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91. 发明专利

AT8985T 未知
公开(公告)号：AT8985T
公开(公告)日：1984-09-15
申请号：AT81109321
申请日：1981-10-30
申请人： DEUTSCHE TEXACO AKTIENGESELLSCHAFT
发明人： GLUZEK, KARL-HEINZ, DR. , PETERSEN, OLAF, DR. , NEIER, WILHELM, DR. , STREHLKE, GUENTER, DR. , HEINEMANN, KARL-HEINZ, DR.
IPC分类号： B01J10/00 , B01J19/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C2/44 , C07C2/50 , C07C7/20 , C07C13/06 , C07C13/20 , C07C13/263 , C07C67/00
摘要： Formation of undesirable popcorn polymer on the walls of a reaction vessel during thermal dimerization of butadiene is prevented by coating the walls with a falling film of aqueous sodium nitrite solution.

92. 发明专利

FR2442900A2 Electrochemical catalytic system - with oxidisable metal anode, platinum etc. cathode and electrolyte contg. di:nitrosyl iron chloride 未知
公开(公告)号：FR2442900A2
公开(公告)日：1980-06-27
申请号：FR7833880
申请日：1978-11-30
申请人： CHARBONNAGES STE CHIMIQUE
IPC分类号： C25B3/29 , C25B3/10 , C07C2/44 , C07C13/20
摘要： Electrochemical catalytic system comprises (a) an anode of an oxidisable metal such as Al or Fe, (b) a cathode of Pt. Fe or vitreous carbon and (c) an electrolyte comprising (i) dinitrosyl Fe chloride (I) or a mixt. of FeCl3 or FeCl2 and NO, and (ii) an electrochemical solvent. The system is esp. useful for selective dimerisation of conjugated diolefins into dimers with a cyclohexenic structure, using an electrochemical cell contg. an anode, a cathode and a reference electrode. The cell contains a suitable solvent, the diolefin to be dimerised, and the (I) or iron chloride + NO. The cathode is then taken to a potential (w.r.t. the reference electrode) corresponding to the highest reduction state of the cpd. The potential is maintained between the cathode and the reference electrode e.g. using an automatic control device which provides the required voltage and current. The proces avoids the use of toxic materials, uses only small amts. of energy, and gives selective dimerisation of conjugated diolefins into cyclohexenic cpds.

93. 发明专利

SE356738B 未知
公开(公告)号：SE356738B
公开(公告)日：1973-06-04
申请号：SE463568
申请日：1968-04-05
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： WILKE G , HEIMBACH P , BRENNER W
IPC分类号： B01J31/00 , C07C2/44 , C07C1/00 , C07C2/46 , C07C13/06 , C07C67/00
摘要： 1,214,513. Dimerizing dienes; cyclobulane derivatives. STUDIENGESELLSCHAFT KOHLE m.b.H. 27 March, 1968 [8 April, 1967], No. 14628/68. Heading C5E. 1,3 - Dienes are cylodimerized by contact with a catalyst prepared by either (1) mixing a reducible nickel compound with an electron donor and a metal, metal hydride or halogenfree organometallic compound, having in each case a reducing action on the nickel compound, or (2) mixing a nickel complex compound containing zero-valent nickel with an electron donor. The cyclodimerization is conducted under conditions resulting in incomplete conversion of the diene. Suitable catalysts are formed from these components: nickel acetylacetonate / diethyl aluminium ethoxyl / tri- (o - phenyl - phenyl) phosphite (i.e. type 1), and bis (cyclooctadienyl) nickel / tri - (o - phenylphenyl) phosphite (i.e. type 2). In examples: (1-5, 8, 11 - 12) butadiene yields mainly cis-divinylcyclobutane and cyclooctadiene; (6 and 7) butadiene yields the same plus 4-vinylcyclohexene; (9) piperylene yields mainly dimethylcyclooctadiene and a mixture of the novel compounds 1,2 - cis - divinyl - 3,4 - dimethylcyclobutane and 1 - propenyl - 2 - vinyl- 3 - methyl - cyclobutane; and (10) a butadiene/ 2-butyne mixture yields mainly cis-divinylcyclobutane, cyclooctadiene, and dimethylcyclodecatriene.

