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21. 发明专利

CA2058762C ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS 未知
公开(公告)号：CA2058762C
公开(公告)日：2001-05-08
申请号：CA2058762
申请日：1990-05-16
申请人： HOECHST AG
发明人： BOEHSHAR MANFRED , KLEINER HANS-JERG , PFAHLER GERHARD
IPC分类号： C07F9/48 , C07F9/6571 , C07F9/6574 , C08K5/53 , C08K5/5393 , C08L23/02 , C09K15/32 , C08L101/00
摘要： A process for the preparation of aryl phosphonites of the formula V (see formula I) in which A is non-existent or a direct bond or a divalent hydrocarbon bridge having 1 to 6 carbon atoms which may be substituted by groups mentioned further below under R1, or is a hetero atom, cycloalkylidene having 4 to 8 carbon atoms or phenylalkylidene having 7 to 12 carbon atoms, n is 1 or 2, R1 as monovalent radical is certain non-aromatic or aromatic hydrocarbon radicals, in which the aromatic radicals are substituents such as alkyl, alkoxy, alkylthio, dialkylamino, aryl, aryloxy or halogen, and as divalent radical a phenylene or naphthylene radical, which may carry non-aromatic hydrocarbon radicals as substituents, R2 is a non-aromatic hydrocarbon radical having 1 to 18 carbon atoms, aryl, arylmethyl, arylethyl or arylisopropyl, in which the aryl in each case contains 6 to carbon atoms, and R3 is hydrogen or a group mentioned under R2, in which process in a first step a hydrocarbon halide R1(-Hal)n, in which R1 has the abovementioned meaning, n is = 1 or 2 and the halogen has an atomic weight of at least 35, is reacted under Grignard conditions with at least molar amounts of magnesium to give the corresponding Grignard compounds R1(MgHal)n and these compounds are reacted in a second step with bisaryl halophosphonites of the formula VI (see formula I) , in which R2, R3 and Hal ha,e the abovementioned meaning, with the formation of the aryl phosphonites V. The invention further relates to a plastic molding composition, in particular a polyolefin molding composition containing aryl phosphonites of the formula V. The molding composition is distinguished by improved properties compared with those molding compositions containing phosphonites prepared by the prior art.

22. 发明专利

IN182462B A process for preparing a trivalent phosphours containing substance with improved hydrolysis stability useful as thermoplastic stabilizers 未知
公开(公告)号：IN182462B
公开(公告)日：1999-04-17
申请号：IN332MA1993
申请日：1993-05-14
申请人： HOECHST AG
发明人： KLEINER HANS-JERG , REGNAT DIETER , PFAHLER GERHARD
IPC分类号： C08K13/02

23. 发明专利

AU701242B2 Process for preparing 2,2'-bis(diphenylphosphinylmethyl) -1,1'-binaphthyls and new compounds from this class of substances 未知
公开(公告)号：AU701242B2
公开(公告)日：1999-01-21
申请号：AU1484995
申请日：1995-03-15
申请人： HOECHST AG
发明人： KLEINER HANS-JERG , REGNAT DIETER , ROSCHERT HORST
IPC分类号： C07C17/14 , C07F9/53 , C07F9/50

24. 发明专利

AU5658798A Process for preparing aluminium salts of dialkylphosphinic acids and diphosphinic acids 未知
公开(公告)号：AU5658798A
公开(公告)日：1998-07-03
申请号：AU5658798
申请日：1997-12-02
申请人： HOECHST AG
发明人： KLEINER HANS-JERG
IPC分类号： C07C311/03 , C07F9/30 , C08K5/5313 , C07F9/00
摘要： A process for preparing aluminum salts (I) of dialkylphosphinic acids or (formula (II)) of alkylated diphosphinic acidswhereR1 and R2 are a linear or branched C1-C8-alkyl radical andR3 is a linear or branched C1-C10-alkylene radical or an arylene radical or an alkylarylene radical or an arylalkylene radical,which comprises reacting a dialkylphosphinic acid ester of the formula (III) or a diphosphinic acid ester of the formula (IV)whereR1, R2 and R3 are as defined above andR4 is a linear or branched C1-C8-alkyl radical,in the presence of a saturated aliphatic monocarboxylic acid having a total of from 1 to 7 carbon atoms, with aluminum hydroxide at a temperature of from 150 to 350° C.

