专利检索_..用含不止一个碳—碳双键的脂肪族化合物的聚合物专利检索_..用含不止一个碳—碳双键的脂肪族化合物的聚合物专利检索查询

序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
161		DEP0043032	1949-05-18	DE875405C	1953-05-04	GOPPEL JOHAN MICHAEL; RUMSCHEIDT GOTTFRIED ERNST
Products obtained by reacting polymers or copolymers of conjugated dienes with sulphur dioxide are stabilized with compounds having at least one condensed or non-condensed aryl nucleus and at least one, preferably esterified, carboxyl group, the carbonyl oxygen atom of which may or may not be substituted by sulphur, or with homologues, derivatives or salts of these compounds. The stabilizer may be benzoic acid, a naphthoic acid, phenyl o-hexadecoxy benzoate, salicylic acid, phenyl salicylate, mono-, di- or tri-allyl phenyl salicylate, zinc or calcium di-isopropyl salicylate, o-hydroxy phenoxy acetic acid, phthalic acid, naphthalic acid, diphenyl phthalate, or thiophthalic acid anhydride. Other stabilizers such as hexamethylene tetramine may be incorporated. The conjugated diene may be butadiene, methyl butadiene, dimethyl butadiene or chloroprene, which substances may be copolymerized with each other or with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile or methacrylonitrile. The reaction products to be stabilized may also comprise products obtained by the reaction of the polymers or copolymers and unsaturated compounds of low molecular weight with sulphur dioxide, suitable low molecular weight compounds being butadiene, 1,5-hexadiene, allyl alcohol, chloride, acetate, capronate, isothiocyanate, and oleate, diallyl phthalate and diallyl adipate. The stabilized polymers may be used in the preparation of threads, fibres, fabrics, tapes and films. Specification 666,644, [Group V], is referred to.
162		DEP0042233	1949-05-10	DE861602C	1953-01-08	RUMSCHEIDT GOTTFRIED E

163	Process for the application of substances, in particular dye-stuffs and stabilizers, in or on reaction products of macro-molecular, poly-unsaturated compounds with sulphur dioxide	GB1551950	1950-06-21	GB680492A	1952-10-08
Dyestuffs and stabilizers are incorporated in or on reaction products obtained by the action of sulphur dioxide on macromolecular polyunsaturated compounds in the form of threads or tapes by squirting a solution of the unsaturated compound through a narrow aperture into a solution of sulphur dioxide and then through solutions or dispersions of the substances to be applied. The compounds may be polymers of butadiene, methyl-butadiene, dimethyl butadiene, and chloroprene; and co-polymers of these monomers with isobutene, styrene, vinyl chloride, acrylonitrile, allyl alcohol, allyl chloride, allyl acetate, diallyl phthalate and diallyl adipate. The dyestuffs include Supraminrot B, noir acetoquinone N.B.N., Cibacet Orange 2R, Tuchrot B, and the stabilizers may be diphenyl-thiourea, diphenyl guanidine, melamine, hexamethylene tetramine, thiocyanates, and phenyl salicylate. Other substances which may be added include cetylpyridinium bromide and sapamines. Specification 616,276 is referred to.ALSO:Dyestuffs and stabilizers are incorporated in or on reaction products obtained by the action of sulphur dioxide or macromolecular poly-unsaturated compounds in the form of threads or tapes by squirting a solution of the unsaturated compound through a narrow aperture into a solution of sulphur dioxide and then through solutions or dispersions of the substances to be applied. The compounds may be natural rubber, gutta percha, or balata. The dyestuffs include Supraminrot B, noir acetoquinone N.B.N., Cibacet Orange 2R, Tuchrot B, and the stabilizers may be diphenylthiourea, diphenyl guanidine, melamine, hexamethylene tetramine thiocyanates, and phenyl salicylate. Other substances which may be added include cetyl-pyridinium bromide and sapamines. Specification 616,276 is referred to.
164		DEP0014720	1948-10-02	DE851256C	1952-10-02	RUMSCHEIDT GOTTFRIED ERNST; GOPPEL JOHAN MICHAEL

