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    • 73. 发明授权
    • Mold release composition, mixtures containing this mold release
composition, a process for the production of molded articles and the
molded articles obtained by this process
    • 脱模组合物,含该脱模组合物的混合物,制造模制品的方法和通过该方法获得的模塑制品
    • US4766172A
    • 1988-08-23
    • US76431
    • 1987-07-21
    • Christian WeberPeter Haas
    • Christian WeberPeter Haas
    • B29C33/60C08G18/32C08G18/50C08K5/098C08K5/16C08K5/17C10M105/00C10M105/60C10N10/04C10N40/36C08G18/30
    • C08K5/16C08K5/098C08K5/17
    • The present invention is directed to mold release compositions based on a solution which is liquid at room temperature and contains(i) at least one zinc salt of a straight or branched chain, saturated or unsaturated aliphatic carboxylic acid containing 8 to 24 carbon atoms in(ii) at least one organic compound containing tertiary nitrogen atoms which is liquid at room temperature,the zinc salt being present in a quantity of about 10 to 75% by weight, based on the total weight of the composition, characterized in that component (ii) is based on at least one compound corresponding to the formula ##STR1## wherein R', R", R"' and R.sup.iv, which may be identical or different, denote alkyl group containing 1 to 4 carbon atoms or any two of the groups R' and R" or R"' and R.sup.iv may combine with the nitrogen atom to form a 6-membered heterocyclic ring optionally containing an oxygen atom or an alkyl substituted nitrogen atom as hetero atom and having a total of 4 or 5 carbon atoms,R denotes hydrogen or a group of the formula--(CH.sub.2).sub.o --NH.sub.2 andm, n and o denote identical or different integers with values from 2 to 6.The present invention is also directed to a mixture suitable for use as a reactant for polyisocyanates containing isocyanate-reactive groups and the mold release composition described above. Finally, the present invention is directed to a process for the production of a elastomeric molded article having a nonporous surface by reacting a polyisocyanate with the previously described mixture containing isocyanate-reactive groups and to the molded articles produced by the process.
    • 本发明涉及基于在室温下为液体的溶液的脱模组合物,其包含(i)至少一种在((i)中含有8或24个碳原子的直链或支链饱和或不饱和脂族羧酸的锌盐, ii)至少一种含有叔氮原子的有机化合物,其在室温下为液体,所述锌盐以组合物的总重量计约10至75重量%的量存在,其特征在于组分(ii )基于至少一种对应于式“IMAGE”的化合物,其中R',R“,R”'和Riv可以相同或不同,表示含有1至4个碳原子的烷基或任何两个 基团R'和R“或R”'和R w可以与氮原子结合形成任选地含有氧原子或烷基取代的氮原子作为杂原子的6元杂环,并且总共具有4或 5个碳原子,R表示hy 氢或式 - (CH 2)o -NH 2的基团,m,n和o表示相同或不同的整数,其值为2-6。本发明还涉及适合用作多异氰酸酯的反应物的混合物,其含有 异氰酸酯反应性基团和上述脱模组合物。 最后,本发明涉及生产具有无孔表面的弹性体模塑制品的方法,所述弹性体模塑制品通过使多异氰酸酯与前述含有异氰酸酯反应性基团的混合物和通过该方法制备的模塑制品反应而制备。