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1. 发明授权

US08450524B2 Process for producing carboxylic acid anhydrides 有权
标题翻译：制备羧酸酐的方法
公开(公告)号：US08450524B2
公开(公告)日：2013-05-28
申请号：US13010865
申请日：2011-01-21
申请人： Hui Ting Wang , Chia Jung Tsai , Chia Hui Shen
发明人： Hui Ting Wang , Chia Jung Tsai , Chia Hui Shen
IPC分类号： C07C51/56
CPC分类号： C07C51/56 , C07C53/12
摘要： The present invention relates to a process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The liquid reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, N-acetylimidazole as a protecting agent, and ethylidene diacetate (EDA) as an organic promoter. By making use of the protecting agent of N-acetylimidazole, metal ions in the reactor can be prevented from reacting with EDA so as to reduce the formation of hardly-soluble tars during the reaction. Also, the EDA organic promoter is kept at a certain content in the system to promote the overall carbonylation reaction rate.
摘要翻译：本发明涉及一种通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中的存在下，通过羰基化反应制备羧酸酐的方法 VIII族B族催化剂生成羧酸酐。液体反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸，作为保护剂的N-乙酰基咪唑，以及亚乙基二乙酸酯（EDA）有机促进剂。通过利用N-乙酰基咪唑的保护剂，可以防止反应器中的金属离子与EDA反应，从而减少反应期间几乎不溶的焦油的形成。此外，EDA有机促进剂在系统中保持一定含量以促进总的羰基化反应速率。

2. 发明申请

US20120053366A1 Process for Producing Carboxylic Acid Anhydrides 有权
标题翻译：生产羧酸酐的方法
公开(公告)号：US20120053366A1
公开(公告)日：2012-03-01
申请号：US13010865
申请日：2011-01-21
申请人： Hui Ting Wang , Chia Jung Tsai , Chia Hui Shen
发明人： Hui Ting Wang , Chia Jung Tsai , Chia Hui Shen
IPC分类号： C07C51/56
CPC分类号： C07C51/56 , C07C53/12
摘要： The present invention relates to a process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The liquid reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, N-acetylimidazole as a protecting agent, and ethylidene diacetate (EDA) as an organic promoter. By making use of the protecting agent of N-acetylimidazole, metal ions in the reactor can be prevented from reacting with EDA so as to reduce the formation of hardly-soluble tars during the reaction. Also, the EDA organic promoter is kept at a certain content in the system to promote the overall carbonylation reaction rate.
摘要翻译：本发明涉及一种通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中的存在下，通过羰基化反应制备羧酸酐的方法 VIII族B族催化剂生成羧酸酐。液体反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸，作为保护剂的N-乙酰基咪唑，以及亚乙基二乙酸酯（EDA）有机促进剂。通过利用N-乙酰基咪唑的保护剂，可以防止反应器中的金属离子与EDA反应，从而减少反应期间几乎不溶的焦油的形成。此外，EDA有机促进剂在系统中保持一定含量以促进总的羰基化反应速率。