165	Non-fogging rubber hydrochloride film	GB328150	1950-02-08	GB675240A	1952-07-09
675,240. Rubber hydrochloride films. WINGFOOT CORPORATION. Feb. 8, 1950 [July 13, 1949], No. 3281/50. Addition to 635,740. Class 70 A non-fogging film of rubber hydrochlordie is produced by adding 1 to 10 per cent, preferably 3 per cent, of a polyethylene glycol ester of an aliphatic acid of 12-20 carbon atoms to a solution of rubber hydrochloride in benzene, casting the solution as a film and evaporating the benzene to produce film which is substantially 0.0008 to 0.002 inch thick. Preferred esters are the di- and tri-glycol esters of oleic acid, lauric acid and stearic acid; and specified esters are triethylene glycol dioleate, tetraethylene glycol dioleate, polyethylene glycol mono-oleate, polyethylene glycol dilaurate and polyethylene glycol monostearate.
166	A process for the application of substances, particularly colouring matters and stabilisers, in or on reaction products of high molecular weight	GB2389448	1948-09-10	GB666644A	1952-02-13
The reaction products of sulphur dioxide with polymers and copolymers of conjugated dienes having a molecular weight greater than 5000 are treated with colouring matters or textile assistants while the reaction products are in the swollen state. The textile assistants are defined as stabilizers, or compounds which improve moisture absorption, render the product water-repellent, reduce combustibility, or affect the gloss or the handle of the reaction product. The polymerized substances may be polymers of butadiene p and pentadiene, methyl butadiene, dimethyl butadiene, and chloro-prene, and copolymers of these substances with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile, or methacrylonitrile. The polymerized substances may be reacted with sulphur dioxide in the presence of a low molecular weight unsaturated compound such as butadiene, 1,5-hexadiene, allyl alcohol, allyl chloride, allyl acetate, allyl capronate, allyl isothiocyanate, allyl oleate, o-diallyl phthalate or diallyl adipate. Swelling is preferably effected by reacting the sulphur dioxide and polymerized material in solvents such as ethanol and a mixture of benzene and toluene respectively, alternatively, after reaction, swelling may be effected to a lesser extent with the aid of dichloroethane or chloroform, or by sulphuric acid, phosphoric acid or a solution of caustic soda. Specification 666,640, [Group V], is referred to.ALSO:The reaction products of sulphur dioxide with polymers and copolymers of conjugated dienes having a molecular weight greater than 5000 are treated with colouring matters or textile assistants while the reaction products are in the swollen state. The textile assistants are defined as stabilizers, or compounds which improve moisture absorption, render the product water-repellent, reduce combustibility, or affect the gloss or the handle of the reaction product. The polymerized substances may be natural rubber, polymers of butadiene and pentadiene, methyl butadiene, dimethyl butadiene, and chloroprene, and copolymers of these substances with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile, or methacrylonitrile. The polymerized substances may be reacted with sulphur dioxide in the presence of a low molecular weight unsaturated compound such as butadiene, 1,5-hexadiene, allyl alcohol, allyl chloride, allyl acetate, allyl capronate, allyl isothiocyanate, allyl oleate, O-diallyl phthalate or diallyl adipate. Swelling is preferably effected by reacting the sulphur dioxide and polymerized material in solvents such as ethanol and a mixture of benzene and toluene respectively, alternatively after reaction swelling may be effected to a lesser extent with the aid of dichloroethane or chloroform, or by sulphuric acid, phosphoric acid or a solution of caustic soda. In examples a swollen thread was produced by spinning by extrusion at -5 DEG C., the reaction product of a solution of rubber and tetraline peroxide in benzene and toluene, and sulphur dioxide in alcohol, and this thread was then soaked in a bath containing either "Supraminrot B" or "Noir acetoquinone N.BN" or Congo Red in water, or "Oil Orange N" in benzene, or in N, N1 diphenyl thiourea in ethanol. Specification 666,640, [Group V], is referred to.
167		FR986241D	1949-05-16	FR986241A	1951-07-30
Products obtained by reacting polymers or copolymers of conjugated dienes with sulphur dioxide are stabilized with compounds having at least one condensed or non-condensed aryl nucleus and at least one, preferably esterified, carboxyl group, the carbonyl oxygen atom of which may or may not be substituted by sulphur, or with homologues, derivatives or salts of these compounds. The stabilizer may be benzoic acid, a naphthoic acid, phenyl o-hexadecoxy benzoate, salicylic acid, phenyl salicylate, mono-, di- or tri-allyl phenyl salicylate, zinc or calcium di-isopropyl salicylate, o-hydroxy phenoxy acetic acid, phthalic acid, naphthalic acid, diphenyl phthalate, or thiophthalic acid anhydride. Other stabilizers such as hexamethylene tetramine may be incorporated. The conjugated diene may be butadiene, methyl butadiene, dimethyl butadiene or chloroprene, which substances may be copolymerized with each other or with isobutylene, styrene, vinyl chloride, vinyl esters, acrylic acid, methacrylic acid, acrylonitrile or methacrylonitrile. The reaction products to be stabilized may also comprise products obtained by the reaction of the polymers or copolymers and unsaturated compounds of low molecular weight with sulphur dioxide, suitable low molecular weight compounds being butadiene, 1,5-hexadiene, allyl alcohol, chloride, acetate, capronate, isothiocyanate, and oleate, diallyl phthalate and diallyl adipate. The stabilized polymers may be used in the preparation of threads, fibres, fabrics, tapes and films. Specification 666,644, [Group V], is referred to.
168		FR981164D	1949-02-22	FR981164A	1951-05-23

