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    • 4. 发明授权
    • Extrusion head for forming polymeric hollow fiber
    • 用于形成聚合物中空纤维的挤出头
    • US5318417A
    • 1994-06-07
    • US536650
    • 1990-07-09
    • Clinton V. KoppRobert J. W. StreetonPaul S. Khoo
    • Clinton V. KoppRobert J. W. StreetonPaul S. Khoo
    • B01D67/00B01D69/02B01D69/08C08J9/28D01D5/24A01J21/00
    • D01D5/24B01D67/0025B01D67/003B01D69/02B01D69/081B01D69/085B01D69/088B01D71/26C08J9/28B01D2323/08C08J2201/052
    • A process for making a polymeric, porous hollow fibre (21) by heating a mixture of a thermoplastic polymer and a solvent to a temperature and for a time for the polymer and solvent to mutually dissolve, then introducing the molten mixture into an extrusion head (FIG. 1) adapted to shape the hollow fibre. The shaped fibre is then cooled in the extrusion head to a temperature so that non-equilibrium liquid-liquid phase separation takes place to form a bi-continuous matrix of the polymer and solvent in which the polymer and solvent form two intermingled separate phases of large interfacial surface area. Finally, the solvent is removed from the polymer.The extrusion head for forming the abovementioned polymeric, porous hollow fibre has an elongated body (17, 18) defining an axial passageway (11) for receiving a lumen-forming fluid (14) and a first annular passage (12) therearound for receiving the molten mixture (15) from which the hollow fibre (21) is formed. A second annular passageway (13) is radially outward of the first annular passageway (12) and receives a coating fluid (16). A third annular passageway (19) receives a cooling fluid and has means (20) for directing the cooling fluid towards the outer surface of the coating fluid (16). The porous polymeric material of the fibre produced by the abovementioned process has a lacey or filamentous structure consisting of a plurality of polymer strands connected together at spaced apart locations along each strand.
    • PCT No.PCT / AU89 / 00480 Sec。 371 1990年7月9日第 102(e)日1990年7月9日PCT 1989年11月10日PCT公布。 出版物WO90 / 05006 日期1990年5月17日。一种通过将热塑性聚合物和溶剂的混合物加热至聚合物和溶剂相互溶解的温度和时间来制备聚合物多孔中空纤维(21)的方法,然后将熔融 混合物变成适于成形中空纤维的挤出头(图1)。 然后将成形的纤维在挤出头中冷却至使得发生非平衡液相分离以形成聚合物和溶剂的双连续基质的温度,其中聚合物和溶剂形成两个相互混合的分离相 界面表面积。 最后,从聚合物中除去溶剂。 用于形成上述聚合物多孔中空纤维的挤出头具有限定用于接收管腔形成流体(14)的轴向通道(11)和其周围的第一环形通道(12)的细长体(17,18),用于接收 形成中空纤维(21)的熔融混合物(15)。 第二环形通道(13)在第一环形通道(12)的径向外侧并且接收涂覆流体(16)。 第三环形通道(19)接收冷却流体并具有用于将冷却流体引向涂布流体(16)的外表面的装置(20)。 通过上述方法制备的纤维的多孔聚合物材料具有花边或丝状结构,其由沿着每条链的间隔开的位置连接在一起的多个聚合物股组成。