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91. 发明授权

US5344896A Water soluble rigid-rod polymers 失效
标题翻译：水溶性刚性棒聚合物
公开(公告)号：US5344896A
公开(公告)日：1994-09-06
申请号：US192901
申请日：1994-02-07
申请人： Thuy D. Dang , Fred E. Arnold
发明人： Thuy D. Dang , Fred E. Arnold
IPC分类号： C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G75/32 , C08G73/18 , C08G73/22
摘要： Water-soluble rigid-rod aromatic heterocyclic polymers having repeating units of the formula: ##STR1## wherein n has a value of 0.05 to 1.00, M is an alkali metal, Q is a benzobisazole of the formula ##STR2## wherein X is --S-- or --O--, and R is selected from the group consisting of: ##STR3##
摘要翻译：具有下式重复单元的水溶性刚性 - 芳族芳族杂环聚合物：其中n的值为0.05至1.00，M为碱金属，Q为下式的苯并二唑：其中X为-S - 或-O-，R选自：

92. 发明授权

US5233014A Rapid advancement of molecular weight in polybenzazole oligomer dopes 失效
标题翻译：聚吲哚低聚物涂料中分子量的迅速提高
公开(公告)号：US5233014A
公开(公告)日：1993-08-03
申请号：US806110
申请日：1991-12-09
申请人： Thomas Gregory , Carl W. Hurtig , Harvey D. Ledbetter , Kenneth J. Quackenbush , Steven Rosenberg
发明人： Thomas Gregory , Carl W. Hurtig , Harvey D. Ledbetter , Kenneth J. Quackenbush , Steven Rosenberg
IPC分类号： C08G73/06 , C08G73/18 , C08G73/22
CPC分类号： C08G73/22 , C08G73/06 , C08G73/18
摘要： The invention is a condensation polymerization reaction in which functionally terminated polybenzazole ligomers are reacted in a solvent acid at a temperature of at least 150.degree. C. and a shear of at least about 10 sec..sup.-1 under conditions so that the desired molecular weight is reached in no more than about 4 hours. The oligomers may be, for example, derived from the reaction of 4,6-diaminoresorcinol bis(hydrochloride) and terephthalic acid. The concentration of oligomers is high enough so that the reaction mixture contains liquid crystalline domains.
摘要翻译：本发明是一种缩聚反应，其中在功能上终止的聚吲哚ligomers是在至少150℃的温度和至少约条件下10个仲1，使得所期望的分子量是剪切反应在溶剂中的酸达到不超过约4小时。低聚物可以是，例如，从4,6-二氨基双（盐酸盐）和对苯二甲酸的反应而得。低聚物的浓度足够高，使得反应混合物含有液晶畴。

93. 发明授权

US5218076A Branch polybenzazole polymer and method of preparation 失效
标题翻译：分支聚吲哚聚合物及其制备方法
公开(公告)号：US5218076A
公开(公告)日：1993-06-08
申请号：US849628
申请日：1992-03-11
申请人： Norman L. Madison , William J. Harris
发明人： Norman L. Madison , William J. Harris
IPC分类号： C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G73/18 , C08G73/22 , C08G75/32
摘要： The invention is a process for making novel branched polybenzazole polymers and the polymers formed thereby. Novel compounds are also disclosed that are useful as branching agents in making the branched polybenzazole polymers. The branched polymers synthesized by the process can be formed into strong, light articles such as fibers and films.
摘要翻译：本发明是制备新型支化聚吲哚聚合物的方法，由此形成聚合物。还公开了新颖的化合物，其可用作制备支链聚吲哚聚合物的支化剂。通过该方法合成的支化聚合物可以形成强的轻质制品如纤维和薄膜。

94. 发明授权

US5200495A Rigid-rod benzobisazole polymer containing cyclic phosphate ester 失效
标题翻译：含有环磷酸酯的刚性 - 苯并唑烷聚合物
公开(公告)号：US5200495A
公开(公告)日：1993-04-06
申请号：US887000
申请日：1992-05-22
申请人： Fred E. Arnold , Jom P. Chen
发明人： Fred E. Arnold , Jom P. Chen
IPC分类号： C08G73/06 , C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G73/18 , C08G73/06 , C08G73/22 , C08G75/32
摘要： Rigid-rod aromatic heterocyclic polymers having repeating units of the formula: ##STR1## wherein Ba is a benzobisazole moiety of the formula: ##STR2## wherein X is --O--, --S-- or --NH.
摘要翻译：具有下式重复单元的刚性 - 芳族芳族杂环聚合物：其中Ba是下式的苯并双唑部分：其中X是-O - ， - S-或-NH。

