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    • 20. 发明授权
    • Bicyclooctane derivatives
    • 双环辛烷衍生物
    • US4707295A
    • 1987-11-17
    • US843407
    • 1986-03-24
    • Ludwig PohlBernhard ScheubleAndreas WachtlerReinhard HittichPeter Fuss
    • Ludwig PohlBernhard ScheubleAndreas WachtlerReinhard HittichPeter Fuss
    • C07C1/00C07C13/44C07C17/00C07C23/10C07C23/20C07C41/00C07C43/115C07C43/18C07C45/00C07C47/34C07C49/115C07C67/00C07C69/608C07C253/00C07C255/45C07C255/46C07C313/00C07C317/10C07C317/18C07C317/20C07C317/24C07C317/44C07C317/46C07C323/06C09K19/30C09K19/32C09K19/44C09K19/46C09K19/54G02F1/13C07C23/32C07C69/753C07C121/46
    • C07C255/00C07C13/44C07C23/20C09K19/321
    • Bicyclooctane derivatives of the formula IR.sup.1 --A.sup.1 --A.sup.2 --R.sup.2 IwhereinR.sup.1 and R.sup.2 independently of one another are each an alkyl group which has 1-12 C atoms and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or CO groups and/or --O13 CO groups and/or --CO--O groups and/or --CH.dbd.CH-- groups, one of the radicals R.sup.1 and R.sup.2 being also --A.sup.3 --R.sup.3,A.sup.1 is a 1,4-cyclohexylene group which is unsubstituted or substituted in the 1-position and/or 2-position and/or 3-position and/or 4-position by alkyl which has in each case 1-5 C atoms and is unsubstituted or substituted or fluorinated, and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by one or two different groupings from the group --O--, --CO--, --CH.dbd.CH--, --S--, --SO-- or --SO.sub.2 --, or is substituted by F, Cl, Br, CN and/or CHO,A.sup.2 is a 1,4-bicyclo[2.2.2] octylene group,--A.sup.3 --R.sup.3 is --Cy--R.sup.3, --Ph--R.sup.3, --Cy--Ph--R.sup.3 or --Ph--Cy--R.sup.3,Cy is 1,4-cyclohexylene or one of the other groups recited for A.sup.1,Ph is 1,4-phenylene which is unsubstituted or substituted by or one two F atoms and/or CH.sub.3 groups andR.sup.3 is an alkyl group which has 1-12 C atoms and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or CO groups and/or O--CO groups and/or --CO--O groups and/or --CH.dbd.CH-- groupsare suitable for use as components of liquid-crystal phases for field effect and/or bistability effect displys.
    • 式I R1-A1-A2-R2 I的双环辛烷衍生物,其中R 1和R 2彼此独立地是具有1-12个C原子的烷基,并且其中一个或两个不相邻的CH 2基团也是可能的 被O原子和/或CO基团和/或-O13CO基团和/或-CO-O基团和/或-CH = CH-基团取代,基团R1和R2之一也是-A3-R3, A1是未取代的或在1位和/或2位和/或3位和/或4位上被烷基取代的1,4-亚环己基,其各自为1-5个C原子和 是未取代或取代或氟化的,并且其中一个或两个不相邻的CH 2基团也可以被-O - , - CO - , - CH = CH - , - S,-SO-或-SO 2 - ,或被F,Cl,Br,CN和/或CHO取代,A2是1,4-双环[2.2.2]亚辛基,-A3-R3是-Cy -R3,-Ph-R3,-Cy-Ph-R3或-Ph-Cy-R3,Cy为1,4-亚环己基或为A1所列举的其它基团之一, Ph是未被取代或被两个F原子和/或CH 3基团取代的1,4-亚苯基,R 3是具有1-12个C原子的烷基,并且其中也可以有一个或两个不相邻的 被O原子和/或CO基团和/或O-CO基团和/或-CO-O基团和/或-CH = CH-基团取代的CH 2基团适用于现场的液晶相的组分 效果和/或双稳性效应不好。