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51. 发明申请

US20170021343A1 Catalysts and Related Processes For Producing Optically Pure Beta-Lactones From Aldehydes and Compositions Produced Thereby 有权
标题翻译：用于从由此产生的醛和组合物制造光学纯的β-内酯的催化剂和相关方法
公开(公告)号：US20170021343A1
公开(公告)日：2017-01-26
申请号：US15099995
申请日：2016-04-15
申请人： The University of Toledo
发明人： Yun-Ming Lin
IPC分类号： B01J31/22 , C07F15/06 , C07C253/30 , C07D305/12 , C07C231/14
CPC分类号： B01J31/2295 , B01J2231/345 , B01J2531/845 , C07C231/14 , C07C253/30 , C07D305/12 , C07D453/04 , C07F15/065
摘要： Bi-functional cobalt-containing catalysts useful for making stereospecific compounds and compositions, along with methods of making, and uses thereof in the syntheses of optically pure β-lactones from aldehydes and ketene are described. Precursors, intermediates, compositions, and particular features of the use if the compositions, such as high enantiomeric selectivity, high yield and low mole percent of catalyst useful are provided.
摘要翻译：描述了用于制备立体选择性化合物和组合物的双官能含钴催化剂及其制备方法及其在从醛和烯酮合成光学纯的β-内酯中的用途。提供了前体，中间体，组合物和使用的特定特征，如果组合物，例如高对映体选择性，高产率和低摩尔百分比的催化剂可用。

52. 发明授权

US09545624B2 Nickel containing hydrosilylation catalysts and compositions containing the catalysts 有权
标题翻译：含镍的氢化硅烷化催化剂和含有催化剂的组合物
公开(公告)号：US09545624B2
公开(公告)日：2017-01-17
申请号：US14232965
申请日：2012-09-20
申请人： Dow Corning Corporation
发明人： Kurt Brandstadt , Simon Cook , Aswini Dash , Matthew Olsen , Avril Surgenor , Richard Taylor , Binh Nguyen , Ming-Shin Tzou
IPC分类号： C07C213/08 , C07D413/14 , B01J31/22 , B01J31/02 , B01J31/24 , B01J37/00 , C07C209/66 , C07C217/92 , C07D213/32 , C07D213/38 , C07D213/53 , C07D215/12 , C07D271/06 , C07D295/135 , C07D307/52 , C07D333/22 , C07D413/10 , C07F1/00 , C07F1/08 , C07F3/06 , C07F7/00 , C07F7/08 , C07F7/18 , C07F9/50 , C07F9/60 , C07F11/00 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/06 , C08G77/08 , G07F13/00 , C09K3/00
CPC分类号： B01J31/2295 , B01J31/0272 , B01J31/22 , B01J31/24 , B01J31/2414 , B01J31/2433 , B01J37/00 , B01J2231/323 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/49 , B01J2531/56 , B01J2531/64 , B01J2531/74 , B01J2531/821 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C209/66 , C07C213/08 , C07C217/92 , C07D213/32 , C07D213/38 , C07D213/53 , C07D215/12 , C07D271/06 , C07D295/135 , C07D307/52 , C07D333/22 , C07D413/10 , C07D413/14 , C07F1/00 , C07F1/005 , C07F1/08 , C07F3/06 , C07F7/00 , C07F7/0805 , C07F7/0838 , C07F7/0872 , C07F7/0879 , C07F7/0889 , C07F7/0896 , C07F7/1804 , C07F7/1876 , C07F9/5045 , C07F9/60 , C07F11/005 , C07F13/00 , C07F13/005 , C07F15/0033 , C07F15/0046 , C07F15/02 , C07F15/065 , C08G77/08 , C09K3/00 , G07F13/00
摘要： A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
摘要翻译：组合物含有（A）氢化硅烷化反应催化剂和（B）具有每分子平均能够进行氢化硅烷化反应的一种或多种脂族不饱和有机基团的脂族不饱和化合物。组合物能够通过氢化硅烷化反应反应形成反应产物，例如硅烷，胶，凝胶，橡胶或树脂。成分（A）含有可以通过使金属前体和配体反应的方法制备的金属 - 配体络合物。

53. 发明授权

US09522925B2 Selective cancer tracking eradicator and the uses thereof 有权
标题翻译：选择性的癌症追踪根除及其用途
公开(公告)号：US09522925B2
公开(公告)日：2016-12-20
申请号：US14934140
申请日：2015-11-05
申请人： Hong Kong Baptist University
发明人： Ka-Leung Wong , Wai-Kwok Wong , Rongfeng Lan , Tao Zhang
IPC分类号： C07F5/00 , C07F15/06 , A61K41/00 , A61K49/00
CPC分类号： C07F5/00 , A61K41/0071 , A61K41/008 , A61K49/0036 , C07F15/06
摘要： The present invention discloses a new modality of photodynamic therapy (PDT) through the design of the present invention's truly dual-functional—PDT and imaging—gadolinium complex (Gd—N) with a molecular formula of: which can target cancer, cells specifically. The present invention provides a PDT drug that can specifically localize on the anionic cell membrane of cancer cells in which its laser-excited photoemission signal can be monitored without triggering the phototoxic generation of reactive oxygen species—singlet oxygen—prior to due excitation. The present invention also provides the use of Gd—N as a tumor selective PDT photosensitizer modality.

