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1. 发明申请

US20160197388A1 Electrochemically Rechargeable Metal-Air Cell with a Replaceable Metal Anode 有权
标题翻译：具有可更换金属阳极的电化学充电金属空气电池
公开(公告)号：US20160197388A1
公开(公告)日：2016-07-07
申请号：US13602443
申请日：2012-09-04
申请人： Iakov Kogan , Anna Khomenko
发明人： Iakov Kogan , Anna Khomenko
IPC分类号： H01M12/08 , H01M4/92 , C25B1/02 , C25B11/04 , C25B11/06 , H01M4/134 , H01M4/38 , H01M4/86 , C25B9/02 , B82Y30/00
CPC分类号： H01M12/08 , C25B1/02 , C25B11/04 , H01M4/42 , H01M4/62 , H01M4/625 , H01M4/661 , H01M4/8668 , H01M4/8673 , H01M4/9008 , H01M10/4242 , H01M2004/027 , H01M2004/8689 , Y02E60/128
摘要： A three electrode metal-air cell with a mechanically replaceable and electrochemically rechargeable metal anode has been proposed. The functions of oxygen reduction and oxygen evolution are split between two air electrodes that form the cell walls. The metal composition of the replaceable metal anode includes a conjugated polymer additive. The current collector of the metal anode has the shape of a spiral spring and is made of alloy of zinc, tin, lead, bismuth or indium. The replaceable metal anode can be used as a universal energy storage unit that produces electricity as the anode of a metal-air battery or hydrogen as the anode of a hydrogen-on-demand generator.
摘要翻译：已经提出了具有机械可替换和电化学可再充电的金属阳极的三电极金属 - 空气电池。氧还原和氧气逸出的功能在形成细胞壁的两个空气电极之间分开。可替换的金属阳极的金属组成包括共轭聚合物添加剂。金属阳极的集电体具有螺旋形弹簧的形状，由锌，锡，铅，铋或铟的合金制成。可更换的金属阳极可以用作作为氢气发电机的阳极产生电作为金属 - 空气电池的阳极或氢的通用能量存储单元。

2. 发明授权

US09145615B2 Method and apparatus for the electrochemical reduction of carbon dioxide 有权
标题翻译：二氧化碳电化学还原的方法和装置
公开(公告)号：US09145615B2
公开(公告)日：2015-09-29
申请号：US13825822
申请日：2011-09-22
申请人： Yumei Zhai , Feng Gui , Shan Guan , Narasi Sridhar , Arun S. Agarwal
发明人： Yumei Zhai , Shan Guan , Narasi Sridhar , Arun S. Agarwal
IPC分类号： C25B3/04 , C25B11/03 , C25B11/06 , C25B11/04
CPC分类号： C25B3/04 , C25B9/08 , C25B11/035 , C25B11/0405 , C25B11/0447 , C25B11/0478 , C25B11/0484 , C25B15/02 , C25B15/08 , Y02P20/142
摘要： A method and apparatus is provided for the electrochemical reduction of carbon dioxide to formate and formic acid. One embodiment features a three-compartment reactor which houses: a gas compartment; a catholyte compartment, which contains a porous cathode having a tin-based catalyst; and an anolyte compartment, which contains an anode having a mixed metal oxide catalyst. Further embodiments include a method for depositing tin onto a porous cathode, tin-zinc cathodes, a reaction method using an acidic anolyte, and pulsed polarization to extend reactor runtimes.
摘要翻译：提供了一种用于将二氧化碳还原成甲酸和甲酸的方法和装置。一个实施例具有三室反应器，其容纳：气室; 阴极电解液室，其包含具有锡基催化剂的多孔阴极; 和阳极电解液室，其含有具有混合金属氧化物催化剂的阳极。其它实施方案包括用于在多孔阴极上沉积锡的方法，锡锌阴极，使用酸性阳极电解液的反应方法和脉冲极化以延长反应器运行时间。

