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    • 51. 发明授权
    • Regenerable sulfur traps for on-board vehicle applications
    • 可再生的用于车载应用的硫捕集器
    • US08507404B2
    • 2013-08-13
    • US12082351
    • 2008-04-10
    • El-Mekki El-MalkiWalter WeissmanPaul J. Polini
    • El-Mekki El-MalkiWalter WeissmanPaul J. Polini
    • B01J23/00B01J21/00B01J20/00
    • B01D53/9495B01D53/9404B01D53/9459B01D53/9477B01D2251/202B01D2255/1021B01D2255/2042B01D2255/2063B01D2255/2065B01D2255/2073B01D2255/20738B01D2255/50B01D2255/9207B01D2257/302F01N3/0807F01N3/0814F01N3/0821F01N3/0842F01N3/085F01N13/009F01N2370/02F01N2610/04
    • Provided are improved regenerable SOx trap formulations for on-board vehicle applications. The regenerable sulfur trap formulations reduce the rate of sulfur poisoning of a downstream nitrogen storage reduction (NSR) catalyst trap in exhaust gas cleaning systems for combustion engines by adsorbing SOx as metal sulfate under lean exhaust conditions and desorbing the accumulated SOx under rich exhaust conditions. The regenerable sulfur oxides trap catalyst compositions include a metal (M) oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof and a metal (M)-La—Zr oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof. In addition, provided are improved exhaust gas cleaning systems and methods for treating exhaust gas from a combustion source that include a hydrogen generation system, a regenerable sulfur oxides trap, and a regenerable nitrogen storage reduction (NSR) catalyst trap. The improved exhaust gas cleaning systems and methods allow for the sulfur released from the sulfur trap to pass through the nitrogen oxide trap with no or little poisoning of NOx storage and reduction sites, which significantly improves NSR catalyst trap lifetime and performance to meet future emissions standards. The disclosed exhaust gas cleaning systems are suitable for use in internal combustion engines (e.g., diesel, gasoline, CNG) which operate with lean air/fuel ratios over most of the operating period.
    • 提供了用于车载车辆应用的改进的可再生SOx捕集剂配方。 可再生硫捕集器配方通过在贫排气条件下吸附SO x作为金属硫酸盐并在富排气条件下解吸累积的SOx,降低了内燃机废气净化系统中下游氮储存还原(NSR)催化剂阱的硫中毒速率。 可再生硫氧化物捕集催化剂组合物包括金属(M)氧化物,其中M选自Cu,Fe,Mn,Ag,Co及其组合和金属(M)-La-Zr氧化物,其中M选自Cu ,Fe,Mn,Ag,Co及其组合。 此外,提供了改进的废气净化系统和用于处理来自燃烧源的废气的废气净化系统和方法,所述燃烧源包括氢气产生系统,可再生硫氧化物捕集器和可再生氮储存还原(NSR)催化剂阱。 改进的废气净化系统和方法允许从硫捕获器释放的硫通过氮氧化物捕集器,没有或少量的NOx储存和还原位点的中毒,这显着地提高了NSR催化剂捕集器的使用寿命和性能以满足未来的排放标准 。 所公开的废气清洁系统适用于在大部分操作周期内以稀薄空气/燃料比运行的内燃机(例如柴油,汽油,CNG)。