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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
181	Preparation of polythiiranes	US3651031D	1968-12-10	US3651031A	1972-03-21	BOUCHERON BERNARD
PROCESS FOR THE PREPARATION OF THERMOSTABLISIABLE POLYTHIIRANES IN WHICH POLYMERISATION IS EFFECTED IN A POLYMERISATION MEDIUM CONTAINING OR CONSISTING OF DIMETHYL SULFOXIDE AND A CATALYST SELECTED FROM THE GROUP CONSISTING OF A TETRAPHENYL PHOSPHONIUM SALT AND A TETRAALKYL AMMONIUM SALT.
182	Catalyst for making high molecular weight stereoregular polymers from olefin oxides and sulfides	US3649561D	1970-02-13	US3649561A	1972-03-14	LAL JOGINDER
AN OLEFIN OXIDE OR SULFIDE POLYMERIZATION CATALYST CONSISTING OF A MIXTURE OF (I) THE METAL-CONTAINING REACTION PRODUCT OF AN ALCOHOL, PHENOL OR MERCAPTAN WITH A COMPOUND HAVING THE FORMULA (R-Q-C(=Q'')-Q''-)-M-(X)(N-1) AND (II) MR"N, WHEREIN R IS MONOVALENT HYDROCARBON, OXYHYDROCARBON OR THIOHYDROCARBON CONTAINING UP TO 10 CARBON ATOMS, R" IS MONOVALENT HYDROCARBON CONTAINING UP TO 14 CARBON ATOMS, Q IS OXYGEN OR SULFUR, Q'' IS OXYGEN OR SULFUR AND AT LEAST ONE Q'' IN EACH MOLECULE IS SULFUR, M IS ZN, CD, MG OR AL, N IS THE VALENCE OF M, AND X IS MONOVALENT HALIDE, ALKOXY, THIOALKYL OR R-Q-C(=Q'')-Q
183	High molecular weight stereoregular polymers from olefin oxides and sulfides	US3632784D	1968-12-18	US3632784A	1972-01-04	LAL JOGINDER
OLEFIN OXIDES (OR SULFIDES) MAY BE POLYMERIZED WITH A CATALYST SYSTEM COMPRISED OF A MIXTURE OF I THE METALCONTAINING REACTION PRODUCT OF (A) AN ALCOHOL, PHENOL OR MERCAPTAN AND (B) A METAL ALKYL THIOCARBONATE AND II AN ORGANOMETALLIC COMPOUND. THE RESULTING POLYMERS HAVE HIGHER MOLECULAR WEIGHT AND/OR HIGHER STEREOREGULARITY THAN THE POLYMERS OBTAINED IN THE ABSENCE OF THE ORGANOMETALLIC COMPOUND. POLYMERS OF PROPYLENE OXIDE PREPARED BY THE USE OF THIS CATALYST SYSTEM YIELD GUM VULCANIZATES HAVING TENSIL STRENGTH VALUES IN EXCESS OF 3500 P.S.I.
184	Curable copolymers of episulfide monomers	US3624055D	1964-05-18	US3624055A	1971-11-30	GOBRAN RIAD H; OSBORN STEPHEN W
Copolymers essentially composed of a major portion of monomeric units derived from one or more monomers which are free from ethylenic unsaturation, have at least three carbon atoms and have a polymerizable thiiranyl group; and a minor portion of monomeric units derived from one or more monomers having both a polymerizable thiiranyl group and a polymerizable ethylenically unsaturated group are disclosed. The monomers free from ethylenic unsaturation may be, for example, ethylene sulfide, propylene sulfide, the 1,2- and 2,3-butylene sulfides, vinyl cyclohexane sulfide, 2-benzyl thiirane, paramethyl styrene episulfide, styrene sulfide, cyclohexene episulfide, and isobutylene sulfide. The ethylenically unsaturated monomers may be, for example, allylthioglycidyl ether, thioglycidyl acrylates, thioglycidyl alkacrylates such as thioglycidyl methacrylate, vinyl cyclohexene episulfide, and butadiene monoepisulfide. The monomers are polymerized through the thiiranyl groups thereof. The copolymers can be cured through the ethylenically unsaturated groups thereof to produce elastomers having good physical properties and solvent resistance.
185	Polymers from olefin oxides and sulfides	US3542698D	1968-08-09	US3542698A	1970-11-24	LAL JOGINDER

186	Catalytic process	US3472821D	1962-07-27	US3472821A	1969-10-14	OSBORN STEPHEN W

187	Enhancement of resistance of ethylene sulfide polymers to heat deterioration	US45989065	1965-05-28	US3405073A	1968-10-08	CHARLES ABRAMOFF

