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1. 发明授权

US09611246B2 Compositions, apparatus, systems, and methods for resolving electronic excited states 有权
公开(公告)号：US09611246B2
公开(公告)日：2017-04-04
申请号：US14792421
申请日：2015-07-06
申请人： HALLSTAR INNOVATIONS CORP.
发明人： Craig A. Bonda , Shengkui Hu , Qing Jean Zhang , Zhihui Zhang
IPC分类号： C07C255/41 , C07C69/618 , C07D335/12 , C07D311/82 , A61K8/37 , A61K8/40 , A61K8/49 , A61Q17/04 , C07C325/04 , C07C327/22 , C07C255/34 , C07C255/40 , A61K8/35 , A61K41/00 , A61K47/14 , A61K47/16 , A61K47/22
CPC分类号： C07D335/12 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/494 , A61K8/498 , A61K8/4986 , A61K41/0071 , A61K47/14 , A61K47/16 , A61K47/22 , A61K2800/522 , A61Q17/04 , C07C69/618 , C07C255/34 , C07C255/40 , C07C255/41 , C07C325/04 , C07C327/22 , C07C2603/18 , C07C2603/24 , C07D311/82 , Y10T428/249921
摘要： The present disclosure relates, according to some embodiments, to molecules, including conjugated fused polycyclic molecules, that may receive excited state energy from other molecules (e.g., light-absorbing molecules) or directly from the irradiation sources. According to some embodiments, the disclosure relates to molecules, including conjugated fused polycyclic molecules, that may resolve (e.g., quench, dissipate) excited state energy, normally by way of releasing it as heat. (e.g., as heat). Conjugated fused polycyclic molecules of various structures are disclosed including Formula III: The disclosure further relates to methods of use and/or therapy using molecules of Formulas I, II, and/or III.

2. 发明授权

US08329148B1 Photostabilization of coenzyme Q compounds with alkoxycrylene compounds 有权
标题翻译：辅酶Q化合物与烷氧基亚芳基化合物的光稳定化
公开(公告)号：US08329148B1
公开(公告)日：2012-12-11
申请号：US13572165
申请日：2012-08-10
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K8/00 , A61K8/18 , A61Q17/04 , A61K38/43
CPC分类号： A61K8/368 , A61K8/361 , A61K8/37 , A61K8/40 , A61K8/49 , A61K8/671 , A61K2800/52 , A61Q17/04 , A61Q19/00 , A61Q19/08
摘要： A method of reducing photodegradation of a coenzyme Q10 compound when exposed to UV radiation in a composition containing said coenzyme Q10 compound comprising combining with said coenzyme Q10 compound a compound of formula (I) in an amount effective to quench singlet excited state energy from the coenzyme Q10 compound and transfer the singlet excited state energy from the coenzyme Q10 compound to the compound of formula (I), wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, and the non-alkoxy R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, thereby photostabilizing the retinoid compound.
摘要翻译：一种当在含有所述辅酶Q10化合物的组合物中暴露于紫外线辐射时降低辅酶Q 10化合物的光降解的方法，包括与所述辅酶Q10化合物结合，其化学式（I）化合物的量有效地从辅酶中淬灭单线态激发态能 Q10化合物，并将单重态能量从辅酶Q10化合物转移到式（I）化合物中，其中R1和R2之一是直链或支链C1-C30烷氧基，非烷氧基R1或R2是氢; 并且R 3是直链或支链C 1 -C 30烷基，由此使类视黄醇化合物光稳定化。

