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    • 5. 发明公开
    • OPTICAL RECORDING MEDIUM
    • OPTISCHES AUFZEICHNUNGSMEDIUM
    • EP0887202A1
    • 1998-12-30
    • EP97949192.5
    • 1997-12-22
    • TDK Corporation
    • KAMBE, Emiko, TDK CorporationSHINKAI, Masahiro, TDK CorporationKITAGAWA, Sumiko, TDK CorporationMONDEN, Atsushi, TDK Corporation
    • B41M5/26
    • G11B7/246G11B7/2467G11B7/2472G11B7/248G11B7/249G11B7/2492G11B7/2495G11B7/2534G11B7/256G11B7/2575G11B7/2595G11B2007/24612G11B2007/24618Y10S428/913Y10S430/146Y10T428/21
    • An optical recording medium is provided in which a recording layer contains a salt-forming dye between an ion of an azo metal complex of the following formula (I) and an ion of a cyanine dye of the following formula (II), having a complex index of refraction in the wavelength region of recording light and/or reading light whose imaginary part k is up to 0.20, or at least one of azo oxovanadium metal complexes having an azo compound of the following formula (III) as a ligand and metal complexes having azo compounds of the following formulae (IV) and (V) as a ligand. Recording and reading can be carried out at a conventional wavelength or a short wavelength of about 630-690 nm or both.

              (A-N=N-B) m · M 1      (I)




              A-N=N-B     (III)



      In formulae (I) and (III), A is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group or a nitrogenous heteroaromatic ring group having an oxovanadium-coordinatable nitrogen atom at a position adjacent to the carbon atom in the ring attached to the diazo group, and B is an aromatic ring group having an active hydrogen-bearing group at a position adjacent to the diazo group. In formula (I), m is equal to 1 or 2, and M 1 is a center metal.
      In formula (II), Q 1 and Q 2 each are a group of atoms forming a 5-membered nitrogenous heterocyclic ring which may have a fused ring, L is a methine chain, R 1 and R 2 each are an alkyl group.
      In formulae (IV) and (V), X is an active hydrogen-bearing group, R 1 and R 2 each are an alkyl group, the total number of carbon atoms in R 1 and R 2 is from 2 to 8, R is a nitro group, and n is equal to 0 or 1.
    • 提供一种光记录介质,其中记录层在下式(I)的偶氮金属络合物的离子与下式(II)的花青染料的离子之间含有形成盐的染料,其具有复合物 记录光的波长区域的折射率和/或虚部k为0.20以上的读取光,或具有下述式(III)的偶氮化合物的偶氮氧化钒金属络合物作为配体和金属配合物中的至少一种 具有下式(IV)和(V)的偶氮化合物作为配体。 记录和读取可以在常规波长或约630-690nm的短波长或两者下进行。 (A-N = N-B)m。 在式(I)和(III)中,A是在与重氮基相邻的位置具有活性含氢基团的芳环基或具有氧代钒的含氮杂芳环基 在与重氮基团连接的环上与碳原子相邻的位置上具有可以键合的氮原子,B是在与重氮基相邻的位置上具有活性含氢基团的芳环基团。 式(I)中,m为1或2,M1为中心金属。 在式(II)中,Q 1和Q 2分别是可以具有稠环的5元含氮杂环的一个原子,L是次甲基链,R 1和R 2 >各为烷基。 在式(Ⅳ)和(Ⅴ)中,X为活性含氢基团,R 1和R 2各自为烷基,R 1和R 2中的碳原子总数 为2至8,R为硝基,n等于0或1.