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1. 发明授权

US10941352B2 Processes for increasing an octane value of a gasoline component 有权
公开(公告)号：US10941352B2
公开(公告)日：2021-03-09
申请号：US16454517
申请日：2019-06-27
申请人： UOP LLC
发明人： Mark P. Lapinski , Michael W. Penninger , Rajeswar Gattupalli , Christopher D. DiGiulio , Bryan J. Egolf , Louis A. Lattanzio
IPC分类号： C10G35/00 , C10G35/085 , C10G7/02 , C10G61/10
摘要： Processes for producing a gasoline blend in which C7 hydrocarbons are separated from a naphtha feed. The C7 hydrocarbons are isomerized and dehydrogenated to increase the octane value of the components therein. In order to avoid conversion of methylcyclohexane to toluene in the dehydrogenation reactor, the various processes provide flow schemes in which the methylcyclohexane bypasses the C7 dehydrogenation reaction zone.

2. 发明授权

US09527007B2 Processes and apparatuses for separating streams to provide a transalkylation feed stream in an aromatics complex 有权
标题翻译：用于分离流以在芳族化合物中提供烷基转移进料流的方法和装置
公开(公告)号：US09527007B2
公开(公告)日：2016-12-27
申请号：US14726151
申请日：2015-05-29
申请人： UOP LLC
发明人： Patrick C. Whitchurch
IPC分类号： B01D3/00 , B01D3/14 , C07C5/00 , C07C5/22 , C07C5/27 , C07C6/00 , C07C6/02 , C07C6/04 , C07C7/00 , C07C7/04 , B01J19/00 , B01J19/24 , C10G35/00 , C10G35/04 , C07C6/06
CPC分类号： B01D3/141 , B01D3/143 , B01J2219/00006 , C07C5/2732 , C07C6/06 , C07C7/04 , C10G35/04
摘要： A process and apparatus for the production of at least one xylene isomer is provided. The process includes passing a first stream to one side of a split shell fractionation column and a second stream to the other side of the column. The second stream has a higher ratio of ethylbenzene to total C8 aromatics than the first stream. A first overhead stream from the one side is separated and passed as a mixed xylene product and a second overhead stream from the other side is separated and passed as feed to a para-xylene separation zone.
摘要翻译：提供了用于生产至少一种二甲苯异构体的方法和设备。该方法包括将第一流送到裂解分级柱的一侧，将第二流送至塔的另一侧。第二流比第一流具有更高的乙苯与总C8芳族化合物的比例。将来自一侧的第一塔顶物流作为混合二甲苯产物分离并通过，另一侧的第二塔顶物流被分离并作为进料进入对二甲苯分离区。

3. 发明授权

US09181147B2 Process for the production of xylenes and light olefins 有权
标题翻译：生产二甲苯和轻质烯烃的方法
公开(公告)号：US09181147B2
公开(公告)日：2015-11-10
申请号：US13465733
申请日：2012-05-07
申请人： Larry L. Iaccino , S. Mark Davis , John D. Y. Ou , Xiaobo Zheng
发明人： Larry L. Iaccino , S. Mark Davis , John D. Y. Ou , Xiaobo Zheng
IPC分类号： C07C1/24 , C07C2/86 , C10G29/20 , C10G35/00 , C10G57/00 , C10G9/00 , C10G9/36 , C10G11/00
CPC分类号： C07C2/864 , C10G9/005 , C10G9/36 , C10G11/00 , C10G29/205 , C10G35/00 , C10G57/005 , C10G2300/1092 , C10G2300/1096 , C10G2400/30 , C07C15/08
摘要： In a hydrocarbon upgrading process, a hydrocarbon feed is treated in at least one of a steam cracker, catalytic cracker, coker, hydrocracker, and reformer under suitable conditions to produce a first stream comprising olefinic and aromatic hydrocarbons. A second stream composed mainly of C4+ olefinic and aromatic hydrocarbons is recovered from the first stream and is fed together with a methylating agent to a reaction zone containing a catalyst under reaction conditions including a temperature of about 450° C. to about 700° C., such that aromatics components in the second stream undergo dealkylation, transalkylation and/or methylation and aliphatic components undergo cracking and aromatization to produce a third stream having an increased xylene content compared with said second stream and a C3− olefin by-product. The C3− olefin by-product is recovered and para-xylene is removed from at least part of said third stream.
摘要翻译：在烃改质方法中，在合适条件下，在蒸汽裂化器，催化裂化器，焦化器，加氢裂化器和重整器中的至少一种中处理烃进料以产生包含烯烃和芳族烃的第一流。从第一流回收主要由C4 +烯烃和芳烃组成的第二料流，并在包括约450℃至约700℃的温度的反应条件下与甲基化剂一起加入含有催化剂的反应区。使得第二流中的芳烃组分经历脱烷基化，烷基转移和/或甲基化，并且脂族组分经历裂化和芳构化以产生与所述第二料流和C3-烯烃副产物相比具有增加的二甲苯含量的第三料流。回收C3-烯烃副产物，并从至少部分所述第三料流中除去对二甲苯。