3. 发明申请

US20130256123A1 ELECTROCATALYST FOR ELECTROCHEMICAL CONVERSION OF CARBON DIOXIDE 审中-公开
标题翻译：二氧化碳电化学转化用电解质
公开(公告)号：US20130256123A1
公开(公告)日：2013-10-03
申请号：US13437766
申请日：2012-04-02
申请人： SALEEM UR RAHMAN , SYED MOHAMMED JAVAID ZAIDI , SHAKEEL AHMED , SK SAFDAR HOSSAIN
发明人： SALEEM UR RAHMAN , SYED MOHAMMED JAVAID ZAIDI , SHAKEEL AHMED , SK SAFDAR HOSSAIN
IPC分类号： C25B11/08 , B01J21/18 , C25B11/06 , B82Y40/00 , B82Y30/00
CPC分类号： C25B11/0478 , B82Y30/00 , C25B3/04 , C25B11/04
摘要： An electrocatalyst for the electrochemical conversion of carbon dioxide to hydrocarbons is provided. The electrocatalyst for the electrochemical conversion of carbon dioxide includes copper material supported on carbon nanotubes. The copper material may be pure copper, copper and ruthenium, copper and iron, or copper and palladium supported on the carbon nanotubes. The electrocatalyst is prepared by dissolving copper nitrate trihydrate in deionized water to form a salt solution. Carbon nanotubes are then added to the salt solution to form a suspension, which is then heated. A urea solution is added to the suspension to form the electrocatalyst in solution. The electrocatalyst is then removed from the solution. In addition to dissolving the copper nitrate trihydrate in the deionized water, either iron nitrate monohydrate, ruthenium chloride or palladium chloride may also be dissolved in the deionized water to form the salt solution.
摘要翻译：提供了用于将二氧化碳电化学转化成烃的电催化剂。用于二氧化碳的电化学转化的电催化剂包括负载在碳纳米管上的铜材料。铜材料可以是纯铜，铜和钌，铜和铁，或者负载在碳纳米管上的铜和钯。通过将硝酸铜三水合物溶解在去离子水中以形成盐溶液制备电催化剂。然后将碳纳米管加入到盐溶液中以形成悬浮液，然后将其加热。向悬浮液中加入尿素溶液以在溶液中形成电催化剂。然后从溶液中除去电催化剂。除了将硝酸铜三水合物溶解在去离子水中外，还可以将硝酸铁一水合物，氯化钌或氯化钯溶解在去离子水中以形成盐溶液。

4. 发明授权

US08366889B2 Anode for electrolysis and manufacturing method thereof 有权
标题翻译：电解阳极及其制造方法
公开(公告)号：US08366889B2
公开(公告)日：2013-02-05
申请号：US13112637
申请日：2011-05-20
申请人： Toshikazu Hayashida
发明人： Toshikazu Hayashida
IPC分类号： C25B11/08 , C25B11/06
CPC分类号： C25B11/0484 , C25B11/0494
摘要： SubjectThe present invention aims to provide an anode for electrolysis by an ion exchange membrane process and the manufacturing method thereof which can show a lower concentration of by-product oxygen gas in chlorine gas and a lower overvoltage stably for a long time, compared with conventional anodes.Solution to ProblemThe present invention is to prepare an anode for electrolysis, comprising a substrate comprising titanium or titanium alloy and a plurality of coating layers provided by the thermal decomposition baking method on the surface of the substrate, wherein the coating layer comprises the first coating layer comprising a mixture of iridium oxide, ruthenium oxide and titanium oxide, provided on the surface of the substrate, the second coating layer comprising a mixture of platinum and iridium oxide, provided on the first coating layer, a unit layer comprising the first coating layer and the second coating layer, provided on the surface of the second coating layer by a single or a plurality of layer, and the second coating layer, provided on the outermost layer of the unit layer; the plurality of layer is provided on the surface of the substrate by means of the thermal decomposition baking method and the coating layer is followed by post-baking at a higher baking temperature than the formerly applied in the thermal decomposition baking method.
摘要翻译：题目本发明旨在提供一种离子交换膜方法的电解用阳极及其制造方法，与常规方法相比，可以在长时间内稳定地显示较低浓度的氯气中的副产物氧气和较低的过电压阳极解决问题的方法本发明是为了制备电解用阳极，其特征在于，在所述基板的表面具有包含钛或钛合金的基板和通过热分解焙烧法提供的多个涂层，其中，所述涂层包含所述第一涂层设置在基板的表面上的包含氧化铱，氧化钌和氧化钛的混合物的层，设置在第一涂层上的包含铂和氧化铱的混合物的第二涂层，包含第一涂层以及设置在所述第二被覆层的表面上的第一被覆层和设置在所述单位层的最外层上的所述第二被覆层，通过热分解焙烧法在基板的表面上设置多个层，然后在比以前在热分解焙烧方法中应用的烘焙温度高的烘烤温度下进行后烘烤。

