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51. 发明授权

US08313724B2 Short, functionalized, soluble carbon nanotubes, methods of making same, and polymer composites made therefrom 有权
标题翻译：短功能化，可溶性碳纳米管，其制备方法和由其制备的聚合物复合材料
公开(公告)号：US08313724B2
公开(公告)日：2012-11-20
申请号：US12280523
申请日：2007-02-22
申请人： Wen-Fang Hwang , Zheyl Chen , James M. Tour
发明人： Wen-Fang Hwang , Zheyl Chen , James M. Tour
IPC分类号： C01B31/00 , C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/176 , C01B2202/02 , C01B2202/28
摘要： In some embodiments, the present invention relates to new processes to simultaneously shorten and functionalize raw or purified carbon nanotubes to improve their dispersity and processibility, and the short functionalized nanotubes that may be made by the processes. This present invention also relates to new compositions of matter using short functionalized carbon nanotubes with thermoset, thermoplastic polymers, high temperature polymers, and other materials; the processes for making such composite materials; and the products of said processes.
摘要翻译：在一些实施方案中，本发明涉及同时缩短和官能化原始或纯化的碳纳米管以提高其分散性和可加工性的新方法以及可通过该方法制备的短官能化纳米管。本发明还涉及使用具有热固性，热塑性聚合物，高温聚合物和其它材料的短官能化碳纳米管的物质的新组合物; 制造这种复合材料的方法; 和所述方法的产品。

52. 发明授权

US08273319B1 Enrichment of specific chirality single wall carbon nanotubes with genomic DNA 有权
标题翻译：用基因组DNA富集特异性手性单壁碳纳米管
公开(公告)号：US08273319B1
公开(公告)日：2012-09-25
申请号：US12843182
申请日：2010-07-26
申请人： Sang N. Kim , Rajesh R. Naik , James G. Grote , Barry L. Farmer
发明人： Sang N. Kim , Rajesh R. Naik , James G. Grote , Barry L. Farmer
IPC分类号： D01F9/12
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/172 , C01B32/174 , C01B2202/02
摘要： An improved method for enriched chirality of single wall carbon nanotubes is described. Genomic DNA, particularly salmon DNA (SaDNA) is shown to sort out single wall carbon nanotubes of specific chirality by a process of solubilization (dissolving in solution) and separation (such as centrifuging), without requiring more complex processes such as anion exchange chromatography. A possible reason for enhanced chirality separation using DNA may be attributed to its lowered GC (guanine-cytosine) content.
摘要翻译：描述了改进的单壁碳纳米管富集手性的方法。基因组DNA，特别是鲑鱼DNA（SaDNA）显示出通过溶解（溶解）和分离（如离心）的过程，整理出具有特定手性的单壁碳纳米管，而不需要更复杂的过程如阴离子交换色谱法。使用DNA增强手性分离的一个可能原因可归因于其降低的GC（鸟嘌呤 - 胞嘧啶）含量。

53. 发明申请

US20120237435A1 Mass Production of Carbon Nanostructures 审中-公开
标题翻译：大量生产碳纳米结构
公开(公告)号：US20120237435A1
公开(公告)日：2012-09-20
申请号：US13459755
申请日：2012-04-30
申请人： Viktor I. Petrik
发明人： Viktor I. Petrik
IPC分类号： D01F9/12 , B82Y30/00 , B82Y40/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02 , Y10S423/10 , Y10S977/734 , Y10S977/742 , Y10T428/2991
摘要： Carbon nanostructures are mass produced from graphite. In particularly preferred aspects, graphene is thermo-chemically derived from graphite and used in numerous compositions. In further preferred aspects, the graphene is re-shaped to form other nanostructures, including nanofractals, optionally branched open-ended SWNT, nanoloops, and nanoonions.
摘要翻译：碳纳米结构由石墨质量生产。在特别优选的方面，石墨烯由石墨热化学衍生并用于许多组合物中。在进一步优选的方面，石墨烯被重新形成以形成其他纳米结构，包括纳米分形，任选的支链开端SWNT，纳米环和纳米单体。

