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71. 发明授权

US07132576B2 Method for isomerizing allyl alcohols 有权
标题翻译：烯丙醇异构化方法
公开(公告)号：US07132576B2
公开(公告)日：2006-11-07
申请号：US10497523
申请日：2002-12-04
申请人： Frank Haese , Klaus Ebel
发明人： Frank Haese , Klaus Ebel
IPC分类号： C07C35/00 , C07C29/00
CPC分类号： B01J31/1805 , B01J31/183 , B01J31/2243 , B01J31/34 , B01J2231/52 , B01J2531/66 , C07C29/56 , C07C33/03 , C07C33/02
摘要： The present invention relates to a process for isomerizing reactant allyl alcohols of the formula (I) to product allyl alcohols of the general formula (II) where R1 to R5 are each hydrogen or a mono- or polyunsaturated or saturated C1–C12-alkyl radical, which can be substituted or unsubstituted, in both directions of the equilibrium, which comprises isomerizing in the presence of a dioxotungsten(VI) complex of the general formula (III), where L1, L2 are each independently a ligand selected from the group consisting of the aminoalcohols, the aminophenols and mixtures thereof, m, n are each 1 or 2, new dioxotungsten(VI) complexes, and also their use.
摘要翻译：本发明涉及将通式（I）的反应物烯丙醇异构化制备成通式（II）的烯丙醇的方法，其中R 1至R 5各自为氢或单或多不饱和或饱和的C 1 可以在平衡的两个方向上取代或未取代的烷基，其包括在通式（III）的二氧六唑（VI）络合物存在下异构化），其中L 1，L 2 2各自独立地为选自氨基醇，氨基苯酚及其混合物的配体，m，n各自为1或2个，新二氧六锇（VI）配合物，以及它们的用途。

72. 发明授权

US07098166B2 Catalyst for preparing fluorine-containing alcohol compound and a process for preparation of fluorine-containing alcohol compound 失效
公开(公告)号：US07098166B2
公开(公告)日：2006-08-29
申请号：US11028327
申请日：2005-01-04
申请人： Toshiyuki Katsube , Yuuki Matsuda , Jun Miki
发明人： Toshiyuki Katsube , Yuuki Matsuda , Jun Miki
IPC分类号： B01J31/00 , C07C27/00 , C07C29/00
CPC分类号： B01J29/85 , B01J29/064 , B01J29/072 , B01J29/83 , C07C29/124 , C07C31/38
摘要： A process for preparing a fluorine-containing alcohol compound, the process comprising the step of reacting water with a halogenated fluorine compound in the presence of a catalyst for preparing a fluorine-containing alcohol compound, the catalyst obtained by supporting an ammine complex containing at least one component selected from the group consisting of the elements in Group 1B, Group 2B, Group 6A, Group 7A and Group 8 of the periodic table on at least one complex oxide selected from the group consisting of Si—Al complex oxides, Al—P complex oxides and Si—Al—P complex oxides.

73. 发明授权

US07030281B2 Synthesis of 3,3,-dimethylbutyraldehyde by the reduction of 3,3,-dimethylbutyric acid 失效
标题翻译：通过还原3,3'-二甲基丁酸合成3,3'-二甲基丁醛
公开(公告)号：US07030281B2
公开(公告)日：2006-04-18
申请号：US10390846
申请日：2003-03-18
申请人： Indra Prakash , Robert L. Augustine , Setrak K. Tanielyan
发明人： Indra Prakash , Robert L. Augustine , Setrak K. Tanielyan
IPC分类号： C07C45/29 , C07C29/00
CPC分类号： C07C45/41 , C07C47/02
摘要： A process for the production of 3,3-dimethylbutyraldehyde is disclosed. The 3,3-dimethylbutyraldehyde is obtained by the reduction of 3,3-dimethylbutyric acid using trimethylacetic anhydride and a phosphine. The 3,3-dimethylbutyric acid is preferably obtained by a process in which tert-butanol and vinylidene chloride are reacted in the presence of sulfuric acid. The disclosed process has improved cost and yield.
摘要翻译：公开了一种制备3,3-二甲基丁醛的方法。通过使用三甲基乙酸酐和膦还原3,3-二甲基丁酸得到3,3-二甲基丁醛。 3,3-二甲基丁酸优选通过在硫酸存在下使叔丁醇和偏二氯乙烯反应的方法获得。所公开的方法具有改善的成本和产量。