3. 发明授权

US08278332B2 Photostabilization of retinoids with alkoxycrylene compounds 有权
标题翻译：类视黄醇与烷氧基亚苄基化合物的稳定化
公开(公告)号：US08278332B2
公开(公告)日：2012-10-02
申请号：US13282667
申请日：2011-10-27
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A01N43/40 , A61K31/44 , A61K38/43 , A61K8/00 , A61K8/18 , A61Q17/04
CPC分类号： A61Q19/08 , A61K8/361 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/49 , A61K8/671 , A61K2800/52 , A61Q17/04 , A61Q19/00
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from retinoid compounds—has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds having an alkoxy radical in the four (para) position (hereinafter “alkoxycrylenes”) on one of the phenyl rings having the formula (I): wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, preferably C1-C8, more preferably methoxy, and the non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, preferably C2-C20. The alkoxycrylene compounds of formula (I) significantly increase the photostability of retinoid compounds in a composition by at least 3-fold.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自类视黄醇化合物的单态能量 - 已经被发现容易地转移到（接受于）四（对）位中具有烷氧基的α-氰基二苯基丙烯酸酯化合物（以下称为烷氧基烯基）具有式（I）的苯环：其中R1和R2之一是直链或支链C1-C30烷氧基，优选C1-C8，更优选甲氧基，非烷氧基R1或R2是氢; 并且R 3是直链或支链C 1 -C 30烷基，优选C 2 -C 20。式（I）的烷氧基亚烷基化合物显着地将组合物中类视黄醇化合物的光稳定性提高至少3倍。

4. 发明申请

US20120114572A1 Photostabilization of coenzyme Q compounds with alkoxycrylene compounds 有权
公开(公告)号：US20120114572A1
公开(公告)日：2012-05-10
申请号：US13294339
申请日：2011-11-11
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K8/40 , A61Q17/04 , A61P17/10 , A61Q19/00 , A61Q19/08 , A61K31/122 , A61P17/00
CPC分类号： A61K8/355 , A61K8/40 , A61K2800/52 , A61Q19/08
摘要： A method of reducing photodegradation of a coenzyme Q10 compound when exposed to UV radiation in a composition containing said coenzyme Q10 compound comprising combining with said coenzyme Q10 compound a compound of formula (I) in an amount effective to quench singlet excited state energy from the coenzyme Q10 compound and transfer the singlet excited state energy from the coenzyme Q10 compound to the compound of formula (I), wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, and the non-alkoxy R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, thereby photostabilizing the retinoid compound.

5. 发明授权

US08075808B2 Method of quenching electronic excitation of chromophore-containing organic molecules in photoactive compositions 有权
标题翻译：在光活性组合物中淬灭含有发色团的有机分子的电子激发的方法
公开(公告)号：US08075808B2
公开(公告)日：2011-12-13
申请号：US12432542
申请日：2009-04-29
申请人： Craig A. Bonda , Anna Pavlovic
发明人： Craig A. Bonda , Anna Pavlovic
IPC分类号： F21V9/04 , F21V9/06 , G02B5/22 , G02B5/26 , A61K8/00 , A61K8/18 , A61Q17/04
CPC分类号： A61K8/40 , A61K2800/52 , A61Q17/04
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from a UV-absorbing molecule has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds of formulas (I) and (V) having an alkoxy radical preferably in the four (para) position (hereinafter methoxycrylenes) on one or both of the phenyl rings: wherein at least one of R1 and R2 is a straight or branched chain C1-C12 alkoxy radical, preferably C1-C8, more preferably C1-C4, and most preferably methoxy, and any non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C24 alkyl radical, preferably C12-C24, more preferably C20; wherein A and B are the same or different and are selected from the group consisting of oxygen, amino and sulfur; R1 and R3 are the same or different and are selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne, aryl, substituted aryl, heteroaryl, heterocycloalkyl, substituted heteroaryl and substituted heterocycloalkyl; R2 is selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkyl, C3-C8 substituted cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne; R4, R5, R6 and R7 are the same or different and are selected from the group consisting of C1-C30 alkoxy straight chin on branched and a, b, c and d are each either 0 or 1, and a, b, c and d add up to 1, 2, 3, or 4.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自UV吸收分子的单态能量已被发现易于转移到具有烷氧基的式（I）和（V）的α-氰基二苯基丙烯酸酯化合物（优选在四（对位）位置（以下为甲氧基）;其中R 1和R 2中的至少一个为直链或支链C 1 -C 12烷氧基，优选C 1 -C 8，更优选C 1 -C 4，最优选优选甲氧基，任何非烷氧基R 1或R 2为氢; 并且R 3是直链或支链C 1 -C 24烷基，优选C 12 -C 24，更优选C 20; 其中A和B相同或不同，并且选自氧，氨基和硫; R 1和R 3相同或不同，选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔基，芳基，取代的芳基，杂芳基，杂环烷基，取代的杂芳基和取代的杂环烷基; R 2选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的烷基，C 3 -C 8取代的环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔烃 R4，R5，R6和R7相同或不同，选自支链上的C1-C30烷氧基直链，a，b，c和d各自为0或1，a，b，c和 d加起来1，2，3或4。

