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    • 81. 发明授权
    • Cleanly removable tapes and methods for the manufacture thereof
    • 清洁可拆卸的磁带及其制造方法
    • US06866928B2
    • 2005-03-15
    • US10118120
    • 2002-04-08
    • Timothy N. NarumJames J. KobeRodger J. PereyraZhiming Zhou
    • Timothy N. NarumJames J. KobeRodger J. PereyraZhiming Zhou
    • B32B27/00B32B5/00B32B7/06C09J7/02C09J9/00C09J11/00C09J201/00
    • C09J9/00C09J7/22C09J7/38C09J2201/128C09J2201/618Y10S428/92Y10S428/921Y10T428/14Y10T428/28Y10T428/2809Y10T428/2813Y10T428/2848Y10T428/2891
    • The present invention provides a multi-layer tape, comprising: a first adhesive layer comprising a pressure sensitive adhesive; a core layer having an outer surface, the first adhesive layer adhered to at least a portion of the outer surface; and fibrous reinforcing material dispersed within the core layer, the fibrous reinforcing material imparting stretch release properties to the tape. The tape may comprise a second adhesive layer wherein the outer surface comprises a first major surface and a second major surface, the first adhesive layer being adhered to the first major surface, and the second adhesive layer being adhered to the second major surface. A fire retardant may be disposed in any of the first adhesive layer, the second adhesive layer, and the core layer. The tape may be cleanly removable. The fibrous reinforcing material typically comprises substantially continuous viscoelastic microfibers having a yield strength and a tensile break strength, and the tensile break strength is at least about 150% of the yield strength. In another aspect, the tapes of the invention may be formulated to be cleanly removable without including fibrous reinforcing material therein. The invention also provides a method for the manufacture of the foregoing tape as well as an assembly comprising: a substrate; a carpet overlying the substrate; and a tape according to the invention disposed between the carpet and the substrate and adhering the carpet to the substrate.
    • 本发明提供了一种多层带,包括:包含压敏粘合剂的第一粘合剂层; 芯层,其具有外表面,所述第一粘合剂层粘附到所述外表面的至少一部分; 纤维增强材料分散在芯层内,纤维增强材料赋予带的拉伸脱模性能。 带可以包括第二粘合剂层,其中外表面包括第一主表面和第二主表面,第一粘合剂层粘附到第一主表面,并且第二粘合剂层粘附到第二主表面。 阻燃剂可以设置在第一粘合剂层,第二粘合剂层和芯层中的任一个中。 磁带可能是干净可拆卸的。 纤维增强材料通常包括具有屈服强度和拉伸断裂强度的基本上连续的粘弹性微纤维,并且拉伸断裂强度是屈服强度的至少约150%。 在另一方面,本发明的带可以配制成可干净地移除,而不包括其中的纤维增强材料。 本发明还提供了一种用于制造前述带的方法以及一种组件,其包括:基底; 覆盖衬底的地毯; 以及根据本发明的设置在地毯和基底之间并且将地毯粘附到基底上的带。
    • 82. 发明申请
    • Multi-phase structural adhesives
    • 多相结构胶
    • US20050022929A1
    • 2005-02-03
    • US10867652
    • 2004-06-15
    • Rainer SchoenfeldHubert Schumann
    • Rainer SchoenfeldHubert Schumann
    • C08L55/00C08L63/00C09J5/06C09J163/00C09J201/00B32B31/00
    • C09J163/00C08L55/00C08L63/00C08L2666/02C08L2666/24C09J5/06C09J201/00C09J2400/163C09J2400/226C09J2455/00C09J2463/00
    • Hot-curing structural adhesives with multiphase polymer morphology, wherein the binder matrix of the cured chemically reactive adhesive displays (a) a continuous phase containing a polymer P1 having a glass transition temperature of over 100° C.; (b) a heterodisperse phase consisting of individual continuous domains of a thermoplastic or elastomeric polymer P2 having a glass transition temperature of below −30° C. and an average particle size of between 0.5 and 50 μm, which itself contains separate phases of another thermoplastic or elastomeric polymer P3 having a glass transition temperature of below −30° C. and a size of between 1 nm and 100 nm, parts of which can be in aggregated form as larger agglomerates; and (c) another heterodisperse phase embedded in the continuous phase and consisting of domains of the polymer P3, at least parts of which have an average particle size of between 1 nm and 50 nm, wherein P3 is not identical to P2; are suitable as high-strength, impact resistant structural adhesives, for internal stiffeners for cavities in automobile construction and for the production of reinforcing coatings for thin-wall sheet components.