94. 发明专利

CH497355A Verfahren zur katalytischen Dimerisation von 1,3-Diolefinen zu Divinylcyclobutanen 未知
公开(公告)号：CH497355A
公开(公告)日：1970-10-15
申请号：CH437868
申请日：1968-03-25
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： WILKE GUENTHER PROF , HEIMBACH PAUL DR , BRENNER WOLF-BERND DR
IPC分类号： C07C2/44 , B01J31/00 , C07C1/00 , C07C2/46 , C07C13/06 , C07C67/00

95. 发明专利

AT280986B 未知
公开(公告)号：AT280986B
公开(公告)日：1970-05-11
申请号：AT301168
申请日：1968-03-27
申请人： STUDIENGESELLSCHAFT KOHLE MBH
IPC分类号： C07C2/44 , B01J31/00 , C07C1/00 , C07C2/46 , C07C13/06 , C07C67/00 , C07C3/10
摘要： 1,214,513. Dimerizing dienes; cyclobulane derivatives. STUDIENGESELLSCHAFT KOHLE m.b.H. 27 March, 1968 [8 April, 1967], No. 14628/68. Heading C5E. 1,3 - Dienes are cylodimerized by contact with a catalyst prepared by either (1) mixing a reducible nickel compound with an electron donor and a metal, metal hydride or halogenfree organometallic compound, having in each case a reducing action on the nickel compound, or (2) mixing a nickel complex compound containing zero-valent nickel with an electron donor. The cyclodimerization is conducted under conditions resulting in incomplete conversion of the diene. Suitable catalysts are formed from these components: nickel acetylacetonate / diethyl aluminium ethoxyl / tri- (o - phenyl - phenyl) phosphite (i.e. type 1), and bis (cyclooctadienyl) nickel / tri - (o - phenylphenyl) phosphite (i.e. type 2). In examples: (1-5, 8, 11 - 12) butadiene yields mainly cis-divinylcyclobutane and cyclooctadiene; (6 and 7) butadiene yields the same plus 4-vinylcyclohexene; (9) piperylene yields mainly dimethylcyclooctadiene and a mixture of the novel compounds 1,2 - cis - divinyl - 3,4 - dimethylcyclobutane and 1 - propenyl - 2 - vinyl- 3 - methyl - cyclobutane; and (10) a butadiene/ 2-butyne mixture yields mainly cis-divinylcyclobutane, cyclooctadiene, and dimethylcyclodecatriene.

96. 发明专利

GB1155926A Alkenyl-Cyclobutane 未知
公开(公告)号：GB1155926A
公开(公告)日：1969-06-25
申请号：GB789467
申请日：1967-02-20
申请人： MONTEDISON SPA
IPC分类号： C07C2/44 , C07C13/06
摘要： 1,155,926. Alkenyl cyclobutanes. MONTECATINI EDISON S.p.A. 20 Feb., 1967 [24 Feb., 1966], No. 7894/67. Heading C5E. The invention comprises trans-1-vinyl-2-cispropenyl-3-methyl-cyclobutane, trans-1-vinyl- 2 - trans - propenyl - 3 - methyl - cyclobutane and 1,2 - dipropenyl - 3,4 - dimethyl - cyclobutane. These compounds are prepared by the irradiation with ultraviolet light of 2,4-hexadiene and 1,3 - butadiene in mol. ratios 1À5 : 1 to 1 : 1.5 or 2,4 - hexadiene alone (as appropriate) in an inert atmosphere at- 20‹ to + 30‹ C. in the presence of a carbonyl compound as sensitizer. Sensitizers specified are acetophenone, benzil, benzanthrone, anthraquinone, p,p 1 - tetramethyl - aminobenzophenone, 1- acetonaphthone, 2-acetonaphthone, benzophenone and 2 - naphthaldehyde. The process may be carried out in the presence of an alkane or cycloalkane.

