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    • 2. 发明公开
    • METHOD FOR INTEGRATED UTILIZATION OF CALCIUM CHLORIDE SOLUTION AND CARBON DIOXIDE
    • US20240286916A1
    • 2024-08-29
    • US18438051
    • 2024-02-09
    • East China University of Science and Technology
    • Chenglin LIUJianguo YUYing YANGYuan MA
    • C01F11/18C02F1/469C02F103/34
    • C01F11/181C02F1/4693C01P2004/61C02F2103/34C02F2201/46115
    • The present invention provides a method for integrated utilization of a calcium chloride solution and CO2. In this method, with the calcium chloride solution and the CO2 being taken as raw materials, a water-soluble amine is added as an auxiliary agent to promote the occurrence of a mineralization reaction. As a result of crystallization following the reaction, calcium carbonate and a solution of a hydrochloride of the water-soluble amine are obtained. After the reaction is completed, the water-soluble amine is regenerated by subjecting a liquid phase resulting from separation to bipolar membrane electrodialysis, and dilute hydrochloric acid is obtained as a by-product at the same time. The method provides a novel perspective and approach to integrated utilization of calcium chloride-containing liquid waste and flue gas CO2. The water-soluble amine allows excellent mineralization, and the bipolar membrane electrodialysis enables excellent regeneration of the amine. By means of process regulation, a calcium carbonate product of high value with controlled morphology and particle size can be obtained. For applications equipped with a lime kiln and allowing recycling of calcium carbonate, such as the ammonia-soda industry, the present invention also provides a combined cycle process for carbon and calcium resources, in which calcium carbonate produced by a mineralization reaction is calcined in lieu of limestone used in the soda production process to provide the soda production process with CO2 and milk of lime, enabling recycling of carbon and calcium resources in an ammonia soda plant. The entire process is free of waste discharge, showing a promising prospect of application. It is of great significance to the fields of calcium chloride-containing liquid waste disposal and carbon emission reduction.