95. 发明授权

US5198526A Heterocycle oligomers with multidimensional morphology 失效
标题翻译：具有多维形态的杂环低聚物
公开(公告)号：US5198526A
公开(公告)日：1993-03-30
申请号：US904865
申请日：1992-06-26
申请人： Hyman R. Lubowitz , Clyde H. Sheppard
发明人： Hyman R. Lubowitz , Clyde H. Sheppard
IPC分类号： C07C317/22 , C07D413/14 , C08G73/10 , C08G73/12 , C08G73/18 , C08G73/22 , C08G75/32 , C08J5/24
CPC分类号： C07D413/14 , C07C317/22 , C08G73/1046 , C08G73/1064 , C08G73/1067 , C08G73/1071 , C08G73/122 , C08G73/18 , C08G73/22 , C08G75/32 , C08J5/24
摘要： Linear or multidimensional, crosslinking, solvent resistant oxazole, thiazole, or imidazole (i.e., heterocycle) oligomers and blends of the crosslinking oligomers and noncrosslinking comparable polymers are described. The oligomers are prepared by reacting tetraamines, diaminodiols, or diaminothiols (i.e. four-functional compounds) with poly-carboxylic acid halides, and crosslinking phenylimide end cap monomers in a suitable solvent under an inert atmosphere.
摘要翻译：描述了线性或多维交联，耐溶剂的恶唑，噻唑或咪唑（即杂环）低聚物和交联低聚物和非交联的可比聚合物的共混物。低聚物通过四胺，二氨基二醇或二氨基硫醇（即四官能化合物）与聚羧酸卤化物反应，并在惰性气氛下，在合适的溶剂中将苯基酰亚胺封端单体交联。

96. 发明授权

US5120825A Polymers containing both imidazole and imidazolone structural units 失效
标题翻译：含有咪唑和咪唑啉酮结构单元的聚合物
公开(公告)号：US5120825A
公开(公告)日：1992-06-09
申请号：US631557
申请日：1990-12-21
申请人： Rohitkumar H. Vora , Paul N. Chen, Sr.
发明人： Rohitkumar H. Vora , Paul N. Chen, Sr.
IPC分类号： C08G73/06 , C08G73/18
CPC分类号： C08G73/0672 , C08G73/18
摘要： The present invention provides for hybrid polybenzimidazole and polybenzimidazolone polymers which are characterized as containing both imidazole and imidazolone structural units in the polymer chain. These polymers are characterized as containing at least one recurring monomer unit containing the structure of the formula: ##STR1## wherein Ar is a tetravalent aromatic moiety derived from an aromatic tetraamine and Ar.sub.1 is a trivalent aromatic moiety derived from a trifunctional acid, an acid anhydride or amine-reactive derivatives thereof, said polymers further characterized by an inherent viscosity of at least about 0.01 dl/g measured as a 0.5% solution in N-methyl pyrrolidone at 25.degree. C.The polymers of this invention exhibit many of the advantageous properties of both polybenzimidazole and polybenzimidazolone polymers. They are characterized as being extremely resistant to chemical attack such as by solvents, acids and bases. Their high thermal stability and excellent electrical properties (low dielectric constant) render them useful in electrical and electronic applications.
摘要翻译：本发明提供了混合聚苯并咪唑和聚苯并咪唑酮聚合物，其特征在于在聚合物链中含有咪唑和咪唑啉酮结构单元。这些聚合物的特征在于含有至少一个含有下式结构的重复单体单元：其中Ar是衍生自芳族四胺的四价芳香部分，Ar 1是衍生自三官能酸的三价芳族部分，酸酐或其胺反应性衍生物，所述聚合物的特征还在于其在25℃下作为N-甲基吡咯烷酮中的0.5％溶液测量的至少约0.01dl / g的特性粘度。本发明的聚合物显示出许多有利的性质的聚苯并咪唑和聚苯并咪唑酮聚合物。它们的特征是具有极强的耐化学腐蚀性，如溶剂，酸和碱。它们的高热稳定性和优异的电性能（低介电常数）使其在电气和电子应用中非常有用。