6. 发明申请

US20110142771A1 Photostabilization of Retinoids with Alkoxycrylene Compounds 有权
标题翻译：类视黄醇与烷氧基化合物的光稳定化
公开(公告)号：US20110142771A1
公开(公告)日：2011-06-16
申请号：US13032215
申请日：2011-02-22
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K8/40 , A61K8/49 , A61K31/07 , A61K31/11 , A61K31/203 , A61K31/215 , A61K31/192 , A61K31/382 , A61K31/122 , A61Q17/00 , A61Q19/00 , A61Q19/08 , A61P17/00 , A61P17/10
CPC分类号： A61Q19/08 , A61K8/361 , A61K8/368 , A61K8/37 , A61K8/40 , A61K8/49 , A61K8/671 , A61K2800/52 , A61Q17/04 , A61Q19/00
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from retinoid compounds—has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds having an alkoxy radical in the four (para) position (hereinafter “alkoxycrylenes”) on one of the phenyl rings having the formula (I): wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, preferably C1-C8, more preferably methoxy, and the non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, preferably C2-C20. The alkoxycrylene compounds of formula (I) significantly increase the photostability of retinoid compounds in a composition by at least 3-fold and as much as 10-fold or greater. The ability of the alkoxycrylene compounds to stabilize the retinoid compound is concentration dependent, with the amount of retinoid photostabilization increasing with the concentration of the alkoxycrylene compound.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自类视黄醇化合物的单态态能够容易地转移到（接受）在四（对）位置具有烷氧基的α-氰基二苯基丙烯酸酯化合物（以下称为“烷氧基烯”）的具有式（I）的苯环：其中R 1和R 2中的一个是直链或支链C 1 -C 30烷氧基，优选C 1 -C 8，更优选甲氧基，并且非烷氧基R 1或R 2是氢; 并且R 3是直链或支链C 1 -C 30烷基，优选C 2 -C 20。式（I）的烷氧基化亚烷基化合物显着地将组合物中类视色素化合物的光稳定性提高至少3倍和10倍或更高。氧化烯化合物稳定类视黄醇化合物的能力是浓度依赖性的，随着烷氧基化合物浓度的增加，类视黄醇光稳定化的量增加。

