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51. 发明授权

US5849944A Polyurethane elastomers having improved green strength and demold time, and polyoxyalkylene polyols suitable for their preparation 失效
公开(公告)号：US5849944A
公开(公告)日：1998-12-15
申请号：US863264
申请日：1997-05-27
申请人： Gary L. Allen , Nigel Barksby , Stephen D. Seneker , Usama E. Younes
发明人： Gary L. Allen , Nigel Barksby , Stephen D. Seneker , Usama E. Younes
IPC分类号： A43B13/04 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/67 , C08G65/26 , C08L71/02 , C07C271/08
CPC分类号： C08G65/2663 , C08G18/10 , C08G18/12 , C08G18/4804 , C08G18/4808 , C08G18/4825 , C08G18/4841 , C08G18/4866 , C08G65/2642 , C08L71/02 , C08G2101/0008 , C08G2101/0066 , C08G2101/0083 , C08G2410/00
摘要： Elastomers exhibiting decreased demold times and improved green strength are prepared by reacting a di- or polyisocyanate with a monodisperse polyoxypropylene diol having ultra-low unsaturation, and preferably prepared by the double metal cyanide.t-butyl alcohol catalyzed polymerization of propylene oxide. Further improved demold times and elevated elastomer physical properties are made possible by the use of multidisperse polyoxyalkylene polyether polyol blends having an overall unsaturation of less than 0.010 meq/g and a polydispersity of about 1.4 or greater.

52. 发明授权

US5728745A Polyurethane elastomers having improved green strength and demold time, and polyoxyalkylene polyols suitable for their preparation 失效
标题翻译：具有改善的生坯强度和脱模时间的聚氨酯弹性体和适用于其制备的聚氧化烯多元醇
公开(公告)号：US5728745A
公开(公告)日：1998-03-17
申请号：US770188
申请日：1996-12-19
申请人： Gary L. Allen , Nigel Barksby , Stephen D. Seneker , Usama E. Younes
发明人： Gary L. Allen , Nigel Barksby , Stephen D. Seneker , Usama E. Younes
IPC分类号： A43B13/04 , C08G18/10 , C08G18/12 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/67 , C08G65/26 , C08L71/02 , C08J9/08
CPC分类号： C08G65/2663 , C08G18/10 , C08G18/12 , C08G18/4804 , C08G18/4808 , C08G18/4825 , C08G18/4841 , C08G18/4866 , C08G65/2642 , C08L71/02 , C08G2101/0008 , C08G2101/0066 , C08G2101/0083 , C08G2410/00
摘要： Elastomers exhibiting decreased demold times and improved green strength are prepared by reacting a di- or polyisocyanate with a monodisperse polyoxypropylene diol having ultra-low unsaturation, and preferably prepared by the double metal cyanide.t-butyl alcohol catalyzed polymerization of propylene oxide. Further improved demold times and elevated elastomer physical properties are made possible bythe use of multidisperse polyoxyalkylene polyether polyol blends having an overall unsaturation of less than 0.010 meq/g and a polydispersity of about 1.4 or greater.
摘要翻译：通过使二异氰酸酯或多异氰酸酯与具有超低不饱和度的单分散聚氧丙烯二醇反应，优选通过环氧丙烷的双金属氰化物叔丁醇催化聚合反应制备显示降低脱模时间和改善生坯强度的弹性体。通过使用具有小于0.010meq / g的总不饱和度和约1.4或更大的多分散性的多分散聚氧化烯聚醚多元醇共混物，进一步提高脱模时间和提高的弹性体物理性能成为可能。

53. 发明授权

US5677413A Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation 失效
标题翻译：具有改进的脱模绿强度和吸水性的聚氨酯弹性体和适用于它们制备的无混浊多元醇
公开(公告)号：US5677413A
公开(公告)日：1997-10-14
申请号：US490828
申请日：1995-06-15
申请人： Nigel Barksby , Stephen D. Seneker
发明人： Nigel Barksby , Stephen D. Seneker
IPC分类号： C08G65/12 , C08G18/10 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/67 , C08G18/76 , C08G65/02 , C08G65/26
CPC分类号： C08G65/2696 , C08G18/10 , C08G18/4804 , C08G18/4837 , C08G18/4841 , C08G18/4866 , C08G18/6674 , C08G65/2609 , C08G65/2663 , C08G2101/0066 , C08G2410/00 , Y10S521/914
摘要： Polyurethane elastomers exhibiting improved green strength while maintaining short demold times are prepared from ultra-low unsaturation polyoxypropylene polyols containing up to 20 weight percent internal random oxyethylene moieties. The elastomers adsorb less than 10 weight percent water at 0.degree. C. The internal polyoxyethylene moiety-containing polyoxypropylene polyols may be used to prepare ultra-low unsaturation polyoxyethylene capped polyols which are haze-free and which may be used to prepare haze-free 4,4'-MDI prepolymers. Multidisperse blends of monodisperse internal oxyethylene moiety-containing polyoxypropylene polyols of ultra-low unsaturation provide yet further improvements in elastomer processing.
摘要翻译：具有改善的生坯强度同时保持短脱模时间的聚氨酯弹性体由含有至多20重量％的内部随机氧化乙烯部分的超低不饱和度聚氧丙烯多元醇制备。弹性体在0℃下吸附少于10重量％的水。含内聚氧乙烯部分的聚氧丙烯多元醇可用于制备无雾的超低不饱和聚氧乙烯封端的多元醇，其可用于制备无雾4 ，4'-MDI预聚物。具有超低不饱和度的单分散内含氧化乙烯部分的聚氧丙烯多元醇的多分散共混物提供弹性体加工的进一步改进。