54. 发明申请

US20160348243A1 PROCESS FOR THE GENERATION OF THIN INORGANIC FILMS 审中-公开
标题翻译：无机薄膜生成工艺
公开(公告)号：US20160348243A1
公开(公告)日：2016-12-01
申请号：US15114666
申请日：2015-01-22
申请人： BASF SE
发明人： Ke XU , Christian SCHILDKNECHT , Jan SPIELMANN , Juergen FRANK , Florian BLASBERG , Daniel LOEFFLER , Martin GAERTNER , Sabine WEIGUNY , Kerstin SCHIERLE-ARNDT , Katharina FEDERSEL , Falko ABELS
IPC分类号： C23C16/455 , C07F15/06 , C07F15/04 , B01J13/00 , C07F3/00
CPC分类号： C23C16/45553 , C07F3/00 , C07F3/003 , C07F15/045 , C07F15/065
摘要： The present invention relates to a process for the generation of thin inorganic films on substrates, in particular an atomic layer deposition process. This process comprises bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R1, R2, R3, R4, R5, and R6 are independent of each other hydrogen, an alkyl group, or a trialkylsilyl group, n is an integer from 1 to 3, M is a metal or semimetal, 1 X is a ligand which coordinates M, and m is an integer from 0 to 4.

55. 发明授权

US09493404B2 Oxo-nitrogenated complex of cobalt, catalytic system comprising said oxo-nitrogenated complex and process for the (CO) polymerization of conjugated dienes 有权
标题翻译：钴的氧化氮化络合物，包含所述含氧氮化络合物的催化体系和共轭二烯的（CO）聚合方法
公开(公告)号：US09493404B2
公开(公告)日：2016-11-15
申请号：US14646051
申请日：2013-12-18
申请人： Versalis S.P.A.
发明人： Anna Sommazzi , Giovanni Ricci , Francesco Masi , Giuseppe Leone
IPC分类号： C08F4/42 , C08F36/06 , C08F136/06 , C07C251/08 , C07F15/06
CPC分类号： C07C251/08 , C07F15/065 , C08F36/06 , C08F136/06 , C08F4/7096
摘要： The present invention relates to an oxo-nitrogenated complex of cobalt having the general formula (I) wherein the residues R1, R2, R3, X1 and X2 are as defined in the claims. Said oxo-nitrogenated complex of cobalt having general formula (I) can be advantageously used in a catalytic system for the (co) polymerization of conjugated dienes.

56. 发明授权

US09469722B2 Metal cyanide complex catalyst and its preparation and application 有权
标题翻译：金属氰化物复合催化剂及其制备与应用
公开(公告)号：US09469722B2
公开(公告)日：2016-10-18
申请号：US14484490
申请日：2014-09-12
申请人： ZHEJIANG UNIVERSITY
发明人： Xinghong Zhang , Guorong Qi , Binyang Du , Renjian Wei , Xueke Sun
IPC分类号： C08G59/68 , C08F24/00 , C07F15/06 , C08G63/42 , C08G63/82 , C08G64/34 , C08G65/26
CPC分类号： C08G59/686 , C07F15/065 , C08F24/00 , C08G63/42 , C08G63/82 , C08G64/34 , C08G65/2663
摘要： A metal cyanide complex catalyst and its preparation and application are disclosed. The formula of this catalyst is M1a[M2(CN)bL1c]d(X)m(L2)n.xSu.yL3.zH2O and its preparation method comprises: (A) adjusting pH of a mixed solution I′ of L3, M3e[M2(CN)bL1c]f, de-ionized water I, alcohol and/or ether solvent to less than 7.0, and adding it into a mixed solution II′ of M1(X)g salt, Su or Su precursor, de-ionized water II, stirring for reaction under 20° C.-120° C. for 0.5-200 hours, separating and drying to obtain a solid product; and (B) repeatedly dispersing the solid into an anhydrous organic solvent containing L2 to form a slurry, distilling, separating and drying to obtain the metal cyanide complex catalyst. The catalyst is useful in preparing polyethers, polycarbonates and polyesters by homopolymerization of epoxides, or copolymerization of epoxides with carbon dioxide or anhydrides.
摘要翻译：公开了一种金属氰化物络合物催化剂及其制备和应用。该催化剂的配方为M1a [M2（CN）bL1c] d（X）m（L2）n.xSu.yL3.zH2O，其制备方法包括：（A）调节L3，M3e的混合溶液I' [M2（CN）bL1c] f，去离子水I，醇和/或醚溶剂至小于7.0，并将其加入M1（X）g盐，Su或Su前体的混合溶液II' 电离水II，在20〜120℃下搅拌反应0.5〜200小时，分离并干燥得到固体产物; 和（B）将固体重复分散在含有L2的无水有机溶剂中以形成浆料，蒸馏，分离和干燥，得到金属氰化物配合物催化剂。该催化剂可用于通过环氧化物的均聚或环氧化物与二氧化碳或酸酐的共聚制备聚醚，聚碳酸酯和聚酯。