4. 发明授权

US08702971B2 Process and apparatus for alkylating and hydrogenating a light cycle oil 失效
标题翻译：用于烷基化和氢化轻循环油的方法和设备
公开(公告)号：US08702971B2
公开(公告)日：2014-04-22
申请号：US12752026
申请日：2010-03-31
申请人： Deng-Yang Jan , Vasant P. Thakkar , Christopher P. Nicholas
发明人： Deng-Yang Jan , Vasant P. Thakkar , Christopher P. Nicholas
IPC分类号： C10G35/00
CPC分类号： C07C5/03 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/60 , B01J29/80 , B01J29/90 , B01J38/30 , B01J2229/42 , C10G29/205 , C10G69/123 , C10G2300/1088 , C10G2300/207 , C10G2300/42 , C10G2400/02
摘要： One exemplary embodiment can be a process for alkylating and hydrogenating a light cycle oil. The process can include passing the light cycle oil, one or more C2-C6 alkenes, and hydrogen through a reaction vessel containing an alkylation zone and a hydrogenation zone. Generally, the hydrogen is at least partially comprised from a hydrocarbon product stream from a fluid catalytic cracking zone.
摘要翻译：一个示例性实施方案可以是用于烷基化和氢化轻循环油的方法。该方法可以包括使光循环油，一种或多种C 2 -C 6烯烃和氢气通过含有烷基化区和氢化区的反应容器。通常，氢气至少部分地由来自流化催化裂化区的烃产物流组成。

5. 发明授权

US08202815B2 Catalyst composition for the hydro-treatment of alkanes and methods of use thereof 有权
标题翻译：用于烷烃的加氢处理的催化剂组合物及其使用方法
公开(公告)号：US08202815B2
公开(公告)日：2012-06-19
申请号：US12344291
申请日：2008-12-26
申请人： Gregg Anthony Deluga , Daniel Lawrence Derr
发明人： Gregg Anthony Deluga , Daniel Lawrence Derr
IPC分类号： B01J29/06 , B01J21/00 , B01J29/00 , B01J23/00 , B01J23/56 , B01J23/44 , B01J23/42 , B01J23/70 , B01J23/74 , C10G69/02 , C10G47/02 , C10G47/24 , C10G47/12 , C10G47/16 , C10G47/04 , C10G47/20 , C10G47/00 , C10G11/02 , C10G11/04 , C10G11/00 , C10G35/00 , C10G35/04 , C10G35/06 , C07C5/13 , C07C4/02 , C07C4/08 , C07C6/00 , C01B33/36 , C01B39/00 , C01F7/00
CPC分类号： B01J21/12 , B01J23/40 , B01J23/42 , B01J23/74 , B01J29/061 , B01J29/064 , B01J29/7415 , B01J2229/42 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G47/18 , C10G47/20 , C10G2300/1081 , C11C3/126 , Y10S423/22 , Y10S423/23 , Y10S423/25 , Y10S423/27
摘要： In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.
摘要翻译：在一个实施方案中，催化剂组合物包含约5重量％至约70重量％的二氧化硅 - 氧化铝; 约30重量％至约90重量％的氧化铝; 和约0.01重量％至约2.0重量％的VIII族金属。在另一个实施方案中，用于处理烃的方法包括在催化剂组合物的存在下氢化烃，其中催化剂包含约5重量％至约70重量％的二氧化硅 - 氧化铝; 约30重量％至约90重量％的氧化铝; 和约0.01重量％至约2.0重量％的VIII族金属。