188	Thioglycidyl compounds	US36838464	1964-05-18	US3404158A	1968-10-01	JUN-SHEN YU ARTHUR

189	Polymerization of olefin oxides and olefin sulfides	US39762464	1964-09-18	US3345308A	1967-10-03	JOGINDER LAL

190	Compositions containing heterocyclic compounds and resinous products prepared therefrom	US23075162	1962-10-15	US3252946A	1966-05-24	HOLM ROY T
A heat curable composition comprises (1) an epoxy- or epithio-alkylester of 3,4-dihydro-1,2-pyran-2-carboxylic acid and (2) and amine containing at least two N-H bonds. Specified esters are glycidyl 3,4-dihydro-1,2-pyran-2-carboxylate and 2,3 - epithiopropyl - 3,4 - dihydro - 1,2 - pyran - 2 carboxylate. Preferred amines are aromatic, aliphatic or cyclo-aliphatic. The two components are mixed, either with or without solvent. Suitable concentrations of amine are 0.8 to 1.5 equivalents per equivalent of heterocyclic compound. Suitable additives are fillers, dyes, plasticizers, stabilizers, vinyl resins, pitches, distillate oils and alkyd resins. Resinification is achieved by heating at 90 to 250 DEG C., optionally in the presence of accelerators or catalysts. The examples describe the preparation of cured compositions from glycidyl-3,4-dihydro-1,2-pyran-2-carboxylate and (1) meta-phenylene diamine; (3) triethylenetetramine, (4) 1,3-diaminocyclohexane; (5) 1,3-diamino-(methyl)cyclohexane; (6) di-(hexamethylene)triamine; (7) meta - xylylene diamine; and (2) from 2,3-epithio-propyl-3,4-dihydro - 2 - pyran - 2 - carboxylate and metaphenylene diamene. Uses:-laminates, adhesives, mouldings, surface coatings.
191	Thermoplastic copolymer of vinyl monomer and sulfur	US19532462	1962-05-16	US3225120A	1965-12-21	BAKER JR WILLIAM P