    • 具有多相聚合物形态的热固化结构粘合剂,其中固化的化学反应性粘合剂的粘合剂基质显示(a)含有玻璃化转变温度超过100℃的聚合物P1的连续相; (b)由玻璃化转变温度低于-30℃的平均粒径为0.5-50微米的热塑性或弹性体聚合物P2的单独连续区组成的异分散相,其本身包含另一种热塑性塑料 或具有低于-30℃的玻璃化转变温度和1nm至100nm的尺寸的弹性体聚合物P3,其中的部分可以作为较大的附聚物呈聚集形式; 和(c)嵌入在连续相中并由聚合物P3的结构域组成的另一个异分散相,其中至少部分具有1nm至50nm的平均粒度,其中P3与P2不相同; 适用于高强度,耐冲击的结构粘合剂,用于汽车结构中的腔的内部加强件以及用于生产用于薄壁片材部件的增强涂层。
    • 84. 发明申请
    • Melt-flow controlling method for elastomer by uv irradiation
    • 通过紫外线照射进行弹性体的熔体流动控制
    • US20050016672A1
    • 2005-01-27
    • US10494561
    • 2002-10-18
    • Tae-Sung KimHyuk-soo MoonJong-Kul Lee
    • Tae-Sung KimHyuk-soo MoonJong-Kul Lee
    • B29C65/52C09J4/06C09J5/00C09J7/02C09J201/00H01L21/52B32B31/00
    • C09J7/38B29L2009/00C09J2205/31
    • A melt-flow controlling method for elastomer by uv irradiation for use in semiconductor packages by ultraviolet irradiation, in which a coated polymer composition is crosslinked by ultraviolet irradiation after a coating process of the polymer composition in producing the elastic adhesives. In producing the elastic adhesives for use as the thermal stress relief layer in semiconductor packages, the inventive method comprises irradiating the polymer composition with ultraviolet light of a 100-500 nm wavelength in order to control the flowability and crosslinking degree of the coated polymer composition. Thus, according to the present invention, a heating furnace is not used such that energy consumption can be reduced. Also, curing can be achieved in a short time so as to increase productivity, and the crosslinking degree is easily controlled by changing the ultraviolet dose as compared to the thermal crossliking process. Furthermore, an installation area of ultraviolet irradiation equipment is smaller than the heating furnace, and little or no epoxy reactive groups participate in the crosslinking reaction upon photo-polymerization so that the resulting film product has an excellent storage stability and thus a long life span.
    • 通过紫外线照射在紫外线照射下使用紫外线照射的弹性体的熔体流动控制方法,其中在制备弹性粘合剂的聚合物组合物的涂布工艺之后,通过紫外线照射将涂覆的聚合物组合物交联。 在制造用作半导体封装中的热应力消除层的弹性粘合剂中,本发明的方法包括用100-500nm波长的紫外光照射聚合物组合物,以控制涂覆的聚合物组合物的流动性和交联度。 因此,根据本发明,不使用加热炉,能够降低能量消耗。 此外,可以在短时间内实现固化,从而提高生产率,并且通过与热交叉处理相比,通过改变紫外线剂量来容易地控制交联度。 此外,紫外线照射设备的安装面积小于加热炉,并且在光聚合时很少或没有环氧反应性基团参与交联反应,使得所得膜产品具有优异的储存稳定性并因此具有长的使用寿命。
    • 87. 发明申请
    • Polyurethane adhesive for windshield applications
    • 用于挡风玻璃应用的聚氨酯胶粘剂
    • US20030070741A1
    • 2003-04-17
    • US10144803
    • 2002-05-15
    • Steven A. RosenbergHong YaoThomas BoveAdrian Van MaurikHans Peter TschanNorman Blank
    • B60J001/00E06B005/00C09J201/00
    • C09J175/04C08G18/10C08G18/12C08G18/307C08G18/289
    • A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5 % by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5 % by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100null C.
