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    • 35. 发明申请
    • Process and Apparatus for Manufacture of Processable Polyvinyl Alcohol
    • US20220002532A1
    • 2022-01-06
    • US17368176
    • 2021-07-06
    • Aquapak Polymers Limited
    • John WilliamsSian GriffithsRobert Ashworth
    • C08L29/04C08F116/06C08J3/05
    • The invention describes a method for the manufacture of a plasticized polyvinyl alcohol polymer mixture including the steps of introducing a polyvinyl alcohol or a blend thereof having a degree of hydrolysis in the range of 93% to 98% or more into a mixing reactor; adding a processing agent, and a plasticizer to form a reaction mixture; wherein the plasticizer is selected from the group consisting of the following compounds and mixtures thereof: (a) sugar alcohols selected from the group consisting of: diglycerol, triglycerol, fructose, ribose, xylose, D-mannitol, triacetin, and mixtures thereof; polyols selected from the group consisting of: pentaerythritol, dipentaerythritol, and mixtures thereof; (b) diols selected from the group consisting of: methyl pentanediol, 1,2-propanediol, 1,4-butanediol, 2-hydroxy-1,3-propanediol, 3-methyl-1,3-butanediol, 3,3-dimethyl-1,2-butanediol, and mixtures thereof; (c) glycols selected from the group consisting of: polyethylene glycol 300, polyethylene glycol 400, alkoxylated polyethylene glycol, and mixtures thereof; (d) caprolactam, tricyclic trimethylolpropane formal, rosin esters, euricamide, and mixtures thereof; reacting the reaction mixture in a reaction zone to form plasticized polymer; and allowing the plasticized polymer to pass from the reaction zone.
    • 39. 发明申请
    • BINDER
    • US20210395507A1
    • 2021-12-23
    • US17291839
    • 2019-11-13
    • JAPAN VAM & POVAL CO., LTD.
    • Shotaro KAWADAMasatoshi KAWANISHI
    • C08L29/04A61K9/16A61K9/28
    • A novel binder is provided. The binder comprises a polyvinyl alcohol-based polymer which has an average saponification value of 85.0 mol % to 89.0 mol % as measured according to JIS K6726 and meets requirement (A): based on data obtained by measurement of the polyvinyl alcohol-based polymer by liquid chromatography, a value represented by formula (3) shown below is 22 or more, wherein the measurement is performed with a liquid chromatography system equipped with a charged aerosol detector and a Thermo Scientific Acclaim™ 300 column (catalog number: 060266, carbon load: 8%, maximum pressure: 4500 psi, particle size: 3 μm, pore size: 300 A, stationary phase: C18, surface area: 100 m2/g, length: 150 mm, diameter: 4.6 mm, pH: 2.5 to 7.5, material: glass lined tubing) under the measurement conditions described below, wherein the data represent a baseline-normalized intensity over a retention time of 5.0 to 12.0 minutes at a sampling interval of 500 ms, and wherein the value represented by formula (3) is calculated from formulae (1) and (2) shown below, wherein the intensity at a retention time Ti [min] is represented by Pi [pA]. Measurement Conditions Concentration of an aqueous polyvinyl alcohol-based polymer solution: 0.1% by mass Injection volume of the aqueous polyvinyl alcohol-based polymer solution: 2 μL Column temperature: 50° C. Flow rate: 1.0 mL/min Eluent: a mixed solvent of water and methanol Eluent gradient conditions: the ratio of water and methanol in the eluent changes from 95:5 to 15:85 at a constant rate over a run time from minutes 0 to 10; and the ratio of water and methanol in the eluent is constant at 15:85 over a run time from minutes 10 to 15. Formulae Tn=Σ(Ti×Pi)/Σ(Pi)  Formula (1) Tw=Σ(Ti2×Pi)/Σ(Ti×Pi)  Formula (2) {(Tw/Tn)−1}×1000  Formula (3)