3. 发明授权

US08097756B2 Process for producing carboxylic acid anhydrides 失效
标题翻译：制备羧酸酐的方法
公开(公告)号：US08097756B2
公开(公告)日：2012-01-17
申请号：US12370268
申请日：2009-02-12
申请人： Ching Liang Tu , Chia Hui Shen , Chia Jung Tsai , Chi He Chen
发明人： Ching Liang Tu , Chia Hui Shen , Chia Jung Tsai , Chi He Chen
IPC分类号： C07C51/54
CPC分类号： C07C51/56 , C07C53/08
摘要： A process for producing carboxylic acid anhydrides by the carbonylation reaction of a carboxylic acid ester, derived from an alcohol and a carboxylic acid, with carbon monoxide containing a small amount of hydrogen in a liquid reaction medium in the presence of a Group VIII B catalyst to produce a carboxylic acid anhydride. The reaction medium comprises the Group VIII B catalyst, an organic halide, the carboxylic acid ester, an alkali metal salt, the carboxylic acid anhydride, the carboxylic acid, and at least one ionic liquid consisting of a cation and an anion where the cation of the ionic liquid has a nitrogen-containing heterocyclic structure. The ionic liquid has at least one of the following structural forms: The reaction rate of the carbonylation reaction is increased by the use of the specified ionic liquid promoters.
摘要翻译：通过在醇和羧酸中衍生的羧酸酯与含有少量氢的一氧化碳在液体反应介质中在VIII VIII族催化剂存在下羰基化反应制备羧酸酐的方法，产生羧酸酐。反应介质包括VIII族B催化剂，有机卤化物，羧酸酯，碱金属盐，羧酸酐，羧酸和至少一种由阳离子和阴离子组成的离子液体，其中阳离子离子液体具有含氮杂环结构。离子液体具有以下结构形式中的至少一种：羰基化反应的反应速率通过使用指定的离子液体促进剂而增加。

4. 发明申请

US20110152558A1 PROCESS FOR PRODUCING DIARYL CARBONATES 有权
标题翻译：生产二氧化碳的方法
公开(公告)号：US20110152558A1
公开(公告)日：2011-06-23
申请号：US12813185
申请日：2010-06-10
申请人： Zhen Wei HUANG , Chih Wei CHANG , Chia Jung TSAI
发明人： Zhen Wei HUANG , Chih Wei CHANG , Chia Jung TSAI
IPC分类号： C07C68/00
CPC分类号： C07C68/005 , C07C69/96
摘要： The present invention relates to a process for producing diaryl carbonates, which is to synthesize diaryl carbonates by oxidative carbonylation of phenols with carbon monoxide and oxygen, and in particular, to synthesize diphenyl carbonate from phenol. The present invention is characterized in that a catalytic system comprising a metal halide catalyst and one or more cocatalysts of nitrogenous heterocyclic compounds is used to increase the convertibility, selectivity and yield of this catalytic reaction.
摘要翻译：本发明涉及一种碳酸二芳基酯的制备方法，该方法是通过苯酚与一氧化碳和氧的氧化羰基化合成碳酸二芳基酯，特别是合成苯酚碳酸二苯酯。本发明的特征在于，使用包含金属卤化物催化剂和一种或多种含氮杂环化合物的助催化剂的催化体系来提高该催化反应的可转换性，选择性和产率。

5. 发明申请

US20080071110A1 Process for preparing carboxylic acid 失效
标题翻译：羧酸的制备方法
公开(公告)号：US20080071110A1
公开(公告)日：2008-03-20
申请号：US11903237
申请日：2007-09-20
申请人： Chi-He Chen , Chin-Yi Lee , Chia-Jung Tsai
发明人： Chi-He Chen , Chin-Yi Lee , Chia-Jung Tsai
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C53/08
摘要： A process for preparing a carboxylic acid by the carbonylation of an alcohol in a reaction medium is provided. The reaction medium includes a catalyst promoter having a metal species selected form the group consisting of group IIIA-IVA metals, group IB-VIIIB metals and lanthanides, together with a hydrohalic acid to prevent catalyst precipitation and to maintain high reaction rates in case of low water content.
摘要翻译：提供了通过在反应介质中羰基化醇制备羧酸的方法。反应介质包括催化剂促进剂，其具有选自IIIA-IVA族金属，IB-VIIB族金属和镧系元素的金属种类，以及氢卤酸，以防止催化剂沉淀并在低的情况下保持高的反应速率含水量。

