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31. 发明授权

US6103419A Solid secondary lithium cell based on lithiated zirconium, titanium or hafnium oxide cathode material 失效
标题翻译：固体二次锂电池基于锂化锆，钛或铪氧化物阴极材料
公开(公告)号：US6103419A
公开(公告)日：2000-08-15
申请号：US708232
申请日：1996-09-06
申请人： M. Yazid Saidi , Jeremy Barker , Rene Koksbang
发明人： M. Yazid Saidi , Jeremy Barker , Rene Koksbang
IPC分类号： H01M4/131 , H01M4/133 , H01M4/48 , H01M4/485 , H01M4/52 , H01M4/525 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/485 , H01M10/0525 , H01M4/525 , H01M4/131 , H01M4/133 , Y02P70/54
摘要： Provided by the present invention is a new cathode material comprised of a lithiated zirconium, titanium or hafnium oxide. The oxide is of the formula Li.sub.2 MXO.sub.4, where M is preferably a transition metal such as Ni, Co, Fe, Mn, V, Cu, or Cr, and X is zirconium, titanium or hafnium. The cathode material provides a useful composite cathode when combined with a polymeric binder and carbon.
摘要翻译：由本发明提供的是由锂化锆，钛或氧化铪组成的新的阴极材料。氧化物具有式Li2MXO4，其中M优选为过渡金属如Ni，Co，Fe，Mn，V，Cu或Cr，X为锆，钛或铪。当与聚合物粘合剂和碳组合时，阴极材料提供有用的复合阴极。

32. 发明授权

US5871866A Lithium-containing phosphates, method of preparation, and use thereof 失效
标题翻译：含锂磷酸盐，其制备方法及其用途
公开(公告)号：US5871866A
公开(公告)日：1999-02-16
申请号：US717979
申请日：1996-09-23
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： C01B25/45 , H01M4/02 , H01M4/04 , H01M4/58 , H01M4/583 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M10/36 , H01M4/48
CPC分类号： H01M10/052 , C01B25/45 , H01M10/0525 , H01M4/04 , H01M4/0404 , H01M4/0409 , H01M4/0416 , H01M4/13 , H01M4/5825 , H01M4/622 , H01M4/625 , H01M2004/021 , H01M2004/028 , H01M4/583 , Y02P70/54
摘要： The invention provides an electrochemical cell which comprises a first electrode and a second electrode which is a counter electrode to said first electrode. The first electrode comprises a phosphorous compound of the general formula, Li.sub.3 M'M" (PO.sub.4).sub.3. M' and M" are the same or different from one another. Where M' and E" are the same, they are metals having more than one oxidation state. Where M' and M" are different from one another, they are selected from the group of metals where at least one of M' and M" has more than one oxidation state.
摘要翻译：本发明提供了一种电化学电池，其包括第一电极和作为与所述第一电极相对的电极的第二电极。第一电极包括通式为Li 3 M'M“（PO 4）3的磷化合物。 M'和M“彼此相同或不同。当M'和E“相同时，它们是具有多于一种氧化态的金属。其中M'和M“彼此不同，它们选自M'和M”中的至少一个具有多于一个氧化态的金属组。