6. 发明申请

US20120067774A1 PROCESSES FOR INCREASING THE OVERALL AROMATICS AND XYLENES YIELD IN AN AROMATICS COMPLEX 有权
标题翻译：增加复合物中整体的芳族化合物和二甲苯的制备方法
公开(公告)号：US20120067774A1
公开(公告)日：2012-03-22
申请号：US12883977
申请日：2010-09-16
申请人： Stanley J. Frey , Jason T. Corradi , Gregory Werba
发明人： Stanley J. Frey , Jason T. Corradi , Gregory Werba
IPC分类号： C10G35/04 , C10G35/00
CPC分类号： C10G69/123 , C10G35/04 , C10G2300/1044 , C10G2300/1096 , C10G2300/4081 , C10G2400/30
摘要： Processes for increasing overall aromatics and xylenes yield in an aromatics complex are provided. A C8+ aromatics stream from an aromatics-rich reformate is separated into a C8 aromatics fraction and a C9+ aromatics fraction comprising higher alkyl group-substituted C9 and C10 aromatics. The C9+ aromatics fraction is separated into a lighter boiling, higher alkyl group-substituted C9 or C9/C10 aromatics fraction and a heavier boiling, C10+ or C11+ aromatics fraction. The lighter boiling, higher alkyl group-substituted C9 or C9/C10 aromatics fraction is isomerized to convert a portion of the higher alkyl group-substituted C9 or C9/C10 aromatics therein into methyl-enriched C9 aromatics or methyl-enriched C9/C10 aromatics. The methyl-enriched C9+ aromatics stream comprising the methyl-enriched C9+ aromatics stream or the methyl-enriched C9/C10 aromatics is transalkylated with a toluene-containing stream.
摘要翻译：提供了用于增加芳族化合物中总体芳族化合物和二甲苯产率的方法。将来自富含芳香族化合物的重整产物的C8 +芳族化合物流分离成C8芳族化合物馏分和包含较高级烷基取代的C9和C10芳族化合物的C9 +芳烃馏分。将C9 +芳族化合物馏分分离成较轻沸点的较高级烷基取代的C9或C9 / C10芳烃馏分和较重沸腾的C10 +或C11 +芳烃馏分。较轻的沸点较高的烷基取代的C9或C9 / C10芳族化合物部分被异构化，以将其中一部分高级烷基取代的C9或C9 / C10芳族化合物转化成甲基富集的C9芳族化合物或甲基富集的C9 / C10芳族化合物。包含甲基富集的C9 +芳族化合物流或甲基富集的C9 / C10芳族化合物的甲基富集的C9 +芳族化合物物流与含甲苯的物流转烷基化。

7. 发明授权

US07807045B2 Layered composition and processes for preparing and using the composition 有权
标题翻译：用于制备和使用组合物的分层组合物和方法
公开(公告)号：US07807045B2
公开(公告)日：2010-10-05
申请号：US12637823
申请日：2009-12-15
申请人： Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
发明人： Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
IPC分类号： C10G11/00 , C10G35/00 , C07C5/00 , C07C27/00 , C07C67/00 , B01J23/00 , B01J21/00 , B01J20/00 , B01J37/00
CPC分类号： C07C5/321 , B01J21/063 , B01J21/066 , B01J23/38 , B01J32/00 , B01J37/0036 , B01J37/0045 , B01J37/0219 , B01J37/0221 , C07C5/333 , C10G11/04 , C10G45/40 , C10G45/62 , C10G47/14 , C07C15/46
摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
摘要翻译：已经开发了可用于各种方法的分层组合物。该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以含有催化金属如金和铂加其他改性剂。通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。该组合物可用于各种烃转化方法中。

