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31. 发明授权

US5846673A Additive to stabilize electrochemical cell 失效
标题翻译：添加剂稳定电化学电池
公开(公告)号：US5846673A
公开(公告)日：1998-12-08
申请号：US762079
申请日：1996-12-09
申请人： M. Yazid Saidi , Feng Gao , Jeremy Barker , Chariclea Scordilis-Kelley
发明人： M. Yazid Saidi , Feng Gao , Jeremy Barker , Chariclea Scordilis-Kelley
IPC分类号： H01M4/131 , H01M4/133 , H01M4/50 , H01M4/505 , H01M4/62 , H01M10/0525 , H01M10/0567 , H01M10/36 , H01M10/40
CPC分类号： H01M10/0567 , H01M4/131 , H01M4/133 , H01M4/62 , H01M10/0525 , H01M4/505 , Y10T29/49108
摘要： The present invention provides a novel composition and method for preventing decomposition of one or more electrochemical cell components comprising an electrode having an active material, and an electrolyte. The method of the invention, for the first time, effectively overcomes problems which arise between the interaction of cell components and contaminate water retained in a cell. Such contaminate water reacts with the electrolyte which comprises a salt of lithium in a solvent. Solubilizing of the salt in solution with attendant interaction between the salt and water causes formation of hydrogen-containing acids. The method of the invention effectively blocks decomposition of a lithium metal oxide cathode active material, and particularly lithium manganese oxide (LMO, nominally LiMn.sub.2 O.sub.4). Such decomposition is prevented by including in the cell a basic compound which forms an electron donor species in the electrolyte solution; and by neutralizing at least a portion of the acid by reacting the donor species with the hydrogen-containing acids thereby preventing decomposition of the lithium manganese oxide by the acid. The preservation of the lithium manganese oxide prevents degradation of other cell components by other mechanism. The basic compound is desirably an organic base, preferably a butylamine.
摘要翻译：本发明提供一种用于防止一种或多种电化学电池元件分解的新型组合物和方法，所述电化学电池组件包括具有活性材料的电极和电解质。本发明的方法第一次有效地克服了细胞成分的相互作用和污染细胞中残留的水之间产生的问题。这种污染水与包含锂在溶剂中的盐的电解质反应。溶解盐中的盐与盐和水之间伴随的相互作用引起含氢酸的形成。本发明的方法有效地阻止锂金属氧化物正极活性物质，特别是锰酸锂（LMO，名义上是LiMn 2 O 4）的分解。通过在电解液中包含在电解质溶液中形成电子供体物质的碱性化合物来防止这种分解; 并且通过使供体物质与含氢酸反应从而中和酸的至少一部分，从而防止酸分解锰酸锂。锂锰氧化物的保存通过其他机理防止其他电池组分的降解。碱性化合物优选为有机碱，优选为丁胺。

32. 发明授权

US08367036B2 Alkali/transition metal halo-and hydroxy-phosphates and related electrode active materials 失效
标题翻译：碱/过渡金属卤代和羟基磷酸盐及相关电极活性物质
公开(公告)号：US08367036B2
公开(公告)日：2013-02-05
申请号：US12835208
申请日：2010-07-13
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： C01D5/00 , C01B25/10 , C01B15/16 , C01B17/45 , C01B17/00 , H01M4/88 , H01M4/13
CPC分类号： C01B25/45 , C01B25/455 , C01G45/006 , C01G49/009 , C01P2006/40 , H01M4/136 , H01M4/5825 , H01M4/587 , H01M4/623 , H01M10/0525
摘要： The invention provides a novel polyanion-based electrode active material for use in a secondary or rechargeable electrochemical cell, wherein the electrode active material is represented by the general formula AaMb(SO4)2Zd.
摘要翻译：本发明提供一种用于次级或可再充电电化学电池的新型聚阴离子型电极活性材料，其中电极活性材料由通式AaMb（SO4）2Zd表示。

