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81. 发明授权

US4946629A Optical element having non-linear optical properties including a substrate having a coating of an azo compound 失效
标题翻译：具有非线性光学特性的光学元件包括具有偶氮化合物涂层的基底
公开(公告)号：US4946629A
公开(公告)日：1990-08-07
申请号：US274926
申请日：1988-11-25
申请人： Simon Allen , Paul F. Gordon , Richard A. Hann
发明人： Simon Allen , Paul F. Gordon , Richard A. Hann
IPC分类号： C09B29/01 , G02F1/361 , G02F1/377 , G02B1/04 , G02B1/08 , G02B6/00
CPC分类号： G02F1/3612 , C09B29/0007 , G02F1/3611 , G02F1/3614 , G02F1/377 , Y10S430/141 , Y10S430/146 , Y10S534/02
摘要： (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 & R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 & R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;and R.sup.6 & R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms;or R.sup.4 & R.sup.6 together comprise ring fused to Ring A and R.sup.5 & R.sup.7 are as hereinbefore defined;or R.sup.5 & R.sup.7 together comprise ring fused to Ring A and R.sup.4 & R.sup.6 are as hereinbefore defined;or R.sup.2 & R.sup.4 together with the N atom to which R.sup.2 is attached from a ring fused to Ring A and R.sup.3 & R.sup.5 are as hereinbefore defined;or R.sup.3 & R.sup.5 together with the N atom to which R.sup.3 is attached form a ring fused to Ring A and R.sup.2 & R.sup.4 are as hereinbefore defined;provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by R.sup.2, R.sup.3, R.sup.4 & R.sup.5 ;(ii) an optical element comprising a compound of Formula I having non-linear optical (NLO) properties for use in the generation of NLO signals.(iii) a method of preparation of such an optical element comprising a plurality of monomolecular layers of the compound of Formula I on the surface of a transparent or reflecting substrate by a Langmuir-Blodgett technique; and(iv) an optical device incorporating such an optical element.

82. 发明授权

US4602084A Monoazo dyes containing a 4-substituted-2-azo-1,1'-diphenylsulfone component 失效
标题翻译：含有4-取代-2-偶氮-1,1'-二苯砜组分的单偶氮染料
公开(公告)号：US4602084A
公开(公告)日：1986-07-22
申请号：US512089
申请日：1983-07-08
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C313/00 , C07C315/00 , C07C315/04 , C07C317/36 , C07C317/40 , C07C317/48 , C07D209/40 , C07D213/77 , C07D215/38 , C07D231/38 , C07D231/46 , C07D235/02 , C07D239/50 , C07D487/04 , C09B29/01 , C09B29/06 , C09B29/08 , C09B29/15 , C09B29/32 , C09B29/36 , C09B62/028 , C09B62/473 , C09B29/033 , C09B29/036 , C09B62/006
CPC分类号： C07D213/77 , C07D209/40 , C07D215/38 , C07D231/38 , C07D231/46 , C07D235/02 , C07D239/50 , C07D487/04 , C09B29/0007 , C09B29/065 , C09B29/10 , C09B29/322 , C09B29/36 , C09B62/028 , C09B62/473
摘要： Monoazo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series, and R is a ##STR2## --CO--R.sub.2 or --SO.sub.2 --O--R.sub.2 group in which R.sub.1 is hydrogen or C.sub.1-4 -alkyl and R.sub.2 is a substituted or unsubstituted monosulfo-C.sub.1-12 -alkyl radical, a substituted or unsubstituted monosulfophenyl, disulfophenyl, monosulfonaphthyl or disulfonaphthyl radical, and X and Y, independently of each other, are hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, halogen, C.sub.2-6 -alkanoylamino, C.sub.1-5 -alkylsulfonylamino or a substituted or unsubstituted phenyl or phenoxy radical, produce dyeings on polyamide material which have good light and wet fastness properties.
摘要翻译：式（1）的单偶氮染料其中K是苯或萘系列或杂环系列的偶联组分的基团，R是-CO-R 2或-SO 2 -O- R 2基团，其中R 1是氢或C 1-4 - 烷基，R 2是取代或未取代的单磺酰基-C 1-12 - 烷基，取代或未取代的单磺酰基苯基，二磺基苯基，单磺酰基萘基或二磺基萘基，X和Y各自独立地另一个是氢，C 1-4 - 烷基，C 1-4 - 烷氧基，卤素，C 2-6 - 烷酰基氨基，C 1-5 - 烷基磺酰基氨基或取代或未取代的苯基或苯氧基，在具有良好光线的聚酰胺材料上产生染色，湿牢度特性。