192	Method of manufacturing infusion bags	US23635562	1962-11-08	US3222235A	1965-12-07	NORBERT BUCHNER
945,854. Seaming non-metallic sheet material. FR. HESSER MASCHINENFABRIK A.G. Sept. 4, 1962 [Dec. 11, 1961], No. 33802/62. Heading B5K. [Also in Division B8] Seams in fibrous packaging material, such as paper or cardboard, are formed by applying high frequency pressure impulses in the region to be seamed. Blanks or a web of the fibrous material may be passed between a sonotrode of an ultrasonic generator and a fixed anvil. The sonotrode is pressed under a predetermined pressure against the parts to be seamed whilst the generator transmits pressure impulses, preferably in the supersonic range, to the sonotrode. The pressure vibrations are preferably applied parallel to the plane of the layers of material to be seamed. Seaming may be continuous or intermittent. The method is applicable to seaming tea infusion bags made of coarse fibrous, permeable filter paper.
193	METHOD FOR PRODUCING POLYTHIOETHER COMPOUND	US17800274	2021-02-17	US20230129765A1	2023-04-27	Masanori SAKANE; Kenji KITAYAMA; Bing LIU
It is an object of the present disclosure to provide a method for efficiently and economically producing a polythioether compound by performing a ring-opening polymerization of an alicyclic episulfide compound. The present disclosure provides a method for producing a polythioether compound, the method including performing a ring-opening polymerization of an alicyclic episulfide compound in the presence of a base. The base is preferably an amine compound. Further, the base is preferably a strong base.
194	POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, POLYMERIZABLE PREPOLYMER COMPOSITION FOR OPTICAL MATERIAL, CURED PRODUCT, AND METHOD FOR PRODUCING OPTICAL MATERIAL	US17909516	2021-03-10	US20230111506A1	2023-04-13	Kouji SUESUGI; Shinsuke ITO; Yusuke MATSUI
A polymerizable composition for optical material including two or more different monomers for optical material and a polymerization catalyst, in which the content of the polymerization catalyst relative to the total amount of the monomers for optical material is from 0.1150 to 0.2000 parts by mass, the viscosity of the polymerizable composition for optical material is from 10 mPa·s to 1000 mPa·s as measured with a B-type viscometer at 20° C. and 60 rpm, and at least one of the two or more different monomers for optical material is an episulfide compound.
195	METHOD FOR SETTING POLYMERIZATION CONDITION AND METHOD FOR MANUFACTURING OPTICAL MATERIAL	US17262265	2019-07-24	US20210372984A1	2021-12-02	Masayuki FURUYA; Takeshi NISHIMURA
The method for setting polymerization conditions includes a physical property acquiring step, in which, when a composition which includes a polymerizable reactive compound including an episulfide compound, and a polymerization catalyst is heated and maintained at a predetermined temperature, a physical property value a derived from a functional group of the polymerizable reactive compound before heating and a physical property value b derived from a remaining functional group after maintaining heat for a predetermined time, are acquired; a remaining functional group ratio calculating step of calculating a remaining functional group ratio; a reaction rate coefficient calculating step for calculating a reaction rate coefficient; and a polymerization temperature calculating step of back-calculating each polymerization temperature every predetermined time in a polymerization time.
196	Optical material composition and method for producing same	US15031450	2014-12-19	US09658365B2	2017-05-23	Akinobu Horita; Yousuke Imagawa; Teruo Kamura; Hiroshi Horikoshi
Through an optical material composition containing a compound (a), a compound (b), a polythiol (c) and sulfur (d) according to the present invention, good mold release properties are obtained, and the occurrence of separation mark defects can be suppressed.Compound (a): a compound having the structure represented by formula (1): (In formula (1), m is an integer of 0 to 4 and n is an integer of 0 to 2.) Compound (b): a compound having the structure represented by formula (2): (In formula (2), m is an integer of 0 to 4 and n is an integer of 0 to 2.)
197	Polymerizable composition for optical materials	US14380809	2013-02-27	US09518153B2	2016-12-13	Eiji Koshiishi; Hitoshi Okazaki; Motoharu Takeuchi
The present invention addresses the problem of providing: a catalyst for preliminary reaction and a preliminary reaction method, which are suitable for a composition that is obtained by adding a thiol compound and an isocyanate compound to an episulfide compound; and a polymerizable composition for optical materials, which is capable of preventing yellowing of an optical material which contains a composition that is obtained by adding a thiol compound and an isocyanate compound to an episulfide compound. The above-mentioned problem can be solved by a polymerizable composition for optical materials, which contains a thiourethane oligomer that is obtained by preliminarily reacting the whole or a part of a thiol compound and an isocyanate compound in a composition that contains an episulfide compound, the thiol compound and the isocyanate compound, while using a compound represented by formula (2) below as a catalyst for preliminary reaction In formula (2), R represents an alkyl group having 1 to 4 carbon atoms; and X represents an organic group which has 2 to 11 carbon atoms and contains a vinyl group, a vinylidene group or a vinylene group.
198	BLOCK COPOLYMERS AND USES THEREOF	US15017028	2016-02-05	US20160256569A1	2016-09-08	James Brandon DIXON; Jeffrey A. HUBBELL; Conlin P. O'NEIL; Melody SWARTZ; Diana VELLUTO
Block copolymers containing charged blocks or chemical moieties sensitive to oxidation or hydrolysis have been developed. We describe the use of such block copolymers in supramolecular structures, e.g., micelles or vesicles, and pharmaceutical compositions and in methods of preparing the supramolecular structures and pharmaceutical compositions. The invention is particularly useful for the delivery of pharmaceutical agents, e.g., nucleic acids, to cells.
199	Composition and Polymer	US15081228	2016-03-25	US20160222168A1	2016-08-04	Akitake Nakamura; Takeshi Endo
Disclosed is a composition comprising (A) at least one compound selected from the group consisting of an ether compound having two or more ether groups, a trivalent phosphorus compound, and a ketone compound, (B) a boron trihalide, and (C) an episulfide compound.
200	Composition for optical materials, process for production thereof, and optical materials made from the composition	US14672922	2015-03-30	US09260566B2	2016-02-16	Kouhei Takemura; Hiroshi Horikoshi
The present invention has an object of providing, for example, a composition for optical materials which contains a polythiol that can be predicted and assessed, in a stage prior to polymerization/curing, as being clouded or not clouded after polymerization/curing, and thus can be determined as being good or defective. According to the present invention, the above-described object is achieved by, for example, a composition for optical materials which comprises a polythiol that exhibits an initial turbidity of 0.5 ppm or less and a turbidity of 0.6 ppm or less after the storage at 50° C. for 7 days, and an episulfide. Namely, an optical material made from a composition for optical materials which contains a polythiol satisfying the above turbidity requirements can be prevented from clouding to exhibit excellent transparency.

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