54. 发明授权

US5538779A Polyurethane foam for packaging applications 失效
公开(公告)号：US5538779A
公开(公告)日：1996-07-23
申请号：US541769
申请日：1995-10-10
申请人： Henri L. S. A. Mispreuve , Ulrich Tribelhorn , Simon Waddington
发明人： Henri L. S. A. Mispreuve , Ulrich Tribelhorn , Simon Waddington
IPC分类号： B65D81/107 , B65D81/05 , C08G18/00 , C08G18/48 , C08G18/66 , C08G18/76 , C08G101/00 , C08G18/06 , C08G18/08
CPC分类号： C08G18/4804 , C08G18/7664 , C08G2101/005 , C08G2101/0075 , C08G2101/0083 , C08G2350/00
摘要： Disclosed is a water-blown methylene diphenylisocyanate-based polyurethane foam for use in packaging of shock or vibration sensitive goods, and a process for its manufacture from a particular polyol composition. The polyurethane foam exhibits a broad shock/vibration attenuation profile rendering it especially suitable for packaging of light weight articles.

55. 发明授权

US5344853A Storable polyol mixtures containing mold release agents 失效
标题翻译：含有脱模剂的可储存的多元醇混合物
公开(公告)号：US5344853A
公开(公告)日：1994-09-06
申请号：US90390
申请日：1993-07-12
申请人： Ulrich Knipp , Wulf von Bonin , Alfred Neuhaus
发明人： Ulrich Knipp , Wulf von Bonin , Alfred Neuhaus
IPC分类号： C08G18/28 , C08G18/48 , C08G18/65 , C08G18/66 , C08K5/06 , C08K5/17 , C08K5/20 , C08K5/205 , C08K13/00 , C08L71/02 , C08G18/00
CPC分类号： C08K5/20 , C08G18/4804 , C08G18/6677 , C08G18/6688 , C08K5/205 , C08G2101/0008 , C08G2101/0016 , C08G2101/0025 , C08G2120/00 , C08G2125/00
摘要： Polyol mixtures containing a mixture of internal mold release agents which are storage stable are made up of (a) from about 55 to about 95% by weight of a polyol mixture of (1) 30-70% by weight of at least one polyol with an OH value of more than 700 and (2) from about 30 to about 70% by weight of at least one polyol with an OH value of 700 or less than 700 and (b) from about 5 to about 45% by weight of a mixture of internal mold release agents made up of (1) from about 60 to about 95% by weight of at least one salt-like release agent and (2) from about 5 to about 40% by weight of at least one non-salt-like release agent containing an amide NH function or a urethane NH function. Known auxiliaries and additives may optionally be included. These polyol mixtures are useful in the production of rigid, semirigid and flexible polyurethane materials, particularly molded polyurethanes.
摘要翻译：含有保存稳定的内部脱模剂的混合物的多元醇混合物由以下组成：（a）约55至约95重量％的多元醇混合物（1）30-70重量％的至少一种多元醇与 OH值大于700，（2）约30至约70重量％的至少一种OH值为700或小于700的多元醇和（b）约5至约45重量％的内部脱模剂的混合物由（1）约60至约95重量％的至少一种盐状释放剂和（2）约5至约40重量％的至少一种非盐含有酰胺NH官能团或氨基甲酸酯NH官能团的脱模剂。可以任选地包括已知的助剂和添加剂。这些多元醇混合物可用于生产刚性，半刚性和柔性聚氨酯材料，特别是模塑聚氨酯。