7. 发明申请

US20100093943A1 REACTIVE ESTERS AS PLASTICIZERS FOR ELASTOMERS 审中-公开
标题翻译：作为弹性体的增塑剂的反应性酯
公开(公告)号：US20100093943A1
公开(公告)日：2010-04-15
申请号：US12250938
申请日：2008-10-14
申请人： Stephen O'Rourke , John English , Kimberly L. Stefanisin
发明人： Stephen O'Rourke , John English , Kimberly L. Stefanisin
IPC分类号： C08F36/06 , C08F36/08 , C08F114/02 , C08F8/14 , C08F20/02 , C08F20/06 , C08F20/42
CPC分类号： C08L55/02 , C08F20/42 , C08K3/04 , C08K3/22 , C08K5/0016 , C08K5/0025 , C08K5/10 , C08K5/11 , C08K5/14 , C08L9/00 , C08L21/00 , C08L23/16 , C08L51/04 , C08L2312/00 , C08L15/005 , C08L2666/18 , C08L2666/02
摘要： The present disclosure is directed to plasticized elastomer compositions and methods of preparing plasticized elastomers. The plasticized elastomer compositions comprise an elastomer, and an unsaturated linear or branched dicarboxylic acid diester plasticizer. The compositions are formed by combining the elastic polymer and reactive ester plasticizer with a curing agent to react at least 5% by weight of the diester plasticizer to the elastic polymer. The elastomer includes natural and synthetic rubbers, such as nitrile butadiene rubber, hydrogenated nitrile butadiene rubber, chlorinated polyethylene rubber, and ethylene propylene diene monomer rubber. The plasticized elastomer compositions disclosed herein provide improved solvent immersion properties, and are useful, for example, for hoses, belts, conveyor belts, motor mounts, gaskets, automotive drive train belts, including transmission belts, roofing compounds, and the like.
摘要翻译：本公开涉及增塑弹性体组合物和制备增塑弹性体的方法。增塑弹性体组合物包含弹性体和不饱和直链或支链二羧酸二酯增塑剂。组合物通过将弹性聚合物和活性酯增塑剂与固化剂组合以使至少5重量％的二酯增塑剂与弹性聚合物反应形成。弹性体包括天然和合成橡胶，例如丁腈橡胶，氢化丁腈橡胶，氯化聚乙烯橡胶和乙烯丙烯二烯单体橡胶。本文公开的增塑的弹性体组合物提供改进的溶剂浸渍性能，并且可用于例如软管，皮带，输送带，马达座，垫圈，汽车传动系列，包括传动带，屋顶化合物等。

8. 发明申请

US20100021403A1 DISPERSIONS OF INORGANIC PARTICULATES CONTAINING ALKOXYCRYLENE 有权
标题翻译：含有烷氧基的无机颗粒的分散体
公开(公告)号：US20100021403A1
公开(公告)日：2010-01-28
申请号：US12554329
申请日：2009-09-04
申请人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
发明人： Craig A. Bonda , Anna Pavlovic , Jean Zhang
IPC分类号： A61K8/27 , A61K8/29 , A61Q17/04
CPC分类号： A61K8/40 , A61K2800/52 , A61Q17/04
摘要： A composition comprising an inorganic particulate material in an amount of about 20 wt % to about 70 wt %, a carrier for the particulate material comprising a compound of formula (I) in an amount of about 1 wt % to about 70 wt %, a particulate material coating material in an amount of about 0 wt % to about 5 wt %, and a dispersing agent for the particulate material in an amount of about 0 wt % to about 5 wt %, based on the total weight of the composition, wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, and the non-alkoxy R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical.
摘要翻译：一种组合物，其包含约20重量％至约70重量％的无机颗粒材料，所述颗粒材料的载体包含约1重量％至约70重量％的量的式（I）化合物，约0重量％至约5重量％的颗粒材料涂料，和基于组合物总重量的约0重量％至约5重量％的颗粒材料分散剂，其中 R1和R2之一是直链或支链C1-C30烷氧基，非烷氧基R1或R2是氢; 且R 3为直链或支链C 1 -C 30烷基。

