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    • 3. 发明申请
    • Photosensitive resin composition capable of being developed with aqueous developer and photosensitive dry film resist, and use thereof
    • 能够用水性显影剂和感光性干膜抗蚀剂显影的感光性树脂组合物及其用途
    • US20060199920A1
    • 2006-09-07
    • US10553272
    • 2004-04-13
    • Koji OkadaToshio Yamanaka
    • Koji OkadaToshio Yamanaka
    • C08L77/00C08L83/04
    • G03F7/037H05K3/287
    • A photosensitive resin composition according to the present invention includes at least a base resin component (A) and a (meth)acryls compound (B), wherein the base resin component (A) is any one of: a polyimide resin (A-1) having at least either a hydroxyl group or a carboxyl group in its structure; a polyamide resin (A-2) having at least either a hydroxyl group or a carboxyl group in its structure; and photosensitive imide(meth)acrylsiloxaneoligomer (A-3). On this account, it is possible to realize characteristics such as (1) realization and improvement of water system developing property, (2) improvement of utility as an imidized film, (3) improvement of post-curing property, and (4) simplification of manufacture of a print wiring substrate. Thus, the photosensitive resin composition can be favorably used particularly in a photosensitive dry film resin, a laminate using the same, a print wiring substrate using the same, and the like.
    • 根据本发明的感光性树脂组合物至少包含基础树脂成分(A)和(甲基)丙烯酸类化合物(B),其中,所述基础树脂成分(A)为:聚酰亚胺树脂(A-1 )在其结构中具有至少一个羟基或羧基; 在其结构中具有至少羟基或羧基的聚酰胺树脂(A-2) 和感光酰亚胺(甲基)丙烯酰基硅氧烷寡聚体(A-3)。 因此,可以实现(1)实现和改善水系发展性的特征,(2)提高作为酰亚胺化膜的效用,(3)后固化性的提高,(4)简化 制造印刷布线基板。 因此,感光性树脂组合物特别优选用于感光性干膜树脂,使用该感光性树脂组合物的层叠体,使用该感光性树脂组合物的印刷用布线基板等。
    • 4. 发明申请
    • Phosphazene compound, photosensitive resin composition and use thereof
    • 磷腈化合物,感光性树脂组合物及其用途
    • US20060142542A1
    • 2006-06-29
    • US10559737
    • 2004-06-03
    • Koji OkadaToshio Yamanaka
    • Koji OkadaToshio Yamanaka
    • C08G79/02
    • C08G79/025C07F9/067C07F9/65812G03F7/027G03F7/032G03F7/037G03F7/0388
    • Disclosed is a phosphazene compound and a photosensitive resin composition. The phosphazene compound is obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond and/or an isocyanate compound (C), wherein the phosphazene compound has an unsaturated double bond in its molecule. The photosensitive resin composition includes at least: a soluble polyimide resin (G-1) having a carboxyl group and/or a hydroxyl group and is soluble in an organic solvent, as the polyimide resins (G); and a phenoxyphosphazene compound (H-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (H-2), which is obtained by cross-linking the phenoxyphosphazene compound (H-1) and has at least one phenolic hydroxyl group, as the phosphazene compound (H), and the photosensitive resin composition further includes a (meth)acrylic compound (L).
    • 公开了磷腈化合物和感光性树脂组合物。 通过使具有酚羟基的苯氧基磷腈化合物(A-1)和/或通过将苯氧基磷腈化合物(A-1)交联而获得的交联的苯氧基磷腈化合物(A-2)与环氧化合物 具有不饱和双键的化合物(B)和/或异氰酸酯化合物(C),其中磷腈化合物在其分子中具有不饱和双键。 作为聚酰亚胺树脂(G),感光性树脂组合物至少包括具有羧基和/或羟基并且可溶于有机溶剂的可溶性聚酰亚胺树脂(G-1)。 和具有酚羟基的苯氧基磷腈化合物(H-1)和/或交联的苯氧基磷腈化合物(H-2),其是通过交联苯氧基磷腈化合物(H-1)而得到的,并具有至少一种酚 羟基作为磷腈化合物(H),感光性树脂组合物还含有(甲基)丙烯酸系化合物(L)。
    • 5. 发明授权
    • Phosphazene compound, photosensitive resin composition and use thereof
    • 磷腈化合物,感光性树脂组合物及其用途
    • US08063245B2
    • 2011-11-22
    • US10559737
    • 2004-06-03
    • Koji OkadaToshio Yamanaka
    • Koji OkadaToshio Yamanaka
    • C07F9/547
    • C08G79/025C07F9/067C07F9/65812G03F7/027G03F7/032G03F7/037G03F7/0388
    • Disclosed is a phosphazene compound and a photosensitive resin composition. The phosphazene compound is obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond and/or an isocyanate compound (C), wherein the phosphazene compound has an unsaturated double bond in its molecule. The photosensitive resin composition includes at least: a soluble polyimide resin (G-1) having a carboxyl group and/or a hydroxyl group and is soluble in an organic solvent, as the polyimide resins (G); and a phenoxyphosphazene compound (H-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (H-2), which is obtained by cross-linking the phenoxyphosphazene compound (H-1) and has at least one phenolic hydroxyl group, as the phosphazene compound (H), and the photosensitive resin composition further includes a (meth)acrylic compound (L).
