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    • 52. 发明授权
    • Compound cell for high-temperature electrochemical reactions
    • 用于高温电化学反应的复合电池
    • US4174260A
    • 1979-11-13
    • US950364
    • 1978-10-11
    • Rainer Schmidberger
    • Rainer Schmidberger
    • B01J19/08C25B9/00C25B9/04C25B9/06H01M8/243H01M12/00H01M8/12
    • H01M8/243C25B9/04H01M12/00C02F2201/003
    • A compound cell for performing an electrochemical reaction at high temperature consists essentially of hollow, cylindrical bodies of a ceramic electrolyte, rings of an electronically conductive material coaxially interposed between each pair of electrolyte bodies, annular layers of ceramic insulating material bonding each ring to at least one of the two adjacent electrolyte bodies, the bodies, rings, and annular layers being diffusion welded to each other to form a cylindrical, gas-tight tube. A pair of electrode layers is associated with each electrolyte body, one layer of the pair covering the associated body inside the tube and conductively engaging one of the two adjacent rings, the other electrode layer of the pair covering the associated body outside the tube and conductively engaging the other adjacent ring.
    • 用于在高温下进行电化学反应的复合电池基本上由陶瓷电解质的中空的圆柱体组成,同时插在每对电解质体之间的电子导电材料的环,将每个环至少粘合的环形陶瓷绝缘材料层 两个相邻的电解质体之一,主体,环和环形层彼此扩散焊接以形成圆柱形的气密管。 一对电极层与每个电解质体相关联,该层中的一层覆盖管内的相关体,并导电地接合两个相邻的环中的一个,另一个电极层覆盖管外的相关体并且导电 接合另一个相邻的环。
    • 53. 发明授权
    • Electrochemical generator comprising an electrode in the form of a
suspension
    • 电化学发生器包括悬浮液形式的电极
    • US4126733A
    • 1978-11-21
    • US826700
    • 1977-08-22
    • Denis Doniat
    • Denis Doniat
    • H01M8/22H01M12/00H01M8/08
    • H01M12/00H01M8/225
    • A separator free electrochemical generator wherein one of the electrodes, particularly the anode, is formed of a particulate active material suspended within an electrolyte and which comprises means for causing the circulation of the suspension formed within the corresponding electrode compartment in contact with a current collector, wherein further the active material forms a coating on cores formed of an inert material, the separation of the opposite electrode compartments being achieved by the collector itself which is provided with holes having sizes sufficient for authorizing the free passage of the electrolyte, however lower than the size of the inert cores of said particles.
    • 一种无分离器的电化学发生器,其中电极中的一个,特别是阳极由悬浮在电解质内的颗粒活性材料形成,并包括用于使形成在相应的电极室内的悬浮液与集电器接触的装置, 其中所述活性材料还形成由惰性材料形成的芯上的涂层,所述相对电极隔室的分离由集电器本身实现,所述收集器本身设置有具有足以授权电解质自由通过的尺寸的孔,然而低于 所述颗粒的惰性芯的尺寸。
    • 54. 发明授权
    • Electrochemical generators with a sedimentation bed and divergent feed
    • 具有沉淀床和发散饲料的电化学发生器
    • US4101717A
    • 1978-07-18
    • US821759
    • 1977-08-04
    • Pierre Durand
    • Pierre Durand
    • H01M8/04H01M8/00H01M8/22H01M12/00H01M12/04
    • H01M8/00H01M12/00Y02P70/56
    • A process for the production of electric current in an electrochemical generator comprising a cell having a compartment contaning a liquid electrolyte, the surface of the lower face of the compartment being formed by all or part of the surface of an electron collector arranged on the electrolyte side, this process consisting in creating a flow through the compartment of the electrolyte containing active solid particles or solid particles transporting an active material, the density of the particles being greater than the density of the electrolyte, is characterized by the fact that a divergence of the streamlines of the flow is brought about before the flow penetrates into the compartment and by the fact that the particles move within the compartment in the form of a sedimentation bed which is contiguous to the surface of the lower face and substantially homogeneous over the entire width of the lower face, the sedimentation bed being entrained by the electrolyte.
    • 一种用于在电化学发生器中产生电流的方法,包括具有包含液体电解质的室的电池,所述隔室的下表面由布置在电解质侧上的电子收集器的全部或部分表面形成 ,该方法包括产生通过电解质室的流动,其中含有活性固体颗粒或输送活性材料的固体颗粒,颗粒的密度大于电解质的密度,其特征在于以下事实: 在流动进入隔室之前产生流动的流线,以及颗粒以沉积床的形式在隔室内移动的事实,该沉降床与下表面的表面相邻并且在整个宽度上基本均匀 下表面,沉积床被电解质夹带。