9. 发明申请

US20090291054A1 METHOD OF QUENCHING ELECTRONIC EXCITATION OF CHROMOPHORE-CONTAINING ORGANIC MOLECULES IN PHTOACTIVE COMPOSITIONS 有权
标题翻译：电化学组合物中包含有机分子的电子激发的方法
公开(公告)号：US20090291054A1
公开(公告)日：2009-11-26
申请号：US12432542
申请日：2009-04-29
申请人： Craig A. Bonda , Anna Pavlovic
发明人： Craig A. Bonda , Anna Pavlovic
IPC分类号： A61K8/40 , A61Q17/04
CPC分类号： A61K8/40 , A61K2800/52 , A61Q17/04
摘要： The photostabilizing electronic excited state energy—particularly singlet state energy from a UV-absorbing molecule has been found to be readily transferred to (accepted by) α-cyanodiphenylacrylate compounds of formulas (I) and (V) having an alkoxy radical preferably in the four (para) position (hereinafter methoxycrylenes) on one or both of the phenyl rings: wherein at least one of R1 and R2 is a straight or branched chain C1-C12 alkoxy radical, preferably C1-C8, more preferably C1-C4, and most preferably methoxy, and any non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C24 alkyl radical, preferably C12-C24, more preferably C20; wherein A and B are the same or different and are selected from the group consisting of oxygen, amino and sulfur; R1 and R3 are the same or different and are selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne, aryl, substituted aryl, heteroaryl, heterocycloalkyl, substituted heteroaryl and substituted heterocycloalkyl; R2 is selected from the group consisting of C1-C30 alkyl, C2-C30 alkylene, C2-C30 alkyne, C3-C8 cycloalkyl, C1-C30 substituted alkyl, C3-C8 substituted cycloalkyl, C1-C30 substituted alkylene, C2-C30 substituted alkyne; R4, R5, R6 and R7 are the same or different and are selected from the group consisting of C1-C30 alkoxy straight chin on branched and a, b, c and d are each either 0 or 1, and a, b, c and d add up to 1, 2, 3, or 4.
摘要翻译：已经发现光稳定化电子激发态能量 - 特别是来自紫外线吸收分子的单态能量已经被发现容易地转移到具有烷氧基的式（I）和（V）的α-氰基二苯基丙烯酸酯化合物（接受）（对位）位置（以下为甲氧基）;其中R 1和R 2中的至少一个为直链或支链C 1 -C 12烷氧基，优选C 1 -C 8，更优选C 1 -C 4，最优选优选甲氧基，任何非烷氧基R 1或R 2为氢; 并且R 3是直链或支链C 1 -C 24烷基，优选C 12 -C 24，更优选C 20; 其中A和B相同或不同，并且选自氧，氨基和硫; R 1和R 3相同或不同，选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔基，芳基，取代的芳基，杂芳基，杂环烷基，取代的杂芳基和取代的杂环烷基; R 2选自C 1 -C 30烷基，C 2 -C 30亚烷基，C 2 -C 30炔基，C 3 -C 8环烷基，C 1 -C 30取代的烷基，C 3 -C 8取代的环烷基，C 1 -C 30取代的亚烷基，C 2 -C 30取代的炔烃 R4，R5，R6和R7相同或不同，选自支链上的C1-C30烷氧基直链，a，b，c和d各自为0或1，a，b，c和 d加起来1，2，3或4。

10. 发明申请

US20090069466A1 PHOTOSTABILIZING SILICONE FLUIDS 有权
标题翻译：光敏硅胶
公开(公告)号：US20090069466A1
公开(公告)日：2009-03-12
申请号：US12205546
申请日：2008-09-05
申请人： Craig A. Bonda , Anna Pavlovic , Anthony J. O'Lenick, JR.
发明人： Craig A. Bonda , Anna Pavlovic , Anthony J. O'Lenick, JR.
IPC分类号： C08K5/3437 , C07C69/76 , C08F283/12 , C08L83/04 , C08K5/07 , C08K5/17 , C08K5/3492 , C08K5/09 , C08K5/42 , C08K5/1545 , C08K5/3472
CPC分类号： A61K8/40 , A61K8/898 , A61K2800/52 , A61Q17/04 , C08K5/315 , C09B69/103
摘要： A silicone fluid comprising a chromophore-substituted polyorganosiloxane having a formula (2): wherein x is an integer in the range of 60 to 2000; y is an integer in the range of 5 to 100; a ratio x:y is in a range of about 10:1 to about 20:1; and X is a photostabilizing chromophore.
摘要翻译：包含具有式（2）的发色团取代的聚有机硅氧烷的硅氧烷流体：其中x是在60至2000的范围内的整数; y为5〜100的整数，比例x：y在约10:1至约20:1的范围内; X是光稳定发色团。

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