25. 发明专利

AT154369T 未知
公开(公告)号：AT154369T
公开(公告)日：1997-06-15
申请号：AT94911149
申请日：1994-03-10
申请人： SIEMENS AG , HOECHST AG
发明人： VON GENTZKOW WOLFGANG , HUBER JUERGEN , KAPITZA HEINRICH , ROGLER WOLFGANG , KLEINER HANS-JERG
IPC分类号： B05D7/24 , B29C39/00 , B32B27/38 , C08G59/14 , C08G59/18 , C08G59/20 , C08G59/30 , C08G59/32 , C08G59/40 , C08G59/50 , C08J5/24 , C08K5/3477 , C08L63/00 , C09D163/00 , H01B3/40 , H05K1/03
摘要： PCT No. PCT/EP94/00750 Sec. 371 Date Sep. 14, 1995 Sec. 102(e) Date Sep. 14, 1995 PCT Filed Mar. 10, 1994 PCT Pub. No. WO94/21706 PCT Pub. Date Sep. 29, 1994Epoxy resin mixtures for producing prepregs and composites that are available at low cost and can be processed well yield flame-retardant molding materials even without the addition of flame retardants, and these molding materials have a high glass transition temperature and also have an improved interlaminar adhesion and adhesion to copper when they contain the following components: a phosphorus-modified epoxy resin with an epoxy value of 0.02 to 1 mol/100 g, composed of structural units derived from (A) polyepoxy compounds with at least two epoxy groups per molecule and (B) at least one compound from the group consisting of phosphinic acids, phosphonic acids, pyrophosphonic acids and phosphonic acid half-esters, and an aromatic polyamine as the hardener.

26. 发明专利

CA1337723C OPTICALLY ACTIVE RHODIUM COMPLEXES OF 3,4-BIS(DIARYLPHOSPHINO)PYRROLIDINES AND THEIR USE FOR THE PREPARATION OF PHOSPHINOTHRICIN BY ASYMMETRIC HYDROGENATION 未知
公开(公告)号：CA1337723C
公开(公告)日：1995-12-12
申请号：CA591406
申请日：1989-02-17
申请人： HOECHST AG
发明人： MUELLER WOLF-DIETER , KLEINER HANS-JERG
IPC分类号： C07F9/30 , C07F9/32 , C07F9/572 , C07F15/00 , C08G18/10 , C08G18/28 , C08G18/83 , C08G65/32 , C08G65/329
摘要： The invention relates to rhodium complexes of the formula ¢A - 0 - (CH2CH20)n - A!2+ 2 X- Ia and ¢A - 0 - (CH2CH20)m - CH3!+ X- Ib in which n = 5-1,000, m = 5- 250, X denotes a tetrafluoroborate, hexafluorophosphate or per-chlorate anion, A denotes a radical of the formula II (en)2 denotes two molecules of a monoolefin or one mole cule of a diolefin Ar denotes phenyl or phenyl which is substituted by one or two alkyl groups having 1 or 2 carbon atoms and R1 denotes an arylene or alkylene bridge, and their use for the preparation of L-phosphinothricin and its derivatives by enantioselective catalytic hydrogenation of 2,3-dehydrophosphinothricin (derivatives).

27. 发明专利

CA2145255A1 PROCESS FOR PREPARING 2,2'-BIS(DIPHENYLPHOSPHINYLMETHYL)-1,1'-BINAPHTHYLS AND NEW COMPOUNDS FROM THIS CLASS OF SUBSTANCES 未知
公开(公告)号：CA2145255A1
公开(公告)日：1995-09-24
申请号：CA2145255
申请日：1995-03-22
申请人： HOECHST AG
发明人： KLEINER HANS-JERG , REGNAT DIETER , ROESCHERT HORST
IPC分类号： C07C17/14 , C07F9/53 , C07F9/50 , B01J19/08
摘要： Process for preparing2,2'-bis(diphenylphosphinylmethyl)-1,1'-binaphthyls and new compounds from this class of substances. The present invention relates to a process for preparing 2,2'-bis(diphenylphosphinylmethyl)-1,1'-binaphthyls, by reacting a reaction mixture prepared in a solvent by reaction of 2,2'-dimethyl-1,1'-binaphthyl with a brominating agent and containing 2,2'-bis(bromomethyl)-1,1'-binaphthyl and further brominated binaphthyls, if desired after removal of unreacted brominating agent, reacted brominating agent and/or solvent, with an alkyl diphenylphosphinite of the formula RO-P(Ph-(R')n)2, where R is an alkyl radical having from 1 to 5 carbon atoms, Ph is phenyl, R' is an alkyl radical having from 1 to 4 carbon atoms, CF3, fluorine, chlorine or bromine and n is 0, 1 or 2, at from 70 to 180.degree.C in the presence or absence of a further solvent. The invention further relates to compounds of the formula where R' is an alkyl radical having from 1 to 4 carbon atoms, CF3, fluorine, chlorine or bromine and n is 1 or 2.