83. 发明授权

US4594411A Sulfonated monoazo colorant lake obtained by di-azo coupling of 5-acetylamino-2-aminobenzene-1-sulfonic acid with 1-(3'-sulfophenyl)-3-methylphyrazol-5-one 失效
标题翻译：通过5-乙酰氨基-2-氨基苯-1-磺酸与1-（3'-磺基苯基）-3-甲基吡唑-5-酮的偶氮偶合获得的磺化单偶氮染料色淀
公开(公告)号：US4594411A
公开(公告)日：1986-06-10
申请号：US617155
申请日：1984-06-06
申请人： Georg Henning
发明人： Georg Henning
IPC分类号： C09B29/01 , C09B29/50 , C09B63/00 , C09B29/03 , C09B29/10 , C09B29/36 , D06P1/39
CPC分类号： C09B29/366 , C09B29/0007 , C09B63/00 , Y10S534/01 , Y10S534/04
摘要： This invention relates to a method of dyeing thermoplastics with sulfonated monoazo colorant lakes having a sulfophenyl pyrazole substituent, of general formula ##STR1## wherein R is CH.sub.3 or COO.sup.- ; X is Cl, CH.sub.3, CH.sub.3 O, C.sub.2 H.sub.5 O, C.sub.2 H.sub.5 CONH, NH.sub.2 CONH, C.sub.6 H.sub.5 CONH, CH.sub.3 SO.sub.2 NH, C.sub.6 H.sub.5 SO.sub.2 NH, CH.sub.3 CONH, or hydrogen; Y is hydrogen, Cl, or CH.sub.3 ; Z is hydrogen or Cl, n is 0, 1 or 2; and Me.sup.+ is one equivalent of a cation selected from the group consisting of NH.sub.4.sup.+, Li.sup.+, K.sup.+, Na.sup.+, 1/2Sr.sup.2+, 1/2Mn.sup.2+, 1/2Ni.sup.2+, 1/2Ba.sup.2+, 1/2Mg.sup.2+ and 1/2Ca.sup.2+ ; with the proviso that if R is COO.sup.-, the additional equivalent charge is compensated by a further equivalent of said or another cation. These compounds, which are insoluble in organic solvents and sparingly soluble in water, are useful as lakes with good pigmentary characteristics and possessing very good lightfastness in plastics, such as polyolefins, polyvinyl chloride, polystyrene, and ABS. They are also useful in surface coatings, and particularly suitable for coloring thermoplastics. Noteworthy is their good plasticizer fastness, their high stability to heat and the absence of blooming they produce when used.
摘要翻译：本发明涉及一种通过具有通式（I）的磺酰基苯基吡唑取代基的磺化单偶氮染料盐染色热塑性塑料的方法，其中R是CH 3或COO-; X是Cl，CH 3，CH 3 O，C 2 H 5 O，C 2 H 5 CONH，NH 2 CONH，C 6 H 5 CONH，CH 3 SO 2 NH，C 6 H 5 SO 2 NH，CH 3 CONH或氢; Y是氢，Cl或CH 3; Z是氢或Cl，n是0,1或2; 和Me +是选自NH4 +，Li +，K +，Na +，1 / 2Sr2 +，1 / 2Mn2 +，1 / 2Ni2 +，1 / 2Ba2 +，1 / 2Mg2 +和1 / 2Ca2 +的阳离子的1当量。条件是如果R是COO-，则额外的等效电荷由另外的等价的所述阳离子补偿。这些不溶于有机溶剂并微溶于水的化合物可用作具有良好颜料特征的湖泊，并且在塑料如聚烯烃，聚氯乙烯，聚苯乙烯和ABS中具有非常好的耐光性。它们也可用于表面涂层，特别适用于着色热塑性塑料。值得注意的是它们具有良好的增塑剂坚牢度，它们对热的高稳定性和使用时不产生起霜。

84. 发明授权

US4324722A Water-soluble substituted aminocarbonyl monoazo dyestuffs 失效
标题翻译：水溶性取代氨基羰基单偶氮染料
公开(公告)号：US4324722A
公开(公告)日：1982-04-13
申请号：US186375
申请日：1980-09-12
申请人： Dieter vor der Bruck , Gerhard Wolfrum
发明人： Dieter vor der Bruck , Gerhard Wolfrum
IPC分类号： C09B29/085 , C09B29/01 , C09B29/08 , C07C107/06 , C09B29/18
CPC分类号： C09B29/08 , C09B29/0007 , C09B29/0803
摘要： Water-soluble monoazo dyestuffs are described, which, in the form of the free acid, correspond to the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and A have the meaning indicated in the description, and their preparation and suitability for dyeing natural and synthetic fibre materials, in particular for dyeing polyamide fibres.
摘要翻译：描述了以游离酸的形式存在的水溶性单偶氮染料，其对应于下式：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和A具有在本说明书中指出，以及它们对天然和合成纤维材料的染色，特别是染色聚酰胺纤维的制备和适用性。