    • 提供了可用于粘合多孔和无孔表面的聚氨酯粘合剂。 粘合剂特别适用于在各种环境条件下将挡风玻璃粘合到汽车框架中,特别是在后市场挡风玻璃更换应用中。 聚氨酯包括至少一种基于至少一种热塑性多元醇的氨基甲酸酯预聚物。 在一个实施方案中,氨基甲酸酯预聚物可以由一种或多种多异氰酸酯,一种或多种聚醚多元醇和一种或多种热塑性聚酯多元醇形成,其中预聚物的游离异氰酸酯含量为约0.6至约3.5重量%,基于重量 的聚氨酯。 在另一个实施方案中,提供了一部分粘合剂组合物,其包括异氰酸酯官能和热塑性聚氨酯预聚物,其具有约0.6至约3.5重量%的游离异氰酸酯含量,基于聚氨酯的重量,以及 能够催化异氰酸酯部分与异氰酸酯反应性部分的反应的几种催化剂,同时提供较少的温度依赖性催化异氰酸酯部分与水之间的反应。 还提供了使用聚氨酯粘合剂将两个或更多个基材结合在一起的方法。 在汽车挡风玻璃更换应用中,聚氨酯粘合剂允许足够的工作时间和绿色强度的发展,以在约0至约100℃的温度下在1小时内提供安全的驱走时间。
    • 89. 发明申请
    • Stenoprophiluric matrices, and methods of making and using the same
    • US20020045057A1
    • 2002-04-18
    • US09776198
    • 2001-02-02
    • Dennis A. Guritza
    • C14C009/00A61L002/00B27K001/00C12P001/00C08L001/00C08K003/00C09J101/00C08L063/00C08K005/00C09J201/00C09J004/00C08J003/00C12N001/00B32B009/04B05D003/00
    • B32B27/08A61L2/0082B08B17/00B32B9/04B32B27/36B32B27/40B32B2363/00B32B2367/00B32B2375/00C08K5/0058C09D5/1612Y10T428/31504Y10T428/31511Y10T428/31515Y10T428/31551Y10T428/31663Y10T428/31678Y10T428/31786Y10T428/31938Y10T428/31989Y10T428/4935Y10T428/662Y10T428/8305
    • This invention relates to an article comprising a bio-supportive media which bio-degrades at a preferred rate, comprising at least one bio-limiting agent and at least one nutritional source on a substrate. The media may be characterized as a polymer, composite, or amalgam of commonly used materials. The invention relates to altering the physical/chemical composition of the media such that biodegradation can occur at a specific, usually accelerated, preferred rate. Further, the biodegradation rate may be managed and balanced concurrently with the ability to provide for the exposure of integral component(s) which are bio-active. This relationship essentially provides for a managed release or managed availability of agent(s) which creates a new set of ecological conditions. These sustained conditions can maintain a micro-habitat; a limited consort of species, often slime which, due to this ecological trophic niche position, can utilize innate allelopathic means to further protect their position and deter predation. The relationships of the nutrients, bio-limiters, and biomass comprise a unique micro-habitat as an interface which provides protection from corrosion and deterioration of the substrate upon which it is fixed, and limits the biomass accumulation on the surface thereby providing control of fouling by reducing higher order organism(s) attachments, which otherwise are very economically costly. Specifically the invention relates to modifying the media formation whether as a polymer or composite or amalgam such that the physical and chemical properties of the media are altered to become more degradable in the host habitat. This is accomplished by altering the polymerization or formation of the composite or amalgam to provide for increased inter-granular or molecular locations which permit enhanced bio-degradative activity. Then by occluding or interspersing physically or chemically an agent which has bio-active properties, the organisms of various species which may attach or be attracted to the surface can be limited by their nutrition and tolerance of bio-active preference without the need for toxification or mechanical removal of undesirable or unwanted organisms as settlers. Once the community of selected organisms establishes a natural equilibrium with the host habitat any capacity for allelopathic protection of the biofilm can be utilized or enhanced by this new and unique biological community to its benefit through management of the media components.