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    • 54. 发明授权
    • Process for producing amorphous alloy material
    • 生产非晶合金材料的方法
    • US5296059A
    • 1994-03-22
    • US943703
    • 1992-09-11
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • C22C45/00B22F3/00C22C1/00C22C45/08C22F1/00C22F1/04C22F1/06C22F1/18
    • C22F1/186B22F3/006C22C1/00C22F1/00C22F1/04C22F1/06C22F1/18C21D2201/03
    • A process for producing an amorphous alloy material characterized by imparting ductility to an amorphous alloy having a supercooled liquid region by giving a prescribed amount of strain at a prescribed strain rate to the alloy in the glass transition temperature region of the alloy. The amorphous alloy may be in the form of spherical or irregular-shaped powders or thin ribbons or in the form of primary consolidated shapes thereof or an amorphous alloy casting. The amount of strain and strain rate are preferably 50% or greater and 2.times.10.sup.-2 /sec or higher, respectively, and the worked amorphous alloy material is preferably allowed to cool in a furnace or spontaneously. Suitable examples of the amorphous alloy to be employed include Al-TM-Ln, Mg-TM-Ln, Zr-TM-Al and Hf-TM-Al alloys, wherein TM is a transition metal element and Ln is a rare earth metal element. The thus obtained amorphous alloy is greatly improved in the prevention of embrittlement in hot working peculiar to the alloy.
    • 一种非晶态合金材料的制造方法,其特征在于,在合金的玻璃化转变温度区域中,通过以规定的应变速率向合金赋予规定量的应变率,赋予具有过冷液体区域的非晶质合金的延展性。 非晶合金可以是球形或不规则形状的粉末或薄带的形式,或者是其主要固结形状或非晶态合金铸件的形式。 应变量和应变速率分别优选为50%以上且2×10 -2 /秒以上,加工后的非晶态合金材料优选在炉内自发冷却。 所使用的非晶合金的合适实例包括Al-TM-Ln,Mg-TM-Ln,Zr-TM-Al和Hf-TM-Al合金,其中TM是过渡金属元素,Ln是稀土金属元素 。 由此获得的非晶态合金在防止合金特有的热加工中脆化方面大大提高。
    • 56. 发明授权
    • Method for superplastic forming of rapidly solidified magnesium base
metal alloys
    • 快速凝固的镁基金属合金的超塑性成形方法
    • US5078806A
    • 1992-01-07
    • US481402
    • 1990-02-20
    • Santosh K. DasChin-Fong ChangDerek Raybould
    • Santosh K. DasChin-Fong ChangDerek Raybould
    • B21C23/00B21J5/00B22F3/00C22C1/04C22C23/02C22F1/06
    • C22F1/06B22F3/006C22C1/0408C22C23/02Y10S420/902
    • A complex part composed of rapidly solidified magnesium base metal alloy is produced by superplastic forming at a temperature ranging from 160.degree. C. to 275.degree. C. and at a rate ranging from 0.00021 m/sec to 0.00001 mm/sec, to improve the formability thereof and allow forming to be conducted at lower temperature. The rapidly solidified magnesium based alloy has a composition consisting essentially of the formula Mg.sub.bal Al.sub.a Zn.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of manganese, cerium, neodymium, praseodymium and yttrium, "a" ranges from 0 to about 15 atom percent, "b" ranges from 0 to about 4 atom percent and "c" ranges from about 0.2 to 3 atom percent, the balance being magnesium and incidental impurities, with the proviso that the sum of aluminum and zinc present ranges from about 2 to 15 atom percent. Such an alloy contains fine grain size and finely dispersed magnesium-, aluminum- rare earth intermetallic phases. When formed, the part exhibits good corrosion resistance together with high ultimate tensile strength and good ductility at room temperature, which properties are, in combination, far superior to those of conventional magnesium alloys. The part is suitable for application as a structural member in helicopters, missiles and air frames where good corrosion resistance in combination with high strength and ductility is important.
    • 由快速凝固的镁基金属合金构成的复合部分通过在160℃至275℃的温度和0.00021m / sec至0.00001mm / sec的范围内的超塑性成型制备,以提高成形性 并且允许成形在较低温度下进行。 快速凝固的镁基合金具有基本由式MgbalAlaZnbXc组成的组合物,其中X是选自锰,铈,钕,镨和钇中的至少一种元素,“a”为0至约15原子% ,“b”为0至约4原子百分数,“c”为约0.2至3原子%,余量为镁和附带杂质,条件是存在的铝和锌的总和范围为约2至15 原子百分比。 这种合金含有细晶粒度和细分散的镁,铝 - 稀土金属间相。 当形成时,该部件在室温下表现出良好的耐腐蚀性以及高极限拉伸强度和良好的延展性,其组合远远优于传统的镁合金。 该部件适用于作为直升机,导弹和空气框架中的结构构件,其具有良好的耐腐蚀性以及高强度和延展性的重要性。