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    • 34. 发明授权
    • Process for the production of synthetic rutile
    • 合成金红石的生产工艺
    • US4199552A
    • 1980-04-22
    • US910051
    • 1978-05-26
    • Theodore A. Rado
    • Theodore A. Rado
    • C22B34/12C01G23/04
    • C22B34/1227C22B34/1204Y02P10/23
    • An improved process for the production of synthetic rutile from ore containing titanium and iron, such as ilmenite ore, by a multi-step procedure employing controlled reduction, controlled oxidation and acid leaching. More specifically, the ilmenite ore first is reduced thermally such that substantially all of the iron (III) present has been converted to iron (II) and some metallic iron. The reduced ore then is oxidized with an oxidizing gas substantially free of elemental oxygen to convert the metallic iron to iron (II) without the substantial formation of iron (III). The oxidized ore then is leached to remove the iron (II) and calcined to produce synthetic rutile. The synthetic rutile so produced contains in excess of 92 percent titanium dioxide and less than 2 percent iron (III), by weight. Often, the synthetic rutile contains less than 1 percent total iron by weight.
    • 通过使用受控还原,受控氧化和酸浸的多步法,从含有钛和铁的矿石如钛铁矿生产合成金红石的改进方法。 更具体地,钛铁矿矿石首先被热降解,使得存在的铁(III)基本上全部已经转化为铁(II)和一些金属铁。 然后,还原的矿石用基本上不含元素氧的氧化气体氧化,以将金属铁转化成铁(II)而不大量形成铁(III)。 然后将氧化的矿石浸出以除去铁(II)并煅烧以产生合成金红石。 如此生产的合成金红石含有超过92%的二氧化钛和小于2%的铁(III)重量比。 通常,合成金红石含有少于1重量%的铁。
    • 40. 发明申请
    • Process for making titanium dioxide
    • 制备二氧化钛的方法
    • US20040166054A1
    • 2004-08-26
    • US10374266
    • 2003-02-25
    • Donald Theodore Turnbaugh JR.Bruce Lynn Roberts
    • C01G023/047
    • C01G23/07C22B34/1222C22B34/1227C22B34/1231G01N21/33G01N21/3504Y02P10/23
    • An improved process for producing titanium dioxide by reacting a titanium dioxide ore with chlorine to produce a gaseous stream containing titanium tetrachloride, condensing titanium tetrachloride from the gaseous stream containing titanium tetrachloride to produce chlorinator tail gas, vaporizing the condensed titanium tetrachloride, reacting the vaporized titanium tetrachloride with oxygen to produce a gaseous stream containing titanium dioxide particles and chlorine, separating the titanium dioxide particles from the gaseous stream containing titanium dioxide particles and chlorine to produce burner tail gas, analyzing the chlorinator tail gas for residual chlorine to control the step of reacting the titanium dioxide ore with chlorine, analyzing the burner tail gas for oxygen to control the step of reacting the condensed titanium tetrachloride with oxygen. The improvement is to analyze the chlorinator tail gas for residual chlorine (and/or the burner tail gas for oxygen) using an on-line analyzer.
    • 一种通过使二氧化钛矿石与氯反应生成含四氯化钛的气流产生二氧化钛的改进方法,将四氯化钛从含有四氯化钛的气流中冷凝出来,产生氯化氢尾气,蒸发冷凝的四氯化钛,汽化钛 四氯化碳与氧气产生含有二氧化钛颗粒和氯的气流,将二氧化钛颗粒与含有二氧化钛颗粒和氯的气流分离,产生燃烧器尾气,分析氯化剂尾气残留氯以控制反应步骤 二氧化钛矿石与氯,分析燃烧器尾气为氧,以控制使缩合的四氯化钛与氧气反应的步骤。 改进之处是使用在线分析仪来分析残留氯(和/或氧气的燃烧器尾气)的氯化物尾气。