56. 发明授权

US5238732A Waterproof breathable polyurethane membranes and porous substrates protected therewith 失效
标题翻译：防水透气聚氨酯膜和多孔基材
公开(公告)号：US5238732A
公开(公告)日：1993-08-24
申请号：US2640
申请日：1993-01-11
申请人： Sundaram Krishnan
发明人： Sundaram Krishnan
IPC分类号： B32B5/26 , B32B27/40 , C08G18/08 , C08G18/48 , C08G18/61 , D06M15/564 , D06M15/568 , D06M15/643 , D06M17/10 , D06N3/14
CPC分类号： C08G18/0852 , B32B27/40 , B32B5/26 , C08G18/4804 , C08G18/61 , D06M15/564 , D06M15/568 , D06M15/643 , D06M17/10 , D06N3/14 , Y10S428/913 , Y10T428/31562 , Y10T442/2139 , Y10T442/2246
摘要： Disclosed herein are polyurethane compositions specifically adapted to produce non-porous membranes exhibiting waterproof and water vapor transmissible characteristics. The membranes can be produced as free standing products or can be produced as coatings on porous substrates to confer similar properties to such substrates. Also disclosed are coated fabrics and fabric laminates utilizing the membranous coatings of the invention and exhibiting waterproof and water vapor transmissible characteristics. Such coated fabrics and fabric laminates find utility in the fabrication of tenting, rainwear and other garments where waterproofness, coupled with breathability, are important features.
摘要翻译：本文公开的是聚氨酯组合物，其特别适于产生具有防水和水蒸气传播特性的非多孔膜。膜可以作为独立产品生产，或者可以作为多孔基材上的涂层生产，以赋予与这种基材相似的性质。还公开了使用本发明的膜性涂层的涂布织物和织物层压体，并且具有防水和水蒸气传播特性。这种涂层织物和织物层压材料可用于制造帐篷，雨衣和其他防水性以及透气性的重要特征。

57. 发明授权

US5146628A Slip-resistant protective glove and method for manufacturing slip-resistant glove 失效
标题翻译：防滑防护手套和制造防滑玻璃的方法
公开(公告)号：US5146628A
公开(公告)日：1992-09-15
申请号：US604589
申请日：1990-10-26
申请人： Raymond J. Herrmann , Keith A. Furgalus
发明人： Raymond J. Herrmann , Keith A. Furgalus
IPC分类号： A41D19/00 , A41D19/015 , B29C41/00 , B29C41/08 , B29C70/88 , B29D99/00 , C08G18/48 , D02G3/44 , D06M15/564 , D06M101/00 , D06M101/16 , D06M101/18 , D06M101/30 , D06M101/34 , D06M101/36
CPC分类号： D02G3/442 , B29C41/003 , B29C70/887 , B29D99/0067 , C08G18/4804 , A41D19/0065 , A41D19/01547 , B29C41/08 , B29K2075/00 , B29L2031/4864 , D10B2101/20 , D10B2321/0211 , D10B2331/02 , D10B2331/021 , D10B2331/04
摘要： A glove having patterned polyurethane coating adhered to outer surface. The coating is about 1/32 inch high and about 1/16 inch wide to give the glove slip-resistant and gripping properties. The coating is formed from (a) a pre-mixed thixotropic component, a non-thixotropic component in a 2.5 to 1 ratio, and an accelerator, and (b) a cross-linking agent. The method of manufacturing the glove involves applying a mixture of (a) and (b) as a strip to the glove, allowing the strip of coating to wet the fibers and then curing at a low temperature for a relatively short period of time.

58. 发明授权

US5109035A Process for the production of moldings or films of cross-linked polyisocyanate polyadducts and the moldings thus obtained 失效
标题翻译：制造交联聚异氰酸酯多糖的胶片或胶片的方法及其获得的胶片
公开(公告)号：US5109035A
公开(公告)日：1992-04-28
申请号：US628766
申请日：1990-12-17
申请人： Joachim Wagner , Werner Rasshofer , Thomas Elsner , Hans-Albrecht Freitag
发明人： Joachim Wagner , Werner Rasshofer , Thomas Elsner , Hans-Albrecht Freitag
IPC分类号： C08G18/28 , C08G18/30 , C08G18/32 , C08G18/48 , C08G18/65 , C08G18/66 , C08J9/02 , C08J9/36 , C08K7/00 , C08L75/00 , C08L75/04
CPC分类号： C08J9/36 , C08G18/4804 , C08G18/6674 , C08G2101/0008 , C08G2101/0066 , C08G2120/00 , C08J2375/04 , Y10T428/249953 , Y10T428/249986 , Y10T428/31551
摘要： The present invention is directed to a process of thermoplastically molding a specific foam composition. The composition is formed by reacting an isocyanate and a relatively low molecular weight tri or higher polyol in the presence of a blowing agent.
摘要翻译：本发明涉及对特定泡沫组合物进行热塑性模塑的方法。通过使异氰酸酯和相对低分子量的三元醇或更高级的多元醇在发泡剂存在下反应形成组合物。

