P20/152 , C07C11/02 , C07C31/04 , C07C31/08 , C07C31/10 , C07C43/043
摘要： The invention relates to regenerative, supported amine sorbents that includes an amine or an amine/polyol composition deposited on a nano-structured support such as nanosilica. The sorbent provides structural integrity, as well as high selectivity and increased capacity for efficiently capturing carbon dioxide from gas mixtures, including the air. The sorbent is regenerative, and can be used through multiple operations of absorption-desorption cycles.
摘要翻译：本发明涉及再生的，负载的胺吸附剂，其包含沉积在纳米结构的载体如纳米二氧化硅上的胺或胺/多元醇组合物。吸附剂提供结构完整性，以及高选择性和提高的有效捕集包括空气在内的气体混合物中的二氧化碳的能力。吸附剂是再生的，可以通过吸收 - 解吸循环的多个操作来使用。

37. 发明授权

US07038094B2 Hydrogenolysis of 5-carbon sugars, sugar alcohols, and methods of making propylene glycol 有权
标题翻译： 5-碳糖，糖醇的氢解和制备丙二醇的方法
公开(公告)号：US07038094B2
公开(公告)日：2006-05-02
申请号：US10676497
申请日：2003-09-30
申请人： Todd A. Werpy , John G. Frye, Jr. , Alan H. Zacher , Dennis J. Miller
发明人： Todd A. Werpy , John G. Frye, Jr. , Alan H. Zacher , Dennis J. Miller
IPC分类号： C07C29/149 , C07C29/147 , C07C29/136
CPC分类号： C07C29/00 , B01J21/18 , B01J23/36 , B01J23/8896 , C07C29/149 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/225 , C07C31/202
摘要： Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
摘要翻译：描述了在含Re催化剂上的氢与含有5-碳糖，糖醇或乳酸的组合物的反应的方法和组合物。已经令人惊讶地发现与含氢多金属催化剂上的氢反应导致对所需产物如丙二醇的优异的转化率和选择性。还描述了从乳酸或乳酸合成PG的方法。

38. 发明申请

US20050222452A1 Process for preparing dioxy-functionalized propane compounds 审中-公开
标题翻译：制备二官能化丙烷化合物的方法
公开(公告)号：US20050222452A1
公开(公告)日：2005-10-06
申请号：US10814859
申请日：2004-03-31
申请人： Raghunath Chaudhari , Yogesh Borole , Shubhangi Umbarkar
发明人： Raghunath Chaudhari , Yogesh Borole , Shubhangi Umbarkar
IPC分类号： C07C29/14 , C07C29/147 , C07C67/29 , C07C69/76
CPC分类号： C07C29/147 , C07C67/29 , C07C67/293 , C07C69/003 , C07C69/14 , C07C69/145 , C07C31/205
摘要： The present invention relates to a process for preparing, dioxy functionalised propane compounds using cobalt and/or rhodium catalysts. More particularly, the present invention relates to a process for the preparation of the dioxy functionalised propane compounds of the formula X—CH2—CH(Y)—CH2-Z, wherein X=R—C(═O)—O— or H or —OH, Y and Z=—H or —OH or —C(═O)H, and wherein at a time, only one of X, Y and Z is —H, in high yields from vinyl carboxylates of formula R—C(═O)—O—CH═CH2 wherein, R=substituted or unsubstituted alkyl or aryl group.
摘要翻译：本发明涉及使用钴和/或铑催化剂制备二氧官能化丙烷化合物的方法。更具体地说，本发明涉及一种制备式X-CH 2 -CH（Y）-CH 2 -Z -Z（CH 2）-CH 2的二氧官能化丙烷化合物的方法，其中X = RC（-O）-O-或H或-OH，Y和Z = -H或-OH或-C（-O）H，并且其中一次只有X，Y和Z中的一个是-H，以高得率的式RC（-O）-O-CH-CH 2乙烯基羧酸酯，其中R =取代或未取代的烷基或芳基。