33. 发明授权

US5851696A Rechargeable lithium battery 失效
标题翻译：可充电锂电池
公开(公告)号：US5851696A
公开(公告)日：1998-12-22
申请号：US593636
申请日：1996-01-29
申请人： M. Yazid Saidi , Jeremy Barker
发明人： M. Yazid Saidi , Jeremy Barker
IPC分类号： H01M4/02 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/485 , H01M10/0525 , H01M4/505 , H01M2004/027 , H01M2300/0025
摘要： The present invention provides an electrochemical cell or battery, which has a nonmetal negative electrode (anode). That is, no solid metal active material is used in the cell. Rather than the conventional solid lithium metal anode, the active material of the new anode comprises a compound of vanadium oxide. Accordingly, the lithium cell of the invention comprises a positive electrode and a negative electrode, where the negative electrode comprises a compound of vanadium oxide which in a fully discharged state is represented by the nominal general formula V.sub.6 O.sub.13 or Li.sub.y V.sub.6 O.sub.13, y equal to 0; and, in a fully or partially lithiated, fully or partially charged state, is represented by the nominal general formula Li.sub.y V.sub.6 O.sub.13, where y is greater than 0 and less than or equal to 8. The unique negative electrode of the invention demonstrates exceptional performance without the disadvantages of metallic lithium negative electrodes.
摘要翻译：本发明提供一种具有非金属负极（阳极）的电化学电池或电池。也就是说，在电池中不使用固体金属活性材料。而不是传统的固体锂金属阳极，新阳极的活性材料包括氧化钒的化合物。因此，本发明的锂电池包括正极和负极，其中负极包括氧化钒的化合物，其在完全放电状态下由标称通式V6O13或LiyV6O13表示，y等于0; 并且在完全或部分锂化的完全或部分充电状态下，由标称通式Li y V 6 O 13表示，其中y大于0且小于或等于8.本发明的独特负极表现出卓越的性能，而没有金属锂负极的缺点。

34. 发明授权

US5698338A Solid secondary lithium cell based on Li.sub.x Ni.sub.y Co.sub.1-y VO.sub.4 < or=x< or=1.1 and 0<y<1 cathode material 失效
标题翻译：基于LixNiy Co1-yVO4的固体二次锂电池，其中0.9 <或= x <或= 1.1且0
公开(公告)号：US5698338A
公开(公告)日：1997-12-16
申请号：US616900
申请日：1996-03-15
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： C01G53/00 , H01M4/131 , H01M4/133 , H01M4/48 , H01M4/485 , H01M4/52 , H01M4/525 , H01M10/0525 , H01M10/36 , H01M9/48
CPC分类号： H01M4/485 , C01G53/42 , H01M4/525 , C01P2002/54 , C01P2002/72 , C01P2006/40 , H01M10/0525 , H01M4/131 , H01M4/133
摘要： Non-aqueous lithium solid electrochemical cells with improved performance can be fabricated by employing intercalation based carbon anodes and cathodes comprising Li.sub.x Ni.sub.y CO.sub.1-y VO.sub.4 wherein 0.9.ltoreq.X.ltoreq.1.1 and 0.1
摘要翻译：具有改进性能的非水性锂固体电化学电池可以通过采用基于嵌层的碳阳极和包含LixNiy CO1-yVO4的阴极来制造，其中0.9

35. 发明授权

US5670277A Lithium copper oxide cathode for lithium cells and batteries 失效
标题翻译：锂电池用锂铜氧阴极
公开(公告)号：US5670277A
公开(公告)日：1997-09-23
申请号：US664092
申请日：1996-06-13
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： H01M4/131 , H01M4/133 , H01M4/48 , H01M4/485 , H01M6/10 , H01M10/052 , H01M10/0525 , H01M10/0569 , H01M10/36 , H01M4/02
CPC分类号： H01M4/485 , H01M10/0525 , H01M10/052 , H01M10/0569 , H01M4/131 , H01M4/133
摘要： The invention provides a rechargeable lithium battery which comprises an electrolyte; a negative electrode having a compatible active material; and a positive electrode comprising a lithium copper oxide intercalation compound. The positive electrode active material is characterized by an ability to deintercalate lithium ions for intercalation into the negative electrode active material. The lithium copper oxide has a proportion of 2 lithium ions per formula unit of the copper oxide and upon electrochemical interaction with a negative electrode deintercalates lithium ions whereupon the proportion of lithium ions per copper oxide formula unit is less than 2. The lithium copper oxide is a compound represented by the nominal general formula Li.sub.2 CuO.sub.2. The lithium copper oxide compound is alternatively represented by the nominal general formula Li.sub.2-x CuO.sub.2, signifying its capability to deintercalate lithium.
摘要翻译：本发明提供一种可充电锂电池，其包括电解质; 具有相容的活性物质的负极; 以及包含锂铜氧化物插层化合物的正极。正极活性物质的特征在于将锂离子脱嵌插入负极活性物质中的能力。锂二氧化铜每氧化铜的配方单位具有2个锂离子的比例，并且与负极的电化学相互作用脱去锂离子，因此每个氧化铜配方单元的锂离子的比例小于2.氧化铜锂是由标称通式Li 2 CuO 2表示的化合物。氧化锂铜化合物可替代地由标称通式Li 2-x Cu 2 O 2表示，表示其脱嵌锂的能力。