    • 公开了磷腈化合物和感光性树脂组合物。 通过使具有酚羟基的苯氧基磷腈化合物(A-1)和/或通过将苯氧基磷腈化合物(A-1)交联而获得的交联的苯氧基磷腈化合物(A-2)与环氧化合物 具有不饱和双键的化合物(B)和/或异氰酸酯化合物(C),其中磷腈化合物在其分子中具有不饱和双键。 作为聚酰亚胺树脂(G),感光性树脂组合物至少包括具有羧基和/或羟基并且可溶于有机溶剂的可溶性聚酰亚胺树脂(G-1)。 和具有酚羟基的苯氧基磷腈化合物(H-1)和/或交联的苯氧基磷腈化合物(H-2),其是通过交联苯氧基磷腈化合物(H-1)而得到的,并具有至少一种酚 羟基作为磷腈化合物(H),感光性树脂组合物还含有(甲基)丙烯酸系化合物(L)。
    • 6. 发明申请
    • PHOTOSENSITIVE DRY FILM RESIST, PRINTED WIRING BOARD MAKING USE OF THE SAME, AND PROCESS FOR PRODUCING PRINTED WIRING BOARD
    • 光敏干胶片,印刷线路板及其制造方法,以及生产印刷线路板的工艺
    • US20100218984A1
    • 2010-09-02
    • US12223196
    • 2007-01-23
    • Toshio YamanakaKoji OkadaKohei KojimaHitoshi Nojiri
    • Toshio YamanakaKoji OkadaKohei KojimaHitoshi Nojiri
    • H05K1/00G03F7/004
    • G03F7/0955G03F7/037G03F7/161H05K3/287H05K2201/012H05K2201/0195
    • The present invention is to provide (i) a photosensitive dry film resist which allows water system development and which is excellent in resolution, flame retardancy, adhesiveness, moisture resistance, electric reliability, and preservation stability, (ii) a method for producing the photosensitive dry film resist, and (iii) usage thereof.The foregoing object can be achieved by using a multi-layer photosensitive dry film resist comprising at least: a first photosensitive layer which essentially includes a binder polymer (A1), a (meth)acrylic compound (B1), a photoreaction initiator (C1), and a flame retardant (D1), and a second photosensitive layer which essentially includes a binder polymer (A2), a (meth)acrylic compound (B2), a photoreaction initiator (C2) and which substantially does not include a flame retardant (D2), wherein: when a weight ratio of the flame retardant (D1) to an entire weight of the first photosensitive layer is defined as a first photosensitive layer flame retardant content and a weight ratio of the flame retardant (D2) to an entire weight of the second photosensitive layer is defined as a second photosensitive layer flame retardant content, the second photosensitive layer flame retardant content is 0 wt % or more and 10 wt % or less, and in case where the first photosensitive layer flame retardant content is 100, the second photosensitive layer flame retardant content is 0 wt % or more and 50 wt % or less.
    • 本发明提供(i)允许水系开发并且分辨率,阻燃性,粘合性,耐湿性,电可靠性和保存稳定性优异的感光性干膜抗蚀剂,(ii)感光性的制造方法 干膜抗蚀剂,和(iii)使用。 上述目的可以通过使用多层感光性干膜抗蚀剂来实现,该抗蚀剂至少包括:基本上包含粘合剂聚合物(A1),(甲基)丙烯酸类化合物(B1),光反应引发剂(C1) ,和阻燃剂(D1)和基本上包含粘合剂聚合物(A2),(甲基)丙烯酸化合物(B2),光反应引发剂(C2),并且基本上不包含阻燃剂的第二感光层 D2),其中:当阻燃剂(D1)与第一感光层的整体重量的重量比定义为第一感光层阻燃剂含量和阻燃剂(D2)与总重量的重量比 第二感光层被定义为第二感光层阻燃剂含量,第二感光层阻燃剂含量为0重量%以上且10重量%以下,并且在第一感光层阻燃剂 t含量为100,第二感光层阻燃剂含量为0重量%以上且50重量%以下。
    • 8. 发明授权
    • Transfer unit, transfer method, and image forming apparatus
    • 转印单元,转印方法和图像形成装置
    • US07548709B2
    • 2009-06-16
    • US11410966
    • 2006-04-26
    • Masashi HiraiKuniaki NakanoMasanori YamadaTakahiko YoshidaKazuaki IshikawaHiroshi TachikiToshio Yamanaka
    • Masashi HiraiKuniaki NakanoMasanori YamadaTakahiko YoshidaKazuaki IshikawaHiroshi TachikiToshio Yamanaka
    • G03G15/16
    • G03G15/168
    • A transfer unit includes: an intermediate transfer belt that (i) holds a toner image that has been transferred from a photoreceptor drum and (ii) moves a surface holding the toner image; and a secondary transfer belt that comes into contact with the intermediate transfer belt. The transfer unit (i) transfers the toner image from the intermediate transfer belt to a sheet conveyed to the secondary transfer part and (ii) includes a cleaning unit that removes and collects toner from the surface of the intermediate transfer belt. The transfer unit also includes a power source for sequentially applying, to the secondary transfer belt, (i) a first voltage for generating an electric field that transfers normally-charged toner from the secondary transfer belt to the intermediate transfer belt and (ii) a second voltage for generating an electric field that transfers oppositely-charged toner from the secondary transfer belt to the intermediate transfer belt.
    • 转印单元包括:中间转印带,其(i)保持已经从感光鼓转印的调色剂图像,和(ii)移动保持调色剂图像的表面; 以及与中间转印带接触的二次转印带。 转印单元(i)将调色剂图像从中间转印带传送到传送到二次转印部件的纸张,(ii)包括从中间转印带的表面去除和收集调色剂的清洁单元。 转印单元还包括一个电源,用于顺序地向二次转印带施加(i)第一电压,用于产生将正常充电的调色剂从二次转印带传送到中间转印带的电场,以及(ii) 用于产生将相反充电的调色剂从二次转印带传送到中间转印带的电场的第二电压。