8. 发明授权

US07780845B2 Process to manufacture low sulfur distillates 有权
标题翻译：制造低硫馏分的方法
公开(公告)号：US07780845B2
公开(公告)日：2010-08-24
申请号：US11096498
申请日：2005-04-01
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
IPC分类号： C10G35/00 , C10G35/06 , C10G45/04 , C10G45/60 , C10G11/02 , C10G11/04 , C10G47/02 , C10G47/04 , B01J38/22 , B01J35/02 , B01J8/08
CPC分类号： C10G45/08 , B01J23/8877 , B01J23/888 , B01J37/0009 , B01J37/04 , C10G65/02
摘要： The instant invention relates to a process to produce low sulfur distillate products through the hydrotreating of distillate boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst.
摘要翻译：本发明涉及通过在本体金属加氢处理催化剂存在下加热馏出馏出物沸程进料流来生产低硫馏分产物的方法。

9. 发明申请

US20100155300A1 Process for producing gasoline of increased octane and hydrogen-containing co-produced stream 审中-公开
标题翻译：生产汽油增加辛烷值和含氢共同生产流的方法
公开(公告)号：US20100155300A1
公开(公告)日：2010-06-24
申请号：US12317513
申请日：2008-12-24
申请人： Craig Y. Sabottke , John Gerard Matragrano , Alberto Ravella , Katie Severson , Stuart S. Shih , Bal Krishan Kaul , Jeenok Theresa Kim , John Harland Thurtell
发明人： Craig Y. Sabottke , John Gerard Matragrano , Alberto Ravella , Katie Severson , Stuart S. Shih , Bal Krishan Kaul , Jeenok Theresa Kim , John Harland Thurtell
IPC分类号： C10G35/04 , C10G35/00
CPC分类号： C10G61/02 , C10G35/04 , C10G61/00 , C10G63/00 , C10G63/04
摘要： The present invention is directed to a process for producing an increased yield of gasoline of increased octane rating by the integration of a membrane separation processing step into the gasoline production process. The integrated process also increases hydrogen production from the reformer.
摘要翻译：本发明涉及通过将膜分离处理步骤整合到汽油生产过程中来提高辛烷值等级提高的汽油产率的方法。整合过程还增加了重整器的氢产量。

10. 发明授权

US07642294B2 Process to prepare lower olefins from a carbon containing feedstock 有权
标题翻译：从含碳原料制备低级烯烃的方法
公开(公告)号：US07642294B2
公开(公告)日：2010-01-05
申请号：US11664657
申请日：2005-10-06
申请人： Emil Eduard Antonius Cruijsberg , Jan Lodewijk Maria Dierickx , Arend Hoek , Johannes Marie Gemma Van Schijndel , Jeroen Van Westrenen
发明人： Emil Eduard Antonius Cruijsberg , Jan Lodewijk Maria Dierickx , Arend Hoek , Johannes Marie Gemma Van Schijndel , Jeroen Van Westrenen
IPC分类号： C07C27/00 , C10G47/02 , C10G35/00
CPC分类号： C10G9/00 , C10G2/30
摘要： A process is provided to make ethylene and propylene from a carbonaceous feedstock. The process comprises preparing a gaseous mixture of carbon monoxide and hydrogen from a feedstock. A Fischer Tropsch synthesis is then performed on the gaseous mixture to obtain a Fischer Tropsch product along with unconverted carbon monoxide and hydrogen. The Fischer Tropsch product in admixture with the unconverted carbon monoxide and hydrogen from the previous step is then subjected to terminal cracking to form ethylene and propylene.
摘要翻译：提供了从碳质原料制备乙烯和丙烯的方法。该方法包括从原料制备一氧化碳和氢气的气体混合物。然后在气体混合物上进行费 - 托合成，以获得费 - 托产物以及未转化的一氧化碳和氢气。然后将与前一步骤中未转化的一氧化碳和氢气混合的费托产品进行末端裂化以形成乙烯和丙烯。

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