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    • 3. 发明授权
    • Process for the preparation of microcapsules
    • 微胶囊制备方法
    • US07807076B2
    • 2010-10-05
    • US10493277
    • 2002-10-17
    • Ann HuntRobert Montgomery O'Neil
    • Ann HuntRobert Montgomery O'Neil
    • B01J13/02B01J13/18B41M5/165
    • D21H21/54B01J13/18B41M5/165Y10T428/2984Y10T428/2985
    • An improved process for the preparation of microcapsules consisting essentially of a wall material and a core material in condensing a melamine-formaldehyde precondensate and/or methyl ethers thereof in an aqueous dispersion of a water-insoluble core material and in the presence of an acrylic acid/acrylamide copolymer at acidic pH and at a temperature in the range of from 20° to 100° C., and hardening thereafter the melamine-formaldehyde precondensate to form the walls of the microcapsules at an elevated temperature, wherein the core material is dispersed in the precondensate/copolymer solution without initial partial condensation of the precondensate and copolymer and wherein the hydrophobe point of the precondensate and/or its methyl esters is less than 90° C., as well as microcapsules, paper and pressure-sensitive recording material comprising such microcapsules.
    • 一种用于制备基本上由壁材料和核心材料组成的微胶囊的改进方法,其在水不溶性核心材料的水分散体中和在丙烯酸存在下缩合三聚氰胺 - 甲醛预缩合物和/或其甲基醚 /丙烯酰胺共聚物,并且在20℃至100℃的温度范围内,然后硬化三聚氰胺 - 甲醛预缩合物以在高温下形成微胶囊的壁,其中芯材分散在 预缩合物/共聚物溶液,其不具有预缩合物和共聚物的初始部分缩合,并且其中预缩合物和/或其甲酯的疏水点小于90℃,以及微胶囊,纸和压敏记录材料 微胶囊。
    • 6. 发明授权
    • Heat-stable diketopyrrolopyrrole pigment mixtures
    • 热稳定二酮吡咯并吡咯颜料混合物
    • US07786313B2
    • 2010-08-31
    • US12218904
    • 2008-07-17
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • Olof WallquistRoman LenzLeonhard FeilerMathias DüggeliTaher YousafGerardus De Keyzer
    • C07D487/04C09B67/22
    • C09B67/0033C09B57/004
    • The present invention relates to a process for the preparation of a mixture comprising at least two structurally different diketopyrrolopyrrole pigments of formula wherein A1 and A2 are each independently of the other an aromatic or heteroaromatic radical, by reacting a succinic acid ester with at least one unsubstituted or substituted aromatic or heteroaromatic nitrile, which process comprises carrying out the reaction in the presence of at least one compound of formula wherein A is an aromatic or heteroaromatic radical, R3 is hydrogen, halogen, methyl, methoxy, —CF3 or —CN, R4 is a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, X is —S—, —O—, —CR5R5′—, —COO—, —CONR5—, —SO—, SO2—, —SO2NR5— or —NR5— and R5 and R5′ are each independently of the other hydrogen or a linear or, from C3 upwards, optionally branched C1-C30alkyl, C6-C10aryl or C6-C24aralkyl radical, to the use of such a mixture in the coloring of organic material and in cosmetics, and also to novel diketopyrrolopyrrole pigment mixtures.
    • 本发明涉及制备包含至少两种结构不同的下式的二酮吡咯并吡咯颜料的混合物的方法,其中A1和A2各自独立地为芳族或杂芳族基团,琥珀酸酯与至少一种未取代的 或取代的芳族或杂芳族腈,该方法包括在至少一种下式化合物存在下进行反应其中A是芳族或杂芳族基,R 3是氢,卤素,甲基,甲氧基,-CF 3或-CN,R 4 C 1 -C 10烷基,C 6 -C 10芳基或C 6 -C 24芳烷基,X是-S-,-O-,-CR 5 R 5'-,-COO-,-CONR 5 - ,-SO- ,SO 2 - ,-SO 2 NR 5 - 或-NR 5 - 以及R 5和R 5'各自独立地为氢或直链或从C3向上任选支链的C 1 -C 30烷基,C 6 -C 10芳基或C 6 -C 24芳烷基, 这样的混合物在 有机材料和化妆品着色,以及新型二酮吡咯并吡咯颜料混合物。
    • 8. 发明授权
    • Pyrido thiazinium dyes
    • 吡啶并噻嗪染料
    • US07785375B2
    • 2010-08-31
    • US11922660
    • 2006-06-21
    • Victor Paul EliuBeate FröhlingDominique Kauffmann
    • Victor Paul EliuBeate FröhlingDominique Kauffmann
    • A61Q5/10C07D279/00
    • A61Q5/10A61K8/49C07D513/04C09B23/0091
    • Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R1, R2, R3, R4 independently from each other are hydrogen; hydroxy; —S—H; —S—C1-C12alkyl; halogen; C1-C12alkyl or C1-C12alkoxy, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy, —(CO)—H or —(CO)—C1-C5alkyl; —NR5R6; —NO2; —(CO)H or (CO)—C1-C5alkyl; C6-C12aryl, C6-C12aryl-C1-C4alkyl or C6-C12aryl-C1-C4alkoxy, wherein the aryl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, —(CO)—H or —(CO)—C1-C5alkyl; R5 and R6 independently from each other are hydrogen; hydroxy; C1-C12alkyl; hydroxy-C1-C12alkyl; —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C5alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; and An is an anion. Furthermore, the present invention relates to novel heterocyclic compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation and application to hair dying.