6. 发明授权

US06784313B2 Process for producing carboxylic acids 失效
标题翻译：制备羧酸的方法
公开(公告)号：US06784313B2
公开(公告)日：2004-08-31
申请号：US10263643
申请日：2002-10-04
申请人： Chia Jung Tsai , Yao Lung Liu , Hsi Chin Tsai
发明人： Chia Jung Tsai , Yao Lung Liu , Hsi Chin Tsai
IPC分类号： C07C5110
CPC分类号： C07C51/12 , C07C53/08
摘要： A process for producing a carboxylic acid having (n+1) carbon atoms, which includes carbonylating an alcohol having n carbon atoms, and/or an ester of the alcohol and the carboxylic acid in each alkyl group with carbon monoxide in the presence of a catalytic system containing a rhodium catalyst. The process uses a reaction medium for the carbonylation that includes: (1) a rhodium catalyst, (2) an organic halide corresponding to said alcohol, (3) an ester of the alcohol and the carboxylic acid, (4) the carboxylic acid, optionally (5) water, a haloid acid, an inorganic halogen salt or an acetate, and (6) a cocatalyst selected from arginine, N-acetyl alanine, or nitrogen- and oxygen-containing organic compounds.
摘要翻译：一种具有（n + 1）个碳原子的羧酸的方法，该方法包括在每个烷基中羰基化具有n个碳原子的醇，和/或每个烷基中的醇和羧酸的酯与一氧化碳在一种含有铑催化剂的催化体系。该方法使用羰基化反应介质，其包括：（1）铑催化剂，（2）对应于所述醇的有机卤化物，（3）醇和羧酸的酯，（4）羧酸，任选的（5）水，卤代酸，无机卤素盐或乙酸盐，和（6）选自精氨酸，N-乙酰丙氨酸或含氮和氧的有机化合物的助催化剂。

7. 发明授权

US08519187B2 Process for producing organic carboxylic acid amides 有权
标题翻译：生产有机羧酸酰胺的方法
公开(公告)号：US08519187B2
公开(公告)日：2013-08-27
申请号：US12639284
申请日：2009-12-16
申请人： Chia Hui Shen , Chin Yi Lee , Chia Jung Tsai
发明人： Chia Hui Shen , Chin Yi Lee , Chia Jung Tsai
IPC分类号： C07C231/06
CPC分类号： C07C231/065 , C07C233/05 , C07C233/11
摘要： The present invention relates to a process for producing organic carboxylic acid amides by nitrile hydrolysis of a nitrile compound at certain temperature and pressure in the presence of a catalyst to produce an organic carboxylic acid amide.
摘要翻译：本发明涉及一种在催化剂存在下，在一定温度和压力下通过腈化合物腈水解产生有机羧酸酰胺以制备有机羧酸酰胺的方法。

8. 发明授权

US07888525B2 Method for preparing organic carbonates 有权
标题翻译：有机碳酸酯的制备方法
公开(公告)号：US07888525B2
公开(公告)日：2011-02-15
申请号：US12079206
申请日：2008-03-25
申请人： Min-Sheng Chen , Chia-Jung Tsai , Chih-Wei Chang
发明人： Min-Sheng Chen , Chia-Jung Tsai , Chih-Wei Chang
IPC分类号： C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： A method for preparing organic carbonates comprising subjecting an alcohol compound to oxidative carbonylation in the presence of carbon monoxide, oxygen and a liquid-phase catalytic system, to form a organic carbonates, wherein the liquid-phase catalytic system includes at least one catalyst, at least one additive and at least one ionic liquid composed of a cation, which has a nitrogen-containing heterocyclic structure, and an anion. Through using the additive and the ionic liquid, the activity and the performance of the catalyst are enhanced, and increased reaction rate and yield can be obtained.
摘要翻译：一种制备有机碳酸酯的方法，包括在一氧化碳，氧气和液相催化体系的存在下使醇化合物进行氧化羰基化以形成有机碳酸酯，其中液相催化体系包括至少一种催化剂，至少一种添加剂和至少一种由具有含氮杂环结构的阳离子和阴离子组成的离子液体。通过使用添加剂和离子液体，可以提高催化剂的活性和性能，提高反应速度和产率。

