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    • 66. 发明授权
    • Process for the production of 2-chlorobutadiene-1,3 from
3,4-dichlorobutene-1
    • 从3,4-二氯丁烯-1生产2-氯丁二烯-1,3的方法
    • US3965203A
    • 1976-06-22
    • US437906
    • 1974-01-31
    • Lawrence A. Smith, Jr.
    • Lawrence A. Smith, Jr.
    • C07C17/00C07C17/25C07C21/21C07C67/00C07C21/20
    • C07C17/25
    • A process is described whereby 2-chlorobutadiene-1,3 is produced from 3,4-dichlorobutene-1 in a two-phase reaction system wherein the reaction predominantly occurs in the organic phase and the production of undesirable by-products, particularly 1-chlorobutadiene-1,3 and acetaldehyde, is suppressed. The practice of the process results in a brine effluent from the reactor containing small amounts of organic materials resulting in a waste product which is less polluting and more easily cleaned.The organic phase is selected from primary and secondary alcohols, alkoxyethanols and mixtures thereof, preferably alkoxyethanols wherein the alkyl group has two or more carbon atoms. Surprisingly, I have discovered that the selection of the organic phase of the reaction system is made by a screening test wherein a two-phase system of a 20% brine and 3,4-dichlorobutene-1 is prepared and the alcohol or alkoxyethanol being investigated is added to obtain equilibrium in the system. Materials selected as the organic phase material are selected from those where the product of the weight percent water in the organic phase and weight percent alcohol being investigated in the organic phase is greater than 200.
    • 描述了一种方法,其中在二相反应体系中由3,4-二氯丁烯-1产生2-氯丁二烯-1,其中反应主要发生在有机相中,并产生不期望的副产物,特别是1- 氯代丁二烯-1,3和乙醛被抑制。 该方法的实践导致来自反应器的盐水流出物含有少量有机材料,导致污染物较少并且更容易清洁的废物。