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61. 发明授权

US5434031A Positive-working naphthoquinone diazide photoresist composition containing specific hydroxy compound additive 失效
标题翻译：含有特定羟基化合物添加剂的正性萘醌二叠氮光致抗蚀剂组合物
公开(公告)号：US5434031A
公开(公告)日：1995-07-18
申请号：US153100
申请日：1993-11-17
申请人： Taku Nakao , Remi Numata , Kousuke Doi , Nobuo Tokutake , Hidekatsu Kohara , Toshimasa Nakayama
发明人： Taku Nakao , Remi Numata , Kousuke Doi , Nobuo Tokutake , Hidekatsu Kohara , Toshimasa Nakayama
IPC分类号： G03C1/61 , G03F7/022 , G03F7/023
CPC分类号： G03F7/0226 , G03C1/61
摘要： Disclosed is a positive-working photoresist composition suitable for use in the photolithographic fine patterning work in the manufacture of electronic devices such as VLSIs. The composition comprises, in addition to an alkali-soluble novolac resin as a film-forming ingredient and an esterification product of naphthoquinone-1,2-diazide sulfonic acid as a photosensitive ingredient, a unique additive compound which is an alkyl or aralkyl ester of 2-hydroxy benzoic acid, such as benzyl salicylate, or a phenol compound substituted at least one alkyl group such as 2-tert-butyl-4-methyl phenol. By virtue of the addition of this unique additive, the inventive photoresist composition exhibits an excellent performance of suppressing the standing wave effect in addition to the excellent photosensitivity, resolving power and depth of focusing in the patterning exposure to light as well as good heat resistance of the patterned resist layer.
摘要翻译：公开了一种适用于制造诸如VLSI的电子设备的光刻精细图案化工作中的正性光致抗蚀剂组合物。除了作为成膜成分的碱溶性酚醛清漆树脂和萘醌-1,2-二叠氮磺酸作为感光成分的酯化产物之外，组合物还包含作为感光成分的独特的添加剂化合物，其为烷基或芳烷基酯 2-羟基苯甲酸，如水杨酸苄酯，或取代至少一个烷基的酚化合物如2-叔丁基-4-甲基苯酚。通过添加这种独特的添加剂，本发明的光致抗蚀剂组合物除了在图案曝光中具有优异的光敏性，分辨能力和聚焦深度以及良好的耐热性外，还表现出优异的抑制驻波效应的性能图案化的抗蚀剂层。

62. 发明授权

US4824759A Method for forming an image 失效
标题翻译：图像形成方法
公开(公告)号：US4824759A
公开(公告)日：1989-04-25
申请号：US827139
申请日：1986-02-07
申请人： Kozo Sato , Hiroshi Kitaguchi , Masashi Takeuchi , Masaaki Tsukase , Masatoshi Kato
发明人： Kozo Sato , Hiroshi Kitaguchi , Masashi Takeuchi , Masaaki Tsukase , Masatoshi Kato
IPC分类号： G03C7/00 , G03C1/498 , G03C1/61 , G03C8/40 , G03C1/06 , G03C
CPC分类号： G03C1/49845 , G03C1/61 , Y10S430/156 , Y10S430/158 , Y10S430/161
摘要： A method for forming an image, which comprises heating a light-sensitive material in the presence of a compound capable of forming a 2-mercaptobenzazole ring by a ring closing reaction when heated.In accordance with the method of the present invention, development is stopped at an appropriate time of development whereby an image having a high maximum density and low fog is obtained.A heat-developable light-sensitive material containing the compound is also disclosed.
摘要翻译：一种形成图像的方法，其包括在加热时通过闭环反应在能够形成2-巯基吲唑环的化合物的存在下加热感光材料。根据本发明的方法，在合适的显影时间停止显影，从而获得具有高的最大浓度和低雾度的图像。还公开了含有该化合物的可热显影的感光材料。

63. 发明授权

US4584256A Diazotype materials which can be developed by heat and contain an activator precursor having 2-carboxy carboxamide group releasing a strong base during heating 失效
标题翻译：可以通过加热显影并含有具有2-羧基羧酰胺基团的活化剂前体在加热过程中释放强碱的二嗪型材料
公开(公告)号：US4584256A
公开(公告)日：1986-04-22
申请号：US674347
申请日：1984-11-21
申请人： Claude Ceintrey , Michel Crochemore
发明人： Claude Ceintrey , Michel Crochemore
IPC分类号： G03C20060101 , G03C1/52 , G03C1/61 , G03C7/14 , G03C1/60
CPC分类号： G03C1/615 , G03C1/61
摘要： The invention relates to new diazotype materials of which the sensitive layer contains, as a base generator, a compound comprising a basic part and an acid part, the acid part being a 2-carboxycarboxamide group and the basic part consisting of an alkali metal cation or alkaline earth metal cation or a tetraalkylammonium cation.These diazotype materials develop rapidly and possess an excellent resistance to ageing.
摘要翻译： PCT No.PCT / FR81 / 00151 Sec。 371日期1982年7月30日 102（e）1982年7月30日PCT PCT 1991年11月19日PCT公布。出版物WO82 / 01944 日本1982年6月10日。本发明涉及新的二氮类材料，其敏感层含有作为碱产生剂的包含碱性部分和酸性部分的化合物，酸部分为2-羧基羧酰胺基团和碱性部分由碱金属阳离子或碱土金属阳离子或四烷基铵阳离子组成。这些二嗪类材料发展迅速，具有优异的耐老化性。

