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    • 72. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 使用金属复合化合物作为氧化催化剂
    • WO2004039932A1
    • 2004-05-13
    • PCT/GB2003/004625
    • 2003-10-28
    • RECKITT BENCKISER N.V.RECKITT BENCKISER (UK) LIMITEDWIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • WIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • C11D3/39
    • C11D3/3932C11D3/168
    • An automatic dishwasher detergent formulation comprising: - (a) a metal complex compounds of formula (1) [ L n Me m ,X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a co-ordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z / (charge Y), and L is a ligand of formula (2); wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 1O and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -N(R 13 ) -NR' 13 R ' ' 13 wherein R 13 , R ' 13 and R ' ' 13 are as defined above for R 13 ; -NR 14 NR 15 or - N ⊕ R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them from an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are not simultaneously hydrogen, as a catalyst for oxidation reactions; and (b) an enzyme.
    • 一种自动洗碗机洗涤剂配方,其包含:(a)式(1)的金属络合物[LnMem,Xp] zq其中Me是锰,钛,铁,钴,镍或铜,X是配位的 或桥接基团,n和m各自独立地为具有1至8的整数的整数,p为0至32的整数,z为金属络合物的电荷,Y为计数器 - ,q = z /(电荷Y),L是式(2)的配体; 其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R1O和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; SR13,-SO2R13或-OR13,其中R13各自为氢或未取代或取代的C1-C18烷基或芳基; -N(R 13)-NR 13 R 13,其中R 13,R'13和R“13如上文对R 13所定义; -NR14NR15或-N4R15R16,其中R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或者R14和R15与氮原子一起与未取代或未取代的 取代的5-,6-或7-元环,其可以任选地含有另外的杂原子; 条件是作为氧化反应的催化剂,R1,R2,R3,R4,R5,R6,R7,R8,R9,R10和R11不同时为氢; 和(b)酶。
    • 75. 发明申请
    • WATER SOLUBLE SACHET CONTAINING HARD SURFACE CLEANER
    • 含硬表面清洁剂的水溶性溶剂
    • WO2004020560A2
    • 2004-03-11
    • PCT/GB2003/003707
    • 2003-08-26
    • RECKII BENCKISER, INC.RECKITT BENCKISER (UK) LIMITEDBURT, Diane, JoyceCHRISTMAS, DelfordFENG, James, Chi-ChengFRANCHI, LuciaGENCARELLI, Ralph
    • BURT, Diane, JoyceCHRISTMAS, DelfordFENG, James, Chi-ChengFRANCHI, LuciaGENCARELLI, Ralph
    • C11D1/835
    • C11D17/043C11D1/62C11D1/72C11D1/835C11D3/43
    • The invention relates to a water soluble container which containing concentrate composition useful for hard surface disinfecting and cleaning comprising: (a) at least one cationic surfactant having germicidal properties; (b) at least one non-ionic surfactant; (c) at least one organic solvent having a solubility in water of at least 4%wt.; (d) optionally, at least one alkanolamine; (e) optionally, at least one polyethylene glycol; and (f) optionally, up to about 10% wt. of one or more conventional additives selected from coloring agents, fragrances and fragrance solubilizers, viscosity modifying agents, other surfactants, other antimicrobial/germicidal agents, pH adjusting agents and pH buffers including organic and inorganic salts, optical brighteners, opacifying agents, hydrotropes, antifoaming agents, enzymes, anti-spotting agents, anti-oxidants, preservatives, and anti-corrosion agents; wherein said concentrate composition contains no more than 20%wt. water, and desirably contains less. The water soluble containers can be made by thermoforming or injection molding. Methods for the manufacture of such containers containing the concentrate compositions and methods for the treatment of hard surfaces using the concentrate compositions and especially aqueous dilutions of the concentrate compositions are disclosed.
    • 本发明涉及含有用于硬表面消毒和清洁的浓缩物组合物的水溶性容器,其包含:(a)至少一种具有杀菌性能的阳离子表面活性剂; (b)至少一种非离子表面活性剂; (c)至少一种在水中的溶解度为至少4重量%的有机溶剂; (d)任选地,至少一种链烷醇胺; (e)任选地,至少一种聚乙二醇; 和(f)任选地,至多约10重量%。 一种或多种选自着色剂,香料和香料增溶剂,粘度调节剂,其他表面活性剂,其他抗微生物/杀菌剂,pH调节剂和pH缓冲剂,包括有机和无机盐,荧光增白剂,不透明剂,水溶助长剂,消泡剂 试剂,酶,防斑剂,抗氧化剂,防腐剂和抗腐蚀剂; 其中所述浓缩物组合物含有不超过20重量% 水,并且理想地包含较少。 水溶性容器可以通过热成型或注塑成型来制造。 公开了制造含有浓缩物组合物的这种容器的方法和使用浓缩物组合物特别是浓缩物组合物的含水稀释物处理硬表面的方法。