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    • 1. 发明申请
    • PROCESS FOR PRODUCING WATER-ABSORBENT RESIN
    • 生产吸水树脂的方法
    • US20160030919A1
    • 2016-02-04
    • US14759762
    • 2014-11-04
    • SUMITOMO SEIKA CHEMICALS CO., LTD.
    • Tetsuhiro HinayamaMasahiro MurakamiJunichi Takatori
    • B01J20/26A61L15/24A61L15/60B01J20/30
    • B01J20/261A61L15/60B01J20/3085C08F2/32C08F220/06
    • The present invention provides a process for producing a water-absorbent resin, characterized in that a reverse-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer is carried out in a hydrocarbon dispersion medium comprising a dispersion stabilizer while an azo-based compound and a peroxide are combined in the presence of an internal-crosslinking agent, in that the following formulae are satisfied, 0.10≦B/(A+B)  (1), and 0.055≦B+9×C≦0.120  (2), wherein A mol, B mol and C mol represent used amounts of the azo-based compound, the peroxide and the internal-crosslinking agent, respectively, relative to 100 mol of the water-soluble ethylenically unsaturated monomer used in the polymerization, and in that a post-crosslinking reaction is carried out by adding a post-crosslinking agent after the polymerization. The present invention also relates to a water-absorbent resin having specific performance and produced by the process.
    • 本发明提供一种吸水性树脂的制造方法,其特征在于,在包含分散稳定剂的烃分散介质中进行水溶性烯属不饱和单体的反相悬浮聚合,而偶氮类化合物和 在内部交联剂的存在下将过氧化物组合,其中满足下列公式:0.10≦̸ B /(A + B)(1)和0.055& NlE; B + 9×C≦̸ 0.120(2) 其中A mol,B mol和C mol分别表示相对于聚合中使用的水溶性烯属不饱和单体100摩尔的偶氮类化合物,过氧化物和内部交联剂的使用量, 通过在聚合后添加后交联剂进行后交联反应。 本发明还涉及具有特定性能并通过该方法生产的吸水性树脂。