74. 发明授权

US06919488B2 Process for producing saleable liquids from organic material 失效
标题翻译：从有机材料生产可销售液体的方法
公开(公告)号：US06919488B2
公开(公告)日：2005-07-19
申请号：US10441273
申请日：2003-05-20
申请人： Larry Jack Melnichuk , Karen Venita (Sue) Kelly
发明人： Larry Jack Melnichuk , Karen Venita (Sue) Kelly
IPC分类号： B01D53/56 , B01D53/62 , B01D53/73 , C01B3/12 , C01B3/22 , C07C29/00 , C07C29/32 , C07C33/08
CPC分类号： C07C29/1518 , B01D53/56 , B01D53/62 , B01D53/73 , C01B3/12 , C01B3/22 , C01B2203/06 , C01B2203/061 , C07C29/00 , C07C29/32 , Y02A50/2345 , Y02C10/04 , Y02E50/343 , Y02P20/152 , C07C31/04 , C07C31/08
摘要： A process for producing saleable liquids from organic material comprising the following steps. Providing organic material and separating it into solids, liquids and vapor. Reacting the liquids, combining it with water vapor and producing a volatized gas stream. Removing nitrogen dioxide from the gas stream to produce a scrubbed volatized gas stream. Reacting the scrubbed volatized gas stream with water vapor to produce a combined volatized gas stream. Removing carbon dioxide from the combined volatized gas stream to produce a subtracted volatized gas stream. Reacting the subtracted volatized gas stream with methanol to produce an enhanced volatized gas stream. Distilling the enhanced volatized gas stream to produce ethanol.
摘要翻译：一种从有机材料制备可售液体的方法，包括以下步骤。提供有机材料并将其分离成固体，液体和蒸气。使液体反应，将其与水蒸气结合并产生挥发的气流。从气流中除去二氧化氮以产生洗涤的挥发气流。用水蒸汽使洗涤的挥发气流反应以产生组合的挥发气流。从组合的挥发气流中除去二氧化碳以产生减去的挥发气流。用甲醇反应减去的挥发气流，产生增强的挥发气流。蒸馏增强的挥发气流产生乙醇。

75. 发明申请

US20050043541A1 Metal complexes useful in metathesis and other reactions 有权
标题翻译：用于复分解和其他反应的金属络合物
公开(公告)号：US20050043541A1
公开(公告)日：2005-02-24
申请号：US10894308
申请日：2004-07-19
申请人： Francis Walter , Bob Clercq
发明人： Francis Walter , Bob Clercq
IPC分类号： C07D321/00 , B01J31/28 , C07B61/00 , C07C4/10 , C07C6/04 , C07C13/12 , C07C13/20 , C07C29/00 , C07C35/06 , C07C229/12 , C07C251/24 , C07F1/00 , C07F1/08 , C07F7/28 , C07F9/00 , C07F9/40 , C07F9/572 , C07F11/00 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F19/00 , C08F2/38 , C08F4/00 , C08F4/40 , C08F4/72 , C08G61/08
CPC分类号： C07F15/0053 , B01J31/1633 , B01J31/2243 , B01J31/2265 , B01J31/2404 , B01J2231/125 , B01J2231/543 , B01J2531/0288 , B01J2531/821 , C07B2200/11 , C07F15/0046 , C08F4/7022 , C08F12/08 , C08F220/18 , C08F2438/01 , C08G61/08 , C08G2261/3322 , C08G2261/3324 , C08G2261/418 , C08G2261/419 , C08F212/08
摘要： This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.
摘要翻译：本发明提供金属络合物，其用作复分解反应中的催化剂组分，以及涉及将原子或基团转移到烯属或炔属不饱和化合物或其它反应性底物的反应中，并且关于其亚类，用于聚合 α-烯烃和任选的共轭二烯，在中等温度下具有高活性。它还提供了通过活性反应获得具有非常窄的分子量分布的聚合物的方法。它还提供了制备所述金属络合物和涉及这些方法的新型中间体的方法。它还提供了适合于与载体共价键合的所述金属络合物的衍生物，这种共价键的产物可用作多相催化反应的负载型催化剂。它还提供了二烯丙基化合物的吡咯，呋喃和噻吩化合物的直接一步合成。

