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    • 96. 发明授权
    • Lithium-ion secondary battery and electrolyte thereof
    • 锂离子二次电池及其电解质
    • US09564658B2
    • 2017-02-07
    • US14558589
    • 2014-12-02
    • Ningde Amperex Technology Limited
    • Chunbo ChuChenghua Fu
    • H01M10/05H01M10/0567H01M10/0569H01M10/0525
    • H01M10/0567H01M10/0525H01M10/0569H01M2300/0025H01M2300/0037Y02P70/54
    • The present disclosure provides a lithium-ion secondary battery and an electrolyte thereof. The electrolyte comprises a lithium salt; a non-aqueous solvent and an additive comprising a first additive and a second additive, the first additive comprises at least one of vinylene carbonate and vinyl ethylene carbonate, the second additive is 4-methylene-1,3-dioxolan-2-one and its derivatives with a structural formula 1 and/or 4,5-dimethylene-1,3-dioxolan-2-one and its derivatives with a structural formula 2; in the structural formula 1 and the structural formula 2, R1, R2, R3 and R4 each are hydrogen, halogen, C1˜C3 alkyl or halogenated alkyl; a weight percentage of the first additive in the electrolyte is 0.2%˜2.0%, a weight percentage of the second additive in the electrolyte is 0.3%˜4.0%. The lithium-ion secondary battery comprises the aforementioned electrolyte. The lithium-ion secondary battery has better cycle performance, better low temperature discharging performance, and higher first coulombic efficiency.
    • 本公开内容提供了一种锂离子二次电池及其电解质。 电解质包含锂盐; 非水溶剂和包含第一添加剂和第二添加剂的添加剂,第一添加剂包括碳酸亚乙烯酯和碳酸亚乙烯酯中的至少一种,第二添加剂是4-亚甲基-1,3-二氧戊环-2-酮, 其具有结构式1和/或4,5-二甲基-1,3-二氧戊环-2-酮的衍生物及其具有结构式2的衍生物; 在结构式1和结构式2中,R 1,R 2,R 3和R 4各自为氢,卤素,C 1 -C 3烷基或卤代烷基; 电解质中第一添加剂的重量百分比为0.2%〜2.0%,电解质中第二种添加剂的重量百分数为0.3%〜4.0%。 锂离子二次电池包含上述电解质。 锂离子二次电池具有更好的循环性能,更好的低温放电性能和更高的第一库仑效率。