54. 发明授权

US08257678B2 Systems and methods related to the formation of carbon-based nanostructures 有权
标题翻译：与碳基纳米结构形成相关的系统和方法
公开(公告)号：US08257678B2
公开(公告)日：2012-09-04
申请号：US12847905
申请日：2010-07-30
申请人： Stephen A. Steiner, III , Brian L. Wardle
发明人： Stephen A. Steiner, III , Brian L. Wardle
IPC分类号： D01C5/00
CPC分类号： C01B32/16 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/18 , C01B32/186 , C01B2202/02 , C01B2202/06 , Y10S977/742 , Y10S977/842 , Y10S977/843
摘要： Systems and methods for the formation of carbon-based nanostructures are generally described. In some embodiments, the nanostructures may be formed on a nanopositor. The nanopositor can comprise, in some embodiments, at least one of metal atoms in a non-zero oxidation state and metalloid atoms in a non-zero oxidation state. For example, the nanopositor may comprise a metal oxide, a metalloid oxide, a metal chalcogenide, a metalloid chalcogenide, and the like. The carbon-based nanostructures may be grown by exposing the nanopositor, in the presence or absence of a growth substrate, to a set of conditions selected to cause formation of carbon-based nanostructures on the nanopositor. In some embodiments, metal or metalloid atoms in a non-zero oxidation state are not reduced to a zero oxidation state during the formation of the carbon-based nanostructures. In some cases, metal or metalloid atoms in a non-zero oxidation state do not form a carbide during the formation of the carbon-based nanostructures.
摘要翻译：通常描述用于形成碳基纳米结构的系统和方法。在一些实施方案中，纳米结构可以形成在纳米激光器上。在一些实施方案中，纳米导体可以包括非零氧化态的金属原子和非零氧化态的准金属原子中的至少一种。例如，纳米阳极剂可以包含金属氧化物，类金属氧化物，金属硫族化物，准金属硫族化物等。碳纳米结构可以通过在存在或不存在生长衬底的情况下将纳米孔体暴露于所选择的一系列条件来生长，所述条件被选择用于在纳米反应器上形成碳基纳米结构。在一些实施方案中，非零氧化态的金属或准金属原子在形成碳基纳米结构期间不会降低至零氧化态。在一些情况下，非零氧化态的金属或准金属原子在形成碳基纳米结构期间不形成碳化物。

55. 发明授权

US08246928B1 Methods and compositions for the separation of single-walled carbon nanotubes 有权
标题翻译：用于分离单壁碳纳米管的方法和组合物
公开(公告)号：US08246928B1
公开(公告)日：2012-08-21
申请号：US13078154
申请日：2011-04-01
申请人： Chintamani Nagesa Ramachandra Rao , Subi Jacob George , Rakesh Voggu , K. Venkata Rao
发明人： Chintamani Nagesa Ramachandra Rao , Subi Jacob George , Rakesh Voggu , K. Venkata Rao
IPC分类号： C09C1/56
CPC分类号： C09C1/56 , B82Y30/00 , B82Y40/00 , C01B32/172 , C01B2202/02 , C01B2202/10 , C01B2202/22 , C01P2002/82 , C01P2004/03 , C01P2004/13 , C01P2006/40 , C09C1/48
摘要： Embodiments herein describe a composition including at least one water-soluble complex having a water-soluble separation agent including a planar portion, at least one pi electron on the planar portion and at least one electron withdrawing group; and a semiconducting single-walled carbon nanotube in an aqueous solution. Further embodiments describe a method of separating metallic single-walled carbon nanotubes and semiconducting single-walled carbon nanotubes including providing carbon nanotubes having an admixture of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes; and combining the admixture with a water-soluble separation agent in an aqueous solution to form a mixture, in which the water-soluble separation agent includes a planar portion, at least one pi electron on the planar portion and at least one electron withdrawing group.
摘要翻译：本文的实施方案描述了包含至少一种具有水溶性分离剂的水溶性络合物的组合物，所述水溶性络合物包含平面部分，平面部分上至少一个π电子和至少一个吸电子基团; 和在水溶液中的半导体单壁碳纳米管。另外的实施方案描述了分离金属单壁碳纳米管和半导体单壁碳纳米管的方法，其包括提供具有半导体单壁碳纳米管和金属单壁碳纳米管的混合物的碳纳米管; 并将所述混合物与水溶性分离剂在水溶液中混合以形成其中水溶性分离剂包括平面部分，平面部分上的至少一个π电子和至少一个吸电子基团的混合物。