    • 公开了一种染色含角蛋白纤维的方法,包括用至少一种式(1)化合物处理纤维,其中R 1,R 2,R 3,R 4彼此独立地为氢; 羟基; -S-H; -S-C 1 -C 12烷基; 卤素; C 1 -C 12烷基或C 1 -C 12烷氧基,其可以被一个或多个C 1 -C 5烷基,C 1 -C 5 - 烷氧基,羟基, - (CO)-H或 - (CO)-C 1 -C 5烷基取代; -NR5R6; -NO2; - (CO)H或(CO)-C 1 -C 5烷基; C 1 -C 12芳基,C 6 -C 12芳基-C 1 -C 4烷基或C 6 -C 12芳基-C 1 -C 4烷氧基,其中芳基部分可被一个或多个C 1 -C 5烷基,C 1 -C 5烷氧基, - (CO)-H或 - (CO) -C 1 -C 5烷基; R5和R6彼此独立地是氢; 羟基; C 1 -C 12烷基; 羟基-C 1 -C 12烷基; - (CO)-H; - (CO)-C 1 -C 5烷基; 苯基或苯基-C 1 -C 5烷基,其中苯基部分可被一个或多个C 1 -C 5烷基,C 1 -C 5烷氧基,卤素,-NH 2,单C 1 -C 5烷基氨基,二-C 1 -C 5烷基氨基,-NO 2,羧基或羟基 ; 而An是阴离子。 此外,本发明涉及新颖的杂环化合物,其组合物,特别是其它染料,以及其制备和应用于染发的方法。
    • 10. 发明授权
    • Method of coloring a coating composition
    • 着色涂料组合物的方法
    • US07727702B2
    • 2010-06-01
    • US11547153
    • 2005-03-29
    • Johannes BenkhoffKarin Powell
    • Johannes BenkhoffKarin Powell
    • G03F7/00G03F7/004G03F7/20
    • G03F7/105B41M5/30B41M5/323B41M5/327B41M2205/04C09D5/032C09D7/41C09D11/50G03C1/732Y10S430/106Y10S430/146
    • A method is provided for irreversibly coloring a coating composition containing a color former comprising the steps of a) providing a coating composition that contains an UV curable resin, a thermosetting resin or an alkyd resin with the proviso that the coating composition contains no developer nor any additive which may function as developer; b) mixing the coating composition with the color former whereby no color is formed; c) applying the colorless composition obtained in step b) to a substrate; d) in case of a thermosetting resin curing the resin between 100 and 300° C., preferably between 100 and 150° C., whereby no color is formed, in case of alkyd resin drying of the resin at room temperature, whereby no color is formed; e) exposure to UV or high energy radiation below 400 nm whereby the color is formed.
    • 提供了一种用于不可逆地着色含有着色剂的涂料组合物的方法,包括以下步骤:a)提供含有UV可固化树脂,热固性树脂或醇酸树脂的涂料组合物,条件是涂料组合物不含显影剂,也不含任何 可用作显影剂的添加剂; b)将涂料组合物与成色剂混合,不形成颜色; c)将步骤b)中得到的无色组合物加到基材上; d)在热固性树脂固化树脂100至300℃之间,优选在100至150℃之间的情况下,在室温下树脂的醇酸树脂干燥的情况下,不会形成颜色,因此没有颜色 形成了; e)暴露于低于400nm的UV或高能量辐射,从而形成颜色。