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21. 发明授权

US08513474B2 Process for the manufacture of fluorinated olefins 有权
标题翻译：制造氟化烯烃的方法
公开(公告)号：US08513474B2
公开(公告)日：2013-08-20
申请号：US12822365
申请日：2010-06-24
申请人： Haiyou Wang , Hsueh Sung Tung
发明人： Haiyou Wang , Hsueh Sung Tung
IPC分类号： C07C17/00 , C07C17/10
CPC分类号： C07C17/04 , C07C17/354 , C07C17/357 , C07C21/18 , C07C19/08
摘要： Provided are methods for producing fluorinated organic compounds, which preferably comprises converting at least one compound of formula (I) CH2XCHZCF3 to at least one compound of formula (II) CHX═CZCF3 where X and Z are independently H or F, with the proviso that X and Z are not the same. The converting step comprises catalytically reacting at least one compound of formula (I), preferably via dehydrogenation or oxidative dehydrogenation. In another aspect, the inventive method of preparing fluorinated organic compounds comprises converting a reaction stream comprising at least one pentafluoropropene to a product stream comprising at least one pentafluoropropane and at least one compound of formula (I), separating out the compound of formula (I) from the product stream, and converting the compound of formula (I) separated from the product stream to at least one compound of formula (II), wherein the conversion the compound of formula (I) to 3,3,3-trifluoropropyne is substantially limited.
摘要翻译：提供了用于生产氟化有机化合物的方法，其优选包括将至少一种式（I）CH 2 XCHZCF 3化合物转化为至少一种式（II）的化合物，其中X和Z独立地为H或F，式（II）化合物为CHX = CZCF3，条件是 X和Z不一样。转化步骤包括使至少一种式（I）化合物催化反应，优选通过脱氢或氧化脱氢。在另一方面，制备含氟有机化合物的本发明方法包括将包含至少一种五氟丙烯的反应物流转化为包含至少一种五氟丙烷和至少一种式（I）化合物的产物流，将式（I）化合物），并将从产物流分离的式（I）化合物转化为至少一种式（II）化合物，其中式（I）化合物与3,3,3-三氟丙炔的转化率为基本上有限。

22. 发明授权

US08487144B2 Process for producing fluorinated propene 有权
标题翻译：制备氟化丙烯的方法
公开(公告)号：US08487144B2
公开(公告)日：2013-07-16
申请号：US13062560
申请日：2009-09-04
申请人： Hideo Hamasaki , Yasuo Hibino
发明人： Hideo Hamasaki , Yasuo Hibino
IPC分类号： C07C17/00
CPC分类号： C07C21/18 , B01J21/18 , B01J23/26 , C07C17/206 , C07C17/25 , C09K3/30 , C09K5/045
摘要： There is provided according to the present invention a process for producing 1-chloro-3,3,3-trifluoropropene or 1,3,3,3-tetrafluoropropene, including: reacting 1,1,1,3,3-pentafluoropropane with hydrogen chloride in a gas phase in the presence of a solid catalyst. By the use of a specific solid catalyst such as a catalyst in which chromium is supported on alumina or activated carbon or an alumina catalyst, the 1-chloro-3,3,3-trifluoropropene or 1,3,3,3-tetrafluoropropene can be obtained with high yield from the 1,1,1,3,3-pentafluoropropane, which can be commercially available or prepared on an industrial scale.
摘要翻译：根据本发明提供了一种生产1-氯-3,3,3-三氟丙烯或1,3,3,3-四氟丙烯的方法，包括：使1,1,1,3,3-五氟丙烷与氢反应氯化物在气相中在固体催化剂存在下进行。通过使用特定的固体催化剂如催化剂，其中铬负载在氧化铝或活性炭或氧化铝催化剂上，1-氯-3,3,3-三氟丙烯或1,3,3,3-四氟丙烯可以可以从1,1,1,3,3-五氟丙烷以高产率获得，其可以商业上获得或者以工业规模制备。

