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    • 43. 发明申请
    • METHOD FOR REGULATING THE STRUCTURE AND PROPERTIES OF THE COMPOSITE NANOABSORBENT
    • 用于调节复合纳米粒子的结构和性能的方法
    • US20140120253A1
    • 2014-05-01
    • US13818834
    • 2011-11-04
    • Bingcai PanJing WangShujuan ZhangLu LvWeiming Zhang
    • Bingcai PanJing WangShujuan ZhangLu LvWeiming Zhang
    • B01J20/32
    • B01J20/3295B01J20/06B01J20/267B01J20/321B01J20/3236C02F1/288C02F2101/103C02F2101/20C02F2305/08
    • A method for regulating the structure and properties of the composite nanoabsorbent is provided. This method uses nanoporous chloromethylated polystyrene-divinylbenzene beads as the support material and adopts in situ precipitation method to load dissociative functional nanoparticles thereon; the composite nanoabsorbent of different absorption capacity and absorption speed can be prepared through regulating the pore structure, which is realized herein by means of starting crosslinking reactions through heating chloromethylated beads under existence of the swelling agent and the catalyst; through changing the proportions of different components in the reaction system, modes of heating and time of reaction, the polymer support with different pore structures can be prepared. This invention can successfully regulate the distribution and size of inorganic nanoparticles; the composite nanomaterials prepared by the resin of different degrees of crosslinking present different structures and properties, and the specific structure and properties can be selected in order to meet practical requirements.
    • 提供了一种用于调节复合纳米吸收剂的结构和性能的方法。 该方法采用纳米多氯甲基化聚苯乙烯 - 二乙烯基苯珠作支撑材料,采用原位沉淀法在其上负载解离功能纳米粒子; 可以通过调节孔结构来制备不同吸收容量和吸收速度的复合纳米吸收剂,这是通过在溶胀剂和催化剂存在下加热氯甲基化珠来开始交联反应而实现的; 通过改变反应体系中不同组分的比例,加热方式和反应时间,可制备不同孔结构的聚合物载体。 本发明可以成功调节无机纳米颗粒的分布和尺寸; 由不同交联度的树脂制备的复合纳米材料具有不同的结构和性能,可以选择具体的结构和性能,以满足实际需要。
    • 49. 发明授权
    • Method for removing metal contaminants from a metal containing solution
    • 从含金属溶液中除去金属污染物的方法
    • US08357303B2
    • 2013-01-22
    • US11849867
    • 2007-09-04
    • Alfredo M. Angeles-BozaCharles R. LandisWilliam W. Shumway
    • Alfredo M. Angeles-BozaCharles R. LandisWilliam W. Shumway
    • C02F1/28C02F101/22
    • C22B3/24B01J20/12B01J20/165B01J20/18B01J20/22B01J20/261B01J20/265B01J20/267B01J20/3021B01J20/3204B01J20/3208B01J20/321B01J20/3248B01J20/3251B01J20/3425B01J20/3433B01J20/3475B01J2220/46C02F1/281C02F1/285C02F1/288C02F1/683C02F2101/103C02F2101/203C02F2101/206C02F2101/22C22B3/205Y02P10/234
    • A method for removing a metal from a metal-containing solution comprising contacting the metal-containing solution with a metal-removing composition comprising a substrate, an organic ion, and a metal binding agent, and recovering a solution having a lowered metal concentration when compared to the metal-containing solution. A composition comprising a substrate, an organic ion, and a metal binding agent, wherein the substrate comprises a natural clay, a synthetic clay, a natural zeolite, a synthetic zeolite, a polymer resin, lignite, kaolinite, serpentine, illite, chlorite, smectite, montmorillonite, saponite, sepiolite, nontronite, beidellite, hectorite, fuller's earth, attapulgite, bentonite, analcime, chabazite, heulandite, natrolite, phillipsite, stilbite, diethyl aminoethyl, quaternary aminoethyl, or combinations thereof, wherein the organic ion comprises quaternary amines, imidazolium salts, phosphonium salts, tetra alkyl ammonium, bis-(hydrogenated tallow)-dimethyl-ammonium chloride, bis-(hydrogenated tallow)-benzyl-methyl-ammonium chloride, 4,5-dihydro-1-methyl-2-nortallow-alkyl-1-(2-tallow-amidoethyl)-imidazolium methyl sulfate, 1-ethyl-4,5-dihydro-3-(2-hydroxyethyl)-2-(8-heptadecenyl)-imidazolium ethyl sulfate, or combinations thereof, and wherein the metal-binding agent comprises mercaptan, carboxylic acid, chelating agents, amines, esters, carboxylic acids, alcohols, ethers, aldehydes, ketones, alkenes, alkynes, mercaptans, thiols, tert-dodecanethiol, nonanethiol, octanethiol, n-stearic acid, iso-stearic acid, palmitic acid, or combinations thereof.
    • 一种从含金属溶液中除去金属的方法,包括使含金属溶液与包含基底,有机离子和金属粘合剂的金属去除组合物接触,并且当比较时回收具有降低的金属浓度的溶液 到含金属溶液。 包含基材,有机离子和金属粘合剂的组合物,其中所述基材包括天然粘土,合成粘土,天然沸石,合成沸石,聚合物树脂,褐煤,高岭石,蛇纹石,伊利石,亚氯酸盐, 绿泥石,蒙脱石,皂石,海泡石,白云母,贝得石,锂蒙脱石,富勒土,绿坡缕石,膨润土,顺铂,菱沸石,胡萝卜素,钠钙石,氯化石,二氧化硅,二乙基氨基乙基,季氨基乙基或其组合,其中有机离子包括季胺 ,咪唑鎓盐,鏻盐,四烷基铵,双(氢化牛油) - 二甲基氯化铵,双(氢化牛油) - 苄基 - 甲基 - 氯化铵,4,5-二氢-1-甲基-2- - 烷基-1-(2-牛油酰胺基乙基) - 咪唑鎓甲基硫酸盐,1-乙基-4,5-二氢-3-(2-羟乙基)-2-(8-十七烯基) - 咪唑鎓乙基硫酸盐或其组合 ,并且其中所述金属结合剂包括硫醇,碳酸氢盐 羟基酸,螯合剂,胺,酯,羧酸,醇,醚,醛,酮,烯烃,炔烃,硫醇,硫醇,叔十二烷硫醇,壬硫醇,辛硫醇,正硬脂酸,异硬脂酸,棕榈酸, 或其组合。