5. 发明授权

US08349164B2 Conductive diamond electrode structure and method for electrolytic synthesis of fluorine-containing material 有权
标题翻译：导电金刚石电极结构和电解合成含氟材料的方法
公开(公告)号：US08349164B2
公开(公告)日：2013-01-08
申请号：US12142878
申请日：2008-06-20
申请人： Tsuneto Furuta , Setsuro Ogata , Masaharu Uno
发明人： Tsuneto Furuta , Setsuro Ogata , Masaharu Uno
IPC分类号： C25B1/24 , C25B11/06 , C25B11/12
CPC分类号： C25B11/0447 , C25B1/245 , C25B9/04
摘要： The present invention provides a conductive diamond electrode structure for use in electrolytic synthesis of a fluorine-containing material with a fluoride ion-containing molten salt electrolytic bath, which comprises: a conductive electrode feeder; and a conductive diamond catalyst carrier comprising a conductive substrate and a conductive diamond film carried on a surface thereof, wherein the conductive diamond catalyst carrier is detachably attached to the conductive electrode feeder at a portion to be immersed in the electrolytic bath. Also disclosed is an electrolytic synthesis of a fluorine-containing material using the conductive diamond electrode structure.
摘要翻译：本发明提供一种用于含氟化物离子的熔融盐电解浴的含氟材料的电解合成中的导电金刚石电极结构，其包括：导电电极馈送器; 以及导电性金刚石催化剂载体，其包含在其表面上承载的导电性基板和导电性金刚石膜，其中，所述导电性金刚石催化剂载体在要浸渍于所述电解槽中的部分可拆卸地连接于所述导电性电极给料器。还公开了使用导电金刚石电极结构的含氟材料的电解合成。

6. 发明申请

US20120305408A1 Buffered Cobalt Oxide Catalysts 有权
标题翻译：缓冲的氧化钴催化剂
公开(公告)号：US20120305408A1
公开(公告)日：2012-12-06
申请号：US13509674
申请日：2010-11-29
申请人： James B. Gerken , Shannon S. Stahl
发明人： James B. Gerken , Shannon S. Stahl
IPC分类号： C25B1/04 , C25B11/06
CPC分类号： C25B11/0405 , B01J23/75 , B01J37/348 , C01B13/0207 , C25B1/04 , C25B11/0442 , C25B11/0478 , C25B11/0489 , Y02E60/366
摘要： Disclosed are electrolysis catalysts formed from cobalt, oxygen and buffering electrolytes (e.g. fluoride). They can be formed as a coating on an anode by conducting an electrolysis reaction using an electrolyte containing cobalt and an anionic buffering electrolyte. The catalysts will facilitate the conversion of water to oxygen and hydrogen gas at a range of mildly acidic conditions. Alternatively, these anodes can be used with cathodes that facilitate other desirable reactions such as converting carbon dioxide to methanol.
摘要翻译：公开了由钴，氧和缓冲电解质（例如氟化物）形成的电解催化剂。它们可以通过使用含有钴和阴离子缓冲电解质的电解质进行电解反应而形成为阳极上的涂层。催化剂将促进水在温和酸性条件下转化为氧气和氢气。或者，这些阳极可以与促进其它所需反应的阴极一起使用，例如将二氧化碳转化成甲醇。

7. 发明授权

US08313623B2 Cathode for electrolytic processes 有权
标题翻译：电解工艺的阴极
公开(公告)号：US08313623B2
公开(公告)日：2012-11-20
申请号：US13440292
申请日：2012-04-05
申请人： Antonio Lorenzo Antozzi , Alice Calderara , Marianna Brichese
发明人： Antonio Lorenzo Antozzi , Alice Calderara , Marianna Brichese
IPC分类号： C25B11/06 , C25B11/08
CPC分类号： C25B11/0484 , C23C18/08 , C23C18/1216 , C23C18/1225 , C23C18/1241 , C25B1/34 , C25B11/0494
摘要： A cathode for electrolytic processes, particularly suitable for hydrogen evolution in chlor-alkali electrolysis comprises a metal substrate provided with a catalytic coating made of two layers containing palladium, rare earths (such as praseodymium) and a noble component selected between platinum and ruthenium. The rare earth percent amount by weight is lower in the outer layer than in the inner layer.
摘要翻译：用于电解方法的阴极，特别适用于氯碱电解中的析氢，包括一金属基底，该金属基底上设有由钯，稀土（如镨）和选自铂和钌之间的贵金属构成的两层催化剂涂层。外层中的稀土百分比重量比内层低。