56. 发明授权

US08231854B2 Method for treating carbon nanotubes, carbon nanotubes and carbon nanotubes device comprising thereof 失效
标题翻译：用于处理碳纳米管的方法，碳纳米管和包含它们的碳纳米管装置
公开(公告)号：US08231854B2
公开(公告)日：2012-07-31
申请号：US12270026
申请日：2008-11-13
申请人： Hisashi Kajiura , Yongming Li , Xianglong Li , Yunqi Liu , Lingchao Cao , Lei Fu , Dacheng Wei , Yu Wang , Daoben Zhu
发明人： Hisashi Kajiura , Yongming Li , Xianglong Li , Yunqi Liu , Lingchao Cao , Lei Fu , Dacheng Wei , Yu Wang , Daoben Zhu
IPC分类号： D01F9/12 , C01B31/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , C01B2202/28 , H01M4/9083 , Y10S977/845
摘要： An efficient and cost-effective method for treating carbon nanotubes (CNTs) is provided. The method includes comprising: dispersing said carbon nanotubes in a dispersing medium to prepare a dispersion system; mixing said dispersion system with adsorbent so that type-specific carbon nanotubes contained in said dispersion system are absorbed onto the adsorbent, wherein the adsorbent is modified by a chemical/biological modifier so as to have different adsorption selectivity to carbon nanotubes of different types; and separating the adsorbent from the dispersion system, whereby the type-specific carbon nanotubes adsorbed onto the adsorbent is separated from the carbon nanotubes of another type enriched in the dispersion system; carbon nanotubes produced by the treatment method, and CNTs devices comprising thereof.
摘要翻译：提供了一种用于处理碳纳米管（CNT）的有效且经济有效的方法。该方法包括：将所述碳纳米管分散在分散介质中以制备分散系统; 将所述分散系统与吸附剂混合，使包含在所述分散系统中的型号碳纳米管被吸附到吸附剂上，其中吸附剂被化学/生物改性剂改性，以对不同类型的碳纳米管具有不同的吸附选择性; 从分散体系分离吸附剂，由此吸附在吸附剂上的特定类型的碳纳米管与分散系统中富集的另一种类型的碳纳米管分离; 通过处理方法制造的碳纳米管，以及包含它们的CNTs器件。

57. 发明申请

US20120164372A1 CARBON NANOTUBE FILM STRUCTURE 审中-公开
标题翻译：碳纳米管膜结构
公开(公告)号：US20120164372A1
公开(公告)日：2012-06-28
申请号：US13411691
申请日：2012-03-05
申请人： XUE-SHEN WANG , QUN-QING LI , KAI-LI JIANG , SHOU-SHAN FAN
发明人： XUE-SHEN WANG , QUN-QING LI , KAI-LI JIANG , SHOU-SHAN FAN
IPC分类号： B32B5/12 , B32B5/16 , B82Y99/00
CPC分类号： C01B31/0226 , B01J21/185 , B01J23/74 , B01J23/745 , B01J23/881 , B01J23/8906 , B01J37/0219 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/162 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/08 , C01B2202/34 , C01B2202/36 , C01P2004/13 , Y10S977/843 , Y10T428/24132 , Y10T428/249924
摘要： A carbon nanotube film structure includes at least one carbon nanotube film or at least two stacked carbon nanotube films. Each carbon nanotube film includes a plurality of carbon nanotubes parallel to the surface of the carbon nanotube film and parallel to each other. A length of the carbon nanotube is equal to or greater than 1 centimeter.
摘要翻译：碳纳米管膜结构包括至少一个碳纳米管膜或至少两个堆叠的碳纳米管膜。每个碳纳米管膜包括平行于碳纳米管膜的表面并且彼此平行的多个碳纳米管。碳纳米管的长度等于或大于1厘米。