59. 发明授权

US5028684A Process for the production of molded polyurethane bodies 失效
标题翻译：生产模塑聚氨酯体的工艺
公开(公告)号：US5028684A
公开(公告)日：1991-07-02
申请号：US81958
申请日：1987-08-05
申请人： Alfred Neuhaus , Otto Ganster , Bruno Luckas
发明人： Alfred Neuhaus , Otto Ganster , Bruno Luckas
IPC分类号： C08G18/40 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/76
CPC分类号： C08G18/4804 , C08G18/4072 , C08G18/4833 , C08G18/6666 , C08G18/7664 , C08G2120/00
摘要： The present invention is directed to a process for the preparation of molded polyurethane articles having densities of about 0.8 to 1.4 g/cm.sup.3 and a flex moduli according to DIN 53,457 of at least about 1800 N/mm.sup.2 by reacting according to the technique of reaction injection molding(a) di- and/or polyisocyanates of the diphenylmethane series with(b) polyether polyols in the molecular weight range of 500 to 999,(c) organic polyhydroxyl compounds in the molecular weight range of 62 to 499 and optionally(d) polyethers in the molecular weight range of 1000 to about 10,000 containing at least two isocyanate reactive groups and/or(e) aromatic diamines with a molecular weight of less than 500 in the presence of(f) catalysts which accelerate the isocyanate addition reactionwherein(i) the polyether polyols used as component (b) have at least about 30% by weight of ethylene oxide units incorporated in polyether chains,(ii) component (d) is used in a quantity of 0 to about 40% by weight, based on the weight of components (b) to (e), and(iii) the nature and quantitative proportions of components (b) to (e) are chosen so that the average hydroxyl number of the mixture of these components is greater than about 300.
摘要翻译：本发明涉及根据反应注射技术制备具有约0.8至1.4g / cm 3的密度和至少约1800N / mm 2的根据DIN 53,457的挠曲模量的模制聚氨酯制品的方法（a）二苯基甲烷系列的二 - 和/或多异氰酸酯与（b）分子量范围为500至999的聚醚多元醇，（c）分子量范围为62至499的有机多羟基化合物和任选的（d）在（f）加速异氰酸酯加成反应的催化剂的存在下，分子量范围为1000至约10,000的聚醚包含至少两个异氰酸酯反应性基团和/或（e）分子量小于500的芳族二胺，其中（ i）用作组分（b）的聚醚多元醇具有至少约30重量％的掺入聚醚链中的环氧乙烷单元，（ii）组分（d）的用量为0至约40重量％，b 根据组分（b）至（e）的重量，和（iii）选择组分（b）至（e）的性质和定量比例，使得这些组分的混合物的平均羟值大于约 300。

60. 发明授权

US4927044A Heat insulating case and process for preparing the same 失效
标题翻译：隔热箱及其制备方法
公开(公告)号：US4927044A
公开(公告)日：1990-05-22
申请号：US706248
申请日：1985-02-28
申请人： Masao Gotoh , Yasuo Hira , Kenichi Waragai , Shozo Nakamura , Hitoshi Yokono
发明人： Masao Gotoh , Yasuo Hira , Kenichi Waragai , Shozo Nakamura , Hitoshi Yokono
IPC分类号： B29C44/12 , B60H1/00 , C08G18/48 , C08G18/50 , C08J9/34
CPC分类号： C08G18/482 , B29C44/1271 , B60H1/00592 , C08G18/4804 , C08G18/5033 , C08J9/34 , C08G2101/0033 , C08G2101/0058 , C08G2101/0066 , C08G2120/00
摘要： Cases for automobile air conditioners or car-loaded refrigerators are molded in an integrated structure of a body part and fixing parts by reaction injection molding from a mixture of a liquid A comprising 20-60% by weight of an aliphatic amine-based polyol, 30-60% by weight of a PO adduct of 4,4'-diaminodiphenylmethane and 15-40% by weight of an ordinary polyol and further containing a foam-controlling agent, a foaming agent and a catalyst and a liquid B comprising polyisocyanate as obtained through impingement.
摘要翻译：汽车空调或车载冰箱的情况通过反应注射成型由主体部分和固定部件的一体结构模制而成，该液体A包含20-60重量％的脂族胺基多元醇30 -60重量％的4,4'-二氨基二苯基甲烷的PO加合物和15-40重量％的普通多元醇，并进一步含有泡沫控制剂，发泡剂和催化剂以及包含多异氰酸酯的液体B 通过冲击。

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