36. 发明申请

US20100266899A1 Electrodes Comprising Mixed Active Particles 审中-公开
标题翻译：包含混合活性颗粒的电极
公开(公告)号：US20100266899A1
公开(公告)日：2010-10-21
申请号：US12828472
申请日：2010-07-01
申请人： Jeremy Barker , M. Yazid Saidi , Tracy E. Kelley
发明人： Jeremy Barker , M. Yazid Saidi , Tracy E. Kelley
IPC分类号： H01M4/58 , H01M4/00
CPC分类号： H01M4/525 , H01M4/13 , H01M4/364 , H01M4/505 , H01M4/582 , H01M4/5825 , H01M10/0525
摘要： An electrode active material comprising two or more groups of particles having differing chemical compositions, wherein each group of particles comprises a material selected from: (a) materials of the formula A2eM2fOg; and (b) materials of the formula A3hMniO4; wherein (i) A2, and A3 are independently selected from the group consisting of Li, Na, K, and mixtures thereof, 0
摘要翻译：包含两组或更多组具有不同化学组成的颗粒的电极活性材料，其中每组颗粒包含选自以下的材料：（a）式A2eM2fOg的材料; 和（b）式为A3hMniO4的材料; 其中（i）A2和A3独立地选自由Li，Na，K及其混合物组成的组，e＆lt; e1; 6和h＆nlE; 2.0; （ii）M2是一种或多种金属，其包含选自Fe，Co，Ni，Mo，V，Zr，Ti，Mo和Cr中的至少一种金属和1＆lt; lE; f＆nlE; 6; （iii）0

37. 发明授权

US07767332B2 Alkali/transition metal phosphates and related electrode active materials 有权
标题翻译：碱/过渡金属磷酸盐及相关电极活性物质
公开(公告)号：US07767332B2
公开(公告)日：2010-08-03
申请号：US11457047
申请日：2006-07-12
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
IPC分类号： H01M4/00 , H01M4/58
CPC分类号： H01M4/136 , C01B25/45 , C01B33/20 , H01M2/1653 , H01M4/0471 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M2300/0037
摘要： Electrode active materials comprising lithium or other alkali metals, a transition metal, and a phosphate or similar moiety, of the formula: Aa+xMbP1-xSixO4 wherein (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0
摘要翻译：包含下式的锂或其它碱金属，过渡金属和磷酸盐或类似部分的电极活性材料：其中（a）A选自Li，Na，K和其混合物 0 n; 2; 并且选择M，a，b和x以保持所述化合物的电中性。

38. 发明授权

US07759008B2 Sodium ion batteries 失效
标题翻译：钠离子电池
公开(公告)号：US07759008B2
公开(公告)日：2010-07-20
申请号：US10906182
申请日：2005-02-07
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey Swoyer
IPC分类号： H01M4/48 , H01M4/58 , H01M4/02
CPC分类号： H01M4/40 , C01B25/455 , H01M4/5815 , H01M4/582 , H01M4/5825 , H01M4/583 , H01M4/587 , H01M10/054 , H01M10/0564 , H01M10/0565 , H01M2004/021 , H01M2004/028 , H01M2300/0037
摘要： Sodium ion batteries are based on sodium based active materials selected among compounds of the general formula AaMb(XY4)cZd, wherein A comprises sodium, M comprises one or more metals, comprising at least one metal which is capable of undergoing oxidation to a higher valence state, Z is OH or halogen, and XY4 represents phosphate or a similar group. The anode of the battery includes a carbon material that is capable of inserting sodium ions. The carbon anode cycles reversibly at a specific capacity greater than 100 mAh/g.
摘要翻译：钠离子电池基于选自通式AaMb（XY4）cZd的化合物中的钠基活性材料，其中A包含钠，M包含一种或多种金属，其包含能够经历氧化至更高价态的至少一种金属状态，Z是OH或卤素，XY4表示磷酸酯或类似基团。电池的阳极包括能够插入钠离子的碳材料。碳阳极在大于100mAh / g的比容量下可逆地循环。