57. 发明申请

US20160272761A1 CATALYSTS AND METHODS FOR POLYMER SYNTHESIS 有权
公开(公告)号：US20160272761A1
公开(公告)日：2016-09-22
申请号：US15171755
申请日：2016-06-02
申请人： Novomer, Inc.
发明人： Scott D. Allen , Gabriel Job , Jay J. Farmer
IPC分类号： C08G64/34 , B01J31/22 , C07F15/06
CPC分类号： C08G64/34 , B01J31/2217 , B01J2540/42 , C07F15/065 , C09B57/10
摘要： The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.

58. 发明授权

US09387468B2 Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation 有权
标题翻译：钴催化剂及其用于氢化硅烷化和脱氢甲硅烷基化的用途
公开(公告)号：US09387468B2
公开(公告)日：2016-07-12
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G. P. Delis , Renyuan Yu
IPC分类号： C07F15/06 , B01J21/06 , C07F7/18 , B01J31/22 , C08G81/02 , C07F7/08
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译：本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。钴配合物还表现出足够的空气稳定性用于处理和操作。

59. 发明授权

US09353437B2 Diazadiene-based metal compound, method for preparing same and method for forming a thin film using same 有权
标题翻译：二亚乙基基金属化合物，其制备方法以及使用其形成薄膜的方法
公开(公告)号：US09353437B2
公开(公告)日：2016-05-31
申请号：US13885740
申请日：2011-11-17
申请人： Won Seok Han
发明人： Won Seok Han
IPC分类号： C23C16/18 , C07F13/00 , C07F15/04 , C07F15/06 , C23C16/06 , C23C16/40
CPC分类号： C23C16/18 , C07F13/005 , C07F15/045 , C07F15/065 , C23C16/06 , C23C16/406
摘要： The present invention relates to a diazadiene (DAD)-based metal compound, to a method for preparing the same and to a method for forming a thin film using the same. The diazadiene (DAD)-based metal compound of the present invention is provided in a gaseous state to be formed into a metal thin film or a metal oxide thin film by chemical vapor deposition or atomic layer deposition. Particularly, the diazadiene-based organic metal compound of the present invention has advantages in that it may be formed into a metal thin film or a metal oxide thin film and it can be prepared in a relatively inexpensive way without using highly toxic ligands.
摘要翻译：本发明涉及基于二亚甲基二（DAD）的金属化合物及其制备方法以及使用其制备薄膜的方法。本发明的二氮二烯（DAD）类金属化合物以气态提供，通过化学气相沉积或原子层沉积形成金属薄膜或金属氧化物薄膜。特别地，本发明的二硫化二烯类有机金属化合物具有以下优点：其可以形成为金属薄膜或金属氧化物薄膜，并且可以以相对便宜的方式制备而不使用高毒性配体。

60. 发明授权

US09290529B2 Carbonic anhydrase inhibitors and method of their production 有权
标题翻译：碳酸酐酶抑制剂及其生产方法
公开(公告)号：US09290529B2
公开(公告)日：2016-03-22
申请号：US14352210
申请日：2012-10-24
申请人： USTAV ORGANICKE CHEMIE A BIOCHEMIE AKADEMIE VED CESKE REPUBLIKY, v.v.i. , USTAV MOLEKULARNI GENETIKY AKADEMIE VED CESKE REPUBLIKY, v.v.i. , USTAV ANORGANICKE CHEMIE AKADEMIE VED CESKE REPUBLIKY, v.v.i. , UNIVERZITA PALACKEHO V OLOMOUCI
发明人： Jiri Brynda , Petr Cigler , Bohumir Gruner , Pavlina Maloy Rezacova , Pavel Mader , Vaclav Sicha , Mario Bakardjiev , Josef Holub , Petr Dzubak , Marian Hajduch
IPC分类号： C07F15/02 , C07F5/05 , C07F15/06 , C07F5/02
CPC分类号： C07F15/06 , C07F5/027 , C07F5/05 , C07F15/02
摘要： Derivatives of boron cluster compounds of general formula I and their pharmaceutically acceptable salts and solvates, and their specific inhibition effect on the enzyme carbonic anhydrase IX, a protein overexpressed in cancer tissues. Methods of synthesis and the use of the novel derivatives. These inhibitors of human carbonic anhydrase IX can be used as active compounds of pharmaceuticals for diagnostics and/or therapy of cancer diseases.
摘要翻译：通式I的硼簇化合物的衍生物及其药学上可接受的盐和溶剂合物，以及它们对酶碳酸酐酶IX（一种在癌组织中过表达的蛋白质）的特异性抑制作用。合成方法和新型衍生物的应用。人类碳酸酐酶IX的这些抑制剂可以用作用于诊断和/或治疗癌症疾病的药物的活性化合物。

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