97. 发明专利

NL6804835A 未知
公开(公告)号：NL6804835A
公开(公告)日：1968-10-09
申请号：NL6804835
申请日：1968-04-05
IPC分类号： B01J31/00 , C07C2/44 , C07C1/00 , C07C2/46 , C07C13/06 , C07C67/00
摘要： 1,214,513. Dimerizing dienes; cyclobulane derivatives. STUDIENGESELLSCHAFT KOHLE m.b.H. 27 March, 1968 [8 April, 1967], No. 14628/68. Heading C5E. 1,3 - Dienes are cylodimerized by contact with a catalyst prepared by either (1) mixing a reducible nickel compound with an electron donor and a metal, metal hydride or halogenfree organometallic compound, having in each case a reducing action on the nickel compound, or (2) mixing a nickel complex compound containing zero-valent nickel with an electron donor. The cyclodimerization is conducted under conditions resulting in incomplete conversion of the diene. Suitable catalysts are formed from these components: nickel acetylacetonate / diethyl aluminium ethoxyl / tri- (o - phenyl - phenyl) phosphite (i.e. type 1), and bis (cyclooctadienyl) nickel / tri - (o - phenylphenyl) phosphite (i.e. type 2). In examples: (1-5, 8, 11 - 12) butadiene yields mainly cis-divinylcyclobutane and cyclooctadiene; (6 and 7) butadiene yields the same plus 4-vinylcyclohexene; (9) piperylene yields mainly dimethylcyclooctadiene and a mixture of the novel compounds 1,2 - cis - divinyl - 3,4 - dimethylcyclobutane and 1 - propenyl - 2 - vinyl- 3 - methyl - cyclobutane; and (10) a butadiene/ 2-butyne mixture yields mainly cis-divinylcyclobutane, cyclooctadiene, and dimethylcyclodecatriene.

98. 发明专利

GB1076346A Vinyl-alkenyl-cyclobutanes 未知
公开(公告)号：GB1076346A
公开(公告)日：1967-07-19
申请号：GB4002265
申请日：1965-09-20
申请人： MONTEDISON SPA
IPC分类号： C07C2/44 , C07C13/06
摘要： Vinyl-alkenyl-cyclobutanes of the formula in which each R is H or CH3 provided at least one R is H and at least one R is CH3, are obtained by codimerizing butadiene with a C5 or C6 conjugated diene at -20 DEG to +20 DEG C. with ultraviolet radiation in the presence of a sensitizer. The conjugated diene may be isoprene which gives trans - 1,2 - divinyl - 1 - methylcyclo-butane and trans-1-isopropenyl-2-vinylcyclo-butane, piperylene which gives trans-1-propenyl - 2 - vinylcyclobutane or 2,3-dimethyl-butadiene which gives trans-1-methyl-1-isopropenyl-2-vinylcyclobutane, and is used in a molar ratio to butadiene of 1: 1 to 1.5: 5. The sensitizer is a carbonyl compound.ALSO:Vinylalkenylcyclobutanes of the formula in which each R is H or CH3 provided at least one is H and at least one is CH3, can be homopolymerized or copolymerized e.g. to form a terpolymer with ethylene and propylene which is vulcanizable with sulphur and accelerators.

99. 发明专利

DE1239301B 未知
公开(公告)号：DE1239301B
公开(公告)日：1967-04-27
申请号：DEB0069757
申请日：1962-11-27
申请人： BASF AG
发明人： NIEMANN DR GEORG , MUELLER DR HERBERT , WITTENBERG DR DIETMAR , RUEHLE DR-ING WILHELM
IPC分类号： C07C2/44 , C07C2/46

100. 发明公开

EP3873667A1 CALCINATION OF MICROPOROUS MOLECULAR SIEVE CATALYSTS 审中-公开
公开(公告)号：EP3873667A1
公开(公告)日：2021-09-08
申请号：EP19880483.3
申请日：2019-10-10
申请人： ExxonMobil Chemical Patents Inc.
发明人： IACCINO, Larry L. , BEDARD, Jeremy W. , BAO, Xiaoying , PALERMO, Andrew P. , MITTAL, Nitish , MILINA, Maria , LEVIN, Doron , GUNTHER, William R. , LAI, Wenyih, F. , BEUTEL, Tilman W.
IPC分类号： B01J37/08 , B01J37/00 , B01J29/48 , B01J37/02 , C07C5/03 , C07C13/15 , C07C2/44 , B01J8/06 , B01J29/90 , B01J8/26

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