39. 发明申请

US20080157024A1 PRODUCT AND METHOD FOR THE PROCESSING OF PRECURSORS FOR LITHIUM PHOSPHATE ACTIVE MATERIALS 有权
标题翻译：磷酸锂活性材料前处理剂的加工产品及方法
公开(公告)号：US20080157024A1
公开(公告)日：2008-07-03
申请号：US12046942
申请日：2008-03-12
申请人： George Adamson , Jeremy Barker , Allan Dirilo , Titus Faulkner , M. Yazid Saidi , Jeffrey Swoyer
发明人： George Adamson , Jeremy Barker , Allan Dirilo , Titus Faulkner , M. Yazid Saidi , Jeffrey Swoyer
IPC分类号： H01M4/36 , C01B25/12
CPC分类号： H01M4/5825 , H01M4/582 , H01M10/052
摘要： Methods for producing an electrode active material precursor, comprising; a) producing a mixture comprising particles of lithium hydrogen phosphate, having a first average particle size, and a metal hydroxide, having a second average particle size; and b) grinding said mixture in a jet mill for a period of time suitable to produce a generally homogeneous mixture of particles having a third average size smaller than said first average size. The precursor may be used as a starting material for making electrode active materials for use in a battery, comprising lithium, a transition metal, and phosphate or a similar anion.
摘要翻译：电极活性物质前体的制造方法， a）制备具有第一平均粒径的磷酸氢锂颗粒和具有第二平均粒径的金属氢氧化物的混合物; 以及b）在喷射式研磨机中研磨所述混合物一段适当的时间，以生产具有比所述第一平均尺寸小的第三平均尺寸的颗粒的均匀混合物。前体可以用作用于制造用于电池的电极活性材料的起始材料，其包括锂，过渡金属和磷酸盐或类似的阴离子。

40. 发明申请

US20070001153A1 Synthesis of Metal Compounds Under Carbothermal Conditions 审中-公开
标题翻译：在碳热条件下合成金属化合物
公开(公告)号：US20070001153A1
公开(公告)日：2007-01-04
申请号：US11161186
申请日：2005-07-26
申请人： Jeremy Barker , Yazid Saidi , Ming Dong , Jeffrey Swoyer
发明人： Jeremy Barker , Yazid Saidi , Ming Dong , Jeffrey Swoyer
IPC分类号： H01B1/08
CPC分类号： H01M4/5825 , C01B25/37 , C01B25/45 , C01G21/00 , C01G31/00 , C01G39/00 , C01P2006/40 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/1391 , H01M4/1397 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/582 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/0566 , Y10T29/10 , Y10T156/1002
摘要： Active materials of the invention contain at least one alkali metal and at least one other metal capable of being oxidized to a higher oxidation state. Preferred other metals are accordingly selected from the group consisting of transition metals (defined as Groups 4-11 of the periodic table), as well as certain other non-transition metals such as tin, bismuth, and lead. The active materials may be synthesized in single step reactions or in multi-step reactions. In at least one of the steps of the synthesis reaction, reducing carbon is used as a starting material. In one aspect, the reducing carbon is provided by elemental carbon, preferably in particulate form such as graphites, amorphous carbon, carbon blacks and the like. In another aspect, reducing carbon may also be provided by an organic precursor material, or by a mixture of elemental carbon and organic precursor material.
摘要翻译：本发明的活性材料含有至少一种碱金属和至少一种能被氧化成较高氧化态的其它金属。因此，优选的其它金属选自过渡金属（定义为周期表第4-11部分）以及某些其它非过渡金属如锡，铋和铅。活性物质可以在单步反应或多步反应中合成。在合成反应的至少一个步骤中，使用还原性碳作为原料。一方面，还原碳由元素碳提供，优选为颗粒形式，例如石墨，无定形碳，炭黑等。另一方面，还原碳还可以由有机前体材料或元素碳和有机前体材料的混合物提供。

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