8. 发明申请

US20120241315A1 ELECTROLYSIS DEVICE AND REFRIGERATOR 审中-公开
标题翻译：电解设备和制冷器
公开(公告)号：US20120241315A1
公开(公告)日：2012-09-27
申请号：US13408234
申请日：2012-02-29
申请人： Norihiro Yoshinaga , Yoshihiko Nakano , Norihiro Tomimatsu , Yoshihiro Akasaka
发明人： Norihiro Yoshinaga , Yoshihiko Nakano , Norihiro Tomimatsu , Yoshihiro Akasaka
IPC分类号： C25B9/10 , C25B11/06
CPC分类号： C25B1/30 , C25B9/10 , F25D17/042 , F25D2317/0411
摘要： An electrolysis device of an embodiment includes: an anode, a cathode having a nitrogen-containing carbon alloy catalyst, and an electrolysis cell having a membrane electrode assembly composed of an electrolyte present between the anode and the cathode so that voltage is applied to the anode and the cathode, wherein the electrolyte is any one of acidic, neutral, or alkali, water is produced by the electrolysis device at the cathode, when the electrolyte is acidic, and hydroxide ion is produced by the electrolysis device at the anode, when the electrolyte is neutral or alkali.
摘要翻译：一个实施方案的电解装置包括：阳极，具有含氮碳合金催化剂的阴极和具有由阳极和阴极之间存在的电解质构成的膜电极组件的电解槽，使得电压施加到阳极和阴极，其中电解质是阴极中的电解装置产生的酸性，中性或碱性的任何一种，当电解质为酸性时，在阳极处由电解装置产生氢氧根离子，当电解液是中性或碱。

9. 发明申请

US20120234689A1 Electrochemical Process for the Preparation of Nitrogen Fertilizers 有权
标题翻译：用于制备氮肥的电化学工艺
公开(公告)号：US20120234689A1
公开(公告)日：2012-09-20
申请号：US13420979
申请日：2012-03-15
申请人： Ted R. AULICH , Edwin S. OLSON , Junhua JIANG
发明人： Ted R. AULICH , Edwin S. OLSON , Junhua JIANG
IPC分类号： C25B1/00 , C25B11/03 , C25B9/08 , C25B11/06 , C25B9/18
CPC分类号： C05C9/00 , C05C1/00 , C25B1/00 , C25B3/00 , Y02P20/133 , Y02P20/134 , Y02P60/218
摘要： A method for producing fertilizers comprising feeding gaseous reactants comprising at least one nitrogen source and a source of hydrogen selected from the group consisting of a hydrogen-containing salt, a hydrogen-containing compound, and a hydrogen-containing gas to a reactor, the reactor including at least one reaction chamber, at least one anode, at least one cathode, and at least one electrolyte between each at least one anode and each at least one cathode, providing electricity to drive anodic and cathodic reactions, and producing a fertilizer having nitrogen by providing a nitrogen source of the at least one nitrogen source and at least one carbon source to the at least one cathode and a nitrogen source of the at least one nitrogen source to the at least one anode.
摘要翻译：一种生产肥料的方法，包括将含有选自含氢盐，含氢化合物和含氢气体的至少一种氮源和氢源的气态反应物进料到反应器中，反应器包括至少一个反应室，至少一个阳极，至少一个阴极和每个至少一个阳极和每个至少一个阴极之间的至少一个电解质，提供电力以驱动阳极和阴极反应，以及产生具有氮气的肥料通过将至少一个氮源的氮源和至少一个碳源提供给至少一个阴极和至少一个氮源的氮源至至少一个阳极。

10. 发明授权

US08221599B2 Corrosion-resistant anodes, devices including the anodes, and methods of using the anodes 失效
标题翻译：耐腐蚀阳极，包括阳极的装置以及使用阳极的方法
公开(公告)号：US08221599B2
公开(公告)日：2012-07-17
申请号：US12753234
申请日：2010-04-02
申请人： Christopher E. D. Chidsey , Paul C. McIntyre
发明人： Christopher E. D. Chidsey , Paul C. McIntyre
IPC分类号： C25B11/06 , C25B11/08 , C25B11/10 , C25B11/16
CPC分类号： C25B3/02 , C25B1/04 , C25B1/26 , C25B11/0484 , Y02E60/366 , Y02P20/135
摘要： Embodiments of the present disclosure include an anode, devices and systems including the anode (e.g., electrochemical devices and photo-electrochemical devices), methods of using the anode, methods of producing H2 and O2 from H2O, Cl2, oxidixed organic feedstocks, oxidation for the detection and quantification of chemical species, and the like.
摘要翻译：本公开的实施方案包括阳极，包括阳极的装置和系统（例如，电化学装置和光电化学装置），使用阳极的方法，从H 2 O，Cl 2，氧化有机原料生成H 2和O 2的方法，氧化用于化学物质的检测和定量等。

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