169		NL129030	1946-11-27	NL67085C	1951-01-15

170		FR958105D		FR958105A	1950-03-03

171	Procédé pour la fabrication d'articles extrudés.	CH263661D	1946-05-04	CH263661A	1949-09-15	MAATSCHAPPIJ N V DE BATAAFSCHE

172	Improvements in or relating to the manufacture of yarns, fibres, ribbons, films and similar articles	GB3245845	1945-11-30	GB627210A	1949-08-03
Yarns, fibres, ribbons and films are made by reacting a polymer or copolymer of a diene having an average molecular weight of at least 5000, with sulphur dioxide or sulphurous acid and treating the material thus formed to a stretching treatment in the swollen state and subsequently subjecting to drying in the stretched state to remove the swelling. The polymer or copolymer may be polymers of butadiene and its homologues or derivatives such as methyl butadiene, dimethyl butadiene, pentadiene and chloroprene; or copolymers of the above monomers with alkenes such as styrene. In examples, the polymer is dissolved in a solvent such as a benzene-xylene mixture together with tetrahydro naphthalene peroxide and the solution ejected through a spinning nozzle into a mixture of alcohol, water and sulphur dioxide. Stretching was effected by winding on to a reel rotating faster than the reel on which the thread was originally wound. Plasticizers, fillers, colouring matters and substances which diminish inflammability may also be added. Specification 627,209 is referred to. The Specification as open to inspection under Sect. 91 comprises also the use of polymers of acetylene and also copolymers of butadiene, methyl butadiene, dimethyl butadiene, pentadiene, chloroprene and acetylene with isobutene, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, vinylidene chloride, acrolein, methyl isopropyl ketone and vinyl ethyl ether. The sulphur dioxide or sulphurous acid may be replaced by any inorganic acid or anhydride excepting those of which the acid-forming element exists in the highest valency in the case in which the element forms more than one series of compounds. Specified substances are phosphorus trioxide and nitrous anhydride and the corresponding acids. This subject-matter does not appear in the Specification as accepted.ALSO:Yarn, fibres, ribbons, and films are made by reacting a polymer or copolymer of a diene having an average molecular weight of at least 5,000, with sulphur dioxide or sulphurous acid and treating the material thus formed to a stretching treatment in the swollen state and subsequently subjecting to drying in the stretched state to remove the swelling. The polymer or copolymer may be natural rubber, gutta-percha, balata; polymers of butadiene and its homologues or derivatives such as methyl butadiene, dimethyl butadiene, pentadiene, and chloroprene; or copolymers of the above monomers with alkenes such as styrene. In examples the polymer is dissolved in a solvent such as a benzenexylene mixture together with tetrahydro naphthalene peroxide and the solution ejected through a spinning nozzle into a mixture of alcohol, water and sulphur dioxide. Stretching was effected by winding onto a reel rotating faster than the reel on which the thread was originally wound. Plasticisers, fillers, colouring matters and substances which diminish inflammability may also be added. Specification 627,209 is referred to. The Specification as open to inspection under Sect. 91 comprises also the use of polymers of acetylene and also copolymers of butadiene, methyl butadiene, dimethyl butadiene, pentadiene, chloroprene and acetylene with isobutene, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, vinylidene chloride, acrolein, methyl isopropyl ketone and vinyl ethyl ether. The sulphur dioxide or sulphurous acid may be replaced by any inorganic acid or anhydride excepting those of which the acid-forming element exists in the highest valency in the case in which the element forms more than one series of compounds. Specified substances are phosphorous trioxide and nitrous anhydride and the corresponding acids. This subject-matter does not appear in the Specification as accepted.