23. 发明申请

US20130096348A1 CHIRAL DIENE LIGANDS, A FABRICATION METHOD THEREOF AND APPLICATIONS THEREOF 有权
标题翻译： CHIRAL DIENE LIGANDS，其制造方法及其应用
公开(公告)号：US20130096348A1
公开(公告)日：2013-04-18
申请号：US13608222
申请日：2012-09-10
申请人： Hsyueh-Liang WU , Chun-Chih Chen , Chia-Chen Liu , Wei-Ting Wei , Jo-Hsuan Fang
发明人： Hsyueh-Liang WU , Chun-Chih Chen , Chia-Chen Liu , Wei-Ting Wei , Jo-Hsuan Fang
IPC分类号： C07C17/00 , C07C291/00 , C07C1/207 , C07C13/47 , C07C13/42 , C07C25/24 , C07C45/61
CPC分类号： C07C13/39 , C07B2200/07 , C07C25/24 , C07C29/74 , C07C205/06 , C07C2602/42 , C07C31/225
摘要： The present invention proposes a chiral diene ligand, a fabrication method thereof and applications thereof. The chiral diene ligand is a bicyclo[2.2.1] diene ligand having structural specificity and high stability, which favors the bicyclo[2.2.1] diene ligand to take part in asymmetric transformations, particularly an asymmetric addition reaction involving a metal catalyst in a basic environment. Most of the products of the reactions implemented by the chiral diene ligands of the present invention have superior optical activity. The method of the present invention comprises a first oxidation step, a saponification step, a second oxidation step, a deprotonation step, and a cross-coupling step. The chiral diene ligand of the present invention is very suitable to be used in the fabrication or synthesis of various chemicals and medical products.
摘要翻译：本发明提出了一种手性二烯配体，其制备方法和应用。手性二烯配体是具有结构特异性和高稳定性的双环[2.2.1]二烯配体，其有利于双环[2.2.1]二烯配体参与不对称转化，特别是涉及金属催化剂的不对称加成反应基本环境。由本发明的手性二烯配体实现的反应的大部分产物具有优异的光学活性。本发明的方法包括第一氧化步骤，皂化步骤，第二氧化步骤，去质子化步骤和交联反应步骤。本发明的手性二烯配体非常适合用于制造或合成各种化学品和医疗产品。

24. 发明授权

US08383868B2 Method of producing iodizing agent, and method of producing aromatic iodine compound 失效
标题翻译：生产碘化剂的方法，以及芳族碘化合物的制备方法
公开(公告)号：US08383868B2
公开(公告)日：2013-02-26
申请号：US12530274
申请日：2008-03-07
申请人： Junichi Yoshida , Seiji Suga , Kazuhide Kataoka , Koji Midorikawa , Yuji Hagiwara
发明人： Junichi Yoshida , Seiji Suga , Kazuhide Kataoka , Koji Midorikawa , Yuji Hagiwara
IPC分类号： C07C17/00
CPC分类号： C07C17/02 , C07B39/00 , C07C17/12 , C07C37/62 , C07C41/22 , C07C209/74 , C07C253/30 , C25B1/24 , C25B3/06 , C07C25/18 , C07C25/22 , C07C211/52 , C07C255/50 , C07C39/27 , C07C43/225
摘要： A method of the present invention, for producing an iodizing agent, includes the step of electrolyzing iodine molecules in a solution by using an acid as a supporting electrolyte. This realizes (i) a method of producing an iodine cation suitable for use as an iodizing agent that does not require a sophisticated separation operation after iodizing reaction is completed, and (ii) an electrolyte used in the method. Further, a method of the present invention, for producing an aromatic iodine compound, includes the step of causing an iodizing agent, and an aromatic compound whose nucleus has one or more substituent groups and two or more hydrogen atoms, to react with each other under the presence of a certain ether compound. This realizes such a method of producing an aromatic iodine compound that position selectivity in iodizing reaction of an aromatic compound is improved.
摘要翻译：本发明的制备碘化剂的方法包括通过使用酸作为支持电解质在溶液中电解碘分子的步骤。这实现了（i）生产适合用作碘化剂的碘阳离子的方法，其在碘化反应完成后不需要复杂的分离操作，和（ii）该方法中使用的电解质。此外，本发明的芳香族碘化合物的制造方法包括使碘化剂和其中具有一个以上取代基和两个以上氢原子的芳香族化合物在其下反应的工序存在某种醚化合物。这实现了提高芳族化合物的碘化反应中选择性的芳香族碘化合物的制造方法。

25. 发明授权

US08344191B2 Process for preparing 2,3,3,3-tetrafluoropropene 有权
标题翻译：制备2,3,3,3-四氟丙烯的方法
公开(公告)号：US08344191B2
公开(公告)日：2013-01-01
申请号：US13056448
申请日：2009-07-24
申请人： Masatoshi Nose , Daisuke Karube , Akinari Sugiyama , Takashi Shibanuma , Takehiro Chaki
发明人： Masatoshi Nose , Daisuke Karube , Akinari Sugiyama , Takashi Shibanuma , Takehiro Chaki
IPC分类号： C07C17/00
CPC分类号： C07C17/206 , C07C17/25 , Y02P20/582 , C07C21/18
摘要： The present invention provides a process for producing 2,3,3,3-tetrafluoropropene represented by the formula CF3CF═CH2, comprising contacting a fluorine-containing propane represented by the formula CF2XCFYCH2Z, wherein X is Cl, Br, or I; one of Y and Z is H, and the other is F, Cl, Br, or I, with at least one catalyst selected from the group consisting of chromium oxides, fluorinated chromium oxides, and iron fluorides in a gas phase. According to the process of the invention, 2,3,3,3-tetrafluoropropene can be easily produced under economically advantageous conditions.
摘要翻译：本发明提供一种制备由式CF 3CF≡CH2表示的2,3,3,3-四氟丙烯的方法，包括使由式CF 2 XCFYCH 2 Z表示的含氟丙烷，其中X为Cl，Br或I; Y和Z中的一个是H，另一个是F，Cl，Br或I，在气相中使用至少一种选自铬氧化物，氟化铬氧化物和氟化铁的催化剂。根据本发明的方法，可以在经济上有利的条件下容易地制备2,3,3,3-四氟丙烯。