33. 发明申请

US20080241043A1 Method For Making Phosphate-Based Electrode Active Materials 失效
标题翻译：制造磷酸盐电极活性材料的方法
公开(公告)号：US20080241043A1
公开(公告)日：2008-10-02
申请号：US12135271
申请日：2008-06-09
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
IPC分类号： C01B25/26 , C01B25/10
CPC分类号： H01M4/136 , C01B25/455 , H01M4/5825 , H01M4/587 , H01M4/623 , H01M10/0525
摘要： The invention is directed to synthesizing a phosphate-based electrode active material. The method includes the step of reacting two or more starting materials collectively containing at least a PO33− anion, an alkali metal and a metal which is redox active in the final reaction product, at a temperature and for a time sufficient to form the phosphate-based electrode active material.
摘要翻译：本发明涉及合成磷酸盐类电极活性物质。该方法包括使两种或更多种起始材料共同含有至少一种PO 3 - 3 - / - 阴离子，碱金属和在最终的氧化还原活性物质中的金属的步骤反应产物，在足以形成磷酸酯基电极活性材料的温度和时间下进行。

34. 发明授权

US07001690B2 Lithium-based active materials and preparation thereof 有权
公开(公告)号：US07001690B2
公开(公告)日：2006-02-21
申请号：US09484799
申请日：2000-01-18
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： H01M4/48
CPC分类号： H01M4/136 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M10/0525 , H01M2004/028
摘要： The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.

35. 发明授权

US06815122B2 Alkali transition metal phosphates and related electrode active materials 有权
标题翻译：碱金属过渡金属磷酸盐及相关电极活性物质
公开(公告)号：US06815122B2
公开(公告)日：2004-11-09
申请号：US10092317
申请日：2002-03-06
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
IPC分类号： H01M458
CPC分类号： H01M4/136 , C01B25/45 , C01B33/20 , H01M2/1653 , H01M4/0471 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M6/40 , H01M10/0525 , H01M10/0565 , H01M2300/0037
摘要： Electrode active materials comprising lithium or other alkali metals, a transition metal, and a phosphate or similar moiety, of the formula: Aa+xMbP1−xSixO4 wherein (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0
摘要翻译：包含下式的锂或其它碱金属，过渡金属和磷酸盐或类似部分的电极活性材料：其中（a）A选自Li，Na，K及其混合物， a <1.0和0 <= X＆LE; 1;（b）M包含一种或多种金属，其包含至少一种能够经历氧化至更高价态的金属，其中0

36. 发明授权

US06777132B2 Alkali/transition metal halo—and hydroxy-phosphates and related electrode active materials 失效
标题翻译：碱/过渡金属卤代和羟基磷酸盐及相关电极活性物质
公开(公告)号：US06777132B2
公开(公告)日：2004-08-17
申请号：US10014822
申请日：2001-10-26
申请人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
发明人： Jeremy Barker , M. Yazid Saidi , Jeffrey L. Swoyer
IPC分类号： H01M458
CPC分类号： H01M4/5825 , C01B25/455 , H01M4/136 , H01M4/587 , H01M4/623 , H01M10/0525 , H01M2004/028
摘要： The present invention relates to novel electrode active materials represented by the general formula AaMb(XY4)cZd, wherein: (a) A is one or more alkali metals, and 0
摘要翻译：本发明涉及由通式AaMb（XY4）cZd表示的新型电极活性材料，其中：（a）A是一种或多种碱金属，0

37. 发明授权

US06183718B2 Method of making stabilized electrochemical cell active material of lithium manganese oxide 有权
标题翻译：制备锂锰氧化物稳定的电化学电池活性材料的方法
公开(公告)号：US06183718B2
公开(公告)日：2001-02-06
申请号：US09307355
申请日：1999-05-07
申请人： Jeremy Barker , M. Yazid Saidi , Chariclea A. Scordilis-Kelley
发明人： Jeremy Barker , M. Yazid Saidi , Chariclea A. Scordilis-Kelley
IPC分类号： C01G4512
CPC分类号： H01M4/131 , C01G45/1221 , C01G45/1242 , C01P2002/32 , C01P2002/77 , C01P2004/51 , C01P2004/60 , C01P2006/40 , H01M4/1391 , H01M4/505 , H01M4/62 , H01M10/0525 , H01M10/0567
摘要： A method for forming the composition stabilized against capacity degradation comprises particles of spinel lithium manganese oxide (LMO) enriched with lithium by a decomposition product of lithium carbonate forming a part of each said particle and characterized by a reduced surface area and increased capacity expressed in milliamp hours per gram as compared to non-enriched spinel.
摘要翻译：形成稳定防止容量降解的组合物的方法包括通过碳酸锂的分解产物富集锂的尖晶石锂锰氧化物（LMO），其形成每个所述颗粒的一部分，其特征在于表面积减小并且以毫安表示的增加的容量小时/克，与非富集尖晶石相比。

