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21. 发明申请

US20050163699A1 Fluorosulfate-based electrode active materials and method of making the same 审中-公开
标题翻译：基于氟硫酸盐的电极活性材料及其制备方法
公开(公告)号：US20050163699A1
公开(公告)日：2005-07-28
申请号：US10764039
申请日：2004-01-23
申请人： Jeremy Barker , M. Saidi , Jeffrey Swoyer
发明人： Jeremy Barker , M. Saidi , Jeffrey Swoyer
IPC分类号： H01M4/58 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M10/36
CPC分类号： H01M10/0525 , H01M4/5825 , H01M4/62 , H01M10/0568 , H01M10/0569
摘要： The invention provides an electrochemical cell which includes a first electrode and a second electrode which is a counter electrode to said first electrode, and an electrolyte material interposed there between. The first electrode includes a fluorosulfate-based compound.
摘要翻译：本发明提供了一种电化学电池，其包括第一电极和第二电极，第二电极是与所述第一电极对置的电极，以及介于其间的电解质材料。第一电极包括基于氟硫酸盐的化合物。

22. 发明申请

US20050058905A1 Alkali/transition metal phosphates and related electrode active materials 有权
标题翻译：碱/过渡金属磷酸盐及相关电极活性物质
公开(公告)号：US20050058905A1
公开(公告)日：2005-03-17
申请号：US10945304
申请日：2004-09-20
申请人： Jeremy Barker , M. Saidi , Jeffrey Swoyer
发明人： Jeremy Barker , M. Saidi , Jeffrey Swoyer
IPC分类号： C01B33/20 , H01M2/16 , H01M4/131 , H01M4/136 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M6/16 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M10/36 , H01M10/40
CPC分类号： H01M4/136 , C01B25/45 , C01B33/20 , H01M2/1653 , H01M4/0471 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M2300/0037
摘要： Electrode active materials comprising lithium or other alkali metals, a transition metal, and a phosphate or similar moiety, of the formula: Aa+xMbP1−xSixO4 wherein (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0
摘要翻译：包含下式的锂或其它碱金属，过渡金属和磷酸盐或类似部分的电极活性材料：其中（a）A选自Li，Na，K和其混合物 0

23. 发明授权

US06730281B2 Methods of making transition metal compounds useful as cathode active materials 有权
标题翻译：制备用作阴极活性材料的过渡金属化合物的方法
公开(公告)号：US06730281B2
公开(公告)日：2004-05-04
申请号：US10150353
申请日：2002-05-17
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer , Ming Dong
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer , Ming Dong
IPC分类号： C01B2530
CPC分类号： H01M4/5825 , C01B25/37 , C01B25/45 , C01G21/00 , C01G31/00 , C01G39/00 , C01P2006/40 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/1391 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/582 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/0566 , Y10T29/10 , Y10T156/1002
摘要： A method for carrying out solid state reactions under reducing conditions is provided. Solid state reactants include at least one inorganic metal compound and a source of reducing carbon. The reaction may be carried out in a reducing atmosphere in the presence of reducing carbon. Reducing carbon may be supplied by elemental carbon, by an organic material, or by mixtures. The organic material is one that can form decomposition products containing carbon in a form capable of acting as a reductant. The reaction proceeds without significant covalent incorporation of organic material into the reaction product. In a preferred embodiment, the solid state reactants also include an alkali metal compound. The products of the method find use in lithium ion batteries as cathode active materials. Preferred active materials include lithium-transition metal phosphates and lithium-transition metal oxides. In a preferred embodiment, the reaction product contains carbon particles intimately mixed among crystals of the active materials.
摘要翻译：提供了一种在还原条件下进行固态反应的方法。固态反应物包括至少一种无机金属化合物和还原性碳源。反应可以在还原性碳存在下在还原气氛中进行。还原碳可以由元素碳，有机材料或混合物来提供。有机材料可以形成能够作为还原剂形式的含有碳的分解产物。反应进行而没有将有机材料显着共价掺入反应产物中。在优选的实施方案中，固态反应物还包括碱金属化合物。该方法的产品可用于锂离子电池作为阴极活性材料。优选的活性材料包括锂 - 过渡金属磷酸盐和锂 - 过渡金属氧化物。在优选的实施方案中，反应产物含有在活性物质晶体之间密切混合的碳颗粒。

