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    • 65. 发明授权
    • Low-shrink polypropylene tape fibers comprising high amounts of nucleating agents
    • 包含大量成核剂的低收缩聚丙烯带纤维
    • US06887567B2
    • 2005-05-03
    • US10286622
    • 2002-11-02
    • Brian G. MorinMartin E. CowanJack A. Smith
    • Brian G. MorinMartin E. CowanJack A. Smith
    • D01D5/42D01F1/10D01F6/06D01F6/00
    • D01D5/426B29K2023/12B29K2223/12D01F1/10D01F6/06Y10T428/2913Y10T428/2964Y10T428/2967Y10T442/3976
    • Improvements in preventing heat- and moisture-shrink problems in specific polypropylene tape fibers are provided. Such tape fibers are basically manufactured through the initial production of polypropylene films or tubes which are then slit into very thin, though flat (and having very high cross sectional aspect ratios) tape fibers thereafter. These inventive tape fibers (and thus the initial films and/or tubes) require the presence of relatively high amounts of certain compounds that quickly and effectively provide rigidity to the target polypropylene tape fiber. Generally, these compounds include any structure that nucleates polymer crystals within the target polypropylene after exposure to sufficient heat to melt the initial pelletized polymer and allowing such an oriented polymer to cool. The compounds must nucleate polymer crystals at a higher temperature than the target polypropylene without the nucleating agent during cooling. In such a manner, the “rigidifying” nucleator compounds provide nucleation sites for polypropylene crystal growth. Subsequent to slitting the initial film and/or tube, the fiber is then exposed to sufficient heat to grow the crystalline network, thus holding the fiber in a desired position. The preferred “rigidifying” compounds include dibenzylidene sorbitol based compounds, as well as less preferred compounds, such as [2.2.1]heptane-bicyclodicarboxylic acid, otherwise known as HPN-68, sodium benzoate, certain sodium and lithium phosphate salts [such as sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl)phosphate, otherwise known as NA-11]. Specific methods of manufacture of such inventive tape fibers, as well as fabric articles made therefrom, are also encompassed within this invention.
    • 提供了防止特定聚丙烯带纤维中的热收缩和水分收缩问题的改进。 这种带状纤维基本上通过初始生产聚丙烯膜或管制成,然后将其切割成非常薄的(但具有非常高的截面长宽比)的带状纤维。 这些本发明的带状纤维(和因此初始膜和/或管)需要相对高量的某些化合物的存在,其快速且有效地为目标聚丙烯带纤维提供刚性。 通常,这些化合物包括在暴露于足够的热量以熔化初始颗粒聚合物并允许这种取向聚合物冷却之后使目标聚丙烯中的聚合物晶体成核的任何结构。 在冷却期间,化合物必须在比没有成核剂的目标聚丙烯更高的温度下使聚合物晶体成核。 以这种方式,“硬化”成核剂化合物提供聚丙烯晶体生长的成核位点。 在切割初始膜和/或管之后,然后将纤维暴露于足够的热量以生长结晶网络,从而将纤维保持在期望的位置。 优选的“硬化”化合物包括二亚苄基山梨醇基化合物,以及较不优选的化合物,例如[2.2.1]庚烷 - 双环二羧酸,另外称为HPN-68,苯甲酸钠,某些钠和磷酸锂盐[例如 2,2'-亚甲基 - 双 - (4,6-二叔丁基苯基)磷酸钠,另外称为NA-11]。 制造这种本发明的带状纤维的具体方法以及由其制成的织物制品也包括在本发明内。
    • 67. 发明授权
    • Ferroelectric fibers and applications therefor
    • 铁电纤维及其应用
    • US06858551B1
    • 2005-02-22
    • US09267973
    • 1999-03-12
    • Leonid Anthony TurkevichDavid Lewis Myers
    • Leonid Anthony TurkevichDavid Lewis Myers
    • B01D39/16C08K3/00D01F1/10D01F6/04D01F6/06D01F8/00D01F8/06D04H1/42B32B27/18A62B18/02
    • D01F8/06B01D39/1623C08K3/10D01F1/10D01F6/04D01F6/06D01F8/00D04H1/4291D04H1/4382Y10T428/2913Y10T428/2927Y10T428/2929Y10T428/2967Y10T442/693Y10T442/696
    • A fiber which includes a thermoplastic polymer and particles of a ferroelectric material dispersed therein. The thermoplastic polymer may be, for example, a polyolefin, such as polypropylene or polyethylene, and the ferroelectric material may be barium titanate. The ferroelectric material may be present at a level of from about 0.01 to about 50 percent by weight (from about 0.001 to about 13 percent by volume), and will have a longest dimension in a range of from about 10 nanometers to about 10 micrometers. The fiber may be exposed to an electric field. A plurality of the fibers may be employed to form a knitted or woven fabric or a nonwoven web. Also provided is a method of preparing fibers containing particles of a ferroelectric material. The method includes destructuring the ferroelectric material in the presence of a liquid and a surfactant to give destructured particles; the liquid is a solvent for the surfactant and the surfactant is adapted to stabilize the destructured particles against agglomeration. A blend of the stabilized, destructured ferroelectric material particles and a thermoplastic polymer then is formed and extruded to form fibers. The extruded fibers may be collected on a moving foraminous support to form a nonwoven web and, if desired, may be exposed to an electric field. The fiber of the present invention, especially when in the form of a nonwoven web, is especially suited as a filtration medium. For example, the nonwoven web may be adapted to remove particulate matter from a gaseous stream.
    • 包含热塑性聚合物的纤维和分散在其中的铁电体的颗粒。 热塑性聚合物可以是例如聚烯烃,例如聚丙烯或聚乙烯,铁电材料可以是钛酸钡。 铁电材料可以以约0.01至约50重量%(约0.001至约13体积%)的水平存在,并且将具有在约10纳米至约10微米范围内的最长尺寸。 光纤可能暴露于电场。 可以使用多根纤维来形成针织或机织织物或非织造纤维网。 还提供了制备含有铁电材料颗粒的纤维的方法。 该方法包括在存在液体和表面活性剂的情况下破坏铁电材料以产生结构破坏的颗粒; 液体是用于表面活性剂的溶剂,并且表面活性剂适于稳定破坏的颗粒以防止团聚。 然后形成并挤出稳定的,结构化的铁电材料颗粒和热塑性聚合物的混合物以形成纤维。 挤出的纤维可以在移动的多孔载体上收集以形成非织造纤维网,并且如果需要,可以暴露于电场。 本发明的纤维,特别是以非织造纤维网的形式,特别适合作为过滤介质。 例如,非织造纤维网可以适于从气流中除去颗粒物质。