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    • 67. 发明专利
    • PREPARATION OF ZEOLITE 4A FROM TAILINGS AND METHOD FOR TREATMENT OF PB-CONTAINING WASTEWATER
    • AU2020102183A4
    • 2020-10-15
    • AU2020102183
    • 2020-09-09
    • UNIV BEIJING SCIENCE & TECHNOLOGY
    • LI SUQINCAO DANDANXIONG GUOHONG
    • C01B39/14B01J39/02B01J39/14C02F1/42
    • The invention belongs to the field of high value utilization of secondary resources, in particular to a method for preparing zeolite 4A from tailings and its application. The synthetic steps of zeolite 4A are as follows: high temperature alkali melting of sodium carbonate, aging with water, heating crystallization, washing and drying. When tailings are used as raw materials, Al (OH) 3 should be added before alkali melting at high temperature to form zeolite in the process of alkali melting to synthesize NaAlSiO4. The results showed that the optimum pH range was 4-8, the treatment time was within 10s, the treatment effect reached the national discharge standard, and the adsorption capacity was 150mg / G-200 mg/g. The zeolite can be reused after treatment. The overall recovery rate is more than 90%, in which the recovery rate of the first time is more than 92% and the second time is more than 93%. The beneficial effect of the invention is to use high silicon tailings to synthesize zeolite, which realizes high value utilization of tailings secondary resources. Comprehensive utilization of tailings not only solves environmental problems but also creates huge economic benefits from preparation of zeolite 4A. -1/5 Goldflotation gs Lead containing wastewater Ranlminlgrmding A1(OH)3,Na2CO3 Ion enge reacin High-temperature alkalimeltinn filter Essence I wastewater Water aging molecular siev Heating and crystallization Waing|and Molecularsieveaanasyhi dryingfilter zPeolite 4A molecular Filtering wastewaterNa Dry : Pb pre cipitat on reacti on Rccemolecular sieve and Filter and recover Pb S r1 eusye t recover bS Fig. 1
    • 69. 发明专利
    • A Method for Preparing Nano α -Fe2O3 from Solid Waste Containing Iron under Solvent-free
    • AU2020101474A4
    • 2020-08-27
    • AU2020101474
    • 2020-07-24
    • UNIV BEIJING SCIENCE & TECHNOLOGY
    • LI SUQINLUO SHAOJUNWANG LIHUA
    • C01G49/06B22F9/04B22F9/16B82Y40/00
    • Abstract The invention provides a method for preparing nano c-Fe203 from solid waste containing iron under solvent free condition, belonging to technical fields of high value utilization of secondary resources and preparation of nano materials. The method comprises the following steps of: mixing and grinding an iron source and anhydrous sodium carbonate, placing the iron source and anhydrous sodium carbonate into a stainless steel reaction kettle, raising the temperature to 100-200°C, crystallizing for 36-72 hours, and rapidly cooling, washing and drying a filter cake after crystallization to obtain nano a-Fe203. Among them, the iron source used is iron salt soluble in water or solid waste containing more than 95% iron. The method uses a solvent-free method, has no secondary pollution in the preparation process, and is green and environment-friendly. The invention applies a solvent-free method to a process for synthesizing nano c-Fe203 by taking solid waste containing iron as raw materials for the first time. In the invention, iron-containing solid waste is used as a raw material to synthesize nano c-Fe203 by a solvent-free method, and the process is simple, the added value of the product is high, and the application range is wide. The technology can not only alleviate the resource and environmental problems caused by solid waste, but also prepare high value-added products with both economic and ecological benefits. Drawings of Descriptions a-Fe20 20 30 40 50 60 70 20(degree) Figure 1 5,OkV 9 3mrm x100k SE(M) 500nmn Figure 2