38. 发明申请

US20110229765A1 Electrodes Comprising Mixed Active Particles 审中-公开
标题翻译：包含混合活性颗粒的电极
公开(公告)号：US20110229765A1
公开(公告)日：2011-09-22
申请号：US13150401
申请日：2011-06-01
申请人： Jeremy Barker , M. Yazid Saidi , Tracy E. Kelley
发明人： Jeremy Barker , M. Yazid Saidi , Tracy E. Kelley
IPC分类号： H01M4/52 , H01M4/50
CPC分类号： H01M4/525 , H01M4/13 , H01M4/364 , H01M4/505 , H01M4/582 , H01M4/5825 , H01M10/0525
摘要： An electrode active material comprising two or more groups of particles having differing chemical compositions, wherein each group of particles comprises a material selected from: (a) materials of the formula A2eM2fOg; and (b) materials of the formula A3hMniO4; wherein (i) A2, and A3 are independently selected from the group consisting of Li, Na, K, and mixtures thereof, 0
摘要翻译：包含两组或更多组具有不同化学组成的颗粒的电极活性材料，其中每组颗粒包含选自以下的材料：（a）式A2eM2fOg的材料; 和（b）式为A3hMniO4的材料; 其中（i）A2和A3独立地选自由Li，Na，K及其混合物组成的组，e＆lt; e1; 6和h＆nlE; 2.0; （ii）M2是一种或多种金属，其包含选自Fe，Co，Ni，Mo，V，Zr，Ti，Mo和Cr中的至少一种金属和1＆lt; lE; f＆nlE; 6; （iii）0

39. 发明授权

US07771628B2 Electrodes comprising mixed active particles 有权
标题翻译：包含混合活性颗粒的电极
公开(公告)号：US07771628B2
公开(公告)日：2010-08-10
申请号：US11381602
申请日：2006-05-04
申请人： Jeremy Barker , M. Yazid Saidi , Tracy Kelley
发明人： Jeremy Barker , M. Yazid Saidi , Tracy Kelley
IPC分类号： H01B1/08 , H01M4/58
CPC分类号： H01M4/525 , H01M4/13 , H01M4/364 , H01M4/505 , H01M4/582 , H01M4/5825 , H01M10/0525
摘要： Electrode active materials comprising two or more groups of particles having differing chemical compositions, wherein each group of particles comprises a material selected from: (a) materials of the formula A1 aM1 b(XY4)cZd; and (b) materials of the formula A2eM2fOg; and (c) materials of the formula A3hMniO4; wherein (i) A1, A2, and A3 are Li, Na, or K; (ii) M1and M3 comprise a transition metal; (iv) XY4 a phosphate or similar moiety; and (v) Z is OH, or halogen.
摘要翻译：包含两组或更多组具有不同化学组成的颗粒的电极活性材料，其中每组颗粒包括选自以下的材料：（a）式A1aM1b（XY4）cZd的材料; 和（b）式A2eM2fOg的材料; 和（c）式为A3hMniO4的材料; 其中（i）A1，A2和A3是Li，Na或K; （ii）M1和M3包含过渡金属; （iv）XY4磷酸酯或类似部分; 和（v）Z是OH或卤素。

40. 发明授权

US07438992B2 Lithium-based active materials and preparation thereof 有权
标题翻译：锂基活性物质及其制备方法
公开(公告)号：US07438992B2
公开(公告)日：2008-10-21
申请号：US11355584
申请日：2006-02-16
申请人： Jeremy Barker , M. Yazid Saidi
发明人： Jeremy Barker , M. Yazid Saidi
IPC分类号： H01M4/58 , H01M4/62 , H01M10/40
CPC分类号： H01M4/136 , H01M4/131 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5825 , H01M4/623 , H01M10/0525 , H01M2004/028
摘要： The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
摘要翻译：本发明提供新的锂混合金属材料，其在电化学相互作用时释放锂离子，并且能够可逆地循环锂离子。本发明提供一种可再充电锂电池，其包括由新型锂混合金属材料形成的电极。还提供了制备新的锂复合金属材料的方法和在电化学电池中使用这种锂混合金属材料的方法。锂混合金属材料除锂之外还包含锂和至少一种其它金属。优选的材料是除了锂之外还含有锂和另外两种金属的锂混合金属磷酸盐。

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