173	Improvements in or relating to the manufacture of yarns, fibres, ribbons, films and similar articles	GB3245745	1945-11-30	GB627209A	1949-08-03
Yarns, fibres, ribbons and films of unsaturated synthetic polymers or copolymers of dienes with a molecular weight greater than 5000, are prepared by extruding a solution of the polymeric substance into a coagulating bath, stretching, so as to orientate the molecules along the longitudinal axis of the article formed and then reacting with sulphur dioxide or sulphurous acid. The polymeric substance may be polymers of butadiene, methyl butadiene, dimethyl butadiene or pentadiene; and copolymers of these monomers with isobutene. In an example, a solution of the polymer is injected into a spinning bath containing some sulphur dioxide and, after stretching by pulling off by means of rollers, the filaments pass into a second coagulating bath containing sulphur dioxide in methyl alcohol. The Specification as open to inspection under Sect. 91 comprises also the use of polymeric substances obtained by polymerizing chloroprene, acetylene or vinyl acetylene; and copolymerizing isobutene with styrene, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, vinylidene chloride, acrolein, methyl isopropenyl ketone or vinyl ethyl ether. The sulphur dioxide and sulphurous acid may be replaced by any inorganic acid or inorganic acid anhydride excepting those of which the acid-forming element exists in the highest valency in the case in which the element forms more than one series of compounds. Specified substances are phosphorus trioxide, sulphuretted hydrogen, hydrochloric and hydrobromic acid. This subject-matter does not appear in the Specification as accepted.ALSO:Yarns, fibres, ribbons and films of unsaturated natural or synthetic polymers or copolymers of dienes with a molecular weight greater than 5,000, are prepared by extruding a solution of the polymeric substance into a coagulating bath, stretching, so as to orientate the molecules along the longitudinal axis of the article formed and then reacting with sulphur dioxide or sulphurous acid. The polymeric substance may be natural rubber, polymers of butadiene, methyl butadiene, dimethyl butadiene or pentadiene; and copolymers of these monomers with isobutene. In an example, plasticised natural rubber dissolved in benzene, di-isopropyl ether and tetra hydronaphthalene peroxide, was injected into a spinning bath containing some sulphur dioxide and after stretching by pulling off by means of rollers it then passes into a second coagulating bath containing sulphur dioxide in methyl alcohol. The Specification as open to inspection under Sect. 91 comprises also the use of polymeric substances obtained by polymerising chloroprene, acetylene or vinyl acetylene; and copolymerising isobutene with styrene, vinyl chloride, vinyl acetate, acrylic acid, methacrylic acid, vinylidene chloride, acrolein, methyl isopropenyl ketone or vinyl ethyl ether. The sulphur dioxide and sulphurous acid may be replaced by any inorganic acid or inorganic acid anhydride excepting those of which the acid-forming element exists in the highest valency in the case in which the element forms more than one series of compounds. Specified substances are phosphorous trioxide sulphuretted hydrogen hydrochloric and hydrobromic acid. This subject-matter does not appear in the Specification as accepted.
174	Préparation de produits de réaction de corps de poids moléculaire élevé avec des acides ou anhydrides d'acides anorganiques	BE483618	1948-06-29	BE483618A	1948-07-15

