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    • 97. 发明授权
    • Polystyrene blends
    • 聚苯乙烯共混物
    • US08809459B2
    • 2014-08-19
    • US13754036
    • 2013-01-30
    • Fina Technology, Inc.
    • Camille GrosseteteDavid W. KnoeppelJose M. SosaShane SteagallCarlos Corletto
    • C08F8/00C08L25/02
    • C08L25/06C08L2205/02C08L2207/20
    • A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.
    • 一种制备聚苯乙烯共混物的方法,其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物,所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3%以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料,其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物,使反应混合物聚合并获得聚苯乙烯共混物,其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。
    • 99. 发明授权
    • Polystyrene blends
    • 聚苯乙烯共混物
    • US08389636B2
    • 2013-03-05
    • US13530212
    • 2012-06-22
    • Camille GrosseteteDavid W. KnoeppelJose M. SosaShane SteagallCarlos Corletto
    • Camille GrosseteteDavid W. KnoeppelJose M. SosaShane SteagallCarlos Corletto
    • C08L25/02
    • C08L25/06C08L2205/02C08L2207/20
    • A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.
    • 一种制备聚苯乙烯共混物的方法,其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物,所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3%以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料,其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物,使反应混合物聚合并获得聚苯乙烯共混物,其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。
    • 100. 发明授权
    • Composition with increased stress cracking resistance
    • 具有增加的抗开裂性的组合物
    • US08227549B2
    • 2012-07-24
    • US12600840
    • 2008-04-09
    • Klaus SchultesWerner HoessNils Mehler
    • Klaus SchultesWerner HoessNils Mehler
    • C08L25/02C08L33/02C08L33/04C08L33/14C08L33/18C08L33/20C08L35/02
    • C08L33/08C08L25/12C08L33/10C08L2666/04
    • Composition containing, based in each case on its total weight, A) 50.0% by weight to 99.5% by weight of at least one (meth)acrylate (co)polymer and B) 0.5% by weight to 50.0% by weight of at least one copolymer obtainable by polymerization of a monomer mixture comprising i. 70% by weight to 92% by weight of a vinylaromatic monomer and ii. 8% by weight to 30% by weight of acrylonitrile or methacrylonitrile or mixtures thereof and iii. 0% by weight to 22% by weight of at least one further monomer, the composition having a haze according to ASTM D1003 of less than 2.0% at 23° C. and a haze according to ASTM D1003 of less than 4.0% at 40° C. and the composition containing at least one (meth)acrylate (co)polymer a) having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of greater than 55 ml/g. The moldings obtainable from the composition are distinguished in particular by improved stress cracking resistance and are suitable in particular for coverings, finishes or films.
    • 包含基于每种情况的总重量的组合物A)50.0重量%至99.5重量%的至少一种(甲基)丙烯酸酯(共)聚合物,和B)至少0.5重量%至50.0重量% 一种共聚物,其通过单体混合物的聚合获得,所述单体混合物包含i。 70重量%至92重量%的乙烯基芳族单体,和ii。 8重量%至30重量%的丙烯腈或甲基丙烯腈或其混合物,iii。 0重量%至22重量%的至少一种其它单体,该组合物在-23℃下具有根据ASTM D1003的雾度小于2.0%,并且根据ASTM D1003的雾度小于4.0% 40℃,组合物含有至少一种在-25℃(ISO 1628-第6部分)中溶液粘度在55ml / g以上的(甲基)丙烯酸酯(共)聚合物)a)。 可从组合物获得的模制品特别是通过改进的耐应力开裂性来区分,特别适用于覆盖物,表面处理剂或膜。