85. 发明授权

US4276373A Photosensitive photographic material containing a light-absorbing dye 失效
标题翻译：含有吸光染料的感光感光材料
公开(公告)号：US4276373A
公开(公告)日：1981-06-30
申请号：US131808
申请日：1980-03-19
申请人： Hans Ohlschlager , Lothar Rosenhahn , Wolfgang Sauerteig
发明人： Hans Ohlschlager , Lothar Rosenhahn , Wolfgang Sauerteig
IPC分类号： C09B29/01 , C09B29/50 , G03C1/83 , G03C1/84
CPC分类号： G03C1/831 , C09B29/0007 , C09B29/366
摘要： A photosensitive recording material containing at least one silver halide layer and an azo dye is disclosed.
摘要翻译：公开了含有至少一种卤化银层和偶氮染料的光敏记录材料。

86. 发明授权

US4266939A Composition of 4-amino-4'-nitrostilbene-2,2'-disulphonic acid diazo compounds and coloring process 失效
标题翻译： 4-氨基-4'-硝基茋-2,2'-二磺酸重氮化合物的组成和着色过程
公开(公告)号：US4266939A
公开(公告)日：1981-05-12
申请号：US45522
申请日：1979-06-04
申请人： John D. Hildreth , Anton F. Tschopp , David G. Evans
发明人： John D. Hildreth , Anton F. Tschopp , David G. Evans
IPC分类号： C09B29/01 , C09B29/12 , C09B35/215 , C09B43/28 , C09B56/04 , C09B67/22 , C09B27/00 , D06P1/00
CPC分类号： C09B67/0046 , C09B29/0007 , C09B29/12 , C09B35/215 , C09B43/28 , C09B56/04 , Y10S534/01
摘要： The invention provides dyestuffs of the general formula ##STR1## in which R is hydrogen or an alkyl group having 1 to 6 carbon atoms and R' is an alkyl group having 1 to 6 carbon atoms.
摘要翻译：本发明提供了通式“IMAGE”的染料，其中R是氢或具有1至6个碳原子的烷基，R'是具有1至6个碳原子的烷基。

87. 发明授权

US4118186A Process for the fixation of organic dyestuffs on materials having a fibrous structure 失效
标题翻译：有机染料固定在具有纤维结构的材料上的方法
公开(公告)号：US4118186A
公开(公告)日：1978-10-03
申请号：US796039
申请日：1977-05-11
申请人： Erich Feess , Hartmut Springer , Willy Gronen
发明人： Erich Feess , Hartmut Springer , Willy Gronen
IPC分类号： D06M13/02 , C09B1/32 , C09B5/14 , C09B7/02 , C09B19/02 , C09B29/01 , C09B29/15 , C09B29/20 , C09B29/50 , C09B33/153 , C09B35/215 , C09B47/26 , C09B69/00 , D06M13/322 , D06M13/325 , D06M13/335 , D06M13/35 , D06M13/355 , D06M13/402 , D06M13/438 , D06P1/00 , D06P1/14 , D06P3/52 , D06P3/60 , C09B27/00 , C07D249/00 , D06M13/38
CPC分类号： C09B7/02 , C09B1/325 , C09B19/02 , C09B29/0007 , C09B29/0014 , C09B29/103 , C09B29/20 , C09B29/366 , C09B33/153 , C09B35/215 , C09B47/26 , C09B5/14 , C09B69/00 , D06P1/0048 , D06P1/14 , D06P3/527 , D06P3/6091
摘要： A process for the fixation of organic dyestuffs on materials having a fibrous structure had been found, in which an organic dyestuff containing one or several groups of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent a non-ionic, anionic or cationic substituent, with the exception of a primary or secondary amino group or the salts thereof, is applied in dissolved form onto said materials and subsequently subjected to the action of nitrous acid. The process yields fiber materials on which active substances, such as dyestuffs, brighteners, mothproofing agents, water-repellent agents, etc., are fixed fast; the novel process is especially and advantageously suitable in combination with the ice-color technique.
摘要翻译：发现有机染料固定在具有纤维结构的材料上的方法，其中含有一种或几种式（I）的有机染料（I）其中R1，R2，R3和R4各自代表非离子，阴离子或阳离子取代基，除了伯或仲氨基或其盐，以溶解的形式施加到所述材料上，随后经受亚硝酸的作用。该方法产生纤维材料，其上活性物质如染料，增白剂，防虫剂，防水剂等被快速固定; 该新颖方法特别且有利地适用于冰色技术。