39. 发明授权

US06906228B2 Method for catalytic hydrogenation on rhenium-containing active carbon carrier catalysts 失效
标题翻译：用于含铼活性炭载体催化剂的催化氢化方法
公开(公告)号：US06906228B2
公开(公告)日：2005-06-14
申请号：US10220566
申请日：2001-03-01
申请人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
IPC分类号： B01J21/18 , B01J23/656 , B01J23/89 , C07C29/17 , C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/145 , C07C29/147 , C07C29/149 , C07C29/146 , C07C29/148
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭未经氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

40. 发明授权

US6166156A Method for making photocurable halofluorinated acrylates 有权
标题翻译：制备可光固化的氟氟化丙烯酸酯的方法
公开(公告)号：US6166156A
公开(公告)日：2000-12-26
申请号：US190194
申请日：1998-11-12
申请人： Chengjiu Wu , Baopei Xu , James T. Yardley
发明人： Chengjiu Wu , Baopei Xu , James T. Yardley
IPC分类号： G02B6/12 , C07C29/147 , C07C29/149 , C07C31/42 , C07C51/093 , C07C51/285 , C07C55/32 , C07C67/08 , C07C67/14 , C07C69/63 , C07C69/653 , C08F8/00 , C08F8/04 , C08F8/06 , C08F8/26 , C08F14/18 , C08G63/682 , C08G64/10 , C08G69/42 , C08F20/22 , C08F6/00 , C08F120/22 , C08F220/22
CPC分类号： C07C51/285 , C07C29/149 , C07C31/42 , C07C67/08 , C07C69/653 , C08F8/00 , C08F8/04 , C08F8/06 , C08F8/10 , C08F8/14 , C08F2800/10 , C08F2810/30 , Y10S526/914 , C07C55/32 , C07C69/63 , C08F20/00 , C08F214/24
摘要： Halofluorinated alkylene monomers are made by a method comprising the steps of: (a) subjecting a first polymer which is the reaction product of a fluorinated vinyl monomer and a vinyl comonomer to dehydrohalogenation to form a second polymer; (b) treating the second polymer with an oxidizing agent to form an oxidation product consisting of a .alpha., .omega.-dicarboxylic acid or an ester derivative thereof; and (c) treating said oxidation product with a reducing agent to form a reduction product consisting of a a .alpha., .omega.-diol. Preferably, the first polymer has a structure of --[CH.sub.2 CYZ(CF.sub.2 CFX).sub.n ].sub.m -- wherein X and Y=F, Cl or Br; X and Y may be the same or different; Z=H, F, Cl, Br, alkyl or perfluoroalkyl containing from about 1 to about 10 carbon atoms; n=an integer larger than about 1; and m is an integer between about 2 and about 10.sup.5. The .alpha., .omega.-dicarboxylic acids and .alpha., .omega.-diols produced herein can be directly used as polycondensation monomers. Alternatively, the .alpha., .omega.-dicarboxylic acids and .alpha., .omega.-diols can be further derivitized to tri-, tetra- or other multifunctional alcohols which may be directly used as condensation monomers or they may be converted to acrylates which may be photocured in the presence of a radical photoinitiator into transparent polymers which are useful as optical waveguiding materials.
摘要翻译：通过包括以下步骤的方法制备卤代亚烷基单体：（a）使作为氟化乙烯基单体和乙烯基共聚单体的反应产物的第一聚合物进行脱卤化氢以形成第二聚合物; （b）用氧化剂处理第二聚合物以形成由α，ω-二羧酸或其酯衍生物组成的氧化产物; 和（c）用还原剂处理所述氧化产物以形成由α，ω-二醇组成的还原产物。优选地，第一聚合物具有 - [CH 2 CYZ（CF 2 CFX）n] m - 的结构，其中X和Y = F，Cl或Br; X和Y可以相同或不同; Z = H，F，Cl，Br，含有约1至约10个碳原子的烷基或全氟烷基; n =大于1的整数; m为约2至约105的整数。本文生产的α，ω-二羧酸和α，ω-二醇可直接用作缩聚单体。或者，可以将α，ω-二羧酸和α，ω-二醇进一步衍生为可以直接用作缩合单体的三元，四元或其它多官能醇，或者它们可以转化成丙烯酸酯，其可以在将自由基光引发剂存在于用作光波导材料的透明聚合物中。

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