26. 发明授权

US08309775B2 Method of preparing iodinated aromatic compounds 有权
标题翻译：制备碘化芳香族化合物的方法
公开(公告)号：US08309775B2
公开(公告)日：2012-11-13
申请号：US12599400
申请日：2008-12-17
申请人： Han-Seok Kim , Jae-Bong Lim , Il-Hoon Cha
发明人： Han-Seok Kim , Jae-Bong Lim , Il-Hoon Cha
IPC分类号： C07C17/00
CPC分类号： C07C17/12 , C07C17/383 , C07C17/392 , C07C25/02
摘要： The present invention relates to a method of preparing iodinated aromatic compounds, and more preferably a method of preparing iodinated aromatic compounds comprising a step of iodinating a react ant including an aromatic compound, a di-iodo aromatic compound or water, and iodine (I2) in the presence of a zeolite catalyst and oxygen. The method of the present invention has an advantage that by iodination of a reactant including the aromatic compound, and the di˜ iodo aromatic compound or water in the presence of the zeolite catalyst and oxygen, the temperature of the iodinating reactor can be controlled reliably and constantly, thereby resulting in improved productivity per unit weight of catalyst and inhibition of a side reaction in accordance with suppression of producing impurities. In addition, the productivity of the iodinated aromatic compound, preferably the di-iodo aromatic compound, more preferably a p-di-iodo aromatic compound can be improved, and thus can be widely used in the preparation of a di-iodo aromatic compound such as a p-di-iodo aromatic compound.
摘要翻译：本发明涉及一种制备碘化芳族化合物的方法，更优选的是制备碘化芳族化合物的方法，其包括将包含芳族化合物，二碘芳族化合物或水的碘的反应锑和碘（I 2）在沸石催化剂和氧的存在下。本发明的方法具有的优点是，通过在沸石催化剂和氧气存在下，通过碘化包括芳族化合物和二碘芳香族化合物或水的反应物，可以可靠地控制碘化反应器的温度，从而导致每单位重量催化剂的生产率提高，并且抑制副产物产生杂质。此外，可以提高碘化芳香族化合物，优选二碘芳香族化合物，更优选对二碘芳香族化合物的生产率，因此可以广泛用于制备二碘芳族化合物，例如作为对二碘芳族化合物。

27. 发明授权

US08263818B2 Isomerization of 1,1,3,3-tetrafluoropropene 有权
公开(公告)号：US08263818B2
公开(公告)日：2012-09-11
申请号：US12686857
申请日：2010-01-13
申请人： Haiyou Wang , Konstantin A. Pokrovski , Hsueh S. Tung , Michael Van Der Puy
发明人： Haiyou Wang , Konstantin A. Pokrovski , Hsueh S. Tung , Michael Van Der Puy
IPC分类号： C07C17/00
摘要： The present invention involves methods for isomerization of 1234zc. Also provided are methods for managing 1,1,3,3-tetrafluoropropene produced as a byproduct in a process for synthesizing trans-1,3,3,3-tetrafluoropropene from 245fa, wherein 1234zc is converted into trans/cis-1234ze with the help of a catalyst in the absence of HF and in an isomerization reactor, or is converted into 1234zc and/or 245fa with the help of a catalyst in the presence of HF in a separate reactor or preferably in the same reactor of 245fa dehydrofluorination.

28. 发明授权

US08258353B2 Process for the production of chlorinated and/or fluorinated propenes 有权
标题翻译：用于生产氯化和/或氟化丙烯的方法
公开(公告)号：US08258353B2
公开(公告)日：2012-09-04
申请号：US12799170
申请日：2010-04-20
申请人： William J. Kruper, Jr. , Max M. Tirtowidjojo , Kurt F. Hirsekorn , Debashis Chakraborty , Juergen Eiffler
发明人： William J. Kruper, Jr. , Max M. Tirtowidjojo , Kurt F. Hirsekorn , Debashis Chakraborty , Juergen Eiffler
IPC分类号： C07C17/266 , C07C17/00
CPC分类号： C07C17/269 , Y02P20/582 , C07C21/18 , C07C21/04
摘要： The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures relative to conventional processes, so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts may provide enhancements to conversion rates and selectivity over those seen in conventional processes, as may adjustments to the molar ratio of the reactants.
摘要翻译：本发明提供用于生产氯化和/或氟化丙烯的一步法。该方法提供良好的产物收率，具有低，例如小于约20％，或甚至低于10％的残余物/副产物浓度。有利地，相对于常规方法，该方法可以在低温下进行，从而提供节能和/或在更高的压力下，从而也可以实现高产量。催化剂的使用可以提高转化率和选择性，而不是可以调节反应物的摩尔比。