88. 发明授权

US4017256A Process for the printing and pad-dyeing of mixed fabric 失效
标题翻译：混纺织物的印染方法
公开(公告)号：US4017256A
公开(公告)日：1977-04-12
申请号：US561514
申请日：1975-03-24
申请人： Gerhard Kogel , Roberto Degen , Walter Mundwiler
发明人： Gerhard Kogel , Roberto Degen , Walter Mundwiler
IPC分类号： C09B29/01 , C09B33/147 , C09B41/00 , C09B67/42 , D06P1/12 , D06P1/60 , D06P1/62 , D06P1/651 , D06P1/653 , D06P3/10 , D06P3/54 , D06P3/66 , D06P3/82 , D06P3/872
CPC分类号： D06P3/10 , C09B29/0007 , C09B33/147 , C09B41/00 , C09B67/0071 , D06P1/12 , D06P1/60 , D06P1/62 , D06P1/65125 , D06P1/653 , D06P3/54 , D06P3/66 , D06P3/8214 , D06P3/8252 , Y10S8/907 , Y10S8/908 , Y10S8/909 , Y10S8/911
摘要： Described is a process for the printing and pad-dyeing of mixed fabric made from fiber mixtures consisting of material consisting of materials dyeable with disperse dyestuffs and materials dyeable with reactive dyestuffs, especially polyesters/cotton, by the use of printing pastes or padding liquors containing at least one disperse dyestuff of the azo series and at least one reactive dyestuff, wherein there is used a printing paste or padding liquor in which the disperse dyestuff is formed in the printing paste or padding liquor. There are obtained by this process printing or dyeings which have some advantages over the prior art. The staining of the cellulose constituent can more easily be washed out and only a slight staining of white ground occurs.
摘要翻译：描述了由纤维混合物制成的混合织物的印刷和染色方法，所述混合织物由可分散染料染色的材料和可用活性染料，特别是聚酯/棉可染色的材料组成，所述材料通过使用印刷浆料或填充液至少一种偶氮系分散染料和至少一种活性染料，其中使用其中在印刷浆料或填充液中形成分散染料的印刷浆料或填充液体。通过该方法可获得与现有技术相比具有一些优点的印刷或染色。纤维素成分的染色可以更容易地被洗掉，并且只发生白底的轻微染色。

89. 发明授权

US4000123A Aminosulfonylphenyl-azo-indolyl dyestuffs 失效
标题翻译：氨基磺酰氟苯偶氮染料
公开(公告)号：US4000123A
公开(公告)日：1976-12-28
申请号：US546416
申请日：1975-02-03
申请人： Richard Sommer , Gerhard Wolfrum , Hans Gunter Otten
发明人： Richard Sommer , Gerhard Wolfrum , Hans Gunter Otten
IPC分类号： C09B29/01 , C09B29/40 , C09B62/53 , C09B29/36 , D06P3/24
CPC分类号： C09B62/53 , C09B29/0007 , C09B29/3613
摘要： Monoazo dyestuffs which in the form of the free acid correspond to the general formula ##STR1## wherein R.sub.0, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 have the meaning given in the description and their use for the dyeing of natural and synthetic fibre materials, especially for dyeing polyamide fibres. Dyeings obtained distinguish themselves by very good fastness to light. Dyestuffs are absorbed well on polyamide fibres already in a neutral to weakly acid dye bath. By polyamide fibres there are here especially understood those from synthetic polyamides such as .EPSILON.-polycaprolactam, or condensation products of adipic acid and hexamethylenediamine.

90. 发明授权

US3892872A Edible colouring materials 失效
标题翻译：食用着色材料
公开(公告)号：US3892872A
公开(公告)日：1975-07-01
申请号：US38774973
申请日：1973-08-13
申请人： BEECHAM GROUP LTD
发明人： BILLINGTON ARTHUR ERNEST
IPC分类号： A23L1/275 , A61K8/46 , A61K47/20 , A61Q1/06 , A61Q11/00 , C09B29/01 , C09B29/16 , C09B29/30 , A23L1/26
CPC分类号： A61K47/20 , A23L5/47 , A61K8/466 , A61K9/0014 , A61Q1/06 , A61Q11/00 , C09B29/0007 , C09B29/16 , C09B29/30
摘要： A edible composition comprising 8-amino-2-(azo-benzene-4sulphonic acid) 1-naphthol-3 6-disulphonic acid as a colouring material, named ''''Red AB.
摘要翻译：包含8-氨基-2-（偶氮 - 苯-4-磺酸）1-萘酚-3,6-二磺酸作为着色剂的食用组合物，命名为“Red AB”。

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