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    • 9. 发明授权
    • Polyacrylic acid-type water absorbent resin and method for producing same
    • 聚丙烯酸型吸水性树脂及其制造方法
    • US09315640B2
    • 2016-04-19
    • US14723026
    • 2015-05-27
    • Nippon Shokubai Co., Ltd.
    • Toshihiro TakaaiHidenori WadaSinichi Fujino
    • C08J9/12C08J9/20A61L15/24A61L15/60C08F220/06C08F20/00C08J3/24C08J9/36C08F2/01
    • C08J9/122A61L15/24A61L15/60C08F2/01C08F20/00C08F220/06C08J3/245C08J9/20C08J9/36C08J2203/06C08J2205/05C08J2333/02C08J2335/02Y10T428/2982C08L33/02C08F2222/1013
    • Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like. Disclosed is a method for producing a polyacrylic acid-type water absorbent resin, comprising (A) a step of obtaining an aqueous solution of acrylic acid-type monomers containing gas bubbles dispersed therein; (B) a step of polymerizing the aqueous monomer solution and thereby obtaining a foamed polymer; and (C) a step of heating and drying the foamed polymer, wherein gas bubbles are incorporated such that the volumetric expansion factor defined by the following formula (1); [Formula 1] Volumetric expansion factor=(Volume of aqueous monomer solution after gas bubble dispersion)/(volume of aqueous monomer solution before gas bubble dispersion)  Formula (1); exceeds 1.1 times, and the aqueous monomer solution having a monomer concentration defined by the following formula (2); [Formula 2] Monomer concentration [wt %]=(Weight of a monomer)/{(weight of a monomer)+(weight of solvent)}×100  Formula (2); of 40% by weight or greater is boiling polymerized at a temperature of 100° C. or higher.
    • 提供一种通过更方便的方法促进发泡聚合物(泡沫状吸水性树脂)中形成互连空隙(连续气泡)的吸水性树脂的制造方法,高效率地制造吸水性树脂 即使在卫生用品等中成为片状或粉末状时,也显示出高的吸水率。 公开了一种聚丙烯酸型吸水性树脂的制造方法,其特征在于,包括:(A)获得含有分散在其中的气泡的丙烯酸型单体的水溶液的工序; (B)使单体水溶液聚合,得到发泡聚合物的工序; 和(C)加热和干燥发泡聚合物的步骤,其中加入气泡,使得由下式(1)定义的体积膨胀系数; [式1]体积膨胀系数=(气泡分散后的单体水溶液体积)/(气泡分散前的单体溶液的体积)式(1) 超过1.1倍,单体浓度由下式(2)定义的单体水溶液; [式2]单体浓度[wt%] =(单体重量)/ {(单体重量)+(溶剂重量)}×100式(2) 为40重量%以上时,在100℃以上的温度下进行沸腾聚合。