
基本信息:
- 专利标题: 铝电解槽低浓度二氧化硫烟气循环利用生产硫酸锰的方法
- 申请号:CN201110164204.5 申请日:2011-06-19
- 公开(公告)号:CN102258937A 公开(公告)日:2011-11-30
- 发明人: 何艳明 , 栾景丽 , 白荣林 , 苏其军 , 宁平 , 欧根能 , 杨勇 , 刘维维 , 陶辉旺 , 陈华君 , 熊国焕 , 罗发生 , 邓竟超
- 申请人: 昆明冶金研究院
- 申请人地址: 云南省昆明市圆通北路86号昆明冶金研究院
- 专利权人: 昆明冶金研究院
- 当前专利权人: 昆明冶金研究院有限公司
- 当前专利权人地址: 云南省昆明市圆通北路86号昆明冶金研究院
- 代理机构: 昆明今威专利代理有限公司
- 代理人: 赵云
- 主分类号: B01D53/78
- IPC分类号: B01D53/78 ; B01D53/50 ; C01G45/10 ; C25C3/06
The invention provides a method for producing manganese sulfate by cyclically utilizing low-concentration sulfur dioxide smoke in an aluminum electrolysis cell. The invention relates to low-energy-consumption resource utilization for low-concentration SO2 smoke treatment and waste treatment in the aluminum electrolysis industry, belonging to the fields of energy saving, emission reduction and environmental protection. The method provided by the invention comprises the steps as follows: a chimney subjected to anti-corrosion treatment for exhausting aluminum electrolysis cell smoke is used as atwo-stage absorption tower; an aqueous solution containing MnO is used as an absorption solution; the exhausted SO2 smoke is directly absorbed by adopting an atomization spray and cyclic absorption mode; the nearly saturated solution containing 10-50wt% of manganese sulfate, generated in the reaction, is prepared into a manganese sulfate product through filtration, multiple-effect evaporation andflash vaporization crystallization; and after the residual sulfuric acid mist in the smoke is subjected to demisting treatment, the smoke is exhausted in accordance with the standards. The method provided by the invention can provide technical support for solving the high-standard exhaust problem of the low-concentration SO2 smoke in the aluminum electrolysis cell, enables harmful constituents inindustrial waste gas to be effectively utilized, realizes the sustainable development of resources and environments, has the advantages of low engineering investment, high SO2 absorption efficiency and low operation energy consumption, and can meet higher requirements for environmental protection and exhaust in accordance with the standards.
公开/授权文献:
- CN102258937B 铝电解槽低浓度二氧化硫烟气循环利用生产硫酸锰的方法 公开/授权日:2013-06-26
IPC结构图谱:
B01D53/34 | 组优先于B01D53/02至B01D53/32组。 |
--B01D53/74 | ..净化废气的一般方法;为这类方法特别设计的设备或装置 |
----B01D53/77 | ...液相方法 |
------B01D53/78 | ....利用气—液接触 |