29. 发明授权

US08217208B2 Isomerization of 1-chloro-3,3,3-trifluoropropene 有权
标题翻译： 1-氯-3,3,3-三氟丙烯的异构化
公开(公告)号：US08217208B2
公开(公告)日：2012-07-10
申请号：US12633420
申请日：2009-12-08
申请人： Ryan Hulse , Rajiv R. Singh , Konstantin A. Pokrovski , Hsueh Sung Tung , Daniel Merkel , Haiyou Wang , Michael Van Der Puy
发明人： Ryan Hulse , Rajiv R. Singh , Konstantin A. Pokrovski , Hsueh Sung Tung , Daniel Merkel , Haiyou Wang , Michael Van Der Puy
IPC分类号： C07C17/00
CPC分类号： C07C17/358 , C07C17/383 , C07C21/18
摘要： Disclosed are processes for an isomerization reaction between (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene. Some of the disclosed processes include the step of contacting a feed stream with a heated surface, where the feed stream includes (E)1-chloro-3,3,3-trifluoropropene, (Z)1-chloro-3,3,3-trifluoropropene or mixtures thereof. The resulting product stream includes (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene, where the ratio of (E) isomer to (Z) isomer in the product stream is different than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.
摘要翻译：公开了（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯之间异构化反应的方法。一些所公开的方法包括使进料流与加热表面接触的步骤，其中进料流包含（E）1-氯-3,3,3-三氟丙烯，（Z）1-氯-3,3,3 - 三氟丙烯或其混合物。所得产物流包含（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯，其中（E）异构体与（Z）异构体的比例产品流与进料流比不同。产物流中的（E）和（Z）异构体可以彼此分离。

30. 发明授权

US08207384B2 Catalytic gas phase fluorination of 243db to 1234yf 有权
标题翻译：催化气相氟化243db至1234yf
公开(公告)号：US08207384B2
公开(公告)日：2012-06-26
申请号：US12978288
申请日：2010-12-23
申请人： Laurent Wendlinger , Anne Pigamo , Dominique Deur-Bert
发明人： Laurent Wendlinger , Anne Pigamo , Dominique Deur-Bert
IPC分类号： C07C17/00
CPC分类号： C07C17/206 , B01J23/866 , B01J37/26 , C07C17/25 , C07C17/42 , C07C21/08 , Y02P20/582 , C07C19/10 , C07C21/18
摘要： The invention provides a process for preparing 1234yf, comprising: (i) contacting 243db with hydrogen fluoride HF in gas phase in the presence of a fluorination catalyst under conditions sufficient to produce a reaction mixture; (ii) separating the reaction mixture into a first stream comprising HCl, 1234yf and a second stream comprising HF, 1233xf and 245cb; (iii) recycling at least a part of the second stream at least in part back to step (i). The invention also provides a process for preparing 1234yf, comprising: (i) contacting 243db with hydrogen fluoride HF in gas phase in the presence of a fluorination catalyst under conditions sufficient to produce a reaction mixture; (ii) separating the reaction mixture into HCl and a stream containing the fluorinated products; (iii) separating said stream containing the fluorinated products into a first stream comprising 1234yf and a second stream comprising HF, 1233xf and 245cb; (iv) recycling at least a part of the second stream at least in part back to step (i).
摘要翻译：本发明提供一种制备1234yf的方法，其包括：（i）在足以产生反应混合物的条件下，在氟化催化剂存在下，使气体中的243db与氟化氢HF接触; （ii）将反应混合物分离成包含HCl，1234yf和包含HF，1233xf和245cb的第二料流的第一料流; （iii）至少部分地将第二流的至少一部分再循环回到步骤（i）。本发明还提供了一种制备1234yf的方法，其包括：（i）在足以产生反应混合物的条件下，在氟化催化剂存在下，将气体中的243db与氟化氢HF气相接触; （ii）将反应混合物分离成HCl和含有氟化产物的料流; （iii）将含有氟化产物的物流分离成包含1234yf的第一物流和包含HF，1233xf和245cb的第二物流; （iv）至少部分地将至少一部分第二流再循环到步骤（i）。

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