76. 发明授权

US06852899B2 Process for producing isobutylene and methanol 有权
标题翻译：制备异丁烯和甲醇的方法
公开(公告)号：US06852899B2
公开(公告)日：2005-02-08
申请号：US10173415
申请日：2002-06-18
申请人： Masanobu Yamase , Yoshiaki Suzuki
发明人： Masanobu Yamase , Yoshiaki Suzuki
IPC分类号： C07C29/10 , C07B61/00 , C07C1/20 , C07C7/04 , C07C7/10 , C07C11/09 , C07C29/00 , C07C29/09 , C07C29/74 , C07C29/80 , C07C29/86 , C07C31/04 , C07C1/213
CPC分类号： C07C29/74 , C07C1/20 , C07C29/00 , C07C11/09 , C07C31/04
摘要： A process for producing isobutylene and methanol comprising: a first step of subjecting methyl-tert-butyl ether to decomposition in the presence of a catalyst to obtain a reaction liquid; a second step of washing the resultant with water to separate the reaction liquid into an oil layer and an aqueous layer; a third step of subjecting the oil layer to distillation to obtain a fraction containing isobutylene and a dialkyl ether from the top of a distillation column, a fraction containing methyl-tert-butyl ether and the heavy components from the bottom of the column and a fraction containing methyl-tert-butyl ether from a side cut of the column, and recycling the side cut fraction to the first step; and a fourth step of subjecting the aqueous layer to distillation to obtain a fraction containing methanol from the top of a distillation column and a fraction containing water from the bottom of the column.
摘要翻译：一种制备异丁烯和甲醇的方法，包括：在催化剂存在下使甲基叔丁基醚分解以获得反应液体的第一步骤; 用水洗涤所得物以将反应液分离成油层和水层的第二步骤; 第三步是从蒸馏塔的顶部进行蒸馏以获得含有异丁烯和二烷基醚的馏分，含有甲基叔丁基醚的馏分和来自塔底部的重组分，以及馏分从所述塔的侧馏分中含有甲基叔丁基醚，并将所述侧馏分再循环到所述第一步骤; 以及第四步骤，从蒸馏塔的顶部和从塔的底部含有水的馏分进行蒸馏以获得含有甲醇的馏分。

77. 发明申请

US20010020112A1 Process for preparing (hetero) aromatic substituted benzene derivatives 失效
标题翻译：制备（杂）芳族取代苯衍生物的方法
公开(公告)号：US20010020112A1
公开(公告)日：2001-09-06
申请号：US09841313
申请日：2001-04-24
发明人： Tetsuya Toya , Hidetoshi Shirakura , Junichi Kon
IPC分类号： C07C29/00
CPC分类号： C07D213/55 , C07C67/307 , C07C67/317 , C07C2601/16 , C07C69/753 , C07C69/76
摘要： Three processes are described for preparing (hetero)aromatic substituted benzene derivatives which comprise aromatization of cyclohexenone derivatives via (chloro)cyclohexadiene derivatives.
摘要翻译：描述了三种制备（杂）芳族取代的苯衍生物的方法，其包括通过（氯）环己二烯衍生物的环己烯酮衍生物的芳构化。

78. 发明授权

US6137017A Methanol process for natural gas conversion 有权
标题翻译：用于天然气转化的甲醇工艺
公开(公告)号：US6137017A
公开(公告)日：2000-10-24
申请号：US361949
申请日：1999-07-27
申请人： John E. Stauffer
发明人： John E. Stauffer
IPC分类号： C07C17/04 , C07C17/087 , C07C29/00 , C07C29/124 , C07C29/50 , C07L27/00
CPC分类号： C07C17/087 , C07C17/04 , C07C29/00 , C07C29/124 , C07C29/50
摘要： A process is provided for producing methyl alcohol from natural gas using chlorination technology. The process includes reacting methyl chloride, hydrogen chloride, oxygen and perchloroethylene in a catalytic reactor to give methanol product and hexachloroethane and using the C.sub.2 Cl.sub.6 to chlorinate methane of natural gas feedstock in multiple thermal chlorination reactors, each with a natural gas recycle loop. These reactors are arranged in a cross-flow reactor system whereby a gas purge from the first reactor is fed to the second, and so on if necessary until a last reactor, which is vented to the atmosphere by feeding a purge steam to the catalytic reactor.
摘要翻译：提供了一种使用氯化技术从天然气生产甲醇的方法。该方法包括使甲基氯，氯化氢，氧和全氯乙烯在催化反应器中反应，得到甲醇产物和六氯乙烷，并使用C2Cl6在多个热氯化反应器中对天然气原料甲烷进行氯化，每个反应器具有天然气循环回路。这些反应器设置在交叉流反应器系统中，由此将来自第一反应器的气体吹扫进料至第二反应器，并且如果需要，等等，直到最后一个反应器，其通过将净化蒸汽送入催化反应器而排放到大气中。