24. 发明授权

US06723470B2 Lithium-based active materials and preparation thereof 有权
标题翻译：锂基活性物质及其制备方法
公开(公告)号：US06723470B2
公开(公告)日：2004-04-20
申请号：US09908480
申请日：2001-07-18
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
IPC分类号： H01M458
CPC分类号： H01M4/136 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M10/0525 , H01M2004/028
摘要： The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
摘要翻译：本发明提供新的锂混合金属材料，其在电化学相互作用时释放锂离子，并且能够可逆地循环锂离子。本发明提供一种可再充电锂电池，其包括由新型锂混合金属材料形成的电极。还提供了制备新的锂复合金属材料的方法和在电化学电池中使用这种锂混合金属材料的方法。锂混合金属材料除锂之外还包含锂和至少一种其它金属。优选的材料是除了锂之外还含有锂和另外两种金属的锂混合金属磷酸盐。

25. 发明授权

US06716372B2 Lithium-containing materials 有权
标题翻译：含锂材料
公开(公告)号：US06716372B2
公开(公告)日：2004-04-06
申请号：US10001376
申请日：2001-10-19
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
IPC分类号： C01B2537
CPC分类号： H01M4/5825 , C01B25/37 , C01B25/45 , C01G21/00 , C01G31/00 , C01G39/00 , C01P2006/40 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/1391 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/582 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/0566 , Y10T29/10 , Y10T156/1002
摘要： The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
摘要翻译：本发明提供新的锂混合金属材料，其在电化学相互作用时释放锂离子，并且能够可逆地循环锂离子。本发明提供一种可再充电锂电池，其包括由新型锂混合金属材料形成的电极。还提供了制备新的锂复合金属材料的方法和在电化学电池中使用这种锂混合金属材料的方法。锂混合金属材料除锂之外还包含锂和至少一种其它金属。优选的材料是除了锂之外还含有锂和另外两种金属的锂混合金属磷酸盐。

26. 发明授权

US06468695B1 Active material having extended cycle life 有权
标题翻译：活性物质具有延长的循环寿命
公开(公告)号：US06468695B1
公开(公告)日：2002-10-22
申请号：US09376914
申请日：1999-08-18
申请人： Jeremy Barker
发明人： Jeremy Barker
IPC分类号： H01M450
CPC分类号： H01M4/505 , C01G45/1242 , C01P2002/32 , C01P2002/77 , C01P2006/12 , C01P2006/40 , H01M4/1391 , H01M10/0525
摘要： In one embodiment, the invention provides a novel composition which is stabilized against decomposition when used as an active material for an electrochemical cell. The active material of the present invention comprises particles of spinel lithium manganese oxide (LMO) enriched with lithium by a decomposition product of lithium hydroxide forming a part of each of the LMO particles. The spinel LMO product formed by the decomposition of lithium hydroxide in the presence of the LMO is characterized by a reduced surface area and increased capacity retention (reduced capacity fading) as compared to the initial, non-treated, non-enriched spinel. In another aspect, the treated spinel LMO product is combined with lithium carbonate in a cathode mixture.
摘要翻译：在一个实施方案中，本发明提供了当用作电化学电池的活性材料时稳定的抗分解的新型组合物。本发明的活性物质包含由氢氧化锂的分解产物富含锂的尖晶石锂锰氧化物（LMO），形成每种LMO颗粒的一部分。在LMO存在下通过氢氧化锂分解形成的尖晶石LMO产物的特征在于与初始的未处理的非富集尖晶石相比，表面积减小并且容量保持率（降低的容量衰减）降低。另一方面，将经处理的尖晶石LMO产物与阴极混合物中的碳酸锂混合。

27. 发明授权

US06447951B1 Lithium based phosphates, method of preparation, and uses thereof 有权
标题翻译：锂基磷酸盐，制备方法及其用途
公开(公告)号：US06447951B1
公开(公告)日：2002-09-10
申请号：US09195961
申请日：1998-11-19
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： H01M458
CPC分类号： H01M10/052 , H01M4/136 , H01M4/1397 , H01M4/5825
摘要： The invention provides an electrochemical cell which comprises an electrode having a lithium metal phosphorous compound.
摘要翻译：本发明提供一种电化学电池，其包括具有锂金属磷化合物的电极。