9. 发明授权

US07700785B2 Process for preparation of dialkyl carbonate 有权
标题翻译：碳酸二烷基酯的制备方法
公开(公告)号：US07700785B2
公开(公告)日：2010-04-20
申请号：US12009101
申请日：2008-01-15
申请人： Chih-Wei Chang , Chia-Jung Tsai , Ying-Tien Chen
发明人： Chih-Wei Chang , Chia-Jung Tsai , Ying-Tien Chen
IPC分类号： C07D233/66 , C07D237/10
CPC分类号： C07C68/005 , C07C69/96
摘要： Provided is a process for preparation of dialkyl carbonates, comprising the step of performing oxidative carbonylation of an alcohol in liquid phase in the presence of CO and O2, to form dialkyl carbonate in a catalyst system comprising a metal halide as catalyst and at least one nitrogen-containing compound selected from the group consisting of imidazole derivatives (excluding unsubstituted imidazole), benzoimidazole derivatives, pyridazine derivatives, carbazole, acridine and non-cyclic amines as auxiliary catalyst. The process of the invention, by using above catalyst system, can increase the conversion ratio of alcohol and the selectivity of the oxidative carbonylation reaction, thus increasing the total yield of dialkyl carbonate. In addition, the process of the invention has the advantages of reducing the required amount of the catalyst and causing less corrosion to the reactor.
摘要翻译：提供了一种制备碳酸二烷基酯的方法，包括在CO和O 2存在下，以液相进行醇的氧化羰基化反应，在包含金属卤化物作为催化剂和至少一种氮的催化剂体系中形成碳酸二烷基酯的步骤（不包括未取代的咪唑），苯并咪唑衍生物，哒嗪衍生物，咔唑，吖啶和非环胺作为辅助催化剂。通过使用上述催化剂体系，本发明的方法可以提高醇的转化率和氧化羰基化反应的选择性，从而提高碳酸二烷基酯的总产率。此外，本发明的方法具有减少所需量的催化剂并且对反应器造成较少腐蚀的优点。

10. 发明申请

US20080214856A1 Process for preparation of dialkyl carbonate 有权
标题翻译：碳酸二烷基酯的制备方法
公开(公告)号：US20080214856A1
公开(公告)日：2008-09-04
申请号：US12009101
申请日：2008-01-15
申请人： Chih-Wei Chang , Chia-Jung Tsai , Ying-Tien Chen
发明人： Chih-Wei Chang , Chia-Jung Tsai , Ying-Tien Chen
IPC分类号： C07C69/96
CPC分类号： C07C68/005 , C07C69/96
摘要： Provided is a process for preparation of dialkyl carbonates, comprising the step of performing oxidative carbonylation of an alcohol in liquid phase in the presence of CO and O2, to form dialkyl carbonate in a catalyst system comprising a metal halide as catalyst and at least one nitrogen-containing compound selected from the group consisting of imidazole derivatives (excluding unsubstituted imidazole), benzoimidazole derivatives, pyridazine derivatives, carbazole, acridine and non-cyclic amines as auxiliary catalyst. The process of the invention, by using above catalyst system, can increase the conversion ratio of alcohol and the selectivity of the oxidative carbonylation reaction, thus increasing the total yield of dialkyl carbonate. In addition, the process of the invention has the advantages of reducing the required amount of the catalyst and causing less corrosion to the reactor.
摘要翻译：提供了一种制备碳酸二烷基酯的方法，包括在CO和O 2 2存在下在液相中进行醇的氧化羰基化的步骤，在包含金属的催化剂体系中形成碳酸二烷基酯卤化物作为催化剂和至少一种选自咪唑衍生物（不包括未取代的咪唑），苯并咪唑衍生物，哒嗪衍生物，咔唑，吖啶和非环胺作为辅助催化剂的含氮化合物。通过使用上述催化剂体系，本发明的方法可以提高醇的转化率和氧化羰基化反应的选择性，从而提高碳酸二烷基酯的总产率。此外，本发明的方法具有减少所需量的催化剂并且对反应器造成较少腐蚀的优点。

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