28. 发明专利

FI954292A 未知
公开(公告)号：FI954292A
公开(公告)日：1995-09-13
申请号：FI954292
申请日：1995-09-13
申请人： SIEMENS AG , HOECHST AG
发明人： VON GENTZKOW WOLFGANG , HUBER JUERGEN , KAPITZA HEINRICH , ROGLER WOLFGANG , KLEINER HANS-JERG
IPC分类号： B05D7/24 , B29C39/00 , B32B27/38 , C08G59/14 , C08G59/18 , C08G59/20 , C08G59/30 , C08G59/32 , C08G59/40 , C08G59/50 , C08J5/24 , C08K5/3477 , C08L63/00 , C09D163/00 , H01B3/40 , H05K1/03 , C08G , C09D
摘要： PCT No. PCT/EP94/00750 Sec. 371 Date Sep. 14, 1995 Sec. 102(e) Date Sep. 14, 1995 PCT Filed Mar. 10, 1994 PCT Pub. No. WO94/21706 PCT Pub. Date Sep. 29, 1994Epoxy resin mixtures for producing prepregs and composites that are available at low cost and can be processed well yield flame-retardant molding materials even without the addition of flame retardants, and these molding materials have a high glass transition temperature and also have an improved interlaminar adhesion and adhesion to copper when they contain the following components: a phosphorus-modified epoxy resin with an epoxy value of 0.02 to 1 mol/100 g, composed of structural units derived from (A) polyepoxy compounds with at least two epoxy groups per molecule and (B) at least one compound from the group consisting of phosphinic acids, phosphonic acids, pyrophosphonic acids and phosphonic acid half-esters, and an aromatic polyamine as the hardener.

29. 发明专利

FI954291A0 未知
公开(公告)号：FI954291A0
公开(公告)日：1995-09-13
申请号：FI954291
申请日：1995-09-13
申请人： SIEMENS AG , HOECHST AG
发明人： VON GENTZKOW WOLFGANG , HUBER JUERGEN , KAPITZA HEINRICH , ROGLER WOLFGANG , KLEINER HANS-JERG , SCHOENAMSGRUBER UWE
IPC分类号： B05D7/24 , B29C39/00 , B29K63/00 , B32B27/38 , C08G59/14 , C08G59/18 , C08G59/30 , C08G59/32 , C08G59/40 , C08J5/24 , C09D163/00 , C09K21/14 , H01B3/40 , H05K1/03 , C08G , C09D
摘要： PCT No. PCT/EP94/00748 Sec. 371 Date Oct. 27, 1995 Sec. 102(e) Date Oct. 27, 1995 PCT Filed Mar. 10, 1994 PCT Pub. No. WO94/21704 PCT Pub. Date Sep. 29, 1994The present invention relates to phosphorus-modified epoxy resins having an epoxy number from 0 to 1 mol/100 g, comprising structural units which are derived from (A) polyepoxy compounds having at least two epoxy groups per molecule, and (B) phosphinic and/or phosphonic anhydrides. The invention further provides a process for preparing these phosphorus-modified epoxy resins and provides for the use of the resins in producing moldings, coatings or laminates.\!

30. 发明专利

FI954291A 未知
公开(公告)号：FI954291A
公开(公告)日：1995-09-13
申请号：FI954291
申请日：1995-09-13
申请人： SIEMENS AG , HOECHST AG
发明人： VON GENTZKOW WOLFGANG , HUBER JUERGEN , KAPITZA HEINRICH , ROGLER WOLFGANG , KLEINER HANS-JERG , SCHOENAMSGRUBER UWE
IPC分类号： B05D7/24 , B29C39/00 , B29K63/00 , B32B27/38 , C08G59/14 , C08G59/18 , C08G59/30 , C08G59/32 , C08G59/40 , C08J5/24 , C09D163/00 , C09K21/14 , H01B3/40 , H05K1/03 , C08G , C09D
摘要： PCT No. PCT/EP94/00748 Sec. 371 Date Oct. 27, 1995 Sec. 102(e) Date Oct. 27, 1995 PCT Filed Mar. 10, 1994 PCT Pub. No. WO94/21704 PCT Pub. Date Sep. 29, 1994The present invention relates to phosphorus-modified epoxy resins having an epoxy number from 0 to 1 mol/100 g, comprising structural units which are derived from (A) polyepoxy compounds having at least two epoxy groups per molecule, and (B) phosphinic and/or phosphonic anhydrides. The invention further provides a process for preparing these phosphorus-modified epoxy resins and provides for the use of the resins in producing moldings, coatings or laminates.\!

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