175		NL114379	1943-12-11	NL59325C	1947-04-16

176	Procédé pour la fabrication de fils, fibres, rubans, pellicules et articles de ce genre	BE465060	1946-05-06	BE465030A	1946-06-29

177		FR902496D	1944-03-08	FR902496A	1945-08-31

178		FR888998D	1942-12-10	FR888998A	1943-12-28

179	폴리머의 제조 방법, 폴리머 생성물, 입자, 필름, 성형품, 및 섬유	KR1020167016327	2014-11-18	KR1020160088917A	2016-07-26	네모토다이치; 아라이요코; 이즈미사토시; 히라노시게히로; 시미즈다카유키; 다나카치아키
비닐결합을포함하는모노머를압축성유체와접촉시켜상기비닐결합을포함하는모노머를용융또는용해시킨후, 개시제의존재하에, 상기비닐결합을포함하는모노머의부가중합을수행하는것을포함하는폴리머의제조방법.
180	전자 차폐성 경량 고강도 탄소 복합재료의 제조방법	KR1019980045222	1998-10-28	KR100565385B1	2006-05-29	정두환; 김상진; 임정수; 조영근
수지와 혼합된 고분자 합금물질을 개발하여 탄소섬유 보강 복합재료를 제조하고 이를 열처리 및 후처리하여 전자 차폐성이 우수한 경량의 고강도 탄소 복합재료를 제조하는 방법이 개시된다. 본 발명에 따르면, 코오롱 유화에서 시판중인 페놀 수지(KRD-HM2)를 전처리한후 화이브리트(Fibrite)사에 의해서 시판중에 있는 PAN계 탄소섬유 메트를 페놀 수지 내에 함침시킨다. 페놀 수지의 전처리는, 최종 탄소섬유 복합재료 중에 페놀 수지의 함량이 45∼90% 내외가 되도록 수지의 농도를 조정한 후, 페놀 수지의 함량을 100으로 하였을 때, 3∼15%의 내부 이형제(RA 407), 5∼15%의 착색제(HSC-5694), 100∼300%(=페놀 수지 함량의 1∼3배)의 용매(아세톤, 에탄올 또는 메탄올)를 페놀 수지 속에 첨가시킨다. 전처리가 끝난후에는, 교반 속도를 최대로 하여 착색제가 용매에 완전히 용해될 때까지 교반하고, 페놀 수지와 내부 이형제를 가한후 다시 교반한다. 이렇게 만든 시료에 PAN 섬유 메트를 함침시킨다. 다음에는, 함침시킨 시료를 70℃에서 30∼50분간 건조시켜 프리프레그를 제조하고, 제조된 프리프레그를 몰드속에 적층시킨후, 프레스로 고온 가압한다. 프레싱이 끝난후에 시편을 냉각시킴으로서, 원하는 탄소 복합재료를 얻는다.

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