64. 发明授权

US4487826A Diazotype heat development recording medium with hydrophobic salt of alkyl substituted guanidine 失效
标题翻译：具有烷基取代胍的疏水盐的二亚型热显影记录介质
公开(公告)号：US4487826A
公开(公告)日：1984-12-11
申请号：US458717
申请日：1983-01-17
申请人： Niro Watanabe , Shiro Nemoto , Hiroyuki Yasujima , Kaneki Yoshida
发明人： Niro Watanabe , Shiro Nemoto , Hiroyuki Yasujima , Kaneki Yoshida
IPC分类号： G03C1/52 , B41M5/323 , G03C1/61 , G03C1/60
CPC分类号： G03C1/61
摘要： A diazotype heat development recording medium of the present invention has excellent shelf life and heat sensitivity. The medium comprises a support and a recording layer which is formed on said support and which comprises a diazo compound, a coupler, an acid stabilizer, a thermal developer, and a polymeric binder. The thermal developer is a salt of an organic or inorganic acid having a primary dissociation constant of 2.times.10.sup.-1 to 1.times.10.sup.-4 and an alkyl-substituted guanidine represented by the general formula: ##STR1## (wherein at least one of R1 and R2 is an alkyl group of C.sub.8 to C.sub.24, and the other of R1 and R2 is a hydrogen atom or an alkyl group of C.sub.1 or more).
摘要翻译：本发明的重氮型显影记录介质具有优异的保质期和热敏感性。介质包括载体和记录层，其形成在所述载体上并且包含重氮化合物，偶合剂，酸稳定剂，热显影剂和聚合物粘合剂。热显影剂是主要解离常数为2×10 -1至1×10 -4的有机或无机酸的盐和由以下通式表示的烷基取代的胍：其中R 1和R 2中的至少一个为 C8〜C24的烷基，R1和R2中的另一个为氢原子或C1以上的烷基。

65. 发明授权

US4307170A Negative-working diazo type photoreproduction having improved pH control 失效
标题翻译：具有改进的pH控制的负性重氮型光复制
公开(公告)号：US4307170A
公开(公告)日：1981-12-22
申请号：US160649
申请日：1980-06-18
申请人： Robert C. Desjarlais
发明人： Robert C. Desjarlais
IPC分类号： G03C1/58 , G03C1/61 , G03C1/52
CPC分类号： G03C1/585 , G03C1/61
摘要： Negative-working diazography formulation is comprised of (i) at least one hexafluorophosphate diazonium salt adapted to photolytically cleave into an acid catalyst, (ii) at least one acid labile enolic, preferably arylenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) an effective amount of an additive, such as p-toluenesulfonyl benzamide, capable of controlling the pH of films prepared from said formulation when subjected to a clearing step as defined herein.
摘要翻译：负性重氮基成分制剂包括（i）至少一种适于光解裂解成酸催化剂的六氟磷酸盐重氮盐，（ii）适于在酸存在下转化的至少一种酸不稳定烯醇，优选亚烷基酯封端的偶联剂活性偶氮偶联组分，和（iii）有效量的添加剂，例如对甲苯磺酰基苯甲酰胺，当进行如本文所定义的清除步骤时，能够控制由所述制剂制备的膜的pH。

66. 发明授权

US4230789A Thermal diazotype sheets 失效
标题翻译：热重氮型片
公开(公告)号：US4230789A
公开(公告)日：1980-10-28
申请号：US885877
申请日：1978-03-13
申请人： Herbert J. Fish
发明人： Herbert J. Fish
IPC分类号： G03C1/61 , G03C1/60
CPC分类号： G03C1/61
摘要： Thermal diazotype sheets having substituted imidazoline acid-neutralizers are shown to have shelf stability and short development times.
摘要翻译：具有取代的咪唑啉酸中和剂的热重氮化合物片材显示出具有稳定性和开发时间短的特征。

67. 发明授权

US3904414A Precoated diazotype photocopying materials 失效
标题翻译：预涂重氮复印材料
公开(公告)号：US3904414A
公开(公告)日：1975-09-09
申请号：US37739473
申请日：1973-07-09
申请人： GAF CORP
发明人： WELCH WALTER J
IPC分类号： G03C1/61 , G03C1/60 , G03C1/54
CPC分类号： G03C1/61
摘要： Light-sensitive diazotype photocopying materials comprising a base such as paper having thereon a precoat containing-in addition to a conventionally employed pigment and a binder-an inorganic water soluble salt of zinc, magnesium, aluminum or cadmium, and a two-component light-sensitive diazotype composition applied as coating to the precoat surface.
摘要翻译：感光性重氮型复印材料，其包含基材例如纸，其上含有常规使用的颜料的预涂层和粘合剂 - 锌，镁，铝或镉的无机水溶性盐，以及双组分发光层，敏感的二叠氮化合物组合物作为涂层涂覆到预涂层表面。