28. 发明授权

US6015639A Thermally stable, highly conductive salt 失效
标题翻译：热稳定，高导电性盐
公开(公告)号：US6015639A
公开(公告)日：2000-01-18
申请号：US16608
申请日：1998-01-30
申请人： Feng Gao , Jeremy Barker , Peikang Liu
发明人： Feng Gao , Jeremy Barker , Peikang Liu
IPC分类号： H01B1/12 , H01M10/0525 , H01M10/0568 , H01M6/18
CPC分类号： H01M10/0568 , H01B1/122 , H01M10/0525
摘要： The invention provides a new family of compounds and a method of making the compounds. The new compounds are useful as ion conductive salts, and particularly useful as salts for batteries. The compounds of the invention are prepared from three principal reagents, bis (trifluoromethanesufonyl) methane (CF.sub.3 SO.sub.2).sub.2 CH.sub.2 ; benzoyl chloride; and pyridine which facilitates reaction and then is removed. A precursor sodium salt (CF.sub.3 SO.sub.2).sub.2 CHNa is first prepared. Then, equimolar amounts of the precursor sodium salt and pyridine are dissolved in anhydrous acetonitrile. A stoichiometric amount of the selected substitute benzoyl chloride is then added drop by drop. After addition of Li.sub.3 PO.sub.4, there is pyridine release and formation of the product of the aforesaid two reagents. In the benzene ring, R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are each identical or different and are each independently selected from hydrogen and an electron withdrawing substituent.
摘要翻译：本发明提供一种新的化合物族和一种制备该化合物的方法。新化合物可用作离子导电盐，并且特别用作电池的盐。本发明的化合物由三种主要试剂，二（三氟甲磺酰基）甲烷（CF 3 SO 2）2 CH 2; 苯甲酰氯; 和吡啶，这有助于反应然后被除去。首先制备前体钠盐（CF 3 SO 2）2 CHNa。然后将等摩尔量的前体钠盐和吡啶溶于无水乙腈中。然后逐滴加入化学计量的所选择的替代苯甲酰氯。添加Li3PO4后，存在吡啶释放并形成上述两种试剂的产物。在苯环中，R 1，R 2，R 3，R 4和R 5各自相同或不同，各自独立地选自氢和吸电子取代基。

29. 发明授权

US5922494A Stabilized electrolyte for electrochemical cells and batteries 失效
标题翻译：用于电化学电池和电池的稳定电解质
公开(公告)号：US5922494A
公开(公告)日：1999-07-13
申请号：US843203
申请日：1997-04-14
申请人： Jeremy Barker , Feng Gao
发明人： Jeremy Barker , Feng Gao
IPC分类号： H01M2/16 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0569 , H01M10/40
CPC分类号： H01M10/0569 , H01M10/052 , H01M10/0565 , H01M10/0525 , H01M2/1613 , H01M2/1653
摘要： An electrochemical cell comprising a first electrode; a counter-electrode which forms an electrochemical couple with the first electrode; and an electrolyte comprising a solvent and a solute. The solvent comprises a dialkyl carbonate of the formula R'OCOOR" where each of R' and R' represents an alkyl, and having at least one of R' and R" selected from the group consisting of non-linear, branched alkyls where R' and R" are preferably different from one another.
摘要翻译：一种电化学电池，包括第一电极; 与第一电极形成电化学耦合的对电极; 以及包含溶剂和溶质的电解质。溶剂包括式R'OCOOR“的二烷基碳酸酯，其中R'和R'各自表示烷基，并且具有选自非直链，支链烷基的R'和R”中的至少一个其中R'和R“优选彼此不同。

30. 发明授权

US5871865A Methods of fabricating electrochemical cells 失效
标题翻译：制造电化学电池的方法
公开(公告)号：US5871865A
公开(公告)日：1999-02-16
申请号：US857025
申请日：1997-05-15
申请人： Jeremy Barker , Steven Cochran
发明人： Jeremy Barker , Steven Cochran
IPC分类号： H01M2/12 , H01M4/131 , H01M4/133 , H01M4/139 , H01M10/0525 , H01M10/0565 , H01M10/058 , H01M10/36 , H01M10/44 , H01M10/50 , H01M10/40
CPC分类号： H01M10/44 , H01M10/0525 , H01M10/0565 , H01M10/058 , H01M10/52 , H01M10/446 , H01M10/615 , H01M2/12 , H01M4/131 , H01M4/133 , H01M4/139 , Y10T29/49108 , Y10T29/4911
摘要： Conditioning secondary lithium ion cells at elevated temperatures above ambient reduces the time required to complete this process and produces cells and batteries which demonstrate improved electrochemical performance. Conditioning includes subjecting an electrochemical cell to at least one full charge/discharge cycle whereby gases generated and removed before the cell is sealed and ready for use.
摘要翻译：在高于环境的高温下调节二次锂离子电池可减少完成此过程所需的时间，并生产显示出改进的电化学性能的电池和电池。调节包括使电化学电池经受至少一个完全充电/放电循环，由此在电池被密封并准备使用之前产生和除去气体。

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