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    • 89. 发明授权
    • Process for the production of a lubricating oil additive concentrate
    • 用于生产润滑油添加剂浓缩物的方法
    • US5451331A
    • 1995-09-19
    • US207222
    • 1994-03-04
    • Sean P. O'ConnorJohn CrawfordCharles Cane
    • Sean P. O'ConnorJohn CrawfordCharles Cane
    • C10M159/20C10M125/00C10M125/10C10M125/18C10M125/20C10M129/08C10M129/16C10M129/38C10M129/54C10M129/70C10M135/30C10M159/22C10N10/04C10N20/02C10N60/10C10N70/00
    • C10M159/22
    • A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 comprises reacting at elevated temperaturecomponent (A) a defined salicylic acid derivative,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at internediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri- (C.sub.2 -C.sub.4) glycol, (iv) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative, andcomponent (G) at least one compound which is (i) an inorganic halide of (ii) an ammonium alkanoate or mono-, di-, tri- or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.
    • 生产TBN大于300的润滑油添加剂浓缩物的方法包括在升高的温度下使组分(A)与定义的水杨酸衍生物,组分(B)一起添加的碱土金属碱反应, (C)至少一种化合物,其为(i)水,(ii)具有2至4个碳原子的多元醇,(iii)二(C3或C4)二醇 ,(iv)三 - (C 2 -C 4)二醇,(iv)式(I)R(OR 1)x OR 2(I)的单 - 或多 - 亚烷基二醇烷基醚,其中R是C1至C6烷基 R1为亚烷基R2为氢或C1〜C6烷基,x为1〜6的整数,(vi)C1〜C20一元醇,(vii)C1〜C20酮,(viii)C1 至(C)的碳酸酯,或(ix)C1至C20醚,组分(D)润滑油,组分(E)中添加的组分(B),组分(F) )定义的羧酸或衍生物,和组分(G)至少一种化合物,其是(i)无机卤化物,(ii)烷基铵或烷基甲酸烷基酯或烷酸烷基酯的单,二,三或四烷基铵 当组分(G)为(ⅱ)时,组分(F)不是酰氯,所有组分的重量比都要产生TBN大于300的浓缩物。