68. 发明授权

US3748137A Photosensitive and thermosensitive elements and process for development 失效
标题翻译：敏感性和敏感性元素和开发过程
公开(公告)号：US3748137A
公开(公告)日：1973-07-24
申请号：US3748137D
申请日：1970-12-10
申请人： EASTMAN KODAK CO
发明人： GLOVER C , WORTH J , MILLER H
IPC分类号： G03C1/49 , G03C1/498 , G03C1/61 , G03C1/775 , G03C5/26 , G03G5/10 , G03C1/94
CPC分类号： G03G5/102 , G03C1/49 , G03C1/498 , G03C1/61 , G03C1/775 , G03C5/261 , G03C5/262
摘要： Thermosensitive and photosensitive elements, and a process for the development thereof, are provided which comprise a support, an electrolessly deposited layer of a conductive metal, and a photosensitive layer. Suitable electrolessly deposited layers include nickel, cobalt, and nickel-cobalt alloy. Suitable photosensitive materials include any heat developable or heatstabilizable materials. Of particular interest are photosensitive elements comprising an electrolessly deposited metal in contact with a diazo composition, a heat developable oxidation-reduction image-forming composition, or a stabilizable print-out emulsion as set forth in Bacon et al., U.S. Pat. No. 3,447,927. Such elements may be developed or stabilized by the application of an electric current to the electrolessly deposited conductive metal, to produce heat.
摘要翻译：提供了热敏感和感光元件及其开发方法，其包括载体，导电金属的无电沉积层和感光层。合适的无电沉积层包括镍，钴和镍 - 钴合金。合适的感光材料包括任何可热显影或热稳定材料。特别令人感兴趣的是包含与重氮组合物接触的无电沉积金属，可显影氧化还原成像组合物或稳定印刷乳状液的光敏元件，如Bacon等人，第3,447,927号。可以通过向无化学沉积的导电金属施加电流来产生热量来开发或稳定这些元件。

69. 发明授权

US3679415A Diazotype photographic elements having extended exposure latitude with specific u-v absorber 失效
标题翻译：具有特定U-V吸收体的延长曝光度的DIAZOTYPE摄影元件
公开(公告)号：US3679415A
公开(公告)日：1972-07-25
申请号：US3679415D
申请日：1969-07-18
申请人： EASTMAN KODAK CO
发明人： MCNALLY JAMES G JR
IPC分类号： C09K3/00 , G03C1/61 , G03C1/815 , G03C1/60 , G03C1/52 , G03C1/58
CPC分类号： G03C1/8155 , G03C1/61
摘要： DIAZOTYPE PHOTOGRAPHIC ELEMENTS HAVING STRATIFIED LIGHT-SENSITIVE LAYERS INCLUDING A DIAZONIUM SALT AND A COUPLER COMPOUND WHICH CAN REACT WITH THE DIAZONIUM SALT TO PRODUCE AN AZO DYE ARE ABLE TO REPRODUCE HIGHLIGHT AND SHADOW DETAILS OF CONTINUOUS TONE IMAGES UNDER WIDELY VARYING EXPOSURE CONDITIONS AND WITHOUT BACKGROUND STAIN BY THE INCLUSION THEREIN OF AN ALKALINEBLEACHABLE ULTRAVIOLET ABSORBER LAYER WHICH IS POSITIONED SUCH THAT IT INTERCEPTS ACTIVATING EXPOSING RADIATION NOT LATER THAN ITS PASSAGE THROUGH THE TERMINALLY IRRADIATED LIGHT-SENSITIVE LAYER. ADVANTAGEOUS ULTRAVIOLET ABSORBER MATERIALS INCLUDE SUBSTITUTED PYRYLIUM SALTS AND SUBSTITUTED THIAPYRYLIUM SALTS SUCH AS 2,4,6-TRIPHENYLTHISPYRYLIUM FLUOROBORATE. ADDITIONALLY, DUPLICATING CHARACTERISTICS INCLUDING THE PRINT SPEED AND IMAGE QUALITY OF SUBSEQUENT GENERATION COPIES ARE IMPROVED.

70. 发明授权

US3623875A Background coloration inhibition in diazosulfonate photoreproduction 失效
标题翻译：背景色素抑制在双歧杆菌中的影响
公开(公告)号：US3623875A
公开(公告)日：1971-11-30
申请号：US3623875D
申请日：1969-11-28
申请人： PLASTIC COATING CORP
发明人： DESJARLAIS ROBERT CHARLES
IPC分类号： G03C1/61 , G03C1/56 , G03C1/60
CPC分类号： G03C1/61
摘要： INCLUSION OF A NEUTRAL SALT OF AN AROMATIC SULFINIC ACID IN A REVERSAL DIAZOSULFONATE PHOTOSENSITIVE COMPOSITION PREVENTS BACKGROUND COLORATION.

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