79. 发明授权

US6008417A Process for making metabolites of lycopene 失效
公开(公告)号：US6008417A
公开(公告)日：1999-12-28
申请号：US168143
申请日：1998-10-07
申请人： Hanspeter Pfander , Bruno Traber
发明人： Hanspeter Pfander , Bruno Traber
IPC分类号： C07C27/02 , A61P43/00 , C07C29/00 , C07C29/32 , C07C29/36 , C07C29/44 , C07C29/46 , C07C33/12 , C07C35/06 , C07C45/68 , C07C47/02 , C07C47/198 , C07C47/21 , C07C47/267 , C07C49/105 , C07C49/203 , C07C49/24 , C07C67/02 , C07C67/29 , C07C69/02 , C07C69/14 , C07C69/16 , C07F7/04 , C07F7/08 , C07F7/18 , C07F9/28 , C07F9/54
CPC分类号： C07C29/32 , C07C35/06 , C07C45/68 , C07C47/267 , C07C67/29 , C07F9/5435 , C07B2200/07 , C07C2101/08
摘要： The invention is concerned with a multi-stage process for making an oxidative metabolite of the carotenoid lycopene, 2,6-cyclolycopene-1,5-diol having the formula ##STR1## In this process .alpha.-terpinyl acetate is oxidatively dihydroxylated to a cyclohexanediol (IV), the cyclohexanediol (IV) is oxidatively cleaved to a ketoaldehyde (V), the ketoaldehyde (V) is subjected to an intramolecular aldol condensation to give a cyclopentanol (VI), the cyclopentanol (VI) is silylated to its silylated derivative formylcylopentane (VII), the formylcyclopentane (VII) is subjected to a C.sub.3 -chain lengthening with acetone and simultaneously to a saponification for the cleavage of the acetyl group to give a cyclopentylbutenone (VIII), the cyclopentylbutenone (VIII) is reacted with vinyl magnesium bromide to give a pentadienol (IX), the pentadienol (IX) is converted with deprotection of the silylated hydroxy group into a phosphonium salt (X), this salt is subjected to a Wittig reaction with 2,7-dimethyl-2,4,6-octatriene-1,8-dial to give a tridecahexaenal (XII) and the tridecahexaenal (XII) is subjected to a Wittig reaction with a (3,7,11-trimethyl-dodeca-2,4,6,10-tetraenyl)triphenylphosphonium salt to give the desired 2,6-cyclolycopene-1,5-diol (II). A variant of this process, also in accordance with the invention, comprises converting the cyclopentylbutenone (VIII) into the phosphonium salt (X) via two alternative intermediates, namely a pentadienoic acid ester (XIV) and a different pentadienol (XV), into the same phosphonium salt (X). Moreover, the invention is concerned with the novel intermediates (V), (VI), (VII), (VIII), (IX), (X), (XII), (XIV) as well as (XV) and the individual process steps which lead to these novel intermediates. 2,6-cyclolycopene-1,5-diol is useful in the prevention of cancer growth in human cells.

80. 发明授权

US5981811A Process for preparing polyprenols 失效
标题翻译：聚异戊二烯的制备方法
公开(公告)号：US5981811A
公开(公告)日：1999-11-09
申请号：US066734
申请日：1998-04-27
申请人： Katuji Ujita , Koichi Kanehira , Yoshin Tamai
发明人： Katuji Ujita , Koichi Kanehira , Yoshin Tamai
IPC分类号： C07C29/00 , C07C29/132 , C07C29/58 , C07C33/02
CPC分类号： C07C29/58 , C07C29/00 , C07C29/132 , Y02P20/55
摘要： A process for the preparation of a polyprenol represented by formula (1): ##STR1## where Y and Z individually represent a hydrogen atom or are coupled together to form a carbon-carbon bond; R represents a hydrogen atom or a protective group for a hydroxyl group, and n is 0 or an integer not less than 1, by reacting an organic complex of an alkali metal with a compound represented by formula (2): ##STR2## where either V represents a halogen atom, while W and X are coupled together to form a carbon-carbon bond, or X represents a halogen atom, while V and W are coupled together to form a carbon-carbon bond; A represents a protective group for a hydroxyl group, and Y, Z and n are as defined above.
摘要翻译：一种由式（1）表示的聚异戊二烯的制备方法：其中Y和Z各自表示氢原子或偶联在一起形成碳 - 碳键; R表示氢原子或羟基的保护基，n为0或1以上的整数，通过使碱金属的有机配合物与式（2）表示的化合物反应：其中V表示卤素原子，而W和X连接在一起形成碳 - 碳键，或X表示卤素原子，而V和W连接在一起形成碳 - 碳键; A表示羟基的保护基，Y，Z和n如上所定义。

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