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    • 53. 发明授权
    • Battery active materials and methods for synthesis
    • 电池活性物质和合成方法
    • US07901810B2
    • 2011-03-08
    • US10848452
    • 2004-05-17
    • Jeremy BarkerM. Yazid SaidiJeffrey Swoyer
    • Jeremy BarkerM. Yazid SaidiJeffrey Swoyer
    • H01M4/58H01M4/88H01M4/00
    • C01B25/37H01M4/5825H01M10/0525
    • Active materials for rechargeable batteries have a general formula Aa(MO)bM′cXO4 where A represents an alkali metal or mixture of alkali metals, a is greater than about 0.1 and less than or equal to about 2; MO is an ion containing a transition metal M not in its highest oxidation state, M′ represents a metal, or mixture of metals, and b is greater than 0 and less than or equal to about 1, c is less than 1 wherein a, b and c are selected so as to maintain the electroneutrality of the compound, and X is phosphorus, arsenic, or sulfur, or mixtures thereof. Preferred active materials are alkali metal vanadyl metal phosphates of general formula Aa(VO)bM′cPO4 where a and b are both greater than 0 and c may be zero or greater. New synthetic routes are provided to alkali metal mixed metal phosphates where at least one of the starting materials is a metal-oxo group (MO)3+, where M represents a metal in a +5 oxidation state. Reductive methods are provided for reacting a metal-oxo phosphate with an alkali metal compound in the presence of reducing carbon. The carbothermal reduction step can for example result in the reduction of a +5 metal to a +4 state or lower.
    • 用于可再充电电池的活性材料具有通式Aa(MO)bM'cXO4,其中A表示碱金属或碱金属的混合物,a大于约0.1且小于或等于约2; MO是含有不处于其最高氧化态的过渡金属M的离子,M'表示金属或金属的混合物,b大于0且小于或等于约1,c小于1,其中a, 选择b和c以保持化合物的电中性,X是磷,砷或硫,或其混合物。 优选的活性物质是通式为Aa(VO)bM'cPO4的碱金属氧钒基金属磷酸盐,其中a和b都大于0,c可以为零或更大。 向碱金属混合金属磷酸盐提供新的合成路线,其中至少一种原料是金属 - 氧代基(MO)3+,其中M表示+5氧化态的金属。 提供还原方法,用于在还原性碳存在下使金属 - 氧代磷酸酯与碱金属化合物反应。 碳热还原步骤可以例如将+5金属还原成+4状态或更低。