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    • 3. 发明授权
    • Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds
    • 具有含烷氧基和非烷氧基重氮盐的化合物的混合物的光敏组合物
    • US06861196B2
    • 2005-03-01
    • US10664179
    • 2003-09-17
    • Stephan J. PlatzerMaria T. SypekPaul PerronHarald BaumannMelinda Alden
    • Stephan J. PlatzerMaria T. SypekPaul PerronHarald BaumannMelinda Alden
    • G03F7/016G03F7/021G03F7/30
    • G03F7/016G03F7/021G03F7/0215G03F7/0217
    • The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained.
    • 本发明包括可成像元件,其可以是:(a)包含成像层的可成像元件,其包含:含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐的化合物; 聚乙烯醇缩醛粘合剂; 和片基材; 或(b)包含成像层的可成像元件,其包含:含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐盐化合物; 和片状基材。 成像层包括含有至少10重量%的化合物含量的总芳族重氮盐。 具有烷氧基取代基的含芳族重氮盐的化合物与不含烷氧基取代基的含芳族重氮盐化合物的摩尔比为约1.0:1至70:1。 在成像曝光和显影时,获得成像元件。
    • 8. 发明授权
    • Light-sensitive composition containing diazo resin, polyurethane resin
and fluorine atom-containing copolymer surfactant
    • 含有重氮树脂,聚氨酯树脂和含氟原子的共聚物表面活性剂的感光性组合物
    • US5340685A
    • 1994-08-23
    • US40615
    • 1993-03-31
    • Toshiyuki Sekiya
    • Toshiyuki Sekiya
    • G03F7/00C08G18/66C08L75/08G03F7/004G03F7/021G03F7/035
    • G03F7/021C08G18/6692C08L75/08Y10S430/107
    • A light-sensitive composition comprises a light-sensitive diazo resin, a polymer binder and a fluorine atom-containing surfactant, wherein the polymer binder is a polyurethane resin having acidic hydrogen atom-containing substituents and comprising structural units derived from a diol represented by the following general formula (I); and the fluorine atom-containing surfactant is a copolymer of (i) an acrylate or methacrylate having a fluoroaliphatic group which has a carbon atom number of 3 to 20 and a fluorine atom content of not less than 30% by weight and in which at least three terminal carbon atoms are completely fluorinated, with (ii) poly(oxyalkylene) acrylate or poly(oxyalkylene)methacrylate, the copolymer containing the fluoroaliphatic group-containing acrylate or methacrylate units in an amount ranging from 35 to 50% by weight on the basis of the weight of the copolymer and the copolymer having has a molecular weight ranging from 20,000 to 100,000:HO--(CH.sub.2 CH.sub.2 O).sub.n --H (I)wherein n is an integer of not less than 3. The light-sensitive composition can provide a PS plate having sufficient developability with an exhausted developer and can provide a lithographic printing plate having good printing durability and excellent ink receptivity during printing even after storing under high temperature and humidity conditions or after being exposed to light.
    • 光敏性组合物包含感光重氮树脂,聚合物粘合剂和含氟原子的表面活性剂,其中所述聚合物粘合剂是具有酸性含氢原子的取代基的聚氨酯树脂,并且包含衍生自由 按照通式(I); 含氟原子的表面活性剂是(i)具有碳原子数为3〜20,氟原子含量为30重量%以上的氟代脂族基的丙烯酸酯或甲基丙烯酸酯的共聚物,其中至少 三末端碳原子完全氟化,其中(ii)聚(氧化烯)丙烯酸酯或聚(氧化烯)甲基丙烯酸酯,含有含氟脂族基团的丙烯酸酯或甲基丙烯酸酯单元的共聚物的量为35-50重量% 共聚物的重量和共聚物的分子量范围为20,000至100,000:HO-(CH 2 CH 2 O)n H(I),其中n为不小于3的整数。光敏组合物可提供PS板 具有足够的显影性和排气的显影剂,并且可以提供具有良好的印刷耐久性的平版印刷版,甚至在高温和高湿度储存 暴露或暴露于光后。