97. 发明授权

US5082905A Blended heterocycles 失效
标题翻译：混合杂环
公开(公告)号：US5082905A
公开(公告)日：1992-01-21
申请号：US696492
申请日：1991-05-06
申请人： Hyman R. Lubowitz , Clyde H. Sheppard
发明人： Hyman R. Lubowitz , Clyde H. Sheppard
IPC分类号： C07C317/22 , C07D413/14 , C08G73/10 , C08G73/12 , C08G73/18 , C08G73/22 , C08G75/32 , C08J5/24
CPC分类号： C07D413/14 , C07C317/22 , C08G73/1046 , C08G73/1064 , C08G73/1067 , C08G73/1071 , C08G73/122 , C08G73/18 , C08G73/22 , C08G75/32 , C08J5/24
摘要： Linear or multidimensional, crosslinking, solvent resistant oxazole, thiazole, or imidazole (i.e., heterocycle) oligomers and blends of the crosslinking oligomers and noncrosslinking comparable polymers are described. The oligomers are prepared by reacting tetraamines, diaminodiols, or diaminothiols (i.e. four-functional compounds) with poly-carboxylic acid halides, and crosslinking phenylimide end cap monomers in a suitable solvent under an inert atmosphere.
摘要翻译：描述了线性或多维交联，耐溶剂的恶唑，噻唑或咪唑（即杂环）低聚物和交联低聚物和非交联的相当的聚合物的共混物。低聚物通过四胺，二氨基二醇或二氨基硫醇（即四官能化合物）与聚羧酸卤化物反应，并在惰性气氛下，在合适的溶剂中将苯基酰亚胺封端单体交联。

98. 发明授权

US5041611A Preparation of monomers 失效
标题翻译：单体的制备
公开(公告)号：US5041611A
公开(公告)日：1991-08-20
申请号：US355935
申请日：1989-05-23
申请人： Ian D. H. Towle
发明人： Ian D. H. Towle
IPC分类号： C07C69/773 , C07C327/26 , C07C329/20 , C08G61/12 , C08G73/06 , C08G73/10 , C08G73/18
CPC分类号： C07C327/00 , C07C329/00 , C08G61/12 , C08G73/06 , C08G73/1057 , C08G73/18
摘要： Organic compounds having aromatic ester, thioester, or carbonate groups are prepared by reacting an organometallic reactant where the metal is germanium, tin, lead, gallium, indium, thallium, arsenic, antimony, or bismuth with a suitable second reactant. For example, the ester ##STR1## is prepared by reacting the bis-tri--n-butyl tin derivative of ethyl 4-hydroxybenzoate with 4-phenoxybenzoyl chloride.

99. 发明授权

US4933397A Preparation of N-substituted phenyl polybenzimidazole polymers 失效
标题翻译： N-取代苯基聚苯并咪唑聚合物的制备
公开(公告)号：US4933397A
公开(公告)日：1990-06-12
申请号：US315992
申请日：1989-02-27
申请人： Michael J. Sansone , Mark S. Kwiatek
发明人： Michael J. Sansone , Mark S. Kwiatek
IPC分类号： C08G73/18
CPC分类号： C08G73/18
摘要： This invention discloses a unique process for the preparation of N-substituted phenyl polybenzimidazole polymers from unsubstituted polybenzimidazole polymers. An unsubstituted polybenzimidazole polymer is first reacted with an alkali hydride to produce a polybenzimidazole anion which is then reacted with a substituted or an unsubstituted phenyl fluoride to produce N-substituted phenyl polybenzimidazole polymer. The N-substituted phenyl polybenzimidazole polymer produced by this process can be formed into a wide range of products, such as membranes, films resins or fibers. The produce can be designed to meet special applications by the choice of the substitutent. These N-substituted phenyl polybenzimidazole polymers can be utilized for numerous applications including reverse osmosis, ultrafiltration, microfiltration, electrodialysis, ion exchange and affinity chromatography.

100. 发明授权

US4892921A Pendant benzazole rigid-rod aromatic benzoxazole 失效
标题翻译：吊坠苯唑刚性棒芳香族苯并恶唑
公开(公告)号：US4892921A
公开(公告)日：1990-01-09
申请号：US313766
申请日：1989-02-21
申请人： Tsu-Tzu Tsai , Fred E. Arnold
发明人： Tsu-Tzu Tsai , Fred E. Arnold
IPC分类号： C08G73/08 , C08G73/18 , C08G73/22 , C08G75/32
CPC分类号： C08G75/32 , C08G73/08 , C08G73/18 , C08G73/22
摘要： Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.
摘要翻译：提供了具有下式的重复基团的新型有序芳族杂环聚合物，其中Y是-O - ， - S - 或-NH-，n是1或2，Q是< 其中Z是-O-或-S-。还提供了制备上述聚合物的方法。

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