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    • 63. 发明授权
    • Reduced polydextrose
    • 减少的聚葡萄糖
    • US5601863A
    • 1997-02-11
    • US313940
    • 1994-09-28
    • G. Wayne BordenRaymond C. GlowakyRussell J. HausmanConstantine SklavounosHarry O. Tobiassen
    • G. Wayne BordenRaymond C. GlowakyRussell J. HausmanConstantine SklavounosHarry O. Tobiassen
    • C08B37/00A23L1/236A23L1/29A23L1/308B01J31/04C07B61/00C08L20060101A23L1/00C07H1/00
    • C08B37/0009A23L27/32A23L33/26
    • A polydextrose having improved color, flavor and decreased reactivity toward food ingredients having amine functionality. The polydextrose comprises a water-soluble highly branched polydextrose having been prepared by a process which comprises melting dextrose in the presence of a food-acceptable acid catalyst. The improved polydextrose of this invention has substantially no reducing glucose groups. Another aspect of this invention is directed to a method of making the above-described improved polydextrose which comprises exposing unimproved polydextrose to an environment capable of chemically transforming the reducing glucose groups contained in the unimproved polydextrose, thereby substantially eliminating their reducing properties. An improved polymaltose prepared by heating maltose in the presence of a food-acceptable acid catalyst and chemically transforming the reducing glucose groups contained in the polymaltose, thereby eliminating their reducing properties, is also described.
    • 具有改善的颜色,风味和对具有胺官能团的食品成分的反应性降低的聚葡萄糖。 聚右旋糖包含通过包括在食品可接受的酸催化剂存在下熔融葡萄糖的方法制备的水溶性高度支化的聚右旋糖。 本发明的改进的聚右旋糖基本上没有还原葡萄糖基团。 本发明的另一方面涉及制备上述改进的聚右旋糖的方法,其包括将未改良的聚右旋糖暴露于能够化学转化未改良的聚右旋糖中所含的还原葡萄糖基团的环境,从而基本上消除其还原性能。 还描述了通过在食物可接受的酸催化剂的存在下加热麦芽糖并化学转化聚麦芽糖中包含的还原葡萄糖基,从而消除它们的还原性质而制备的改进的聚麦芽糖。
    • 68. 发明授权
    • Compositions of ethylene polymers, and method for the preparation thereof
    • 乙烯聚合物的组合物及其制备方法
    • US4861834A
    • 1989-08-29
    • US97587
    • 1987-10-06
    • Joel AudureauEdouard Piecuch
    • Joel AudureauEdouard Piecuch
    • C08F20060101C08F8/50C08J3/24C08J5/18C08L20060101C08L23/04C08L23/26
    • C08L23/0815C08F8/50C08L23/10C08F2800/10C08F2810/10C08L23/20
    • The compositions contain:(a) from 90 to 99.8% by weight of at least one modified polymer of ethylene and, where appropriate, at least one .alpha.-olefin having from 3 to 12 carbon atoms, the said polymer containing at least 80 mol % of units derived from ethylene, and(b) from 0.2 to 10% by weight of at least one polymer phase (B) comprising at least one polymer containing at least 90 mol % of units derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms, and at most 10 mol % of units derived from ethylene,the said compositions having a measured limiting viscosity of between 1.5 and 100 times their limiting viscosity calculated from the distribution of the molecular masses.The process for preparing them consists in modifying a polymer (A) containing at least 80 mol % of units derived from ethylene and at most 20 mol % of units derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms, by means of at least one free-radical initiator brought into contact with the said polymer (A) at a temperature above the melting point of the said polymer (A) for a time longer than or equal to one tenth of the half-life of the said initiator at the temperature in question, and is characterized in that the free-radical initiator, prior to being brought into contact with the polymer (A), is dispersed in at least one polymer phase (B) present in an amount such that its proportion in the resulting composition is between 0.2 and 10% by weight.
    • PCT No.PCT / FR86 / 00438 Sec。 371日期1987年10月6日第 102(e)日期1987年10月6日PCT 1986年12月19日PCT PCT。 出版物WO87 / 03888 日期1987年7月2日。该组合物包含:(a)90-99.8%(重量)的至少一种乙烯改性聚合物和适当的至少一种具有3至12个碳原子的α-烯烃,所述 含有至少80摩尔%的衍生自乙烯的单元的聚合物,和(b)0.2至10重量%的至少一种聚合物相(B),其包含至少一种含至少90摩尔%的至少衍生的单元的聚合物 一种具有3至12个碳原子的α-烯烃和至多10摩尔%的衍生自乙烯的单元,所述组合物的测量的特性粘度为其分子量分布计算的其特性粘度的1.5至100倍。 制备它们的方法在于改变含有至少80mol%衍生自乙烯的单元和至多20mol%衍生自至少一个具有3至12个碳原子的α-烯烃的单元的聚合物(A) 的至少一种自由基引发剂在高于所述聚合物(A)的熔点的温度下与所述聚合物(A)接触的时间长于或等于所述聚合物(A)的半衰期的十分之一的时间 引发剂,其特征在于,在与聚合物(A)接触之前,自由基引发剂分散在至少一个存在的聚合物相(B)中,其量使得其比例 所得组合物的重量百分比为0.2-10%。