58. 发明申请

US20120156124A1 Single Wall Carbon Nanotubes By Atmospheric Chemical Vapor Deposition 审中-公开
标题翻译：单壁碳纳米管通过大气化学气相沉积
公开(公告)号：US20120156124A1
公开(公告)日：2012-06-21
申请号：US12029856
申请日：2008-02-12
申请人： Amit Goyal , Iqbal Zafar
发明人： Amit Goyal , Iqbal Zafar
IPC分类号： D01F9/12 , B82B1/00 , B82B3/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02
摘要： The present disclosure provides for systems and methods for producing carbon nanotubes. More particularly, the present disclosure provides for improved systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using a carbon source in the presence of a catalyst. In exemplary embodiments, the present disclosure provides for improved systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using carbon monoxide (CO) disproportionation in the presence of a catalyst composition on a catalyst support material. In one embodiment, the present disclosure provides for systems and methods for producing single wall carbon nanotubes (SWNTs) by chemical vapor deposition (CVD) using carbon monoxide (CO) disproportionation with CO pressure from about 0.20 atm to about 1.0 atm in the presence of a cobalt/molybdenum catalyst composition on a magnesium oxide catalyst support.
摘要翻译：本公开提供了用于生产碳纳米管的系统和方法。更具体地，本公开提供了通过在催化剂存在下使用碳源的化学气相沉积（CVD）来制备单壁碳纳米管（SWNT）的改进的系统和方法。在示例性实施例中，本公开提供了在催化剂载体材料上的催化剂组合物存在下使用一氧化碳（CO）歧化，通过化学气相沉积（CVD）制备单壁碳纳米管（SWNT）的改进的系统和方法。在一个实施方案中，本公开提供了通过化学气相沉积（CVD）使用一氧化碳（CO）歧化制备单壁碳纳米管（SWNT）的系统和方法，其中CO压力为约0.20atm至约1.0atm，在氧化镁催化剂载体上的钴/钼催化剂组合物。

59. 发明申请

US20120148839A1 COMPOSITION CONTAINING SINGLE-WALLED NANOTUBES 有权
标题翻译：包含单壁纳米粒子的组合物
公开(公告)号：US20120148839A1
公开(公告)日：2012-06-14
申请号：US13399849
申请日：2012-02-17
申请人： Shigeo MARUYAMA , Masahito Yoshikawa
发明人： Shigeo MARUYAMA , Masahito Yoshikawa
IPC分类号： D01F9/12 , B32B9/00 , B82Y99/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02 , Y10S977/843 , Y10T428/2918
摘要： An atmosphere of a carbon source comprising an oxygenic compound is brought into contact with a catalyst with heating to yield single-walled carbon nanotubes. The carbon source comprising an oxygenic compound preferably is an alcohol and/or ether. The catalyst preferably is a metal. The heating temperature is preferably 500 to 1,500° C. The single-walled carbon nanotubes thus obtained contain no foreign substances and have satisfactory quality with few defects.
摘要翻译：使包含含氧化合物的碳源的气氛与加热的催化剂接触，得到单壁碳纳米管。包含含氧化合物的碳源优选为醇和/或醚。催化剂优选为金属。加热温度优选为500〜1500℃。由此得到的单壁碳纳米管不含异物，质量良好，缺陷少。

60. 发明申请

US20120082613A1 Method for Production of Carbon Nanotube and Method for Purification of the Same 有权
标题翻译：碳纳米管的制备方法及其纯化方法
公开(公告)号：US20120082613A1
公开(公告)日：2012-04-05
申请号：US13225888
申请日：2011-09-06
申请人： Yoshinori Ando , Xinluo Zhao , Sakae Inoue
发明人： Yoshinori Ando , Xinluo Zhao , Sakae Inoue
IPC分类号： D01F9/12 , B82Y40/00 , B82Y30/00
CPC分类号： C01B31/0233 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B32/17 , C01B2202/02
摘要： The present invention provides a method for producing a carbon nanotube having a high purity and a method for purifying an unpurified carbon nanotube or a carbon nanotube having a low purity. The method for producing a carbon nanotube comprises a step of providing a carbonaceous material containing a carbon nanotube and a step of adding an iron material and hydrogen peroxide to the carbonaceous material to thereby purity a carbon nanotube. It is preferred that an iron powder is used as the iron material. The iron powder is preferably used in a proportion of 0.5 to 20 parts by mass relative to 100 parts by mass of the whole carbonaceous material.
摘要翻译：本发明提供一种纯度高的碳纳米管的制造方法以及纯化碳纳米管或纯度低的碳纳米管的纯化方法。制造碳纳米管的方法包括提供含有碳纳米管的碳质材料和向碳质材料中添加铁物质和过氧化氢的步骤，从而纯化碳纳米管。优选使用铁粉作为铁材料。相对于100质量份的全部碳质材料，铁粉的使用比例优选为0.5〜20质量份。

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